Retaining gob-side entryways and the stability of gas drainage boreholes are two essential techniques in the co-extraction of coal and gas without entry pillars (CECGWEP). However, retained entryways located in deep...Retaining gob-side entryways and the stability of gas drainage boreholes are two essential techniques in the co-extraction of coal and gas without entry pillars (CECGWEP). However, retained entryways located in deep coal mines are hard to maintain, especially for constructing boreholes in confined spaces, owing to major deformations. Consequently, it is difficult to drill boreholes and maintain their stability, which therefore cannot guarantee the effectiveness of gas drainage. This paper presents three measures for conducting CECGWEP in deep mines on the basis of effective space in retained entryways for gas drainage, They are combinations of retaining roadways and face-lagging inclined boreholes, retaining roadways and face-advancing inclined boreholes, and retaining roadways and high return airway inclined boreholes. Several essential techniques are suggested to improve the maintenance of retained entryways and the stabilization of boreholes. For the particular cases considered in this study, two field trials have verified the latter two measures from the results obtained from the faces 1111(1) and 11112(1) in the Zhuji Mine. The results indicate that these models can effectively solve the problems in deep mines. The maximum gas drainage flow for a single hole can reach 8.1 m^3/min and the effective drainage distance can be extended up to 150 m or more.展开更多
Coal and gas are two important resources in China,and it is an effective way to recycle them with the method of co-extraction of coal and gas.In view of actual situation of China's co-extraction of coal and gas,th...Coal and gas are two important resources in China,and it is an effective way to recycle them with the method of co-extraction of coal and gas.In view of actual situation of China's co-extraction of coal and gas,this research adopts the science evaluation of gas extraction of coal by the method of quantitative evaluation,and preliminarily establishes the technical evaluation system of co-extraction of coal and gas.Technical evaluation system of co-extraction of coal and gas includes safety evaluation,economic evaluation and resource recovery evaluation in the process of mining coal and gas.In addition,this paper results in the selected evaluation parameters and target functions that are used in the three evaluation methods.The establishment of evaluation system for co-extraction of coal and gas plays an important theoretical significance and guiding role in co-extraction of coal and gas for China's coal enterprises.展开更多
Blast furnace gas(BFG)is an important by-product energy for the iron and steel industry and has been widely used for heating or electricity generation.However,the undesirable contaminants in BFG(especially H_(2)S)gene...Blast furnace gas(BFG)is an important by-product energy for the iron and steel industry and has been widely used for heating or electricity generation.However,the undesirable contaminants in BFG(especially H_(2)S)generate harmful environmental emissions.The desulfurization of BFG is urgent for integrated steel plants due to the stringent ultra-low emission standards.Compared with other desulfurization materials,zeolite-based adsorbents represent a viable option with low costs and long service life.In this study,an ammonia-induced CuO modified 13X adsorbent(NH_(3)–CuO/13X)was prepared for H_(2)S removal from simulated BFG at low temperature.The XRD,H_(2)-TPR and TEM analysis proved that smaller CuO particles were formed and the dispersion of Cu on the surface of 13X zeolite was improved via the induction of ammonia.Evaluation on H_(2)S adsorption performance of the adsorbent was carried out using simulated BFG,and the results showed that NH_(3)–CuO/13X-3 has better breakthrough sulfur capacity,which was more than twice the sulfur capacity of CuO/13X.It is proposed that the enhanced desulfurization performance of NH_(3)–CuO/13X is attributed to an abundant pore of 13X,and combined action of 13X and CuO.This work provided an effective way to improve the sulfur capacity of zeolite-based adsorbents via impregnation method by ammonia induction.展开更多
Gas sensor is an indispensable part of modern society withwide applications in environmental monitoring,healthcare,food industry,public safety,etc.With the development of sensor technology,wireless communication,smart...Gas sensor is an indispensable part of modern society withwide applications in environmental monitoring,healthcare,food industry,public safety,etc.With the development of sensor technology,wireless communication,smart monitoring terminal,cloud storage/computing technology,and artificial intelligence,smart gas sensors represent the future of gassensing due to their merits of real-time multifunctional monitoring,earlywarning function,and intelligent and automated feature.Various electronicand optoelectronic gas sensors have been developed for high-performancesmart gas analysis.With the development of smart terminals and the maturityof integrated technology,flexible and wearable gas sensors play an increasingrole in gas analysis.This review highlights recent advances of smart gassensors in diverse applications.The structural components and fundamentalprinciples of electronic and optoelectronic gas sensors are described,andflexible and wearable gas sensor devices are highlighted.Moreover,sensorarray with artificial intelligence algorithms and smart gas sensors in“Internet of Things”paradigm are introduced.Finally,the challengesand perspectives of smart gas sensors are discussed regarding the future need of gas sensors for smart city and healthy living.展开更多
Using the software ANSYS-19.2/Explicit Dynamics,this study performedfinite-element modeling of the large-diameter steel pipeline cross-section for the Beineu-Bozoy-Shymkent gas pipeline with a non-through straight crac...Using the software ANSYS-19.2/Explicit Dynamics,this study performedfinite-element modeling of the large-diameter steel pipeline cross-section for the Beineu-Bozoy-Shymkent gas pipeline with a non-through straight crack,strengthened by steel wire wrapping.The effects of the thread tensile force of the steel winding in the form of single rings at the crack edges and the wires with different winding diameters and pitches were also studied.The results showed that the strengthening was preferably executed at a minimum value of the thread tensile force,which was 6.4%more effective than that at its maximum value.The analysis of the influence of the winding dia-meters showed that the equivalent stresses increased by 32%from the beginning of the crack growth until the wire broke.The increment in winding diameter decelerated the disclosure of the edge crack and reduced its length by 8.2%.The analysis of the influence of the winding pitch showed that decreasing the distance between the winding turns also led to a 33.6%reduction in the length of the straight crack and a 7.9%reduction in the maximum stres-ses on the strengthened pipeline cross-section.The analysis of the temperature effect on the pipeline material,within a range from-40℃ to+50℃,resulted in a crack length change of up to 5.8%.As the temperature dropped,the crack length decreased.Within such a temperature range,the maximum stresses were observed along the cen-tral area of the crack,which were equal to 413 MPa at+50℃ and 440 MPa at-40℃.The results also showed that the presence of the steel winding in the pipeline significantly reduced the length of crack propagation up to 8.4 times,depending on the temperature effect and design parameters of prestressing.This work integrated the existing methods for crack localization along steel gas pipelines.展开更多
Invasive inflammation and excessive scar formation are the main reasons for the difficulty in repairing nervous tissue after spinal cord injury.Microglia and astrocytes play key roles in the spinal cord injury micro-e...Invasive inflammation and excessive scar formation are the main reasons for the difficulty in repairing nervous tissue after spinal cord injury.Microglia and astrocytes play key roles in the spinal cord injury micro-environment and share a close interaction.However,the mechanisms involved remain unclear.In this study,we found that after spinal cord injury,resting microglia(M0)were polarized into pro-inflammatory phenotypes(MG1 and MG3),while resting astrocytes were polarized into reactive and scar-forming phenotypes.The expression of growth arrest-specific 6(Gas6)and its receptor Axl were significantly down-regulated in microglia and astrocytes after spinal cord injury.In vitro experiments showed that Gas6 had negative effects on the polarization of reactive astrocytes and pro-inflammatory microglia,and even inhibited the cross-regulation between them.We further demonstrated that Gas6 can inhibit the polarization of reactive astrocytes by suppressing the activation of the Yes-associated protein signaling pathway.This,in turn,inhibited the polarization of pro-inflammatory microglia by suppressing the activation of the nuclear factor-κB/p65 and Janus kinase/signal transducer and activator of transcription signaling pathways.In vivo experiments showed that Gas6 inhibited the polarization of pro-inflammatory microglia and reactive astrocytes in the injured spinal cord,thereby promoting tissue repair and motor function recovery.Overall,Gas6 may play a role in the treatment of spinal cord injury.It can inhibit the inflammatory pathway of microglia and polarization of astrocytes,attenuate the interaction between microglia and astrocytes in the inflammatory microenvironment,and thereby alleviate local inflammation and reduce scar formation in the spinal cord.展开更多
The corrosion behavior and microstructure characteristics of metal inert gas(MIG)welded dissimilar joints of the 6005A alloy modified with Sc(designated as 6005A+Sc)and the 5083 alloy were investigated using corrosion...The corrosion behavior and microstructure characteristics of metal inert gas(MIG)welded dissimilar joints of the 6005A alloy modified with Sc(designated as 6005A+Sc)and the 5083 alloy were investigated using corrosion tests and microscopy techniques.Results show that the dissimilar joints exhibit strong stress corrosion cracking(SCC)resistance,maintaining substantial strength during slow strain rate tensile tests.Notably,the heat-affected zone(HAZ)and base metal(BM)on the 6005A+Sc side show superior performance in terms of inter-granular corrosion(IGC)and exfoliation corrosion(EXCO)compared to the corresponding zones on the 5083 side.The lower corrosion resistance of the 5083-BM and the 5083-HAZ can be attributed to the presence of numerous Al_(2)Mg_(3)phases and micro-scaled Al_(6)(Mn,Fe)intermetallics,mainly distributed along the rolling direction.Conversely,the enhanced corrosion resistance of the 6005A+Sc-BM and the 6005A+Sc-HAZ can be attributed to the discontinuously distributed grain boundary precipitates(β-Mg_(2)Si),the smaller grain size,and the reduced corrosive current density.展开更多
The gas explosion in residential building has always been a highly concerned problem.Explosions in homogeneous mixtures have been extensively studied.However,mixtures are often inhomogeneous in the practical scenarios...The gas explosion in residential building has always been a highly concerned problem.Explosions in homogeneous mixtures have been extensively studied.However,mixtures are often inhomogeneous in the practical scenarios due to the differences in the densities of methane and air.In order to investigate the effects of gas explosions in inhomogeneous mixtures,experimental studies involving gas leakage and explosion are conducted in a full-scale residential building to reproduce the process of gas explosion.By fitting the dimensionless buoyancy as a function of dimensionless height and dimensionless time,a distribution model of gas in large-scale spaces is established,and the mechanism of inhomogeneous distribution of methane is also be revealed.Furthermore,the stratified reconstruction method(SRM)is introduced for efficiently setting up inhomogeneous concentration fields in FLACS.The simulation results highlight that for the internal overpressure,the distribution of methane has no effect on the first overpressure peak(ΔP1),while it significantly influences the subsequent overpressure peak(ΔP2),and the maximum difference between the overpressure of homogeneous and inhomogeneous distribution is174.3%.Moreover,the initial concentration distribution also has a certain impact on the external overpressure.展开更多
The rapid industrial growth and increasing population have led to significant pollution and deterioration of the natural atmospheric environment.Major atmospheric pollutants include NO_(2)and CO_(2).Hence,it is impera...The rapid industrial growth and increasing population have led to significant pollution and deterioration of the natural atmospheric environment.Major atmospheric pollutants include NO_(2)and CO_(2).Hence,it is imperative to develop NO_(2)and CO_(2)sensors for ambient conditions,that can be used in indoor air quality monitoring,breath analysis,food spoilage detection,etc.In the present study,two thin film nanocomposite(nickel oxide-graphene and nickel oxide-silver nanowires)gas sensors are fabricated using direct ink writing.The nano-composites are investigated for their structural,optical,and electrical properties.Later the nano-composite is deposited on the interdigitated electrode(IDE)pattern to form NO_(2)and CO_(2)sensors.The deposited films are then exposed to NO_(2)and CO_(2)gases separately and their response and recovery times are determined using a custom-built gas sensing setup.Nickel oxide-graphene provides a good response time and recovery time of 10 and 9 s,respectively for NO_(2),due to the higher electron affinity of graphene towards NO_(2).Nickel oxide-silver nanowire nano-composite is suited for CO_(2)gas because silver is an excellent electrocatalyst for CO_(2)by giving response and recovery times of 11 s each.This is the first report showcasing NiO nano-composites for NO_(2)and CO_(2)sensing at room temperature.展开更多
The co-extraction behavior of galena-pyrolusite in a sodium chloride solution and the electrochemical mechanism of this process were investigated,and some factors affecting the leaching rate of Pb and Mn were optimize...The co-extraction behavior of galena-pyrolusite in a sodium chloride solution and the electrochemical mechanism of this process were investigated,and some factors affecting the leaching rate of Pb and Mn were optimized.The results show that all the factors such as the concentration of NaCl,HCl and pyrolusite ore,reaction time,temperature,adding times of HCl,affect the leaching rate of Pb.The main affecting factors are the concentration of NaCl,reaction time and temperature.The Tafel polarization curves and EIS plots of the galena and pyrolusite in the NaCl solution demonstrate that during the oxidation process of galena mineral electrode,film forms on the galena surface,which prevents galena from deeper oxidation.However,the film resistance can be greatly reduced in the presence of sodium chloride,thus promoting the reaction rate of galena.展开更多
The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantl...The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantly,but the origin analysis of different gas types has previously been weak.Based on the geochemical parameters of gas samples from different depths and the analysis of geological settings,this research covers the diverse origins of natural gas in different strata.The gas components are mainly methane with a small amount of C_(2+),and non-hydrocarbon gases,including nitrogen(N_(2)),hydrogen(H_(2)),carbon dioxide(CO_(2)),and helium(He).At greater depth,the carbon isotope of methane becomes heavier,and the hydrogen isotope points to a lacustrine sedimentary environment.With increasing depth,the origins of N_(2)and CO_(2)change gradually from a mixture of organic and inorganic to inorganic.The origins of hydrogen gas are complex and include organic sources,water radiolysis,water-rock(Fe^(2+)-containing minerals)reactions,and mantle-derived.The shales of Denglouku and Shahezi Formations,as source rocks,provide the premise for generation and occurrence of organic gas.Furthermore,the deep faults and fluid activities in Basement Formation control the generation and migration of mantle-derived gas.The discovery of a high content of H_(2)in study area not only reveals the organic and inorganic association of natural-gas generation,but also provides a scientific basis for the exploration of deep hydrogen-rich gas.展开更多
Gas hydrate drilling expeditions in the Pearl River Mouth Basin,South China Sea,have identified concentrated gas hydrates with variable thickness.Moreover,free gas and the coexistence of gas hydrate and free gas have ...Gas hydrate drilling expeditions in the Pearl River Mouth Basin,South China Sea,have identified concentrated gas hydrates with variable thickness.Moreover,free gas and the coexistence of gas hydrate and free gas have been confirmed by logging,coring,and production tests in the foraminifera-rich silty sediments with complex bottom-simulating reflectors(BSRs).The broad-band processing is conducted on conventional three-dimensional(3D)seismic data to improve the image and detection accuracy of gas hydratebearing layers and delineate the saturation and thickness of gas hydrate-and free gas-bearing sediments.Several geophysical attributes extracted along the base of the gas hydrate stability zone are used to demonstrate the variable distribution and the controlling factors for the differential enrichment of gas hydrate.The inverted gas hydrate saturation at the production zone is over 40% with a thickness of 90 m,showing the interbedded distribution with different boundaries between gas hydrate-and free gas-bearing layers.However,the gas hydrate saturation value at the adjacent canyon is 70%,with 30-m-thick patches and linear features.The lithological and fault controls on gas hydrate and free gas distributions are demonstrated by tracing each gas hydrate-bearing layer.Moreover,the BSR depths based on broad-band reprocessed 3D seismic data not only exhibit variations due to small-scale topographic changes caused by seafloor sedimentation and erosion but also show the upward shift of BSR and the blocky distribution of the coexistence of gas hydrate and free gas in the Pearl River Mouth Basin.展开更多
Many locations with concentrated hydrates at vents have confirmed the presence of abundant thermogenic gas in the middle of the Qiongdongnan Basin(QDNB).However,the impact of deep structures on gasbearing fluids migra...Many locations with concentrated hydrates at vents have confirmed the presence of abundant thermogenic gas in the middle of the Qiongdongnan Basin(QDNB).However,the impact of deep structures on gasbearing fluids migration and gas hydrates distribution in tectonically inactive regions is still unclear.In this study,the authors apply high-resolution 3D seismic and logging while drilling(LWD)data from the middle of the QDNB to investigate the influence of deep-large faults on gas chimneys and preferred gasescape pipes.The findings reveal the following:(1)Two significant deep-large faults,F1 and F2,developed on the edge of the Songnan Low Uplift,control the dominant migration of thermogenic hydrocarbons and determine the initial locations of gas chimneys.(2)The formation of gas chimneys is likely related to fault activation and reactivation.Gas chimney 1 is primarily arises from convergent fluid migration resulting from the intersection of the two faults,while the gas chimney 2 benefits from a steeper fault plane and shorter migration distance of fault F2.(3)Most gas-escape pipes are situated near the apex of the two faults.Their reactivations facilitate free gas flow into the GHSZ and contribute to the formation of fracture‐filling hydrates.展开更多
During the production period of shale gas, proppant particles and rock debris are produced together,which will seriously erode the elbows of gathering pipelines. In response to this problem, this paper takes the elbow...During the production period of shale gas, proppant particles and rock debris are produced together,which will seriously erode the elbows of gathering pipelines. In response to this problem, this paper takes the elbow of the gathering pipeline in the Changning Shale Gas Field as an example to test the erosion rate and material removal mechanism of the test piece at different angles of the elbow through experiments and compares the four erosion models with the experimental results. Through analysis, it is found that the best prediction model for quartz sand-carbon steel erosion is the Oka model. Based on the Oka model, FLUENT software was used to simulate and analyze the law of erosion of the elbow of the gas gathering pipeline under different gas flow velocities, gas gathering pressure, particle size, length of L1,and bending directions of the elbow. And a spiral pipeline structure is proposed to reduce the erosion rate of the elbow under the same working conditions. The results show that this structure can reduce erosion by 34%.展开更多
In recent years,great breakthroughs have been made in the exploration and development of natural gas in deep coal-rock reservoirs in Junggar,Ordos and other basins in China.In view of the inconsistency between the ind...In recent years,great breakthroughs have been made in the exploration and development of natural gas in deep coal-rock reservoirs in Junggar,Ordos and other basins in China.In view of the inconsistency between the industrial and academic circles on this new type of unconventional natural gas,this paper defines the concept of"coal-rock gas"on the basis of previous studies,and systematically analyzes its characteristics of occurrence state,transport and storage form,differential accumulation,and development law.Coal-rock gas,geologically unlike coalbed methane in the traditional sense,occurs in both free and adsorbed states,with free state in abundance.It is generated and stored in the same set of rocks through short distance migration,occasionally with the accumulation from other sources.Moreover,coal rock develops cleat fractures,and the free gas accumulates differentially.The coal-rock gas reservoirs deeper than 2000 m are high in pressure,temperature,gas content,gas saturation,and free-gas content.In terms of development,similar to shale gas and tight gas,coal-rock gas can be exploited by natural formation energy after the reservoirs connectivity is improved artificially,that is,the adsorbed gas is desorbed due to pressure drop after the high-potential free gas is recovered,so that the free gas and adsorbed gas are produced in succession for a long term without water drainage for pressure drop.According to buried depth,coal rank,pressure coefficient,reserves scale,reserves abundance and gas well production,the classification criteria and reserves/resources estimation method of coal-rock gas are presented.It is preliminarily estimated that the coal-rock gas in place deeper than 2000 m in China exceeds 30×10^(12)m^(3),indicating an important strategic resource for the country.The Ordos,Sichuan,Junggar and Bohai Bay basins are favorable areas for large-scale enrichment of coal-rock gas.The paper summarizes the technical and management challenges and points out the research directions,laying a foundation for the management,exploration,and development of coal-rock gas in China.展开更多
Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer ...Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer interference for tight gas reservoirs are really limited,especially for those reservoirs in the presence of water.In this work,five types of possible inter-layer interferences,including both absence and presence of water,are identified for commingled production of tight gas reservoirs.Subsequently,a series of reservoir-scale and pore-scale numerical simulations are conducted to quantify the degree of influence of each type of interference.Consistent field evidence from the Yan'an tight gas reservoir(Ordos Basin,China)is found to support the simulation results.Additionally,suggestions are proposed to mitigate the potential inter-layer interferences.The results indicate that,in the absence of water,commingled production is favorable in two situations:when there is a difference in physical properties and when there is a difference in the pressure system of each layer.For reservoirs with a multi-pressure system,the backflow phenomenon,which significantly influences the production performance,only occurs under extreme conditions(such as very low production rates or well shut-in periods).When water is introduced into the multi-layer system,inter-layer interference becomes nearly inevitable.Perforating both the gas-rich layer and water-rich layer for commingled production is not desirable,as it can trigger water invasion from the water-rich layer into the gas-rich layer.The gas-rich layer might also be interfered with by water from the neighboring unperforated water-rich layer,where the water might break the barrier(eg weak joint surface,cement in fractures)between the two layers and migrate into the gas-rich layer.Additionally,the gas-rich layer could possibly be interfered with by water that accumulates at the bottom of the wellbore due to gravitational differentiation during shut-in operations.展开更多
The Well Tashen 5(TS5),drilled and completed at a vertical depth of 9017 m in the Tabei Uplift of the Tarim Basin,NW China,is the deepest well in Asia.It has been producing both oil and gas from the Sinian at a depth ...The Well Tashen 5(TS5),drilled and completed at a vertical depth of 9017 m in the Tabei Uplift of the Tarim Basin,NW China,is the deepest well in Asia.It has been producing both oil and gas from the Sinian at a depth of 8780e8840 m,also the deepest in Asia in terms of oil discovery.In this paper,the geochemical characteristics of Sinian oil and gas from the well were investigated and compared with those of Cambrian oil and gas discovered in the same basin.The oil samples,with Pr/Ph ratio of 0.78 and a whole oil carbon isotopic value of31.6‰,have geochemical characteristics similar to those of Ordovician oils from the No.1 fault in the North Shuntuoguole area(also named Shunbei area)and the Middle Cambrian oil from wells Zhongshen 1(ZS1)and Zhongshen 5(ZS5)of Tazhong Uplift.The maturity of light hydrocarbons,diamondoids and aromatic fractions all suggest an approximate maturity of 1.5%e1.7%Ro for the samples.The(4-+3-)methyldiamantane concentration of the samples is 113.5 mg/g,indicating intense cracking with a cracking degree of about 80%,which is consistent with the high bottom hole temperature(179℃).The Sinian gas samples are dry with a dryness coefficient of 0.97.The gas is a mixture of kerogen-cracking gas and oil-cracking gas and has Ro values ranging between 1.5%and 1.7%,and methane carbon isotopic values of41.6‰.Based on the equivalent vitrinite reflectance(R_(eqv)=1.51%e1.61%)and the thermal evolution of source rocks from the Cambrian Yu'ertusi Formation of the same well,it is proposed that the Sinian oil and gas be mainly sourced from the Cambrian Yu'ertusi Formation during the Himalayan period but probably also be joined by hydrocarbon of higher maturity that migrated from other source rocks in deeper formations.The discovery of Sinian oil and gas from Well TS5 suggests that the ancient ultra-deep strata in the northern Tarim Basin have the potential for finding volatile oil or condensate reservoirs.展开更多
基金Acknowledgments The research was supported by Program for Changjiang Scholars and Innovative Research Team in University (IRT_I4R55), and the National Natural Science Foundation of China under Grant No. NSFC-51274193.
文摘Retaining gob-side entryways and the stability of gas drainage boreholes are two essential techniques in the co-extraction of coal and gas without entry pillars (CECGWEP). However, retained entryways located in deep coal mines are hard to maintain, especially for constructing boreholes in confined spaces, owing to major deformations. Consequently, it is difficult to drill boreholes and maintain their stability, which therefore cannot guarantee the effectiveness of gas drainage. This paper presents three measures for conducting CECGWEP in deep mines on the basis of effective space in retained entryways for gas drainage, They are combinations of retaining roadways and face-lagging inclined boreholes, retaining roadways and face-advancing inclined boreholes, and retaining roadways and high return airway inclined boreholes. Several essential techniques are suggested to improve the maintenance of retained entryways and the stabilization of boreholes. For the particular cases considered in this study, two field trials have verified the latter two measures from the results obtained from the faces 1111(1) and 11112(1) in the Zhuji Mine. The results indicate that these models can effectively solve the problems in deep mines. The maximum gas drainage flow for a single hole can reach 8.1 m^3/min and the effective drainage distance can be extended up to 150 m or more.
基金supported by the State Key Basic Research Program of China(No.2011CB201206)the Major Projectof the National Science and Technology of China(No.2011ZX05040-005)the National Natural Science Foundation of Youth Science Foundation(No.50904033)
文摘Coal and gas are two important resources in China,and it is an effective way to recycle them with the method of co-extraction of coal and gas.In view of actual situation of China's co-extraction of coal and gas,this research adopts the science evaluation of gas extraction of coal by the method of quantitative evaluation,and preliminarily establishes the technical evaluation system of co-extraction of coal and gas.Technical evaluation system of co-extraction of coal and gas includes safety evaluation,economic evaluation and resource recovery evaluation in the process of mining coal and gas.In addition,this paper results in the selected evaluation parameters and target functions that are used in the three evaluation methods.The establishment of evaluation system for co-extraction of coal and gas plays an important theoretical significance and guiding role in co-extraction of coal and gas for China's coal enterprises.
基金financially supported by National Natural Science Foundation of China(Grant.22076189)National Key Research and Development Program of China(No.2023YFC3707003)the Joint Fund of Yulin University and Dalian National Laboratory for Clean Energy(Grant.YLU-DNL Fund 2022003).
文摘Blast furnace gas(BFG)is an important by-product energy for the iron and steel industry and has been widely used for heating or electricity generation.However,the undesirable contaminants in BFG(especially H_(2)S)generate harmful environmental emissions.The desulfurization of BFG is urgent for integrated steel plants due to the stringent ultra-low emission standards.Compared with other desulfurization materials,zeolite-based adsorbents represent a viable option with low costs and long service life.In this study,an ammonia-induced CuO modified 13X adsorbent(NH_(3)–CuO/13X)was prepared for H_(2)S removal from simulated BFG at low temperature.The XRD,H_(2)-TPR and TEM analysis proved that smaller CuO particles were formed and the dispersion of Cu on the surface of 13X zeolite was improved via the induction of ammonia.Evaluation on H_(2)S adsorption performance of the adsorbent was carried out using simulated BFG,and the results showed that NH_(3)–CuO/13X-3 has better breakthrough sulfur capacity,which was more than twice the sulfur capacity of CuO/13X.It is proposed that the enhanced desulfurization performance of NH_(3)–CuO/13X is attributed to an abundant pore of 13X,and combined action of 13X and CuO.This work provided an effective way to improve the sulfur capacity of zeolite-based adsorbents via impregnation method by ammonia induction.
基金supported by the National Natural Science Foundation of China(No.22376159)the Fundamental Research Funds for the Central Universities.
文摘Gas sensor is an indispensable part of modern society withwide applications in environmental monitoring,healthcare,food industry,public safety,etc.With the development of sensor technology,wireless communication,smart monitoring terminal,cloud storage/computing technology,and artificial intelligence,smart gas sensors represent the future of gassensing due to their merits of real-time multifunctional monitoring,earlywarning function,and intelligent and automated feature.Various electronicand optoelectronic gas sensors have been developed for high-performancesmart gas analysis.With the development of smart terminals and the maturityof integrated technology,flexible and wearable gas sensors play an increasingrole in gas analysis.This review highlights recent advances of smart gassensors in diverse applications.The structural components and fundamentalprinciples of electronic and optoelectronic gas sensors are described,andflexible and wearable gas sensor devices are highlighted.Moreover,sensorarray with artificial intelligence algorithms and smart gas sensors in“Internet of Things”paradigm are introduced.Finally,the challengesand perspectives of smart gas sensors are discussed regarding the future need of gas sensors for smart city and healthy living.
基金funded by the Science Committee of the Ministry of Science and Higher Education of the Republic of Kazakhstan(Grant No.AP19680589).
文摘Using the software ANSYS-19.2/Explicit Dynamics,this study performedfinite-element modeling of the large-diameter steel pipeline cross-section for the Beineu-Bozoy-Shymkent gas pipeline with a non-through straight crack,strengthened by steel wire wrapping.The effects of the thread tensile force of the steel winding in the form of single rings at the crack edges and the wires with different winding diameters and pitches were also studied.The results showed that the strengthening was preferably executed at a minimum value of the thread tensile force,which was 6.4%more effective than that at its maximum value.The analysis of the influence of the winding dia-meters showed that the equivalent stresses increased by 32%from the beginning of the crack growth until the wire broke.The increment in winding diameter decelerated the disclosure of the edge crack and reduced its length by 8.2%.The analysis of the influence of the winding pitch showed that decreasing the distance between the winding turns also led to a 33.6%reduction in the length of the straight crack and a 7.9%reduction in the maximum stres-ses on the strengthened pipeline cross-section.The analysis of the temperature effect on the pipeline material,within a range from-40℃ to+50℃,resulted in a crack length change of up to 5.8%.As the temperature dropped,the crack length decreased.Within such a temperature range,the maximum stresses were observed along the cen-tral area of the crack,which were equal to 413 MPa at+50℃ and 440 MPa at-40℃.The results also showed that the presence of the steel winding in the pipeline significantly reduced the length of crack propagation up to 8.4 times,depending on the temperature effect and design parameters of prestressing.This work integrated the existing methods for crack localization along steel gas pipelines.
基金supported by the National Natural Science Foundation of China, Nos.81971151 (to YW), 82102528 (to XL), 82102583 (to LW)the Natural Science Foundation of Guangdong Province, China, Nos.2020A1515010265 (to YW), 2020A1515110679 (to XL), and 2021A1515010358 (to XL)
文摘Invasive inflammation and excessive scar formation are the main reasons for the difficulty in repairing nervous tissue after spinal cord injury.Microglia and astrocytes play key roles in the spinal cord injury micro-environment and share a close interaction.However,the mechanisms involved remain unclear.In this study,we found that after spinal cord injury,resting microglia(M0)were polarized into pro-inflammatory phenotypes(MG1 and MG3),while resting astrocytes were polarized into reactive and scar-forming phenotypes.The expression of growth arrest-specific 6(Gas6)and its receptor Axl were significantly down-regulated in microglia and astrocytes after spinal cord injury.In vitro experiments showed that Gas6 had negative effects on the polarization of reactive astrocytes and pro-inflammatory microglia,and even inhibited the cross-regulation between them.We further demonstrated that Gas6 can inhibit the polarization of reactive astrocytes by suppressing the activation of the Yes-associated protein signaling pathway.This,in turn,inhibited the polarization of pro-inflammatory microglia by suppressing the activation of the nuclear factor-κB/p65 and Janus kinase/signal transducer and activator of transcription signaling pathways.In vivo experiments showed that Gas6 inhibited the polarization of pro-inflammatory microglia and reactive astrocytes in the injured spinal cord,thereby promoting tissue repair and motor function recovery.Overall,Gas6 may play a role in the treatment of spinal cord injury.It can inhibit the inflammatory pathway of microglia and polarization of astrocytes,attenuate the interaction between microglia and astrocytes in the inflammatory microenvironment,and thereby alleviate local inflammation and reduce scar formation in the spinal cord.
基金financially supported by the Science and Technology Innovation Program of Hunan Province,China(No.2023RC3055)the Natural Science Foundation of Hunan Province,China(Nos.2023JJ30671,2020JJ4114)+5 种基金the Natural Science Foundation of Changsha City,China(No.Kq2208264)National Key Project of Research and Development Plan of China(Nos.2021YFC1910505,2021YFC1910504)the Young Core Teacher Foundation of Hunan Province,China(No.150220001)Key Research and Development Program of Guangdong Province,China(No.2020B010186002)the National Natural Science Foundation of China(No.51601229)the Key-Area Research and Development Program of Foshan City,China(No.2230032004640).
文摘The corrosion behavior and microstructure characteristics of metal inert gas(MIG)welded dissimilar joints of the 6005A alloy modified with Sc(designated as 6005A+Sc)and the 5083 alloy were investigated using corrosion tests and microscopy techniques.Results show that the dissimilar joints exhibit strong stress corrosion cracking(SCC)resistance,maintaining substantial strength during slow strain rate tensile tests.Notably,the heat-affected zone(HAZ)and base metal(BM)on the 6005A+Sc side show superior performance in terms of inter-granular corrosion(IGC)and exfoliation corrosion(EXCO)compared to the corresponding zones on the 5083 side.The lower corrosion resistance of the 5083-BM and the 5083-HAZ can be attributed to the presence of numerous Al_(2)Mg_(3)phases and micro-scaled Al_(6)(Mn,Fe)intermetallics,mainly distributed along the rolling direction.Conversely,the enhanced corrosion resistance of the 6005A+Sc-BM and the 6005A+Sc-HAZ can be attributed to the discontinuously distributed grain boundary precipitates(β-Mg_(2)Si),the smaller grain size,and the reduced corrosive current density.
基金the financial support from National Natural Science Foundation of China(Grant No.52378488)Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX22_0222)。
文摘The gas explosion in residential building has always been a highly concerned problem.Explosions in homogeneous mixtures have been extensively studied.However,mixtures are often inhomogeneous in the practical scenarios due to the differences in the densities of methane and air.In order to investigate the effects of gas explosions in inhomogeneous mixtures,experimental studies involving gas leakage and explosion are conducted in a full-scale residential building to reproduce the process of gas explosion.By fitting the dimensionless buoyancy as a function of dimensionless height and dimensionless time,a distribution model of gas in large-scale spaces is established,and the mechanism of inhomogeneous distribution of methane is also be revealed.Furthermore,the stratified reconstruction method(SRM)is introduced for efficiently setting up inhomogeneous concentration fields in FLACS.The simulation results highlight that for the internal overpressure,the distribution of methane has no effect on the first overpressure peak(ΔP1),while it significantly influences the subsequent overpressure peak(ΔP2),and the maximum difference between the overpressure of homogeneous and inhomogeneous distribution is174.3%.Moreover,the initial concentration distribution also has a certain impact on the external overpressure.
文摘The rapid industrial growth and increasing population have led to significant pollution and deterioration of the natural atmospheric environment.Major atmospheric pollutants include NO_(2)and CO_(2).Hence,it is imperative to develop NO_(2)and CO_(2)sensors for ambient conditions,that can be used in indoor air quality monitoring,breath analysis,food spoilage detection,etc.In the present study,two thin film nanocomposite(nickel oxide-graphene and nickel oxide-silver nanowires)gas sensors are fabricated using direct ink writing.The nano-composites are investigated for their structural,optical,and electrical properties.Later the nano-composite is deposited on the interdigitated electrode(IDE)pattern to form NO_(2)and CO_(2)sensors.The deposited films are then exposed to NO_(2)and CO_(2)gases separately and their response and recovery times are determined using a custom-built gas sensing setup.Nickel oxide-graphene provides a good response time and recovery time of 10 and 9 s,respectively for NO_(2),due to the higher electron affinity of graphene towards NO_(2).Nickel oxide-silver nanowire nano-composite is suited for CO_(2)gas because silver is an excellent electrocatalyst for CO_(2)by giving response and recovery times of 11 s each.This is the first report showcasing NiO nano-composites for NO_(2)and CO_(2)sensing at room temperature.
基金Project(50774094) supported by the National Natural Science Foundation of China
文摘The co-extraction behavior of galena-pyrolusite in a sodium chloride solution and the electrochemical mechanism of this process were investigated,and some factors affecting the leaching rate of Pb and Mn were optimized.The results show that all the factors such as the concentration of NaCl,HCl and pyrolusite ore,reaction time,temperature,adding times of HCl,affect the leaching rate of Pb.The main affecting factors are the concentration of NaCl,reaction time and temperature.The Tafel polarization curves and EIS plots of the galena and pyrolusite in the NaCl solution demonstrate that during the oxidation process of galena mineral electrode,film forms on the galena surface,which prevents galena from deeper oxidation.However,the film resistance can be greatly reduced in the presence of sodium chloride,thus promoting the reaction rate of galena.
基金supported by the National Natural Science Foundation of China(Grant No.42072168)the National Key R&D Program of China(Grant No.2019YFC0605405)the Fundamental Research Funds for the Central Universities(Grant No.2023ZKPYDC07)。
文摘The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantly,but the origin analysis of different gas types has previously been weak.Based on the geochemical parameters of gas samples from different depths and the analysis of geological settings,this research covers the diverse origins of natural gas in different strata.The gas components are mainly methane with a small amount of C_(2+),and non-hydrocarbon gases,including nitrogen(N_(2)),hydrogen(H_(2)),carbon dioxide(CO_(2)),and helium(He).At greater depth,the carbon isotope of methane becomes heavier,and the hydrogen isotope points to a lacustrine sedimentary environment.With increasing depth,the origins of N_(2)and CO_(2)change gradually from a mixture of organic and inorganic to inorganic.The origins of hydrogen gas are complex and include organic sources,water radiolysis,water-rock(Fe^(2+)-containing minerals)reactions,and mantle-derived.The shales of Denglouku and Shahezi Formations,as source rocks,provide the premise for generation and occurrence of organic gas.Furthermore,the deep faults and fluid activities in Basement Formation control the generation and migration of mantle-derived gas.The discovery of a high content of H_(2)in study area not only reveals the organic and inorganic association of natural-gas generation,but also provides a scientific basis for the exploration of deep hydrogen-rich gas.
基金supported by the State Key Laboratory of Natural Gas Hydrate(No.2022-KFJJ-SHW)the National Natural Science Foundation of China(No.42376058)+2 种基金the International Science&Technology Cooperation Program of China(No.2023YFE0119900)the Hainan Province Key Research and Development Project(No.ZDYF2024GXJS002)the Research Start-Up Funds of Zhufeng Scholars Program.
文摘Gas hydrate drilling expeditions in the Pearl River Mouth Basin,South China Sea,have identified concentrated gas hydrates with variable thickness.Moreover,free gas and the coexistence of gas hydrate and free gas have been confirmed by logging,coring,and production tests in the foraminifera-rich silty sediments with complex bottom-simulating reflectors(BSRs).The broad-band processing is conducted on conventional three-dimensional(3D)seismic data to improve the image and detection accuracy of gas hydratebearing layers and delineate the saturation and thickness of gas hydrate-and free gas-bearing sediments.Several geophysical attributes extracted along the base of the gas hydrate stability zone are used to demonstrate the variable distribution and the controlling factors for the differential enrichment of gas hydrate.The inverted gas hydrate saturation at the production zone is over 40% with a thickness of 90 m,showing the interbedded distribution with different boundaries between gas hydrate-and free gas-bearing layers.However,the gas hydrate saturation value at the adjacent canyon is 70%,with 30-m-thick patches and linear features.The lithological and fault controls on gas hydrate and free gas distributions are demonstrated by tracing each gas hydrate-bearing layer.Moreover,the BSR depths based on broad-band reprocessed 3D seismic data not only exhibit variations due to small-scale topographic changes caused by seafloor sedimentation and erosion but also show the upward shift of BSR and the blocky distribution of the coexistence of gas hydrate and free gas in the Pearl River Mouth Basin.
基金supported by the National Natural Science Foundation of China(42376221,42276083)Director Research Fund Project of Guangzhou Marine Geological Survey(2023GMGSJZJJ00030)+2 种基金National Key Research and Development Program of China(2021YFC2800901)Guangdong Major Project of Basic and Applied Basic Research(2020B030103003)the project of the China Geological Survey(DD20230064).
文摘Many locations with concentrated hydrates at vents have confirmed the presence of abundant thermogenic gas in the middle of the Qiongdongnan Basin(QDNB).However,the impact of deep structures on gasbearing fluids migration and gas hydrates distribution in tectonically inactive regions is still unclear.In this study,the authors apply high-resolution 3D seismic and logging while drilling(LWD)data from the middle of the QDNB to investigate the influence of deep-large faults on gas chimneys and preferred gasescape pipes.The findings reveal the following:(1)Two significant deep-large faults,F1 and F2,developed on the edge of the Songnan Low Uplift,control the dominant migration of thermogenic hydrocarbons and determine the initial locations of gas chimneys.(2)The formation of gas chimneys is likely related to fault activation and reactivation.Gas chimney 1 is primarily arises from convergent fluid migration resulting from the intersection of the two faults,while the gas chimney 2 benefits from a steeper fault plane and shorter migration distance of fault F2.(3)Most gas-escape pipes are situated near the apex of the two faults.Their reactivations facilitate free gas flow into the GHSZ and contribute to the formation of fracture‐filling hydrates.
基金supported by the Petrochina's “14th Five-Year plan” Project(2021DJ2804)Sichuan Natural Science Foundation(2023NSFSC0422)。
文摘During the production period of shale gas, proppant particles and rock debris are produced together,which will seriously erode the elbows of gathering pipelines. In response to this problem, this paper takes the elbow of the gathering pipeline in the Changning Shale Gas Field as an example to test the erosion rate and material removal mechanism of the test piece at different angles of the elbow through experiments and compares the four erosion models with the experimental results. Through analysis, it is found that the best prediction model for quartz sand-carbon steel erosion is the Oka model. Based on the Oka model, FLUENT software was used to simulate and analyze the law of erosion of the elbow of the gas gathering pipeline under different gas flow velocities, gas gathering pressure, particle size, length of L1,and bending directions of the elbow. And a spiral pipeline structure is proposed to reduce the erosion rate of the elbow under the same working conditions. The results show that this structure can reduce erosion by 34%.
基金Supported by the Prospective and Basic Research Project of PetroChina(2021DJ23)。
文摘In recent years,great breakthroughs have been made in the exploration and development of natural gas in deep coal-rock reservoirs in Junggar,Ordos and other basins in China.In view of the inconsistency between the industrial and academic circles on this new type of unconventional natural gas,this paper defines the concept of"coal-rock gas"on the basis of previous studies,and systematically analyzes its characteristics of occurrence state,transport and storage form,differential accumulation,and development law.Coal-rock gas,geologically unlike coalbed methane in the traditional sense,occurs in both free and adsorbed states,with free state in abundance.It is generated and stored in the same set of rocks through short distance migration,occasionally with the accumulation from other sources.Moreover,coal rock develops cleat fractures,and the free gas accumulates differentially.The coal-rock gas reservoirs deeper than 2000 m are high in pressure,temperature,gas content,gas saturation,and free-gas content.In terms of development,similar to shale gas and tight gas,coal-rock gas can be exploited by natural formation energy after the reservoirs connectivity is improved artificially,that is,the adsorbed gas is desorbed due to pressure drop after the high-potential free gas is recovered,so that the free gas and adsorbed gas are produced in succession for a long term without water drainage for pressure drop.According to buried depth,coal rank,pressure coefficient,reserves scale,reserves abundance and gas well production,the classification criteria and reserves/resources estimation method of coal-rock gas are presented.It is preliminarily estimated that the coal-rock gas in place deeper than 2000 m in China exceeds 30×10^(12)m^(3),indicating an important strategic resource for the country.The Ordos,Sichuan,Junggar and Bohai Bay basins are favorable areas for large-scale enrichment of coal-rock gas.The paper summarizes the technical and management challenges and points out the research directions,laying a foundation for the management,exploration,and development of coal-rock gas in China.
基金supported by the National Natural Science Foundation of China(Grant Nos.52304044,52222402,52234003,52174036)Sichuan Science and Technology Program(Nos.2022JDJQ0009,2023NSFSC0934)+2 种基金Key Technology R&D Program of Shaanxi Province(2023-YBGY-30)the Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(Grant No.2020CX030202)the China Postdoctoral Science Foundation(Grant No.2022M722638)。
文摘Due to the dissimilarity among different producing layers,the influences of inter-layer interference on the production performance of a multi-layer gas reservoir are possible.However,systematic studies of inter-layer interference for tight gas reservoirs are really limited,especially for those reservoirs in the presence of water.In this work,five types of possible inter-layer interferences,including both absence and presence of water,are identified for commingled production of tight gas reservoirs.Subsequently,a series of reservoir-scale and pore-scale numerical simulations are conducted to quantify the degree of influence of each type of interference.Consistent field evidence from the Yan'an tight gas reservoir(Ordos Basin,China)is found to support the simulation results.Additionally,suggestions are proposed to mitigate the potential inter-layer interferences.The results indicate that,in the absence of water,commingled production is favorable in two situations:when there is a difference in physical properties and when there is a difference in the pressure system of each layer.For reservoirs with a multi-pressure system,the backflow phenomenon,which significantly influences the production performance,only occurs under extreme conditions(such as very low production rates or well shut-in periods).When water is introduced into the multi-layer system,inter-layer interference becomes nearly inevitable.Perforating both the gas-rich layer and water-rich layer for commingled production is not desirable,as it can trigger water invasion from the water-rich layer into the gas-rich layer.The gas-rich layer might also be interfered with by water from the neighboring unperforated water-rich layer,where the water might break the barrier(eg weak joint surface,cement in fractures)between the two layers and migrate into the gas-rich layer.Additionally,the gas-rich layer could possibly be interfered with by water that accumulates at the bottom of the wellbore due to gravitational differentiation during shut-in operations.
基金funded by projects of the National Natural Science Foundation of China(Nos.:42272167,U19B6003 and 41772153)projects of the Science&Technology Department of Sinopec(Nos.:P22121,P21058-8 and P23167).
文摘The Well Tashen 5(TS5),drilled and completed at a vertical depth of 9017 m in the Tabei Uplift of the Tarim Basin,NW China,is the deepest well in Asia.It has been producing both oil and gas from the Sinian at a depth of 8780e8840 m,also the deepest in Asia in terms of oil discovery.In this paper,the geochemical characteristics of Sinian oil and gas from the well were investigated and compared with those of Cambrian oil and gas discovered in the same basin.The oil samples,with Pr/Ph ratio of 0.78 and a whole oil carbon isotopic value of31.6‰,have geochemical characteristics similar to those of Ordovician oils from the No.1 fault in the North Shuntuoguole area(also named Shunbei area)and the Middle Cambrian oil from wells Zhongshen 1(ZS1)and Zhongshen 5(ZS5)of Tazhong Uplift.The maturity of light hydrocarbons,diamondoids and aromatic fractions all suggest an approximate maturity of 1.5%e1.7%Ro for the samples.The(4-+3-)methyldiamantane concentration of the samples is 113.5 mg/g,indicating intense cracking with a cracking degree of about 80%,which is consistent with the high bottom hole temperature(179℃).The Sinian gas samples are dry with a dryness coefficient of 0.97.The gas is a mixture of kerogen-cracking gas and oil-cracking gas and has Ro values ranging between 1.5%and 1.7%,and methane carbon isotopic values of41.6‰.Based on the equivalent vitrinite reflectance(R_(eqv)=1.51%e1.61%)and the thermal evolution of source rocks from the Cambrian Yu'ertusi Formation of the same well,it is proposed that the Sinian oil and gas be mainly sourced from the Cambrian Yu'ertusi Formation during the Himalayan period but probably also be joined by hydrocarbon of higher maturity that migrated from other source rocks in deeper formations.The discovery of Sinian oil and gas from Well TS5 suggests that the ancient ultra-deep strata in the northern Tarim Basin have the potential for finding volatile oil or condensate reservoirs.