The fullerene complex,C60 RuH2(CO)(PPh3),has been prepared and characterize d by elemental analyses,IR and electronic spectra.In addition,the redox property of t he complex has been studied by cyclic voltammetry.The r...The fullerene complex,C60 RuH2(CO)(PPh3),has been prepared and characterize d by elemental analyses,IR and electronic spectra.In addition,the redox property of t he complex has been studied by cyclic voltammetry.The results s how that the reduction potential of C60 RuH2(CO)(PPh3)is more negative than that of C60.Meanwhile,with the extent of the complex reduction get to increace the stability of the complex ion is on the decrease.展开更多
文摘The fullerene complex,C60 RuH2(CO)(PPh3),has been prepared and characterize d by elemental analyses,IR and electronic spectra.In addition,the redox property of t he complex has been studied by cyclic voltammetry.The results s how that the reduction potential of C60 RuH2(CO)(PPh3)is more negative than that of C60.Meanwhile,with the extent of the complex reduction get to increace the stability of the complex ion is on the decrease.
