A two-year field experiment was conducted to measure the effects of densification methods on photosynthesis and yield of densely planted wheat.Inter-plant and inter-row distances were used to define ratefixed pattern(...A two-year field experiment was conducted to measure the effects of densification methods on photosynthesis and yield of densely planted wheat.Inter-plant and inter-row distances were used to define ratefixed pattern(RR)and row-fixed pattern(RS)density treatments.Meanwhile,four nitrogen(N)rates(0,144,192,and 240 kg N ha-1,termed N0,N144,N192,and N240)were applied with three densities(225,292.5,and 360×10^(4)plants ha^(-1),termed D225,D292.5,and D360).The wheat canopy was clipped into three equal vertical layers(top,middle,and bottom layers),and their chlorophyll density(Ch D)and photosynthetically active radiation interception(FIPAR)were measured.Results showed that the response of Ch D and FIPAR to N rate,density,and pattern varied with different layers.N rate,density,and pattern had significant interaction effects on Ch D.The maximum values of whole-canopy Ch D in the two seasons appeared in N240 combined with D292.5 and D360 under RR,respectively.Across two growing seasons,FIPAR values of RR were higher than those of RS by 29.37%for the top layer and 5.68%for the middle layer,while lower than those of RS by 20.62%for the bottom layer on average.With a low N supply(N0),grain yield was not significantly affected by density for both patterns.At N240,increasing density significantly increased yield under RR,but D360 of RS significantly decreased yield by 3.72%and 9.00%versus D225 in two seasons,respectively.With an appropriate and sufficient N application,RR increased the yield of densely planted wheat more than RS.Additionally,the maximum yield in two seasons appeared in the combination of D360 with N144 or N192 rather than of D225 with N240 under both patterns,suggesting that dense planting combined with an appropriate N-reduction application is feasible to increase photosynthesis capacity and yield.展开更多
Field experiments were carried out at the National Research Center farm, Nubaria area, Behura Governorate, Egypt, to study the effect of nitrogen source, flushing schedule and irrigation method on emitter clogging. Pe...Field experiments were carried out at the National Research Center farm, Nubaria area, Behura Governorate, Egypt, to study the effect of nitrogen source, flushing schedule and irrigation method on emitter clogging. Peanut Giza 5 variety (Arachishy pogaea L.) was planted in sandy soil during two successive growing seasons (2010-2011) in the 1st week of May and harvested after 130 days. Treatments used are: 1) two irrigation methods: surface drip irrigation and sub-surface drip irrigation (SDI;SSDI), 2) nitrogen source (NS):NH4NO3, (NH4)2SO4 and Ca(NO3)2 (NS1, NS2 and NS3) and 3) flushing number (FL) 0, 1 and 4 (FL1, FL2;FL3). The experiments design was split-split plot and three replicates were used. Data obtained were subjected to statistical analysis. The main effects of treatments used on clogging per cent could be written the following ascending orders: SDI 3 2 1, NS1 2 3. Concerning the 1st interaction the following ascending orders denote their effects on clogging percent: SDI × FL3 2 1, SDI × NS1 2 3, SSDI × FL3 2 1, SSDI × NS1 2 3, FL1 × NS1 1 × NS2 1 × NS3, FL2 × NS1 2 × NS2 2 × NS3 and FL3 × NS1 3 × NS2 3 × NS3. The differences between any two treatments and/or any two interactions in clogging percent were significant at the 5% level. The effect of the 2nd interaction on clogging percent was significant at the 5% level. The maximum value of clogging (20.18%) and the lowest one (3.9%) were archived in the interactions: SSDI × FL1 × NS3 and SDI × FL3 × NS1, respectively.展开更多
In order to determine whether long-term no-tillage operation in the loess plateau threatens soil fertility and crop yield,a suitable high-yield and efficient tillage technology system was established.In the Changwu lo...In order to determine whether long-term no-tillage operation in the loess plateau threatens soil fertility and crop yield,a suitable high-yield and efficient tillage technology system was established.In the Changwu loess plateau agri-Gecological experiment station of the Northwest A&F University of Changwu County,Shaanxi Province,the no-tillage experimental field for three consecutive years was selected.In September 2015,no-tillage,tillage,and rotary tillage were carried out before winter wheat was sowed.After the harvest of winter wheat in2016,soil organic carbon,total nitrogen and wheat yield in 0-30 cm soil layers under different tillage methods were analyzed.The results showed that the soil organic carbon and total nitrogen contents in the 0-30 cm soil layer decreased along the profile under the three tillage methods.In this study,the soil organic carbon and total nitrogen content in the 0-10 cm soil layer under different tillage methods were no-tillage>rotary tillage>tillage,the actual yield of winter yield in one hectare was tillage>rotary tillage>no-tillage,and there was significant difference in the actual yield of winter wheat only between the no-tillage and tillage.展开更多
A soil column method was used to compare the effect of drip fertigation (the application of fertilizer through drip irrigation systems, DFI) on the leaching loss and transformation of urea-N in soil with that of surfa...A soil column method was used to compare the effect of drip fertigation (the application of fertilizer through drip irrigation systems, DFI) on the leaching loss and transformation of urea-N in soil with that of surface fertilization combined with flood irrigation (SFI), and to study the leaching loss and transformation of three kinds of nitrogen fertilizers (nitrate fertilizer, ammonium fertilizer, and urea fertilizer) in two contrasting soils after the fertigation. In comparison to SFI, DFI decreased leaching loss of urea-N from the soil and increased the mineral N (NH4+-N + NO3- -N) in the soil. The N leached from a clay loam soil ranged from 5.7% to 9.6% of the total N added as fertilizer, whereas for a sandy loam soil they ranged between 16.2% and 30.4%. Leaching losses of mineral N were higher when nitrate fertilizer was used compared to urea or ammonium fertilizer. Compared to the control (without urea addition), on the first day when soils were fertigated with urea, there were increases in NH4+-N in the soils. This confirmed the rapid hydrolysis of urea in soil during fertigation. NH4+-N in soils reached a peak about 5 days after fertigation, and due to nitrification it began to decrease at day 10. After applying NH4+-N fertilizer and urea and during the incubation period, the mineral nitrogen in the soil decreased. This may be related to the occurrence of NH4+-N fixation or volatilization in the soil during the fertigation process.展开更多
Cellulose carbamates (CC) were synthesized with microcrystalline cellulose as raw materials. The Fourier transform infrared spectra of CC with different nitrogen content were recorded. The accurate results of the nitr...Cellulose carbamates (CC) were synthesized with microcrystalline cellulose as raw materials. The Fourier transform infrared spectra of CC with different nitrogen content were recorded. The accurate results of the nitrogen content for CC can be obtained by using the deconvolution method when the nitrogen content is less than 3.5%. The relationship between the nitrogen content and the absorption intensity ratio of the corresponding separated absorption peaks in FTIR spectra has been expressed bg an equation precisely.展开更多
The ideal reducing reagent in testing available nitrogen of soil by Conway Methodis Devard‘s alloy.The optimum ratio of soil:Devard’s alloy:1.0N NaOH solution is 5.0g:0.2g:5ml.When reaction goes on at 30℃ for 4 hou...The ideal reducing reagent in testing available nitrogen of soil by Conway Methodis Devard‘s alloy.The optimum ratio of soil:Devard’s alloy:1.0N NaOH solution is 5.0g:0.2g:5ml.When reaction goes on at 30℃ for 4 hours,the rate of soil NO<sub>3</sub>-N reduction is about 90%,and the recovery rate of soil NH<sub>4</sub>-N is about 95%.Some organic nitrogen can be measured at thesame time.This method is defined as the Modified Conway Method and the soil N-min is r=0.982(n=10).In predicting soil nitrogen supplying power,the Modified Conway Method takesonly 1/6 of time needed by Conway Method.The Modified Conway Method can also be used forthe measure of soil N-min.展开更多
This paper reprots that with Ni-based catalyst/solvent and with a dopant of NAN3, large green single crystal diamonds with perfect shape are successfully synthesized by temperature gradient method under high pressure ...This paper reprots that with Ni-based catalyst/solvent and with a dopant of NAN3, large green single crystal diamonds with perfect shape are successfully synthesized by temperature gradient method under high pressure and high temperature in a China-type cubic anvil high-pressure apparatus (SPD-6 × 1200), and the highest nitrogen concentration reaches approximately 121-1257 ppm calculated by infrared absorption spectra. The synthesis conditions are about 5.5 CPa and 1240-1300 ℃. The growth behaviour of diamond with high-nitrogen concentration is investigated in detail. The results show that, with increasing the content of NaN3 added in synthesis system, the width of synthesis temperature region for growth high-quality diamonds becomes narrower, and the morphology of diamond crystal is changed from cube-octahedral to octahedral at same temperature and pressure, the crystal growth rate is slowed down, nevertheless, the nitrogen concentration doped in synthetic diamond increases.展开更多
Benzylsulfonamide was used as a source of nitrogen in the syn- thesis of azacrown ethers,and the cyclic intermediates were easily deben- zylsulfonylated by treating with CaF_2/H_2SO_4 to afford the azacrown ethers.
The reduction of molecular nitrogen(N_(2))to ammonia(NH_(3))under mild conditions is one of the most promising studies in the energy field due to the important role of NH_(3)in modern industry,production,and life.The ...The reduction of molecular nitrogen(N_(2))to ammonia(NH_(3))under mild conditions is one of the most promising studies in the energy field due to the important role of NH_(3)in modern industry,production,and life.The photocatalytic reduction of N_(2)is expected to achieve clean and sustainable NH_(3)production by using clean solar energy.To date,the new photocatalysts for photocatalytic reduction of N_(2)to NH_(3)at room temperature and atmospheric pressure have not been fully developed.The major challenge is to achieve high light-absorption efficiency,conversion efficiency,and stability of photocatalysts.Herein,the methods for measuring produced NH_(3)are compared,and the problems related to possible NH_(3)pollution in photocatalytic systems are mentioned to provide accurate ideas for measuring photocatalytic efficiency.The recent progress of nitrogen reduction reaction(NRR)photocatalysts at ambient temperature and pressure is summarized by introducing charge transfer,migration,and separation in photocatalytic NRR,which provides a guidance for the selection of future photocatalyst.More importantly,we introduce the latest research strategies of photocatalysts in detail,which can guide the preparation and design of photocatalysts with high NRR activity.展开更多
基金supported by the National Key Research and Development Program of China(2022YFD2301402)the National Natural Science Foundation of China(32071903)+2 种基金the Jiangsu Provincial Key Technologies R&D Program of China(BE2019386)the Guidance Foundation of the Sanya Institute of Nanjing Agricultural University,China(NAUSY2D01)the Earmarked Fund for Jiangsu Agricultural Industry Technology System(JATS(2022)468,JATS(2022)168)。
文摘A two-year field experiment was conducted to measure the effects of densification methods on photosynthesis and yield of densely planted wheat.Inter-plant and inter-row distances were used to define ratefixed pattern(RR)and row-fixed pattern(RS)density treatments.Meanwhile,four nitrogen(N)rates(0,144,192,and 240 kg N ha-1,termed N0,N144,N192,and N240)were applied with three densities(225,292.5,and 360×10^(4)plants ha^(-1),termed D225,D292.5,and D360).The wheat canopy was clipped into three equal vertical layers(top,middle,and bottom layers),and their chlorophyll density(Ch D)and photosynthetically active radiation interception(FIPAR)were measured.Results showed that the response of Ch D and FIPAR to N rate,density,and pattern varied with different layers.N rate,density,and pattern had significant interaction effects on Ch D.The maximum values of whole-canopy Ch D in the two seasons appeared in N240 combined with D292.5 and D360 under RR,respectively.Across two growing seasons,FIPAR values of RR were higher than those of RS by 29.37%for the top layer and 5.68%for the middle layer,while lower than those of RS by 20.62%for the bottom layer on average.With a low N supply(N0),grain yield was not significantly affected by density for both patterns.At N240,increasing density significantly increased yield under RR,but D360 of RS significantly decreased yield by 3.72%and 9.00%versus D225 in two seasons,respectively.With an appropriate and sufficient N application,RR increased the yield of densely planted wheat more than RS.Additionally,the maximum yield in two seasons appeared in the combination of D360 with N144 or N192 rather than of D225 with N240 under both patterns,suggesting that dense planting combined with an appropriate N-reduction application is feasible to increase photosynthesis capacity and yield.
文摘Field experiments were carried out at the National Research Center farm, Nubaria area, Behura Governorate, Egypt, to study the effect of nitrogen source, flushing schedule and irrigation method on emitter clogging. Peanut Giza 5 variety (Arachishy pogaea L.) was planted in sandy soil during two successive growing seasons (2010-2011) in the 1st week of May and harvested after 130 days. Treatments used are: 1) two irrigation methods: surface drip irrigation and sub-surface drip irrigation (SDI;SSDI), 2) nitrogen source (NS):NH4NO3, (NH4)2SO4 and Ca(NO3)2 (NS1, NS2 and NS3) and 3) flushing number (FL) 0, 1 and 4 (FL1, FL2;FL3). The experiments design was split-split plot and three replicates were used. Data obtained were subjected to statistical analysis. The main effects of treatments used on clogging per cent could be written the following ascending orders: SDI 3 2 1, NS1 2 3. Concerning the 1st interaction the following ascending orders denote their effects on clogging percent: SDI × FL3 2 1, SDI × NS1 2 3, SSDI × FL3 2 1, SSDI × NS1 2 3, FL1 × NS1 1 × NS2 1 × NS3, FL2 × NS1 2 × NS2 2 × NS3 and FL3 × NS1 3 × NS2 3 × NS3. The differences between any two treatments and/or any two interactions in clogging percent were significant at the 5% level. The effect of the 2nd interaction on clogging percent was significant at the 5% level. The maximum value of clogging (20.18%) and the lowest one (3.9%) were archived in the interactions: SSDI × FL1 × NS3 and SDI × FL3 × NS1, respectively.
文摘In order to determine whether long-term no-tillage operation in the loess plateau threatens soil fertility and crop yield,a suitable high-yield and efficient tillage technology system was established.In the Changwu loess plateau agri-Gecological experiment station of the Northwest A&F University of Changwu County,Shaanxi Province,the no-tillage experimental field for three consecutive years was selected.In September 2015,no-tillage,tillage,and rotary tillage were carried out before winter wheat was sowed.After the harvest of winter wheat in2016,soil organic carbon,total nitrogen and wheat yield in 0-30 cm soil layers under different tillage methods were analyzed.The results showed that the soil organic carbon and total nitrogen contents in the 0-30 cm soil layer decreased along the profile under the three tillage methods.In this study,the soil organic carbon and total nitrogen content in the 0-10 cm soil layer under different tillage methods were no-tillage>rotary tillage>tillage,the actual yield of winter yield in one hectare was tillage>rotary tillage>no-tillage,and there was significant difference in the actual yield of winter wheat only between the no-tillage and tillage.
基金Project supported by the National Natural Science Foundation of China (Nos. 30230230 and 30370288)the NationalKey Laboratory for Soil Erosion and Dryland Farming on the Loess Plateau (No. 10501-116).
文摘A soil column method was used to compare the effect of drip fertigation (the application of fertilizer through drip irrigation systems, DFI) on the leaching loss and transformation of urea-N in soil with that of surface fertilization combined with flood irrigation (SFI), and to study the leaching loss and transformation of three kinds of nitrogen fertilizers (nitrate fertilizer, ammonium fertilizer, and urea fertilizer) in two contrasting soils after the fertigation. In comparison to SFI, DFI decreased leaching loss of urea-N from the soil and increased the mineral N (NH4+-N + NO3- -N) in the soil. The N leached from a clay loam soil ranged from 5.7% to 9.6% of the total N added as fertilizer, whereas for a sandy loam soil they ranged between 16.2% and 30.4%. Leaching losses of mineral N were higher when nitrate fertilizer was used compared to urea or ammonium fertilizer. Compared to the control (without urea addition), on the first day when soils were fertigated with urea, there were increases in NH4+-N in the soils. This confirmed the rapid hydrolysis of urea in soil during fertigation. NH4+-N in soils reached a peak about 5 days after fertigation, and due to nitrification it began to decrease at day 10. After applying NH4+-N fertilizer and urea and during the incubation period, the mineral nitrogen in the soil decreased. This may be related to the occurrence of NH4+-N fixation or volatilization in the soil during the fertigation process.
文摘Cellulose carbamates (CC) were synthesized with microcrystalline cellulose as raw materials. The Fourier transform infrared spectra of CC with different nitrogen content were recorded. The accurate results of the nitrogen content for CC can be obtained by using the deconvolution method when the nitrogen content is less than 3.5%. The relationship between the nitrogen content and the absorption intensity ratio of the corresponding separated absorption peaks in FTIR spectra has been expressed bg an equation precisely.
文摘The ideal reducing reagent in testing available nitrogen of soil by Conway Methodis Devard‘s alloy.The optimum ratio of soil:Devard’s alloy:1.0N NaOH solution is 5.0g:0.2g:5ml.When reaction goes on at 30℃ for 4 hours,the rate of soil NO<sub>3</sub>-N reduction is about 90%,and the recovery rate of soil NH<sub>4</sub>-N is about 95%.Some organic nitrogen can be measured at thesame time.This method is defined as the Modified Conway Method and the soil N-min is r=0.982(n=10).In predicting soil nitrogen supplying power,the Modified Conway Method takesonly 1/6 of time needed by Conway Method.The Modified Conway Method can also be used forthe measure of soil N-min.
基金Project supported by the National Natural Science Foundation of China (Grant No. 50572032)
文摘This paper reprots that with Ni-based catalyst/solvent and with a dopant of NAN3, large green single crystal diamonds with perfect shape are successfully synthesized by temperature gradient method under high pressure and high temperature in a China-type cubic anvil high-pressure apparatus (SPD-6 × 1200), and the highest nitrogen concentration reaches approximately 121-1257 ppm calculated by infrared absorption spectra. The synthesis conditions are about 5.5 CPa and 1240-1300 ℃. The growth behaviour of diamond with high-nitrogen concentration is investigated in detail. The results show that, with increasing the content of NaN3 added in synthesis system, the width of synthesis temperature region for growth high-quality diamonds becomes narrower, and the morphology of diamond crystal is changed from cube-octahedral to octahedral at same temperature and pressure, the crystal growth rate is slowed down, nevertheless, the nitrogen concentration doped in synthetic diamond increases.
文摘Benzylsulfonamide was used as a source of nitrogen in the syn- thesis of azacrown ethers,and the cyclic intermediates were easily deben- zylsulfonylated by treating with CaF_2/H_2SO_4 to afford the azacrown ethers.
基金Taishan Scholars Program of Shandong Province,Grant/Award Number:tsqn201812068Higher School Youth Innovation Team of Shandong Province,Grant/Award Number:2019KJA013+1 种基金The Opening Fund of State Key Laboratory of Heavy Oil Processing,Grant/Award Number:SKLOP202002006National Natural Science Foundation of China,Grant/Award Number:51872173。
文摘The reduction of molecular nitrogen(N_(2))to ammonia(NH_(3))under mild conditions is one of the most promising studies in the energy field due to the important role of NH_(3)in modern industry,production,and life.The photocatalytic reduction of N_(2)is expected to achieve clean and sustainable NH_(3)production by using clean solar energy.To date,the new photocatalysts for photocatalytic reduction of N_(2)to NH_(3)at room temperature and atmospheric pressure have not been fully developed.The major challenge is to achieve high light-absorption efficiency,conversion efficiency,and stability of photocatalysts.Herein,the methods for measuring produced NH_(3)are compared,and the problems related to possible NH_(3)pollution in photocatalytic systems are mentioned to provide accurate ideas for measuring photocatalytic efficiency.The recent progress of nitrogen reduction reaction(NRR)photocatalysts at ambient temperature and pressure is summarized by introducing charge transfer,migration,and separation in photocatalytic NRR,which provides a guidance for the selection of future photocatalyst.More importantly,we introduce the latest research strategies of photocatalysts in detail,which can guide the preparation and design of photocatalysts with high NRR activity.