H-ZSM-5 zeolite was synthesized by hydrothermal method. The effects of different synthesis parameters, such as hydrothermal crystallization temperature (170-190 ℃) and Si/A1 molar ratio (100-150), on the catalyti...H-ZSM-5 zeolite was synthesized by hydrothermal method. The effects of different synthesis parameters, such as hydrothermal crystallization temperature (170-190 ℃) and Si/A1 molar ratio (100-150), on the catalytic performance of the dehydration of methanol to dimethyl ether (DME) over the synthesized H-ZSM-5 zeolite were studied. The catalysts were characterized by N2 adsorption-desorption, XRD, NH3-TPD, TGA/DTA, and SEM techniques. The full factorial design of experiments was applied to the synthesis of H-ZSM-5 zeolite and the effects of synthesis conditions and their interaction on the yield of DME as the response variable were determined. Analysis of variance showed that two variables and their interaction significantly affected the response. According to the experimental results, the optimized catalyst prepared at 170℃ with the Si/A1 molar ratio of 100 showed the best catalytic performance among the tested H-ZSM-5 zeolite.展开更多
Artificial neural network(ANN) and full factorial design assisted atrazine(AT) multiple regression adsorption model(AT-MRAM) were developed to analyze the adsorption capability of the main components in the surf...Artificial neural network(ANN) and full factorial design assisted atrazine(AT) multiple regression adsorption model(AT-MRAM) were developed to analyze the adsorption capability of the main components in the surficial sediments(SSs). Artificial neural network was used to build a model(the determination coefficient square r2 is 0.9977) to describe the process of atrazine adsorption onto SSs, and then to predict responses of the full factorial design. Based on the results of the full factorial design, the interactions of the main components in SSs on AT adsorption were investigated through the analysis of variance(ANOVA), F-test and t-test. The adsorption capability of the main components in SSs for AT was calculated via a multiple regression adsorption model(MRAM). The results show that the greatest contribution to the adsorption of AT on a molar basis was attributed to Fe/Mn(–1.993 μmol/mol). Organic materials(OMs) and Fe oxides in SSs are the important adsorption sites for AT, and the adsorption capabilities are 1.944 and 0.418 μmol/mol, respectively. The interaction among the non-residual components(Fe, Mn oxides and OMs) in SSs interferes in the adsorption of AT that shouldn’t be neglected, revealing the significant contribution of the interaction among non-residual components to controlling the behavior of AT in aquatic environments.展开更多
Saline waters treatment has become increasingly important for drinking water supply in a greater part of the world. However, some serious limitations had recently been discovered during water treatment, among them the...Saline waters treatment has become increasingly important for drinking water supply in a greater part of the world. However, some serious limitations had recently been discovered during water treatment, among them the boron problem seems to have a critical meaning. According to the WHO regulations (2011), the boron concentration should be reduced to less than 2.4 mg/L for drinking water. The purpose of this study is to investigate the feasibility of electrocoagulation (EC) as a pretreatment process to remove boron from saline waters. To optimize the experimental conditions of boron removal, the effects of some parameters were studied such as inter-electrode distance (die), electrode connection mode, (S/V) ratio, pHi and initial conductivity of the solution (σi). Subsequently, an experimental design methodology was implemented to evaluate statistically the most significant operating parameters. The effects of current density, EC time and initial boron concentration and their mutual interaction were investigated using 23 full factorial design. At optimal conditions, boron removal from synthetic aqueous solutions containing initial boron concentrations of 5 and 50 mg/L reached 81% and 79%, respectively. Applied to boron removal from seawater samples, EC reduces boron concentration to less to 2.4 mg/L with excessive energy consumption under optimal parameters.展开更多
Based on the consideration of operation environment and structural property, an optimum design model of offshore jacket platform is developed in this paper, namely, the reliability-based full-life cycle optimum design...Based on the consideration of operation environment and structural property, an optimum design model of offshore jacket platform is developed in this paper, namely, the reliability-based full-life cycle optimum design model. In this model, the time-dependent reliability assessment method for structural members is established by combination of the decrease of sectional size and performance deterioration of material. The initial investment, maintenance cost and failure loss cost are assembled into the model. The total cost of the platform structure system in its full service period is chosen as the objective function, and the initial reliabilities of the layer elements partitioned in advance are taken as the design variables. Different models are obtained, depending on whether the system reliability constraint is considered or not. This optimum design model can result in the lowest full-life cost and the optimal initial layer reliability of an offshore jacket platform in the design of marine structures. The feasibility of this model is illustrated with an actual jacket platform in the Liaodong Gulf as an example.展开更多
For the simultaneous wireless information and power transfer(SWIPT), the full-duplex MIMO system can achieve simultaneous transmission of information and energy more efficiently than the half-duplex. Based on the mean...For the simultaneous wireless information and power transfer(SWIPT), the full-duplex MIMO system can achieve simultaneous transmission of information and energy more efficiently than the half-duplex. Based on the mean-square-error(MSE) criterion, the optimization problem of joint transceiver design with transmitting power constraint and energy harvesting constraint is formulated. Next, by semidefinite relaxation(SDR) and randomization method, the SDRbased scheme is proposed. In order to reduce the complexity, the closed-form scheme is presented with some simplified measures. Robust beamforming is then studied considering the practical condition. The simulation results such as MSE versus signal-noise-ratio(SNR), MSE versus the iteration number, well prove the performance of the proposed schemes for the system model.展开更多
In the China merchants property 2013 green architectural design competition,feature of this awardwinning program is the design method based on the principles of passive priority and comprehensive utilization of full l...In the China merchants property 2013 green architectural design competition,feature of this awardwinning program is the design method based on the principles of passive priority and comprehensive utilization of full life cycle. The passive priority can be achieved by building form derived from the simulation and analysis of wind environment,improvement of the building envelope insulation and the dehumidification of fresh air,the use of solar energy. The full life cycle utilization can be accomplished by the combination of exhibition and residents' leisure activities, and the integration with local cultural tradition, thereby improving energy efficiency and the utilization of the building.展开更多
文摘H-ZSM-5 zeolite was synthesized by hydrothermal method. The effects of different synthesis parameters, such as hydrothermal crystallization temperature (170-190 ℃) and Si/A1 molar ratio (100-150), on the catalytic performance of the dehydration of methanol to dimethyl ether (DME) over the synthesized H-ZSM-5 zeolite were studied. The catalysts were characterized by N2 adsorption-desorption, XRD, NH3-TPD, TGA/DTA, and SEM techniques. The full factorial design of experiments was applied to the synthesis of H-ZSM-5 zeolite and the effects of synthesis conditions and their interaction on the yield of DME as the response variable were determined. Analysis of variance showed that two variables and their interaction significantly affected the response. According to the experimental results, the optimized catalyst prepared at 170℃ with the Si/A1 molar ratio of 100 showed the best catalytic performance among the tested H-ZSM-5 zeolite.
基金Supported by the National Natural Science Foundation of China(No.50879025)
文摘Artificial neural network(ANN) and full factorial design assisted atrazine(AT) multiple regression adsorption model(AT-MRAM) were developed to analyze the adsorption capability of the main components in the surficial sediments(SSs). Artificial neural network was used to build a model(the determination coefficient square r2 is 0.9977) to describe the process of atrazine adsorption onto SSs, and then to predict responses of the full factorial design. Based on the results of the full factorial design, the interactions of the main components in SSs on AT adsorption were investigated through the analysis of variance(ANOVA), F-test and t-test. The adsorption capability of the main components in SSs for AT was calculated via a multiple regression adsorption model(MRAM). The results show that the greatest contribution to the adsorption of AT on a molar basis was attributed to Fe/Mn(–1.993 μmol/mol). Organic materials(OMs) and Fe oxides in SSs are the important adsorption sites for AT, and the adsorption capabilities are 1.944 and 0.418 μmol/mol, respectively. The interaction among the non-residual components(Fe, Mn oxides and OMs) in SSs interferes in the adsorption of AT that shouldn’t be neglected, revealing the significant contribution of the interaction among non-residual components to controlling the behavior of AT in aquatic environments.
文摘Saline waters treatment has become increasingly important for drinking water supply in a greater part of the world. However, some serious limitations had recently been discovered during water treatment, among them the boron problem seems to have a critical meaning. According to the WHO regulations (2011), the boron concentration should be reduced to less than 2.4 mg/L for drinking water. The purpose of this study is to investigate the feasibility of electrocoagulation (EC) as a pretreatment process to remove boron from saline waters. To optimize the experimental conditions of boron removal, the effects of some parameters were studied such as inter-electrode distance (die), electrode connection mode, (S/V) ratio, pHi and initial conductivity of the solution (σi). Subsequently, an experimental design methodology was implemented to evaluate statistically the most significant operating parameters. The effects of current density, EC time and initial boron concentration and their mutual interaction were investigated using 23 full factorial design. At optimal conditions, boron removal from synthetic aqueous solutions containing initial boron concentrations of 5 and 50 mg/L reached 81% and 79%, respectively. Applied to boron removal from seawater samples, EC reduces boron concentration to less to 2.4 mg/L with excessive energy consumption under optimal parameters.
文摘Based on the consideration of operation environment and structural property, an optimum design model of offshore jacket platform is developed in this paper, namely, the reliability-based full-life cycle optimum design model. In this model, the time-dependent reliability assessment method for structural members is established by combination of the decrease of sectional size and performance deterioration of material. The initial investment, maintenance cost and failure loss cost are assembled into the model. The total cost of the platform structure system in its full service period is chosen as the objective function, and the initial reliabilities of the layer elements partitioned in advance are taken as the design variables. Different models are obtained, depending on whether the system reliability constraint is considered or not. This optimum design model can result in the lowest full-life cost and the optimal initial layer reliability of an offshore jacket platform in the design of marine structures. The feasibility of this model is illustrated with an actual jacket platform in the Liaodong Gulf as an example.
基金supported by the National Great Science Specif ic Project (Grants No. 2014ZX03002002-004)National Natural Science Foundation of China (Grants No. NSFC-61471067)
文摘For the simultaneous wireless information and power transfer(SWIPT), the full-duplex MIMO system can achieve simultaneous transmission of information and energy more efficiently than the half-duplex. Based on the mean-square-error(MSE) criterion, the optimization problem of joint transceiver design with transmitting power constraint and energy harvesting constraint is formulated. Next, by semidefinite relaxation(SDR) and randomization method, the SDRbased scheme is proposed. In order to reduce the complexity, the closed-form scheme is presented with some simplified measures. Robust beamforming is then studied considering the practical condition. The simulation results such as MSE versus signal-noise-ratio(SNR), MSE versus the iteration number, well prove the performance of the proposed schemes for the system model.
文摘In the China merchants property 2013 green architectural design competition,feature of this awardwinning program is the design method based on the principles of passive priority and comprehensive utilization of full life cycle. The passive priority can be achieved by building form derived from the simulation and analysis of wind environment,improvement of the building envelope insulation and the dehumidification of fresh air,the use of solar energy. The full life cycle utilization can be accomplished by the combination of exhibition and residents' leisure activities, and the integration with local cultural tradition, thereby improving energy efficiency and the utilization of the building.