A thermal-responsive photonic crystal material was fabricated by forming an inverse opal nanocomposite hydrogel of poly(N-isopropylacrylamide)(IONHPNIPAm)within the interstitial space of a polystyrene photonic crystal...A thermal-responsive photonic crystal material was fabricated by forming an inverse opal nanocomposite hydrogel of poly(N-isopropylacrylamide)(IONHPNIPAm)within the interstitial space of a polystyrene photonic crystal template.In IONHPNIPAm,PNIPAm were physically cross-linked with two kinds of nanoparticles(carbon dots and laponite clays).The integration of carbon dots and laponite clays for physical crosslinking endowed IONHPNIPAm sufficient strength and self-healing property.IONHPNIPAm films can be completely peeled from the substrates to be utilized as an independent photonic crystal material.The structural color and optical diffraction of the IONHPNIPAm exhibits a rapid reversible change in response to external thermal stimuli due to its physical cross-linking feature.Moreover,the IONHPNIPAm shows clear fluorescence due to the introduction of carbon dots,which enables a convenient way for chemical detection(such as the detection of silver ions).This stimuli-responsive photonic crystal materials based on physically cross-linked inverse opal nanocomposite hydrogels with fast response and good mechanical stability are promising for applications in the fields of smart optical detectors,thermal-responsive sensors and chemical detectors.展开更多
Cross-linking of silyl-modified polymers occurs at the alkoxysilane groups attached to the ends of polymer chains by hydrolysis and polycondensation mechanisms in the presence of moisture. During these reactions, thre...Cross-linking of silyl-modified polymers occurs at the alkoxysilane groups attached to the ends of polymer chains by hydrolysis and polycondensation mechanisms in the presence of moisture. During these reactions, three different physical states can be identified (viscous, skin effect and cross-linked state). Knowledge of the evolution of these states at each reaction time is essential to determine the open time for the adhe-sive industry and is generally obtained by a manual method. Automation of this moni-toring could avoid operator error and could be used for very long cross linking reac-tions or to screen a large number of catalysts. Thus, a contactless micro process tech-nology was developed to correlate these physical states with an optical technology, Raman spectroscopy, by monitoring the decrease in intensity of the Si-OCH<sub>3</sub> groups during chemical reactions. This online characterization method can also be used to compare the efficiencies of several catalysts for the cross-linking of silyl-modified polymers, using a minimum amount of chemical materials.展开更多
Fog computing is a rapidly growing technology that aids in pipelining the possibility of mitigating breaches between the cloud and edge servers.It facil-itates the benefits of the network edge with the maximized probab...Fog computing is a rapidly growing technology that aids in pipelining the possibility of mitigating breaches between the cloud and edge servers.It facil-itates the benefits of the network edge with the maximized probability of offering interaction with the cloud.However,the fog computing characteristics are suscep-tible to counteract the challenges of security.The issues present with the Physical Layer Security(PLS)aspect in fog computing which included authentication,integrity,and confidentiality has been considered as a reason for the potential issues leading to the security breaches.In this work,the Octonion Algebra-inspired Non-Commutative Ring-based Fully Homomorphic Encryption Scheme(NCR-FHE)was proposed as a secrecy improvement technique to overcome the impersonation attack in cloud computing.The proposed approach was derived through the benefits of Octonion algebra to facilitate the maximum security for big data-based applications.The major issues in the physical layer security which may potentially lead to the possible security issues were identified.The potential issues causing the impersonation attack in the Fog computing environment were identified.The proposed approach was compared with the existing encryption approaches and claimed as a robust approach to identify the impersonation attack for the fog and edge network.The computation cost of the proposed NCR-FHE is identified to be significantly reduced by 7.18%,8.64%,9.42%,and 10.36%in terms of communication overhead for varying packet sizes,when compared to the benchmarked ECDH-DH,LHPPS,BF-PHE and SHE-PABF schemes.展开更多
Different GAP-based CSRP samples with different binder contents were prepared and compared with that of conventional HTPB propellant.The crosslinker mixture of trimethylol propane(TMP)and butane diol(BD)was used in th...Different GAP-based CSRP samples with different binder contents were prepared and compared with that of conventional HTPB propellant.The crosslinker mixture of trimethylol propane(TMP)and butane diol(BD)was used in the GAP matrix beside the addition of dibutyltin dilaurate(DBTDL)to ensure cross-linking and curing completion of the prepared CSRP.The viscosity and hardness of all prepared formulations were monitored continuously during the curing process.The mechanical characteristics of cured samples were tested.The burning rate at operating pressure and specific impulse were measured,while the theoretical specific impulse(I sp)was calculated by ICT code and compared with the measured results.According to the results,DOA was found to be a suitable plasticizer for GAP when using in propellant.The mechanical properties of CSRP with 25%GAP can produce the optimum mechanical behavior,which is close to that of HTPB-based CSRP.The optimum GAP-based formulation is one candidate to replace the traditional HTPB-based CSRP with high burning rate for some applications.展开更多
基金Funded by the National Natural Science Foundation of China(No.51873167)the National Innovation and Entrepreneurship Training Program for College Students(No.S202010497024)。
文摘A thermal-responsive photonic crystal material was fabricated by forming an inverse opal nanocomposite hydrogel of poly(N-isopropylacrylamide)(IONHPNIPAm)within the interstitial space of a polystyrene photonic crystal template.In IONHPNIPAm,PNIPAm were physically cross-linked with two kinds of nanoparticles(carbon dots and laponite clays).The integration of carbon dots and laponite clays for physical crosslinking endowed IONHPNIPAm sufficient strength and self-healing property.IONHPNIPAm films can be completely peeled from the substrates to be utilized as an independent photonic crystal material.The structural color and optical diffraction of the IONHPNIPAm exhibits a rapid reversible change in response to external thermal stimuli due to its physical cross-linking feature.Moreover,the IONHPNIPAm shows clear fluorescence due to the introduction of carbon dots,which enables a convenient way for chemical detection(such as the detection of silver ions).This stimuli-responsive photonic crystal materials based on physically cross-linked inverse opal nanocomposite hydrogels with fast response and good mechanical stability are promising for applications in the fields of smart optical detectors,thermal-responsive sensors and chemical detectors.
文摘Cross-linking of silyl-modified polymers occurs at the alkoxysilane groups attached to the ends of polymer chains by hydrolysis and polycondensation mechanisms in the presence of moisture. During these reactions, three different physical states can be identified (viscous, skin effect and cross-linked state). Knowledge of the evolution of these states at each reaction time is essential to determine the open time for the adhe-sive industry and is generally obtained by a manual method. Automation of this moni-toring could avoid operator error and could be used for very long cross linking reac-tions or to screen a large number of catalysts. Thus, a contactless micro process tech-nology was developed to correlate these physical states with an optical technology, Raman spectroscopy, by monitoring the decrease in intensity of the Si-OCH<sub>3</sub> groups during chemical reactions. This online characterization method can also be used to compare the efficiencies of several catalysts for the cross-linking of silyl-modified polymers, using a minimum amount of chemical materials.
文摘Fog computing is a rapidly growing technology that aids in pipelining the possibility of mitigating breaches between the cloud and edge servers.It facil-itates the benefits of the network edge with the maximized probability of offering interaction with the cloud.However,the fog computing characteristics are suscep-tible to counteract the challenges of security.The issues present with the Physical Layer Security(PLS)aspect in fog computing which included authentication,integrity,and confidentiality has been considered as a reason for the potential issues leading to the security breaches.In this work,the Octonion Algebra-inspired Non-Commutative Ring-based Fully Homomorphic Encryption Scheme(NCR-FHE)was proposed as a secrecy improvement technique to overcome the impersonation attack in cloud computing.The proposed approach was derived through the benefits of Octonion algebra to facilitate the maximum security for big data-based applications.The major issues in the physical layer security which may potentially lead to the possible security issues were identified.The potential issues causing the impersonation attack in the Fog computing environment were identified.The proposed approach was compared with the existing encryption approaches and claimed as a robust approach to identify the impersonation attack for the fog and edge network.The computation cost of the proposed NCR-FHE is identified to be significantly reduced by 7.18%,8.64%,9.42%,and 10.36%in terms of communication overhead for varying packet sizes,when compared to the benchmarked ECDH-DH,LHPPS,BF-PHE and SHE-PABF schemes.
文摘Different GAP-based CSRP samples with different binder contents were prepared and compared with that of conventional HTPB propellant.The crosslinker mixture of trimethylol propane(TMP)and butane diol(BD)was used in the GAP matrix beside the addition of dibutyltin dilaurate(DBTDL)to ensure cross-linking and curing completion of the prepared CSRP.The viscosity and hardness of all prepared formulations were monitored continuously during the curing process.The mechanical characteristics of cured samples were tested.The burning rate at operating pressure and specific impulse were measured,while the theoretical specific impulse(I sp)was calculated by ICT code and compared with the measured results.According to the results,DOA was found to be a suitable plasticizer for GAP when using in propellant.The mechanical properties of CSRP with 25%GAP can produce the optimum mechanical behavior,which is close to that of HTPB-based CSRP.The optimum GAP-based formulation is one candidate to replace the traditional HTPB-based CSRP with high burning rate for some applications.
