Heavy-fuel engines are widely used in UAVs(Unmanned Autonomous Vehicles)because of their reliability and high-power density.In this study,a combustion model for an in-cylinder direct injection engine has been imple-me...Heavy-fuel engines are widely used in UAVs(Unmanned Autonomous Vehicles)because of their reliability and high-power density.In this study,a combustion model for an in-cylinder direct injection engine has been imple-mented using the AVL FIRE software.The effects of the angle of nozzle inclination on fuel evaporation,mixture distribution,and combustion in the engine cylinder have been systematically studied at 5500 r/min and consider-ing full load cruise conditions.According to the results,as the angle of nozzle inclination increases,the maximum combustion explosion pressure in the cylinderfirst increases and then it decreases.When the angle of nozzle incli-nation is less than 45°,the quality of the mixture in the cylinder and the combustion performance can be improved by increasing the angle.When the angle of nozzle inclination is greater than 45°,however,the mixture unevenness increases slightly with the angle,leading to a deterioration of the combustion performances.When the angle of nozzle inclination is between 35°and 55°,the overall combustion performance of the engine is rela-tively good.When the angle of nozzle inclination is 45°,the combustion chamber’s geometry and the cylinder’s airflow are well matched with the fuel spray,and the mixture quality is the best.Compared with 25°,the peak heat release rate increases by 20%,and the maximum combustion burst pressure increases by 5.5%.展开更多
A multitracer-gas method was proposed to study the secondary air(SA)mixing along the bed height in a circulating fluidized bed(CFB)using carbon monoxide(CO),oxygen(O_(2)),and carbon dioxide(CO_(2))as tracer gases.Expe...A multitracer-gas method was proposed to study the secondary air(SA)mixing along the bed height in a circulating fluidized bed(CFB)using carbon monoxide(CO),oxygen(O_(2)),and carbon dioxide(CO_(2))as tracer gases.Experiments were carried out on a cold CFB test rig with a cross-section of 0.42 m×0.73 m and a height of 5.50 m.The effects of superficial velocity,SA ratio,bed inventory,and particle diameter on the SA mixing were investigated.The results indicate that there are some differences in the measurement results obtained using different tracer gases,wherein the deviation between CO and CO_(2) ranges from 42%to 66%and that between O_(2) and CO_(2) ranges from 45%to 71%in the lower part of the fluidized bed.However,these differences became less pronounced as the bed height increased.Besides,the high solid concentration and fine particle diameter in the CFB may weaken the difference.The measurement results of different tracer gases show the same trends under the variation of operating parameters.Increasing superficial velocity and SA ratio and decreasing particle diameter result in better mixing of the SA.The effect of bed inventory on SA mixing is not monotonic.展开更多
The stratification phenomenon resulting from differences in the physical properties of solid-liquid components seriously affect the final combustion and explosion characteristics of mixed fuel under the action of osci...The stratification phenomenon resulting from differences in the physical properties of solid-liquid components seriously affect the final combustion and explosion characteristics of mixed fuel under the action of oscillation.The effects of oscillation on the physical stability of mixed fuel with two solid-liquid ratios and three liquid component distribution ratios have been investigated using a self-designed experimental system at oscillation frequencies of 60-300 r/min.The explosion characteristics of mixed fuel before and after oscillation are gained from a 20 L spherical explosion container system.When the mass ratio of liquid components is controlled at 66.9%,64.7%,62.6%the final explosion characteristics are stable,with a maximum difference of only 0.71%.The volume of liquid fuel precipitation increases with increasing oscillation frequency when the mass ratio of liquid components reaches 71.7%,69.6%,67.7%.The fuel explosion overpressure after oscillation decreases with increasing liquid precipitation volume,and the repeatability is poor,with a maximum standard deviation of 82.736,which is much higher than the ratio without stratification.Properly controlling the mass ratio of liquid components of the mixed fuel can effectively combat the impact of oscillation on the physical state and maintain the stability of the final explosion characteristics.展开更多
Direct air capture(DAC)of CO_(2)plays an indispensable role in achieving carbon-neutral goals as one of the key negative emission technologies.Since large air flows are required to capture the ultradilute CO_(2)from t...Direct air capture(DAC)of CO_(2)plays an indispensable role in achieving carbon-neutral goals as one of the key negative emission technologies.Since large air flows are required to capture the ultradilute CO_(2)from the air,lab-synthesized adsorbents in powder form may cause unacceptable gas pressure drops and poor heat and mass transfer efficiencies.A structured adsorbent is essential for the implementation of gas-solid contactors for cost-and energy-efficient DAC systems.In this study,efficient adsorbent poly(ethyleneimine)(PEI)-functionalized Mg-Al-CO_(3)layered double hydroxide(LDH)-derived mixed metal oxides(MMOs)are three-dimensional(3D)printed into monoliths for the first time with more than 90%adsorbent loadings.The printing process has been optimized by initially printing the LDH powder into monoliths followed by calcination into MMO monoliths.This structure exhibits a 32.7%higher specific surface area and a 46.1%higher pore volume,as compared to the direct printing of the MMO powder into a monolith.After impregnation of PEI,the monolith demonstrates a large adsorption capacity(1.82 mmol/g)and fast kinetics(0.7 mmol/g/h)using a CO_(2)feed gas at 400 ppm at 25℃,one of the highest values among the shaped DAC adsorbents.Smearing of the amino-polymers during the post-printing process affects the diffusion of CO_(2),resulting in slower adsorption kinetics of pre-impregnation monoliths compared to post-impregnation monoliths.The optimal PEI/MeOH ratio for the post-impregnation solution prevents pores clogging that would affect both adsorption capacity and kinetics.展开更多
2nd-order upwind TVD scheme was used to solve the laminar, fully Navier-Stokes equations. The numerical simulations were done on the propagation of a shock wave with Ma(s) = 2 and 4 into a hydrogen and air mixture in ...2nd-order upwind TVD scheme was used to solve the laminar, fully Navier-Stokes equations. The numerical simulations were done on the propagation of a shock wave with Ma(s) = 2 and 4 into a hydrogen and air mixture in a duct and a duct with a rearward step. The results indicate that a swirling vortex: may be generated in the lopsided interface behind the moving shock. Meanwhile, the complex shock system is also formed in this shear flow region. A large swirling vortex is produced and the fuel mixing can be enhanced by a shock wave at low Mach number. But in a duct with a rearward step, the shock almost disappears in hydrogen for Mns = 2. The shack in hydrogen will become strong if Ma(s) is large. Similar to the condition of a shock moving in a duct full of hydrogen and air, a large vortex cart be formed in the shear flow region. The large swirling vortex even gets through the reflected shock and impacts on the lower wall. Then, the distribution of hydrogen behind the rearward step is divided into two regions. The transition from regular reflection to Mach reflection was observed aswell in case Ma(s) = 4.展开更多
Since the Industrial Revolution, greenhouse gas (GHG) emissions have greatly increased with the increased use of fossil fuels, leading to air pollution and global warming. We present the researches on air pollution an...Since the Industrial Revolution, greenhouse gas (GHG) emissions have greatly increased with the increased use of fossil fuels, leading to air pollution and global warming. We present the researches on air pollution and the use of fossil fuels in north China, the economic zone of Changsha-Zhuzhou-Xiangtan and the economic zone of the Pearl River Delta region. Researches indicate that the use of fossil fuels has been the main source of air pollution in the three regions. We present researches on global mean surface temperature (GMST) with the rise of carbon dioxide concentration (CDC) and global fossil fuel consumption (GFFC);researches indicate that the rise in CDC can account for 91% of the rise in GMST, and GFFC can account for 90% of the rise in GMST. We analyse the factors that bring about air pollution and temperature rise, they are the use of fossil fuels and deforestation. It is critically important to replace fossil fuels with clean energy, but renewable energy has also disadvantages. The world faces difficulties in solving air pollution and global warming, so governments of the world should cooperate to solve the technologies of clean energy, and preserve the forests and the natural environment.展开更多
In areas where hot mix asphalt(HMA)is likely to be exposed by any form of mineral oil the layer has to withstand the attack of these substances in order not to damage the construction.The European Standard EN 12697-43...In areas where hot mix asphalt(HMA)is likely to be exposed by any form of mineral oil the layer has to withstand the attack of these substances in order not to damage the construction.The European Standard EN 12697-43 provides a test procedure to determine the resistance of HMA to fuel.The paper reviews this method thoroughly.A completely revised and simplified test device for the brush test was developed meeting the requirements of the standard and creating results with a high repeatability at the same time.The test conditions given by the standard such as the exposure to fuel,cleaning of the specimen after exposure or the contact pressure of the brush were varied to isolate those test conditions with a substantial influence on the result.The research revealed that in the standard some conditions with a rather small influence are set quite strictly while other conditions with a distinct influence on the result are not defined with the required accuracy to obtain comparable and repeatable results.The paper presents suggestions for the improvement of the test method and the standard itself in respect to the layout of the test device and the definition of important test conditions to enhance the outcome of the EN 12697-43.展开更多
A critical challenge to the commercialization of clean and high-efficiency solid oxide fuel cell(SOFC)technology is the insuf-ficient stack lifespan caused by a variety of degradation mechanisms,which are associated w...A critical challenge to the commercialization of clean and high-efficiency solid oxide fuel cell(SOFC)technology is the insuf-ficient stack lifespan caused by a variety of degradation mechanisms,which are associated with cell components and chemical feedstocks.Cell components related degradation refers to thermal/chemical/electrochemical deterioration of cell materials under operating conditions,whereas the latter regards impurities in feedstocks of oxidant(air)and reductant(fuel).This article provides a thermodynamic perspective on the understanding of the impurities-induced degradation mechanisms in SOFCs.The discussion focuses on using thermodynamic ana-lysis to elucidate poisoning mechanisms in cathodes by impurity species such as Cr,CO_(2),H_(2)O,and SO_(2) and in the anode by species such as S(or H_(2)S),SiO_(2),and P_(2)(or PH_(3)).The author hopes the presented fundamental insights can provide a theoretical foundation for search-ing for better technical solutions to address the critical degradation challenges.展开更多
Electro-hydraulic impulse water-air mixing jet by which the quality of metal materials can be improved is described in this paper. The experimental results proved that the hardness and the micro-hardness of the surfac...Electro-hydraulic impulse water-air mixing jet by which the quality of metal materials can be improved is described in this paper. The experimental results proved that the hardness and the micro-hardness of the surface layer of metal materials can be improved with this method, for example, the microhardness of CrWMn can be increased by 35.62 percent.展开更多
In the air combat process,confrontation position is the critical factor to determine the confrontation situation,attack effect and escape probability of UAVs.Therefore,selecting the optimal confrontation position beco...In the air combat process,confrontation position is the critical factor to determine the confrontation situation,attack effect and escape probability of UAVs.Therefore,selecting the optimal confrontation position becomes the primary goal of maneuver decision-making.By taking the position as the UAV’s maneuver strategy,this paper constructs the optimal confrontation position selecting games(OCPSGs)model.In the OCPSGs model,the payoff function of each UAV is defined by the difference between the comprehensive advantages of both sides,and the strategy space of each UAV at every step is defined by its accessible space determined by the maneuverability.Then we design the limit approximation of mixed strategy Nash equilibrium(LAMSNQ)algorithm,which provides a method to determine the optimal probability distribution of positions in the strategy space.In the simulation phase,we assume the motions on three directions are independent and the strategy space is a cuboid to simplify the model.Several simulations are performed to verify the feasibility,effectiveness and stability of the algorithm.展开更多
This study aims to optimize the influence of the inlet inclination angle on the Indoor Air Quality(IAQ),heat,and temperature distribution in mixed convection within a two-dimensional square cavityfilled with an air-CO_(...This study aims to optimize the influence of the inlet inclination angle on the Indoor Air Quality(IAQ),heat,and temperature distribution in mixed convection within a two-dimensional square cavityfilled with an air-CO_(2)mixture.The air-CO_(2)mixture enters the cavity through two inlet openings positioned at the top wall,which is set at the ambient temperature(TC).Three values of the Reynolds numbers,ranging from 1000 to 2000,are considered,while the Prandtl number is kept constant(Pr=0.71).The temperature distribution and streamlines are shown for Rayleigh number(Ra)equal to 104,three inlet inclination anglesϕ(0,π/6 andπ/4)and three CO_(2)concentrations values(1500,2500,3500 ppm)applied at both hot vertical walls(maintained at a constant temperature TH).Afinite volume method is used under the assumption of two-dimensional laminarflow to solve the NavierStokes and energy equations.The results indicate that inlet inclination angle has an impact on the indoor air quality(IAQ),which,in turn,affects the heat transfer distribution and thermal comfort within the cavity.展开更多
Aim To study fuel dispersion in fuel air explosive(FAE) and computational ways of fuel dispersion velocity in the near area. Methods\ The dispersion process of fuel in FAE was analyzed by the use of results measured ...Aim To study fuel dispersion in fuel air explosive(FAE) and computational ways of fuel dispersion velocity in the near area. Methods\ The dispersion process of fuel in FAE was analyzed by the use of results measured with KODAK EKTAPRO EM Motion Analyzer and setting up mechanical models. Results\ Computational methods for fuel dispersion velocity in the acceleration stage is given and taken as a base for the study of fuel dispersion in the intermediate and the far area. Conclusion\ When the fuel flow velocity is higher than that of the explosion gas in the center cavity, the fuel divides with the explosion gas and its velocity of flow reaches a maximum. The acceleration stage ends at that time. The fuel dispersion velocity at this time is the initial conditions for numeral analyses of dispersion process in the intermediate and far areas.展开更多
An improvement in the corrosion resistance of alloys at elevated temperature is a factor for their potential use in gas turbines. In this study, Co Ni Cr Al Y has been coated on the L605 alloy using air plasma spray(A...An improvement in the corrosion resistance of alloys at elevated temperature is a factor for their potential use in gas turbines. In this study, Co Ni Cr Al Y has been coated on the L605 alloy using air plasma spray(APS) and high-velocity oxygen fuel(HVOF) coating techniques to enhance its corrosion resistance. Hot corrosion studies were conducted on uncoated and coated samples in a molten salt environment at 850°C under cyclic conditions. Thermogravimetric analysis was used to determine the corrosion kinetics. The samples were subjected to scanning electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction for further investigation. In coated samples, the formation of Al2O3 and Cr2O3 in the coating acts as a diffusion barrier that could resists the inward movement of the corrosive species present in the molten salt. Coated samples showed very less spallation, lower weight gain, less porosity, and internal oxidation as compared to uncoated sample.HVOF-coated sample showed greater corrosion resistance and inferred that this is the best technique under these conditions.展开更多
In order to improve the energy level of fuel air explosive(FAE) with delayed secondary igniters, high energetic metal powders were added to liquid fuels mainly composed of ether and isopropyl nitrate.Metal powders’ e...In order to improve the energy level of fuel air explosive(FAE) with delayed secondary igniters, high energetic metal powders were added to liquid fuels mainly composed of ether and isopropyl nitrate.Metal powders’ explosive properties and reaction mechanisms in FAE were studied by high-speed video,pressure test system, and infrared thermal imager. The results show that compared with pure liquid fuels, the shock wave overpressure, maximum surface fireball temperature and high temperature duration of the mixture were significantly increased after adding high energetic metal powder. The overpressure values of the liquid-solid mixture at all measuring points were higher than that of the pure liquid fuels. And the maximum temperature of the fireball was up to 1700C, which was higher than that of the pure liquid fuels. After replacing 30% of aluminum powder with boron or magnesium hydride, the shock wave pressure of the mixture was further increased. The high heat of combustion of boron and the hydrogen released by magnesium hydride could effectively increase the blast effect of the mixture. The improvement of the explosion performance of boron was better than magnesium hydride. It shows that adding high energetic metal powder to liquid fuels can effectively improve the explosion performance of FAE.展开更多
A solid state H2S/air electrochemical cell having the configuration of H2S, (MoS2+NiS+Ag)/YSZ/Pt, air has been examined with different H2S flow rates and concentrations at atmospheric pressure and 750-850 ℃. Performa...A solid state H2S/air electrochemical cell having the configuration of H2S, (MoS2+NiS+Ag)/YSZ/Pt, air has been examined with different H2S flow rates and concentrations at atmospheric pressure and 750-850 ℃. Performance of the fuel cell was dependent on anode compartment H2S flow rate and concentration. The cell open-circuit voltage increased with increasing H2S flow rate. It was found that increasing both H2S flow rate and H2S concentration improved current-voltage and power density performance. This is resulted from improved gas diffusion in anode and increased concentration of anodic electroactive species. Operation at elevated H2S concentration improved the cell performance at a given gas flow rate. However, as low as 5% H2S in gas mixture can also be utilized as fuel feed to cells. Highest current and power densities, 17500mA·cm-2 and 200mW·cm-2, are obtained with pure H2S flow rate of 50ml·min-1 and air flow rate of 100ml·min-1 at 850℃.展开更多
This numerical study investigates the effects of using a diluted fuel (50% natural gas and 50% N2) in an industrial furnace under several cases of conventional combustion (air with 21% O2 at 300 and 1273 K) and th...This numerical study investigates the effects of using a diluted fuel (50% natural gas and 50% N2) in an industrial furnace under several cases of conventional combustion (air with 21% O2 at 300 and 1273 K) and the highly preheated and diluted air (1273 K with 10% O2 and 90% N2) combustion (HPDAC) conditions using an in-house computer program. It was found that by applying a combined diluted fuel and oxidant instead of their uncombined and/or undiluted states, the best condition is obtained for the establishment of HPDAC's main unique features. These features are low mean and maximum gas temperature and high radiation/total heat transfer to gas and tubes; as well as more uniformity of theirs distributions which results in decrease in NOx pollutant formation and increase in furnace efficiency or energy saving. Moreover, a variety of chemical flame shape, the process fluid and tubes walls temperatures profiles, the required regenerator efficiency and finally the concentration and velocity patterns have been also qualitatively/quantitatively studied.展开更多
To prevent the oxygen starvation and improve the system output performance, an adaptive inverse control (AIC) strategy is developed to regulate the air supply flow of a proton exchange membrane fuel cell (PEMFC) s...To prevent the oxygen starvation and improve the system output performance, an adaptive inverse control (AIC) strategy is developed to regulate the air supply flow of a proton exchange membrane fuel cell (PEMFC) system in this paper. The PEMFC stack and the air supply system including a compressor and a supply manifold are modeled for the purpose of performance analysis and controller design. A recurrent fuzzy neural network (RFNN) is utilized to identify the inverse model of the controlled system and generates a suitable control input during the abrupt step change of external disturbances. Compared with the PI controller, numerical simulations are performed to validate the effectiveness and advantages of the proposed AIC strategy.展开更多
An infrared colorimetric radiation thermometrical system was established based on the theory of optical radiation. The dynamic temperature history of fuel air explosive (FAE) was measured to obtain the temperature res...An infrared colorimetric radiation thermometrical system was established based on the theory of optical radiation. The dynamic temperature history of fuel air explosive (FAE) was measured to obtain the temperature responses of primary initiation FAE and secondary initiation FAE in real time. And the characteristics of their temperature history curves were compared and analyzed. The results show that the primary initiation FAE has higher explosion temperature and longer duration compared to the secondary initiation FAE.展开更多
Most of the traditional taxi path planning studies assume that the aircraft is in uniform speed,and the optimization goal is the shortest taxi time.Although it is easy to solve,it does not consider the changes in the ...Most of the traditional taxi path planning studies assume that the aircraft is in uniform speed,and the optimization goal is the shortest taxi time.Although it is easy to solve,it does not consider the changes in the speed profile of the aircraft when turning,and the shortest taxi time does not necessarily bring the best taxi fuel consumption.In this paper,the number of turns is considered,and the improved A*algorithm is used to obtain the P static paths with the shortest sum of the straight-line distance and the turning distance of the aircraft as the feasible taxi paths.By balancing taxi time and fuel consumption,a set of Pareto optimal speed profiles are generated for each preselected path to predict the 4-D trajectory of the aircraft.Based on the 4-D trajectory prediction results,the conflict by the occupied time window in the taxiing area is detected.For the conflict aircraft,based on the priority comparison,the waiting or changing path is selected to solve the taxiing conflict.Finally,the conflict free aircraft taxiing path is generated and the area occupation time window on the path is updated.The experimental results show that the total taxi distance and turn time of the aircraft are reduced,and the fuel consumption is reduced.The proposed method has high practical application value and is expected to be applied in real-time air traffic control decision-making in the future.展开更多
文摘Heavy-fuel engines are widely used in UAVs(Unmanned Autonomous Vehicles)because of their reliability and high-power density.In this study,a combustion model for an in-cylinder direct injection engine has been imple-mented using the AVL FIRE software.The effects of the angle of nozzle inclination on fuel evaporation,mixture distribution,and combustion in the engine cylinder have been systematically studied at 5500 r/min and consider-ing full load cruise conditions.According to the results,as the angle of nozzle inclination increases,the maximum combustion explosion pressure in the cylinderfirst increases and then it decreases.When the angle of nozzle incli-nation is less than 45°,the quality of the mixture in the cylinder and the combustion performance can be improved by increasing the angle.When the angle of nozzle inclination is greater than 45°,however,the mixture unevenness increases slightly with the angle,leading to a deterioration of the combustion performances.When the angle of nozzle inclination is between 35°and 55°,the overall combustion performance of the engine is rela-tively good.When the angle of nozzle inclination is 45°,the combustion chamber’s geometry and the cylinder’s airflow are well matched with the fuel spray,and the mixture quality is the best.Compared with 25°,the peak heat release rate increases by 20%,and the maximum combustion burst pressure increases by 5.5%.
基金the Key Project of the National Research Program of China(2020YFB0606201)。
文摘A multitracer-gas method was proposed to study the secondary air(SA)mixing along the bed height in a circulating fluidized bed(CFB)using carbon monoxide(CO),oxygen(O_(2)),and carbon dioxide(CO_(2))as tracer gases.Experiments were carried out on a cold CFB test rig with a cross-section of 0.42 m×0.73 m and a height of 5.50 m.The effects of superficial velocity,SA ratio,bed inventory,and particle diameter on the SA mixing were investigated.The results indicate that there are some differences in the measurement results obtained using different tracer gases,wherein the deviation between CO and CO_(2) ranges from 42%to 66%and that between O_(2) and CO_(2) ranges from 45%to 71%in the lower part of the fluidized bed.However,these differences became less pronounced as the bed height increased.Besides,the high solid concentration and fine particle diameter in the CFB may weaken the difference.The measurement results of different tracer gases show the same trends under the variation of operating parameters.Increasing superficial velocity and SA ratio and decreasing particle diameter result in better mixing of the SA.The effect of bed inventory on SA mixing is not monotonic.
文摘The stratification phenomenon resulting from differences in the physical properties of solid-liquid components seriously affect the final combustion and explosion characteristics of mixed fuel under the action of oscillation.The effects of oscillation on the physical stability of mixed fuel with two solid-liquid ratios and three liquid component distribution ratios have been investigated using a self-designed experimental system at oscillation frequencies of 60-300 r/min.The explosion characteristics of mixed fuel before and after oscillation are gained from a 20 L spherical explosion container system.When the mass ratio of liquid components is controlled at 66.9%,64.7%,62.6%the final explosion characteristics are stable,with a maximum difference of only 0.71%.The volume of liquid fuel precipitation increases with increasing oscillation frequency when the mass ratio of liquid components reaches 71.7%,69.6%,67.7%.The fuel explosion overpressure after oscillation decreases with increasing liquid precipitation volume,and the repeatability is poor,with a maximum standard deviation of 82.736,which is much higher than the ratio without stratification.Properly controlling the mass ratio of liquid components of the mixed fuel can effectively combat the impact of oscillation on the physical state and maintain the stability of the final explosion characteristics.
基金supported by the Shanghai Agricultural Science and Technology Program (2022-02-08-00-12-F01176)he National Natural Science Foundation of China (52006135)
文摘Direct air capture(DAC)of CO_(2)plays an indispensable role in achieving carbon-neutral goals as one of the key negative emission technologies.Since large air flows are required to capture the ultradilute CO_(2)from the air,lab-synthesized adsorbents in powder form may cause unacceptable gas pressure drops and poor heat and mass transfer efficiencies.A structured adsorbent is essential for the implementation of gas-solid contactors for cost-and energy-efficient DAC systems.In this study,efficient adsorbent poly(ethyleneimine)(PEI)-functionalized Mg-Al-CO_(3)layered double hydroxide(LDH)-derived mixed metal oxides(MMOs)are three-dimensional(3D)printed into monoliths for the first time with more than 90%adsorbent loadings.The printing process has been optimized by initially printing the LDH powder into monoliths followed by calcination into MMO monoliths.This structure exhibits a 32.7%higher specific surface area and a 46.1%higher pore volume,as compared to the direct printing of the MMO powder into a monolith.After impregnation of PEI,the monolith demonstrates a large adsorption capacity(1.82 mmol/g)and fast kinetics(0.7 mmol/g/h)using a CO_(2)feed gas at 400 ppm at 25℃,one of the highest values among the shaped DAC adsorbents.Smearing of the amino-polymers during the post-printing process affects the diffusion of CO_(2),resulting in slower adsorption kinetics of pre-impregnation monoliths compared to post-impregnation monoliths.The optimal PEI/MeOH ratio for the post-impregnation solution prevents pores clogging that would affect both adsorption capacity and kinetics.
基金theNationalNaturalScienceFoundationofChina(1 9882 0 0 5 ) China 863High_TecProject (863_2 .99.9)
文摘2nd-order upwind TVD scheme was used to solve the laminar, fully Navier-Stokes equations. The numerical simulations were done on the propagation of a shock wave with Ma(s) = 2 and 4 into a hydrogen and air mixture in a duct and a duct with a rearward step. The results indicate that a swirling vortex: may be generated in the lopsided interface behind the moving shock. Meanwhile, the complex shock system is also formed in this shear flow region. A large swirling vortex is produced and the fuel mixing can be enhanced by a shock wave at low Mach number. But in a duct with a rearward step, the shock almost disappears in hydrogen for Mns = 2. The shack in hydrogen will become strong if Ma(s) is large. Similar to the condition of a shock moving in a duct full of hydrogen and air, a large vortex cart be formed in the shear flow region. The large swirling vortex even gets through the reflected shock and impacts on the lower wall. Then, the distribution of hydrogen behind the rearward step is divided into two regions. The transition from regular reflection to Mach reflection was observed aswell in case Ma(s) = 4.
文摘Since the Industrial Revolution, greenhouse gas (GHG) emissions have greatly increased with the increased use of fossil fuels, leading to air pollution and global warming. We present the researches on air pollution and the use of fossil fuels in north China, the economic zone of Changsha-Zhuzhou-Xiangtan and the economic zone of the Pearl River Delta region. Researches indicate that the use of fossil fuels has been the main source of air pollution in the three regions. We present researches on global mean surface temperature (GMST) with the rise of carbon dioxide concentration (CDC) and global fossil fuel consumption (GFFC);researches indicate that the rise in CDC can account for 91% of the rise in GMST, and GFFC can account for 90% of the rise in GMST. We analyse the factors that bring about air pollution and temperature rise, they are the use of fossil fuels and deforestation. It is critically important to replace fossil fuels with clean energy, but renewable energy has also disadvantages. The world faces difficulties in solving air pollution and global warming, so governments of the world should cooperate to solve the technologies of clean energy, and preserve the forests and the natural environment.
文摘In areas where hot mix asphalt(HMA)is likely to be exposed by any form of mineral oil the layer has to withstand the attack of these substances in order not to damage the construction.The European Standard EN 12697-43 provides a test procedure to determine the resistance of HMA to fuel.The paper reviews this method thoroughly.A completely revised and simplified test device for the brush test was developed meeting the requirements of the standard and creating results with a high repeatability at the same time.The test conditions given by the standard such as the exposure to fuel,cleaning of the specimen after exposure or the contact pressure of the brush were varied to isolate those test conditions with a substantial influence on the result.The research revealed that in the standard some conditions with a rather small influence are set quite strictly while other conditions with a distinct influence on the result are not defined with the required accuracy to obtain comparable and repeatable results.The paper presents suggestions for the improvement of the test method and the standard itself in respect to the layout of the test device and the definition of important test conditions to enhance the outcome of the EN 12697-43.
基金supported by the U.S.Department of Energy’s Office of Energy Efficiency and Renewable Energy(EERE)under the Fuel Cell Technologies Office(FCTO)(No.DE-EE-0008842)the Office of Fossil Energy and Carbon Management under National Energy Technology Lab(No.DE-FE-0032111).
文摘A critical challenge to the commercialization of clean and high-efficiency solid oxide fuel cell(SOFC)technology is the insuf-ficient stack lifespan caused by a variety of degradation mechanisms,which are associated with cell components and chemical feedstocks.Cell components related degradation refers to thermal/chemical/electrochemical deterioration of cell materials under operating conditions,whereas the latter regards impurities in feedstocks of oxidant(air)and reductant(fuel).This article provides a thermodynamic perspective on the understanding of the impurities-induced degradation mechanisms in SOFCs.The discussion focuses on using thermodynamic ana-lysis to elucidate poisoning mechanisms in cathodes by impurity species such as Cr,CO_(2),H_(2)O,and SO_(2) and in the anode by species such as S(or H_(2)S),SiO_(2),and P_(2)(or PH_(3)).The author hopes the presented fundamental insights can provide a theoretical foundation for search-ing for better technical solutions to address the critical degradation challenges.
基金This work was supported by the National Natural Science Foundation of China(No.598740337)
文摘Electro-hydraulic impulse water-air mixing jet by which the quality of metal materials can be improved is described in this paper. The experimental results proved that the hardness and the micro-hardness of the surface layer of metal materials can be improved with this method, for example, the microhardness of CrWMn can be increased by 35.62 percent.
基金National Key R&D Program of China(Grant No.2021YFA1000402)National Natural Science Foundation of China(Grant No.72071159)to provide fund for conducting experiments。
文摘In the air combat process,confrontation position is the critical factor to determine the confrontation situation,attack effect and escape probability of UAVs.Therefore,selecting the optimal confrontation position becomes the primary goal of maneuver decision-making.By taking the position as the UAV’s maneuver strategy,this paper constructs the optimal confrontation position selecting games(OCPSGs)model.In the OCPSGs model,the payoff function of each UAV is defined by the difference between the comprehensive advantages of both sides,and the strategy space of each UAV at every step is defined by its accessible space determined by the maneuverability.Then we design the limit approximation of mixed strategy Nash equilibrium(LAMSNQ)algorithm,which provides a method to determine the optimal probability distribution of positions in the strategy space.In the simulation phase,we assume the motions on three directions are independent and the strategy space is a cuboid to simplify the model.Several simulations are performed to verify the feasibility,effectiveness and stability of the algorithm.
文摘This study aims to optimize the influence of the inlet inclination angle on the Indoor Air Quality(IAQ),heat,and temperature distribution in mixed convection within a two-dimensional square cavityfilled with an air-CO_(2)mixture.The air-CO_(2)mixture enters the cavity through two inlet openings positioned at the top wall,which is set at the ambient temperature(TC).Three values of the Reynolds numbers,ranging from 1000 to 2000,are considered,while the Prandtl number is kept constant(Pr=0.71).The temperature distribution and streamlines are shown for Rayleigh number(Ra)equal to 104,three inlet inclination anglesϕ(0,π/6 andπ/4)and three CO_(2)concentrations values(1500,2500,3500 ppm)applied at both hot vertical walls(maintained at a constant temperature TH).Afinite volume method is used under the assumption of two-dimensional laminarflow to solve the NavierStokes and energy equations.The results indicate that inlet inclination angle has an impact on the indoor air quality(IAQ),which,in turn,affects the heat transfer distribution and thermal comfort within the cavity.
文摘Aim To study fuel dispersion in fuel air explosive(FAE) and computational ways of fuel dispersion velocity in the near area. Methods\ The dispersion process of fuel in FAE was analyzed by the use of results measured with KODAK EKTAPRO EM Motion Analyzer and setting up mechanical models. Results\ Computational methods for fuel dispersion velocity in the acceleration stage is given and taken as a base for the study of fuel dispersion in the intermediate and the far area. Conclusion\ When the fuel flow velocity is higher than that of the explosion gas in the center cavity, the fuel divides with the explosion gas and its velocity of flow reaches a maximum. The acceleration stage ends at that time. The fuel dispersion velocity at this time is the initial conditions for numeral analyses of dispersion process in the intermediate and far areas.
文摘An improvement in the corrosion resistance of alloys at elevated temperature is a factor for their potential use in gas turbines. In this study, Co Ni Cr Al Y has been coated on the L605 alloy using air plasma spray(APS) and high-velocity oxygen fuel(HVOF) coating techniques to enhance its corrosion resistance. Hot corrosion studies were conducted on uncoated and coated samples in a molten salt environment at 850°C under cyclic conditions. Thermogravimetric analysis was used to determine the corrosion kinetics. The samples were subjected to scanning electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction for further investigation. In coated samples, the formation of Al2O3 and Cr2O3 in the coating acts as a diffusion barrier that could resists the inward movement of the corrosive species present in the molten salt. Coated samples showed very less spallation, lower weight gain, less porosity, and internal oxidation as compared to uncoated sample.HVOF-coated sample showed greater corrosion resistance and inferred that this is the best technique under these conditions.
基金supported by the Young Scientists Fund of the National Natural Science Foundation of China (No. 11802136)。
文摘In order to improve the energy level of fuel air explosive(FAE) with delayed secondary igniters, high energetic metal powders were added to liquid fuels mainly composed of ether and isopropyl nitrate.Metal powders’ explosive properties and reaction mechanisms in FAE were studied by high-speed video,pressure test system, and infrared thermal imager. The results show that compared with pure liquid fuels, the shock wave overpressure, maximum surface fireball temperature and high temperature duration of the mixture were significantly increased after adding high energetic metal powder. The overpressure values of the liquid-solid mixture at all measuring points were higher than that of the pure liquid fuels. And the maximum temperature of the fireball was up to 1700C, which was higher than that of the pure liquid fuels. After replacing 30% of aluminum powder with boron or magnesium hydride, the shock wave pressure of the mixture was further increased. The high heat of combustion of boron and the hydrogen released by magnesium hydride could effectively increase the blast effect of the mixture. The improvement of the explosion performance of boron was better than magnesium hydride. It shows that adding high energetic metal powder to liquid fuels can effectively improve the explosion performance of FAE.
基金Supported by the Natural Science Foundation of Guangdong Province (No. 031424).
文摘A solid state H2S/air electrochemical cell having the configuration of H2S, (MoS2+NiS+Ag)/YSZ/Pt, air has been examined with different H2S flow rates and concentrations at atmospheric pressure and 750-850 ℃. Performance of the fuel cell was dependent on anode compartment H2S flow rate and concentration. The cell open-circuit voltage increased with increasing H2S flow rate. It was found that increasing both H2S flow rate and H2S concentration improved current-voltage and power density performance. This is resulted from improved gas diffusion in anode and increased concentration of anodic electroactive species. Operation at elevated H2S concentration improved the cell performance at a given gas flow rate. However, as low as 5% H2S in gas mixture can also be utilized as fuel feed to cells. Highest current and power densities, 17500mA·cm-2 and 200mW·cm-2, are obtained with pure H2S flow rate of 50ml·min-1 and air flow rate of 100ml·min-1 at 850℃.
基金Supported by the National Iranian Oil Company (NIOC)
文摘This numerical study investigates the effects of using a diluted fuel (50% natural gas and 50% N2) in an industrial furnace under several cases of conventional combustion (air with 21% O2 at 300 and 1273 K) and the highly preheated and diluted air (1273 K with 10% O2 and 90% N2) combustion (HPDAC) conditions using an in-house computer program. It was found that by applying a combined diluted fuel and oxidant instead of their uncombined and/or undiluted states, the best condition is obtained for the establishment of HPDAC's main unique features. These features are low mean and maximum gas temperature and high radiation/total heat transfer to gas and tubes; as well as more uniformity of theirs distributions which results in decrease in NOx pollutant formation and increase in furnace efficiency or energy saving. Moreover, a variety of chemical flame shape, the process fluid and tubes walls temperatures profiles, the required regenerator efficiency and finally the concentration and velocity patterns have been also qualitatively/quantitatively studied.
基金Project supported by the National Natural Science Foundation of China (Grant No.20576071)the Natural Science Foundation of Shanghai Municipality (Grant No.08ZR1409800)
文摘To prevent the oxygen starvation and improve the system output performance, an adaptive inverse control (AIC) strategy is developed to regulate the air supply flow of a proton exchange membrane fuel cell (PEMFC) system in this paper. The PEMFC stack and the air supply system including a compressor and a supply manifold are modeled for the purpose of performance analysis and controller design. A recurrent fuzzy neural network (RFNN) is utilized to identify the inverse model of the controlled system and generates a suitable control input during the abrupt step change of external disturbances. Compared with the PI controller, numerical simulations are performed to validate the effectiveness and advantages of the proposed AIC strategy.
基金Sponsored by the National Natural Science Foundation of China (10772032)
文摘An infrared colorimetric radiation thermometrical system was established based on the theory of optical radiation. The dynamic temperature history of fuel air explosive (FAE) was measured to obtain the temperature responses of primary initiation FAE and secondary initiation FAE in real time. And the characteristics of their temperature history curves were compared and analyzed. The results show that the primary initiation FAE has higher explosion temperature and longer duration compared to the secondary initiation FAE.
基金supported by the National Key R&D Project(No.2020YFB1600101)National Natural Science Foundations of China(Nos.U1833103,71801215)Civil Aviation Flight Wide Area Surveillance and Safety Control Technology Key Laboratory Open Fund(No.202008)。
文摘Most of the traditional taxi path planning studies assume that the aircraft is in uniform speed,and the optimization goal is the shortest taxi time.Although it is easy to solve,it does not consider the changes in the speed profile of the aircraft when turning,and the shortest taxi time does not necessarily bring the best taxi fuel consumption.In this paper,the number of turns is considered,and the improved A*algorithm is used to obtain the P static paths with the shortest sum of the straight-line distance and the turning distance of the aircraft as the feasible taxi paths.By balancing taxi time and fuel consumption,a set of Pareto optimal speed profiles are generated for each preselected path to predict the 4-D trajectory of the aircraft.Based on the 4-D trajectory prediction results,the conflict by the occupied time window in the taxiing area is detected.For the conflict aircraft,based on the priority comparison,the waiting or changing path is selected to solve the taxiing conflict.Finally,the conflict free aircraft taxiing path is generated and the area occupation time window on the path is updated.The experimental results show that the total taxi distance and turn time of the aircraft are reduced,and the fuel consumption is reduced.The proposed method has high practical application value and is expected to be applied in real-time air traffic control decision-making in the future.