Smart Gas Sensors:Recent Developments and Future Prospective

Gas sensor is an indispensable part of modern society withwide applications in environmental monitoring,healthcare,food industry,public safety,etc.With the development of sensor technology,wireless communication,smart monitoring terminal,cloud storage/computing technology,and artificial intelligence,smart gas sensors represent the future of gassensing due to their merits of real-time multifunctional monitoring,earlywarning function,and intelligent and automated feature.Various electronicand optoelectronic gas sensors have been developed for high-performancesmart gas analysis.With the development of smart terminals and the maturityof integrated technology,flexible and wearable gas sensors play an increasingrole in gas analysis.This review highlights recent advances of smart gassensors in diverse applications.The structural components and fundamentalprinciples of electronic and optoelectronic gas sensors are described,andflexible and wearable gas sensor devices are highlighted.Moreover,sensorarray with artificial intelligence algorithms and smart gas sensors in“Internet of Things”paradigm are introduced.Finally,the challengesand perspectives of smart gas sensors are discussed regarding the future need of gas sensors for smart city and healthy living.

Novel Methodologies for Preventing Crack Propagation in Steel Gas Pipelines Considering the Temperature Effect

Using the software ANSYS-19.2/Explicit Dynamics,this study performedfinite-element modeling of the large-diameter steel pipeline cross-section for the Beineu-Bozoy-Shymkent gas pipeline with a non-through straight crack,strengthened by steel wire wrapping.The effects of the thread tensile force of the steel winding in the form of single rings at the crack edges and the wires with different winding diameters and pitches were also studied.The results showed that the strengthening was preferably executed at a minimum value of the thread tensile force,which was 6.4%more effective than that at its maximum value.The analysis of the influence of the winding dia-meters showed that the equivalent stresses increased by 32%from the beginning of the crack growth until the wire broke.The increment in winding diameter decelerated the disclosure of the edge crack and reduced its length by 8.2%.The analysis of the influence of the winding pitch showed that decreasing the distance between the winding turns also led to a 33.6%reduction in the length of the straight crack and a 7.9%reduction in the maximum stres-ses on the strengthened pipeline cross-section.The analysis of the temperature effect on the pipeline material,within a range from-40℃ to+50℃,resulted in a crack length change of up to 5.8%.As the temperature dropped,the crack length decreased.Within such a temperature range,the maximum stresses were observed along the cen-tral area of the crack,which were equal to 413 MPa at+50℃ and 440 MPa at-40℃.The results also showed that the presence of the steel winding in the pipeline significantly reduced the length of crack propagation up to 8.4 times,depending on the temperature effect and design parameters of prestressing.This work integrated the existing methods for crack localization along steel gas pipelines.

Mutual regulation of microglia and astrocytes after Gas6 inhibits spinal cord injury

Invasive inflammation and excessive scar formation are the main reasons for the difficulty in repairing nervous tissue after spinal cord injury.Microglia and astrocytes play key roles in the spinal cord injury micro-environment and share a close interaction.However,the mechanisms involved remain unclear.In this study,we found that after spinal cord injury,resting microglia(M0)were polarized into pro-inflammatory phenotypes(MG1 and MG3),while resting astrocytes were polarized into reactive and scar-forming phenotypes.The expression of growth arrest-specific 6(Gas6)and its receptor Axl were significantly down-regulated in microglia and astrocytes after spinal cord injury.In vitro experiments showed that Gas6 had negative effects on the polarization of reactive astrocytes and pro-inflammatory microglia,and even inhibited the cross-regulation between them.We further demonstrated that Gas6 can inhibit the polarization of reactive astrocytes by suppressing the activation of the Yes-associated protein signaling pathway.This,in turn,inhibited the polarization of pro-inflammatory microglia by suppressing the activation of the nuclear factor-κB/p65 and Janus kinase/signal transducer and activator of transcription signaling pathways.In vivo experiments showed that Gas6 inhibited the polarization of pro-inflammatory microglia and reactive astrocytes in the injured spinal cord,thereby promoting tissue repair and motor function recovery.Overall,Gas6 may play a role in the treatment of spinal cord injury.It can inhibit the inflammatory pathway of microglia and polarization of astrocytes,attenuate the interaction between microglia and astrocytes in the inflammatory microenvironment,and thereby alleviate local inflammation and reduce scar formation in the spinal cord.

Mesenteric ischemia with intrasplenic gas:A case report

BACKGROUND Acute mesenteric ischemia is a life-threatening disease.Intrasplenic gas is an extremely rare finding in such cases.CASE SUMMARY We report a case of a 79-year-old woman with a history of end-stage renal disease on hemodialysis for approximately 20 years,type 2 diabetes mellitus,and atrial fibrillation who presented with two days of epigastric pain.A computed tomography scan of the abdomen revealed intraperitoneal free air and significant intrasplenic gas.Laparoscopy revealed diffuse intestinal gangrene,and acute superior mesenteric ischemia was diagnosed.The patient died within 24 hours owing to profound shock.CONCLUSION Intrasplenic gas is an extremely rare finding on computed tomography imaging in cases of acute mesenteric ischemia.

Construction and realization of the knowledge base and inference engine of an IDSS model for air-conditioning cooling/heating sources selection

The knowledge representation mode and inference control strategy were analyzed according to the specialties of air-conditioning cooling/heating sources selection. The constructing idea and working procedure for knowledge base and inference engine were proposed while the realization technique of the C language was discussed. An intelligent decision support system (IDSS) model based on such knowledge representation and inference mechanism was developed by domain engineers. The model was verified to have a small kernel and powerful capability in list processing and data driving, which was successfully used in the design of a cooling/heating sources system for a large-sized office building.

Application of water loop variable refrigerant flow air-conditioning system in large-scale buildings in northern China

A water loop variable refrigerant flow（WLVRF）air-conditioning system is designed to be applied in large-scale buildings in northern China.The system is energy saving and it is an integrated system consisting of a variable refrigerant flow（VRF）air-conditioning unit,a water loop and an air source heat pump.The water loop transports energy among different regions in the buildings instead of refrigerant pipes,decreasing the scale of the VRF air-conditioning unit and improving the performance.Previous models for refrigerants and building loads are cited in this investigation.Mathematical models of major equipment and other elements of the system are established using the lumped parameter method based on the DATAFIT software and the MATLAB software.The performance of the WLVRF system is simulated.The initial investments and the running costs are calculated based on the results of market research.Finally,a contrast is carried out between the WLVRF system and the traditional VRF system.The results show that the WLVRF system has a better working condition and lower running costs than the traditional VRF system.

Entropy Assessment on Environmental Influence of Condense Heat in Recovery System in Air-Conditioning Refrigerating Machine

This paper presented an entropy evaluation method for the influences of condense heat recovery system on the environment.Aiming at the damage of the condense heat to the environment,an entropy of resource loss and an emission entropy from the condense heat recovery system in the air conditioning refrigerating machine were introduced.For the evaluation of the entropies,we developed a new algorithm for the parameter identification,called the composite influence coefficient,based on the Least Squares Support Vector Machine method.By simulation,the numerical experiments shows that the Least Squares Support Vector Machine method is one of the powerful methods for the parameter identification to compute the damage entropy of the condense heat,with the largest training error being-0.025(the relative error being-3.56%),and the biggest test error being 0.015(the relative error being 2.5%).

Impact of summer office set air-conditioning temperature on energy consumption and thermal comfort

To explore the relationship between summer office set air-conditioning temperature and energy consumption related to air conditioning use to provide human thermal comfort,a comparison experiment was conducted in three similar offices at temperatures of 24,26 and 28 ℃ respectively. A thermal comfort questionnaire survey was conducted. It is demonstrated that air-conditioner energy consumption at the set temperature of 28 ℃ is 113% and 271% lower than at 26 ℃ and 24 ℃,respectively. A linear relationship exists between air-conditioner energy consumption and the indoor and outdoor temperature difference. When comfortably dressed,over 80% of research participants accept the set temperature of 28 ℃. The regression analysis leads to a neutral temperature of 26.2 ℃ and an acceptable temperature of 28.2 ℃ for over 80% of the research participants subjects,indicating that the current 26 ℃ set temperature for offices in summer,required by Chinese General Office of the State Council,can be increased to 28 ℃. Moreover,analysis of predicted mean vote(PMV) index shows that a set temperature of 27 ℃,not 26 ℃,is sufficiently comfortable for office staff wearing long-sleeve shirts,long pants and leather shoes.

Genetic Optimization Algorithm of PID Decoupling Control for VAV Air-Conditioning System

Variable-air-volume (VAV) air-conditioning system is a multi-variable system and has multi coupling control loops. While all of the control loops are working together, they interfere and influence each other. A multivariable decoupling PID controller is designed for VAV air-conditioning system. Diagonal matrix decoupling method is employed to eliminate the coupling between the loop of supply air temperature and that of thermal-space air temperature. The PID controller parameters are optimized by means of an improved genetic algorithm in floating point representations to obtain better performance. The population in the improved genetic algorithm mutates before crossover, which is helpful for the convergence. Additionally the micro mutation algorithm is proposed and applied to improve the convergence during the later evolution. To search the best parameters, the optimized parameters ranges should be amplified 10 times the initial ideal parameters. The simulation and experiment results show that the decoupling control system is effective and feasible. The method can overcome the strong coupling feature of the system and has shorter governing time and less over-shoot than non-optimization PID control.

Selection of Weather Parameters for Air-Conditioning System Design for Buildings with Long Thermal Lag

Two building factors-a longer thermal lag of more than one hour for building envelops and a lag of indoor radiation to convert into cooling load-have impact on the instantaneous heat input and instantaneous cooling load.So the two factors should be taken into account when selecting the weather parameters for air-conditioning system design.This paper developed a new statistic method for the rational selection of coincident solar irradiance,dry-bulb and wet-bulb temperatures.The method was applied to historic weather records of 25 years in Hong Kong to generate coincident design weather data.And the results show that traditional design solar irradiance,dry-bulb and wet-bulb temperatures may be significantly overestimated in many conditions,and the design weather data for the three different constructions is not kept constant.

The Experiment and Simulation of Solid Desiccant Dehumidification for Air-Conditioning System in a Tropical Humid Climate

The aim of this research was to study and design a solid desiccant dehumidification system suitable for tropical climate to reduce the latent load of air-conditioning system and improve the thermal comfort. Different dehumidifiers such as desiccant column and desiccant wheel were investigated. The ANSYS and TRASYS software were used to predict the results of dehumidifiers and the desiccant cooling systems, respectively. The desiccant bed contained approximately 15 kg of silica-gel, with 3 mm average diameter. Results indicated that the pressure drop and the adsorption rate of desiccant column are usually higher than those of the desiccant wheel. The feasible and practical adsorption rate of desiccant wheel was 0.102 kgw/h at air flow rate 1.0 kg/min, regenerated air temperature of 55?C and at a wheel speed of 2.5 rpm. The humidity ratio of conditioning space and cooling load of split-type air conditioner was decreased to 0.002 kgw/kgda (14%) and 0.71 kWth (19.26%), respectively. Consequently, the thermal comfort was improved from 0.5 PMV (10.12% PPD) to 0.3 PMV (7.04% PPD).

Geochemistry and origins of hydrogen-containing natural gases in deep Songliao Basin,China:Insights from continental scientific drilling

The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantly,but the origin analysis of different gas types has previously been weak.Based on the geochemical parameters of gas samples from different depths and the analysis of geological settings,this research covers the diverse origins of natural gas in different strata.The gas components are mainly methane with a small amount of C_(2+),and non-hydrocarbon gases,including nitrogen(N_(2)),hydrogen(H_(2)),carbon dioxide(CO_(2)),and helium(He).At greater depth,the carbon isotope of methane becomes heavier,and the hydrogen isotope points to a lacustrine sedimentary environment.With increasing depth,the origins of N_(2)and CO_(2)change gradually from a mixture of organic and inorganic to inorganic.The origins of hydrogen gas are complex and include organic sources,water radiolysis,water-rock(Fe^(2+)-containing minerals)reactions,and mantle-derived.The shales of Denglouku and Shahezi Formations,as source rocks,provide the premise for generation and occurrence of organic gas.Furthermore,the deep faults and fluid activities in Basement Formation control the generation and migration of mantle-derived gas.The discovery of a high content of H_(2)in study area not only reveals the organic and inorganic association of natural-gas generation,but also provides a scientific basis for the exploration of deep hydrogen-rich gas.

An Energy-Saving Control Strategy on Central Air-Conditioning System

An energy-saving control strategy based on predictive control for central air-conditioning systems is proposed in this paper. The cold load model is developed to describe the dynamic characteristics of temperature control systems, and then parameters in the cold load model and in the central air-conditioning system model are estimated. Generalized predictive control (GPC) is used to establish an optimization model to minimize the consumption of energy and the control error of temperature. The simulated annealing (SA) algorithm, combined with quadratic programming, is adopted to solve the optimal problem. Contrasted with the simulation of traditional PID control, the results prove the effectiveness of this proposed strategy.

Constraints on Characteristics and Distribution of Gas Hydrate and Free Gas Using Broad-Band Processing of Three-Dimensional Seismic Data

Gas hydrate drilling expeditions in the Pearl River Mouth Basin,South China Sea,have identified concentrated gas hydrates with variable thickness.Moreover,free gas and the coexistence of gas hydrate and free gas have been confirmed by logging,coring,and production tests in the foraminifera-rich silty sediments with complex bottom-simulating reflectors(BSRs).The broad-band processing is conducted on conventional three-dimensional(3D)seismic data to improve the image and detection accuracy of gas hydratebearing layers and delineate the saturation and thickness of gas hydrate-and free gas-bearing sediments.Several geophysical attributes extracted along the base of the gas hydrate stability zone are used to demonstrate the variable distribution and the controlling factors for the differential enrichment of gas hydrate.The inverted gas hydrate saturation at the production zone is over 40% with a thickness of 90 m,showing the interbedded distribution with different boundaries between gas hydrate-and free gas-bearing layers.However,the gas hydrate saturation value at the adjacent canyon is 70%,with 30-m-thick patches and linear features.The lithological and fault controls on gas hydrate and free gas distributions are demonstrated by tracing each gas hydrate-bearing layer.Moreover,the BSR depths based on broad-band reprocessed 3D seismic data not only exhibit variations due to small-scale topographic changes caused by seafloor sedimentation and erosion but also show the upward shift of BSR and the blocky distribution of the coexistence of gas hydrate and free gas in the Pearl River Mouth Basin.

Application of Fuzzy Comprehensive Evaluation to Air-conditioning Competitive Power Analysis

As the conceptual design of air-conditioning is done using the theory of Quality Function Deployment (QFD),cus- tomer requirements should be understood and the product competitive power be analyzed as exactly as possible for new product de- signing.Lots of information in the process of this research is fuzzy and uncertain,but traditional QFD can not deal with it well. Fuzzy theory can solve the problem.So a fuzzy model for analyzing product competitive power is formulated in this paper to im- prove traditional QFD,after that it is applied to analyze air-conditioning competitive power.When air-conditioning competitive power is analyzed using this model,firstly the importance weight of the customer requirements o fair-conditioning is determined us- ing the Analytic Hierarchy Process (AHP) weighting process,then air-conditloning competitive power is evaluated using fuzzy comprehensive evaluation.It is proved that the model is feasible and has good applicability.

GAS6-AS1调节miR-370-3p/SPATA2轴对卵巢癌细胞增殖、迁移、侵袭、凋亡和EMT的影响

目的:探讨长链非编码RNA GAS6反义RNA1(long non-coding RNA GAS6 antisense RNA1, lncRNA GAS6-AS1)调节miR-370-3p/精子发生相关蛋白2 (spermatogenesis-associated protein 2, SPATA2)轴对卵巢癌细胞增殖、迁移、侵袭、凋亡和上皮间质转化(epithelial mesenchymal transformation, EMT)的影响。方法:qRT-PCR、Western blot分别检测癌旁组织、卵巢癌组织、人正常卵巢上皮细胞IOSE80及卵巢癌细胞系HO-8910、SKOV3、A2780中GAS6-AS1、miR-370-3p及SPATA2蛋白表达。将SKOV3细胞分为:对照组(NC组)、 si-NC组、si-GAS6-AS1组、mimic NC组、miR-370-3p mimic组、si-GAS6-AS1+inhibitor NC组、si-GAS6-AS1+miR-370-3p inhibitor组,qRT-PCR检测细胞中GAS6-AS1、miR-370-3p表达;CCK-8法检测细胞增殖;流式细胞术检测细胞凋亡;划痕愈合实验检测细胞迁移;Transwell实验检测细胞侵袭;Western blot检测SPATA2、细胞周期素D1(CyclinD1)、Bcl-2相关X蛋白(Bcl-2-associated X,Bax)、E-钙黏蛋白(E-cadherin)、波形蛋白(Vimentin)、神经钙黏蛋白(N-cadherin)表达;双荧光素酶报告基因实验检测GAS6-AS1与miR-370-3p、 miR-370-3p与SPATA2的关系。结果:在卵巢癌组织和细胞中GAS6-AS1、SPATA2蛋白高表达,miR-370-3p低表达,且在SKOV3细胞中GAS6-AS1、SPATA2蛋白表达量最高,miR-370-3p表达水平最低,因此,选择SKOV3细胞为后续研究对象。与NC组、si-NC组比较,si-GAS6-AS1组GAS6-AS1、OD450值(24 h、48 h、72 h)、划痕愈合率、侵袭细胞数、SPATA2、CyclinD1、Vimentin、N-cadherin蛋白表达降低,miR-370-3p表达、细胞凋亡率、Bax、E-cadherin蛋白表达升高(P<0.05);与NC组、mimic NC组比较,miR-370-3p mimic组OD450值(24 h、48 h、72 h)、划痕愈合率、侵袭细胞数、SPATA2、CyclinD1、Vimentin、N-cadherin蛋白表达降低,miR-370-3p表达、细胞凋亡率、Bax、E-cadherin蛋白表达升高(P<0.05);miR-370-3p inhibitor减弱了沉默GAS6-AS1对SKOV3细胞增殖、迁移、侵袭及EMT的抑制及对细胞凋亡的促进作用。GAS6-AS1与miR-370-3p、miR-370-3p与SPATA2存在靶向调控关系。结论:沉默GAS6-AS1通过上调miR-370-3p来抑制SPATA2表达,从而抑制SKOV3细胞增殖、迁移、侵袭及EMT,并促进细胞凋亡。

Coal-rock gas:Concept,connotation and classification criteria

In recent years,great breakthroughs have been made in the exploration and development of natural gas in deep coal-rock reservoirs in Junggar,Ordos and other basins in China.In view of the inconsistency between the industrial and academic circles on this new type of unconventional natural gas,this paper defines the concept of"coal-rock gas"on the basis of previous studies,and systematically analyzes its characteristics of occurrence state,transport and storage form,differential accumulation,and development law.Coal-rock gas,geologically unlike coalbed methane in the traditional sense,occurs in both free and adsorbed states,with free state in abundance.It is generated and stored in the same set of rocks through short distance migration,occasionally with the accumulation from other sources.Moreover,coal rock develops cleat fractures,and the free gas accumulates differentially.The coal-rock gas reservoirs deeper than 2000 m are high in pressure,temperature,gas content,gas saturation,and free-gas content.In terms of development,similar to shale gas and tight gas,coal-rock gas can be exploited by natural formation energy after the reservoirs connectivity is improved artificially,that is,the adsorbed gas is desorbed due to pressure drop after the high-potential free gas is recovered,so that the free gas and adsorbed gas are produced in succession for a long term without water drainage for pressure drop.According to buried depth,coal rank,pressure coefficient,reserves scale,reserves abundance and gas well production,the classification criteria and reserves/resources estimation method of coal-rock gas are presented.It is preliminarily estimated that the coal-rock gas in place deeper than 2000 m in China exceeds 30×10^(12)m^(3),indicating an important strategic resource for the country.The Ordos,Sichuan,Junggar and Bohai Bay basins are favorable areas for large-scale enrichment of coal-rock gas.The paper summarizes the technical and management challenges and points out the research directions,laying a foundation for the management,exploration,and development of coal-rock gas in China.

Deep-large faults controlling on the distribution of the venting gas hydrate system in the middle of the Qiongdongnan Basin, South China Sea

Many locations with concentrated hydrates at vents have confirmed the presence of abundant thermogenic gas in the middle of the Qiongdongnan Basin(QDNB).However,the impact of deep structures on gasbearing fluids migration and gas hydrates distribution in tectonically inactive regions is still unclear.In this study,the authors apply high-resolution 3D seismic and logging while drilling(LWD)data from the middle of the QDNB to investigate the influence of deep-large faults on gas chimneys and preferred gasescape pipes.The findings reveal the following:(1)Two significant deep-large faults,F1 and F2,developed on the edge of the Songnan Low Uplift,control the dominant migration of thermogenic hydrocarbons and determine the initial locations of gas chimneys.(2)The formation of gas chimneys is likely related to fault activation and reactivation.Gas chimney 1 is primarily arises from convergent fluid migration resulting from the intersection of the two faults,while the gas chimney 2 benefits from a steeper fault plane and shorter migration distance of fault F2.(3)Most gas-escape pipes are situated near the apex of the two faults.Their reactivations facilitate free gas flow into the GHSZ and contribute to the formation of fracture‐filling hydrates.

Application of Dual Throttling Air-Conditioning System to Explosion-Proof Frequency Converter

An explosion-proof dual throttling air-conditioning system was put forward to solve the heat dissipation and internal dewing problems of explosion-proof frequency converter in the underground coal mine. This study investigated the feasibility and benefits of explosion-proof dual throttling cooling and dehumidification air-conditioning system applied to the explosion-proof frequency converter. The physical model of dual throttling air-conditioning system was established and its performance parameter was described by mathematical method. The design calculation of the system has also been done. The experimental result showed that the system reached the steady state at the refrigeration mode after running 45 min, and the maximum internal temperature of the flame-proof cavity was 31.0 ℃. The system reached the steady state at the dehumidification mode after running 37 min. The maximum internal relative humidity and temperature of the flame-proof cavity were 33.4% and 36.3 ℃, respectively. Therefore, the proposed system had excellent ability of heat dissipation and avoided internal dewing. Compared with water cooling system, it was more energy-saving and economical. The airflow field of dual throttling air-conditioning system was also studied by CFD simulation. It was found that the result of CFD numerical simulation was highly consistent with the experimental data.

Simulation of Artificial Intelligence for Automotive Air-conditioning System

The artificial intelligence is applied to the simulation of the automotive air-conditioning system ( AACS )According to the system's characteristics a model of AACS, based on neural network, is developed. Different control methods of AACS are discussed through simulation based on this model. The result shows that the neural- fuzzy control is the best one compared with the on-off control and conventional fuzzy control method.It can make the compartment's temperature descend rapidly to the designed temperature and the fluctuation is small.