The reactions of anionic zirconium oxide clusters ZrxOy- with C2H6 and C4H10 are investi-gated by a time of flight mass spectrometer coupled with a laser vaporization cluster source.Hydrogen containing products Zr2O5H...The reactions of anionic zirconium oxide clusters ZrxOy- with C2H6 and C4H10 are investi-gated by a time of flight mass spectrometer coupled with a laser vaporization cluster source.Hydrogen containing products Zr2O5H- and Zr3O7H- are observed after the reaction. Den-sity functional theory calculations indicate that the hydrogen abstraction is favorable in the reaction of Zr2O5- with C2H6, which supports that the observed Zr2O5H- and Zr3O7H- are due to hydrogen atom abstraction from the alkane molecules. This work shows a newpossible pathway in the reaction of zirconium oxide cluster anions with alkane molecules.展开更多
This article studies some convergence results for the McShane integral of functions mapping the interval [0, 1] into a Banach space X from the point of view of an open problem proposed by D.H.Fremlin and J. Mendoza in...This article studies some convergence results for the McShane integral of functions mapping the interval [0, 1] into a Banach space X from the point of view of an open problem proposed by D.H.Fremlin and J. Mendoza in [2], also the authors give a negative answer to this open problem.展开更多
Using the axiomatic method, abstract concepts such as abstract mean, abstract convex function and abstract majorization are proposed. They are the generalizations of concepts of mean, convex function and majorization,...Using the axiomatic method, abstract concepts such as abstract mean, abstract convex function and abstract majorization are proposed. They are the generalizations of concepts of mean, convex function and majorization, respectively. Through the logical deduction, the fundamental theorems about abstract majorization inequalities are established as follows: for arbitrary abstract mean Σ and $ \Sigma ' $ and abstract ∑ ? $ \Sigma ' $ strict convex function f(x) on the interval I, if x i , y i ∈ I (i = 1, 2,..., n) satisfy that $ (x_1 ,x_2 , \ldots ,x_n ) \prec _n^\Sigma (y_1 ,y_2 , \ldots ,y_n ) $ then $ \Sigma ' $ {f(x 1), f(x 2),..., f(x n )} ? $ \Sigma ' $ {f(y 1), f(y 2),..., f(y n )}. This class of inequalities extends and generalizes the fundamental theorem of majorization inequalities. Moreover, concepts such as abstract vector mean are proposed, the fundamental theorems about abstract majorization inequalities are generalized to n-dimensional vector space. The fundamental theorem of majorization inequalities about the abstract vector mean are established as follows: for arbitrary symmetrical convex set $ \mathcal{S} \subset \mathbb{R}^n $ , and n-variable abstract symmetrical $ \overline \Sigma $ ? $ \Sigma ' $ strict convex function $ \phi (\bar x) $ on $ \mathcal{S} $ , if $ \bar x,\bar y \in \mathcal{S} $ , satisfy $ \bar x \prec _n^\Sigma \bar y $ , then $ \phi (\bar x) \geqslant \phi (\bar y) $ ; if vector group $ \bar x_i ,\bar y_i \in \mathcal{S}(i = 1,2, \ldots ,m) $ satisfy $ \{ \bar x_1 ,\bar x_2 , \ldots ,\bar x_m \} \prec _n^{\bar \Sigma } \{ \bar y_1 ,\bar y_2 , \ldots ,\bar y_m \} $ , then $ \Sigma '\{ \phi (\bar x_1 ),\phi (\bar x_2 ), \ldots ,\phi (\bar x_m )\} \geqslant \Sigma '\{ \phi (\bar y_1 ),\phi (\bar y_2 ), \ldots ,\phi (\bar y_m )\} $ .展开更多
基金This work was supported by the Chinese Academy of Sciences （Hundred Talents Fund）, the National Natural Science Foundation of China （No.20703048 and No.20803083）, and the Center of Molecular Science Foundation of Institute of Chemistry, Chinese Academy of Sciences （No.CMS-LX200902）.
文摘The reactions of anionic zirconium oxide clusters ZrxOy- with C2H6 and C4H10 are investi-gated by a time of flight mass spectrometer coupled with a laser vaporization cluster source.Hydrogen containing products Zr2O5H- and Zr3O7H- are observed after the reaction. Den-sity functional theory calculations indicate that the hydrogen abstraction is favorable in the reaction of Zr2O5- with C2H6, which supports that the observed Zr2O5H- and Zr3O7H- are due to hydrogen atom abstraction from the alkane molecules. This work shows a newpossible pathway in the reaction of zirconium oxide cluster anions with alkane molecules.
基金Supported by NNSF of China(10571085)Science Foundation of Hohai University and grant No.201/04/0690 of the GA of the Czech Republic
文摘This article studies some convergence results for the McShane integral of functions mapping the interval [0, 1] into a Banach space X from the point of view of an open problem proposed by D.H.Fremlin and J. Mendoza in [2], also the authors give a negative answer to this open problem.
基金supported by the National Key Basic Research Project of China (Grant No. 2004CB318003)the Foundation of the Education Department of Sichuan Province of China (Grant No. 07ZA087)
文摘Using the axiomatic method, abstract concepts such as abstract mean, abstract convex function and abstract majorization are proposed. They are the generalizations of concepts of mean, convex function and majorization, respectively. Through the logical deduction, the fundamental theorems about abstract majorization inequalities are established as follows: for arbitrary abstract mean Σ and $ \Sigma ' $ and abstract ∑ ? $ \Sigma ' $ strict convex function f(x) on the interval I, if x i , y i ∈ I (i = 1, 2,..., n) satisfy that $ (x_1 ,x_2 , \ldots ,x_n ) \prec _n^\Sigma (y_1 ,y_2 , \ldots ,y_n ) $ then $ \Sigma ' $ {f(x 1), f(x 2),..., f(x n )} ? $ \Sigma ' $ {f(y 1), f(y 2),..., f(y n )}. This class of inequalities extends and generalizes the fundamental theorem of majorization inequalities. Moreover, concepts such as abstract vector mean are proposed, the fundamental theorems about abstract majorization inequalities are generalized to n-dimensional vector space. The fundamental theorem of majorization inequalities about the abstract vector mean are established as follows: for arbitrary symmetrical convex set $ \mathcal{S} \subset \mathbb{R}^n $ , and n-variable abstract symmetrical $ \overline \Sigma $ ? $ \Sigma ' $ strict convex function $ \phi (\bar x) $ on $ \mathcal{S} $ , if $ \bar x,\bar y \in \mathcal{S} $ , satisfy $ \bar x \prec _n^\Sigma \bar y $ , then $ \phi (\bar x) \geqslant \phi (\bar y) $ ; if vector group $ \bar x_i ,\bar y_i \in \mathcal{S}(i = 1,2, \ldots ,m) $ satisfy $ \{ \bar x_1 ,\bar x_2 , \ldots ,\bar x_m \} \prec _n^{\bar \Sigma } \{ \bar y_1 ,\bar y_2 , \ldots ,\bar y_m \} $ , then $ \Sigma '\{ \phi (\bar x_1 ),\phi (\bar x_2 ), \ldots ,\phi (\bar x_m )\} \geqslant \Sigma '\{ \phi (\bar y_1 ),\phi (\bar y_2 ), \ldots ,\phi (\bar y_m )\} $ .
