The interaction between stress and galvanic during the corrosion process of 5050 aluminum alloys was studied and the evolution of mechanics properties was indicated. Electrochemical impedance technique and scanning el...The interaction between stress and galvanic during the corrosion process of 5050 aluminum alloys was studied and the evolution of mechanics properties was indicated. Electrochemical impedance technique and scanning electron microscopy were used to analyze the surface electrochemical states and the corrosion morphology. At the same time, corrosion kinetics and thermodynamic theory were used to analyze the influencing mechanism of the stress factor and the galvanic factor. The results show that both of galvanic factor and tensile stress factor can increase the corrosion potential of aluminum alloys and result in the corrosion resistance decrease. With decreasing corrosion resistance, the mechanical properties of aluminum alloys decrease. These phenomena are attributed to two reasons： One is that aluminum alloys may under the condition of anodic polarization after coupled with 40 Cr Ni Mo A steel, so the corrosion can be promoted; The other is that with increasing stress, the electrochemical potential of 5050 aluminum alloys decreases and the potential difference between two materials increases, so the corrosion becomes serious. Compared to the stress factor, the galvanic factor is significant.展开更多
Galvanic corrosion on samples of AZ91D magnesium alloy coupled with 2A12 aluminum alloy during neutral salt spray test was investigated.The variations of the surface potential were measured using scanning kelvin probe...Galvanic corrosion on samples of AZ91D magnesium alloy coupled with 2A12 aluminum alloy during neutral salt spray test was investigated.The variations of the surface potential were measured using scanning kelvin probe（SKP）.The results showed that galvanic effect on the corrosion of AZ91D magnesium alloy is closely related to the potential difference between the anodic and cathodic materials.In the initial period,corrosion only occurred in a narrow area at the coupling interface because of the limited distance galvanic current.Then,the corrosion rate of 2A12 aluminum alloy was accelerated due to its poor stability in strong alkali environment,which was attributed to the strong alkalization caused by the corrosion of AZ91D magnesium alloy.With the increase of the potential of 2A12 aluminum alloy as a result of the continuous covering of corrosion products,the potential difference between the two materials was enlarged,which enhanced the galvanic corrosion.展开更多
文摘The interaction between stress and galvanic during the corrosion process of 5050 aluminum alloys was studied and the evolution of mechanics properties was indicated. Electrochemical impedance technique and scanning electron microscopy were used to analyze the surface electrochemical states and the corrosion morphology. At the same time, corrosion kinetics and thermodynamic theory were used to analyze the influencing mechanism of the stress factor and the galvanic factor. The results show that both of galvanic factor and tensile stress factor can increase the corrosion potential of aluminum alloys and result in the corrosion resistance decrease. With decreasing corrosion resistance, the mechanical properties of aluminum alloys decrease. These phenomena are attributed to two reasons： One is that aluminum alloys may under the condition of anodic polarization after coupled with 40 Cr Ni Mo A steel, so the corrosion can be promoted; The other is that with increasing stress, the electrochemical potential of 5050 aluminum alloys decreases and the potential difference between two materials increases, so the corrosion becomes serious. Compared to the stress factor, the galvanic factor is significant.
基金Funded by the National Natural Science Foundation of China(No.51271032)
文摘Galvanic corrosion on samples of AZ91D magnesium alloy coupled with 2A12 aluminum alloy during neutral salt spray test was investigated.The variations of the surface potential were measured using scanning kelvin probe（SKP）.The results showed that galvanic effect on the corrosion of AZ91D magnesium alloy is closely related to the potential difference between the anodic and cathodic materials.In the initial period,corrosion only occurred in a narrow area at the coupling interface because of the limited distance galvanic current.Then,the corrosion rate of 2A12 aluminum alloy was accelerated due to its poor stability in strong alkali environment,which was attributed to the strong alkalization caused by the corrosion of AZ91D magnesium alloy.With the increase of the potential of 2A12 aluminum alloy as a result of the continuous covering of corrosion products,the potential difference between the two materials was enlarged,which enhanced the galvanic corrosion.
