Photoinduced electron transfer processes between fullerenes (C60 / C70) and N, N, N, N tetra - ( p-methylphenyl ) - 4, 4 diamino - 1, 1- diphenyl ether ( TPDAE ) have been studied by nanosecond laser flash photolysis....Photoinduced electron transfer processes between fullerenes (C60 / C70) and N, N, N, N tetra - ( p-methylphenyl ) - 4, 4 diamino - 1, 1- diphenyl ether ( TPDAE ) have been studied by nanosecond laser flash photolysis. Quantum yields and rate constants of electron transfer from TPDAE to excited triplet state of fullerenes (C60 / C70 ) in benzonitrile have been evaluated by observing the transient absorption bands in the near-IR region where the excited triplet state, radical anion of fullerenes ( C60 / C70 ) and radical cations of TPDAE appear.展开更多
The solubilities of C60 and C70 in toluene, o-xylene and CS2 between melting point and boiling point have been measured. The temperature-dependent solubillty of C60 displays the anomalous behavior. A solubility maximu...The solubilities of C60 and C70 in toluene, o-xylene and CS2 between melting point and boiling point have been measured. The temperature-dependent solubillty of C60 displays the anomalous behavior. A solubility maximum of C60 around O℃ for toluene and CS2, and around 30℃ for o-xylene was observed. The temperature-dependent solu bility of C70 displays the normal behavior in the same solvents.展开更多
A micro-oxygen-boinb calorimeter with a bomb of 4.8 cm3 internal volume was constructed in our laboratory. About 10 mg of sample was needed for each combustion experiment.The energy equivalent of this calorimeter was ...A micro-oxygen-boinb calorimeter with a bomb of 4.8 cm3 internal volume was constructed in our laboratory. About 10 mg of sample was needed for each combustion experiment.The energy equivalent of this calorimeter was determmed with electric energy. The standard diviation of mean from 5 measurements was 0.02 %.The enthalpies of combustion of pure C60 and C70 were determined, kJ. mol-1,kJ·mol. The enthalpies of formation of the two compounds were derived. Using the Laidlertype bond parameters for aromatic hydrocarbons, the estimated strain energies in C60 and C70 molecules were close each other and close to the estimated value from the model compound, corannulene.展开更多
文摘Photoinduced electron transfer processes between fullerenes (C60 / C70) and N, N, N, N tetra - ( p-methylphenyl ) - 4, 4 diamino - 1, 1- diphenyl ether ( TPDAE ) have been studied by nanosecond laser flash photolysis. Quantum yields and rate constants of electron transfer from TPDAE to excited triplet state of fullerenes (C60 / C70 ) in benzonitrile have been evaluated by observing the transient absorption bands in the near-IR region where the excited triplet state, radical anion of fullerenes ( C60 / C70 ) and radical cations of TPDAE appear.
文摘The solubilities of C60 and C70 in toluene, o-xylene and CS2 between melting point and boiling point have been measured. The temperature-dependent solubillty of C60 displays the anomalous behavior. A solubility maximum of C60 around O℃ for toluene and CS2, and around 30℃ for o-xylene was observed. The temperature-dependent solu bility of C70 displays the normal behavior in the same solvents.
文摘A micro-oxygen-boinb calorimeter with a bomb of 4.8 cm3 internal volume was constructed in our laboratory. About 10 mg of sample was needed for each combustion experiment.The energy equivalent of this calorimeter was determmed with electric energy. The standard diviation of mean from 5 measurements was 0.02 %.The enthalpies of combustion of pure C60 and C70 were determined, kJ. mol-1,kJ·mol. The enthalpies of formation of the two compounds were derived. Using the Laidlertype bond parameters for aromatic hydrocarbons, the estimated strain energies in C60 and C70 molecules were close each other and close to the estimated value from the model compound, corannulene.
