To study the effect of inert dust on gas explosion suppression mechanism,SiO_2 fine powders were sprayed to suppress premixed CH_4-Air gas explosion in a 20 L spherical experimental system.In the experiment,high speed...To study the effect of inert dust on gas explosion suppression mechanism,SiO_2 fine powders were sprayed to suppress premixed CH_4-Air gas explosion in a 20 L spherical experimental system.In the experiment,high speed schlieren image system was adopted to record explosion flame propagation behaviors,meanwhile,pressure transducers and ion current probes were used to clearly record the explosion flame dynamic characteristics.The experimental results show that the SiO_2 fine powders suppressed evidently the gas explosion flame,and reduced the peak value of pressure and flame speed by more than 40%.The ion current result shows that the SiO_2 super fine powders were easy to contact with and absorb free radicals near the combustion reaction region,which greatly reduced the combustion reaction intensity,and in turn influenced the flame propagation and pressure rising.展开更多
In order to study the gas explosion suppression performance based on ferrocene, the self-constructed experimental facility was used to accomplish the experiment of gas explosion suppression. By means of thermogravimet...In order to study the gas explosion suppression performance based on ferrocene, the self-constructed experimental facility was used to accomplish the experiment of gas explosion suppression. By means of thermogravimetric analysis, the thermal characteristics of ferrocene have been gotten and the gas explosion suppression mechanism of ferrocene has been analyzed. The results show that ferrocene had good effects on gas explosion suppression, and the explosion pressure and flame propagation speed declined obviously. When ferrocene concentration is 0.08 g/L and methane volume concentration is 9.5%, the maximum explosion overpressure and maximum flame propagation speed of methane-air respectively decreased by about 59.5% and 19.6%, respectively. TG and DSC curves showed that the mass loss of ferrocene consists of two processes, which are sublimation and lattice fracture. The temperature of mass loss ranged from 128 ℃ to 230 ℃. The results showed profoundly theoretical significance to gas explosion suppression by ferrocene in coal mines.展开更多
Combined effects of obstacles and fine water mist on a methane-air explosion of a semi-closed pipe were investigated experimentally.In this study,the diameter of the water mist,the location,and the number of obstacles...Combined effects of obstacles and fine water mist on a methane-air explosion of a semi-closed pipe were investigated experimentally.In this study,the diameter of the water mist,the location,and the number of obstacles was considered.The results demonstrated that 5 μm water mist present a significant suppression affected while 45 μm shows a slight promotion effected on a gas explosion of the condition without obstacles.In the presence of an obstacle,however,the inhibitory effect of 5 μm water veils of mist dropped significantly during flame propagation,and the effect of 45 μm water veils of mist changed from the enhancement of inhibition,and its inhibitory effect was significant.The inhibitory effect of 45 μm water veils of mist on gas explosion weakened firstly and then enhanced with the increasing distance between obstacle location from the ignition location as well as in several obstacles.展开更多
Using a 20 L spherical explosion suppressing test system, the largest gas explosion pressure and maximum pressure rising rate with additives of ultra-fine ABC dry powder and diatomite powder were tested and compared, ...Using a 20 L spherical explosion suppressing test system, the largest gas explosion pressure and maximum pressure rising rate with additives of ultra-fine ABC dry powder and diatomite powder were tested and compared, and the explosion suppression effect of the two kinds of powder was analyzed. Experimental results show that both powders can suppress gas ex- plosion and ABC dry powder is superior to diatomite powder. Adding two powders under the same experimental conditions, when methane concentration is 7.0%, the maximum explosion pressure decreased 39% and 4%, respectively, while the rising rate of the maximum pressure decreased 80% and 53%, respectively. When methane concentration is 9.5%, the maximum ex- plosion pressure decreased 14% and 12%, respectively, the rising rate of maximum pressure decreased 62% and 27%, respec- tively, the maximum explosion pressure decreased 23% and 18%, respectively, while the rising rate of the maximum pressure decreased 77% and 70%, respectively. When methane concentration is 12.0%, the explosion suppression effect of ultra-fine ABC dry powder is not affected by the methane concentration, and the explosion suppression effect of diatomite powder under high methane concentrations is more obvious.展开更多
Potentially explosive atmosphere can occur not only in the production systems of the food,energy,chemical and petrochemical industries but also in the production processes of the mining industry.Gases,vapours,mists an...Potentially explosive atmosphere can occur not only in the production systems of the food,energy,chemical and petrochemical industries but also in the production processes of the mining industry.Gases,vapours,mists and dusts arise can escape in an uncontrolled way during production,processing,transportation and storage of flammable substances.In combination with oxygen,they create explosive atmospheres that,if ignited,lead to an explosion causing catastrophic damage to peopled lives and property.To protect against the results of hazardous dust-gas mixtures explosions in a confined work space,where employees can stay,various control and protection mechanisms are used in the form of an active explosion-proof system.The article presents the results of tests on an active system for limiting the effects of ignition of gas and/or dust based on a highly efficient explosion suppression system-equipped with an ignition detection system,high-pressure fire extinguisher and a power supply and trigger system.Smokeless powder was used as the explosive charge and sodium bicarbonate as the suppressive material.Tests of the effectiveness of the active explosion suppression system were carried out on two devices:a small-size dry dust collector and a zone extinguishing system adapted for direct explosion suppression in closed working spaces.In both cases,the explosion suppression process took place through the action of extinguishing powder blown out of the fire extinguisher after membrane perforation by compressed combustion products.展开更多
采用van der Waals等效单组分流体模型和Ross硬球微扰理论软球修正模型,计算了爆轰气相产物的状态方程;用石墨相、金刚石相、类石墨液相和类金刚石液相4种相态描述凝聚成分,由Gibbs自由能最小确定了不同状态下的凝聚产物相态。对爆轰产...采用van der Waals等效单组分流体模型和Ross硬球微扰理论软球修正模型,计算了爆轰气相产物的状态方程;用石墨相、金刚石相、类石墨液相和类金刚石液相4种相态描述凝聚成分,由Gibbs自由能最小确定了不同状态下的凝聚产物相态。对爆轰产物混合系统采用自由能最小原理,通过化学平衡方程组求解了炸药爆轰产物系统的平衡组分。使用该理论计算了高含碳炸药PBX9502 Chapman-Jouguet(CJ)点的爆轰参数,计算值与实验值符合很好;同时计算了3条等温线,并与Sesame库比较,发现温度超过1000℃时,计算值与Sesame库的计算结果比较接近。在计算的5 802K等温线上发现了一个拐点,分析发现是由于在此处游离态的碳发生了相变。展开更多
The water-based materials for mine gas absorption and explosion suppression were prepared, in which the mixed organic aggregate of Span80 and alkaline salt can be used as methane absorbent. Methane was used as a model...The water-based materials for mine gas absorption and explosion suppression were prepared, in which the mixed organic aggregate of Span80 and alkaline salt can be used as methane absorbent. Methane was used as a model of mine gas, and the absorptions of methane with different complex materials were studied using head space gas chromatography. Then the state of aqueous material was characterized with laser light scattering instrument and the effects of different complex materials on explosion suppression were preliminarily studied in explosion chamber which can simulate mine gas explosion. The research results showed that complex material could absorb methane and there was some corre- lation between the mean diameter of organic aggregate in aqueous material and the absorption effect. Additionally, the aqueous material could suppress the methane explosion to some degree. The material can absorb mine gas in atomization condition, therefore, degrease mine gas concentration and influence the distribution of mine gas in the space, and then suppress the mine gas explosion to some extent.展开更多
基金supported by the National Natural Science Foundation of China(50804038)Specialized Research Fund for the Doctoral Program of Higher Education of China (200804971055)Open Foundation of State Key Lab of Explosion Science and Technology(KFJJ 07-06)
文摘To study the effect of inert dust on gas explosion suppression mechanism,SiO_2 fine powders were sprayed to suppress premixed CH_4-Air gas explosion in a 20 L spherical experimental system.In the experiment,high speed schlieren image system was adopted to record explosion flame propagation behaviors,meanwhile,pressure transducers and ion current probes were used to clearly record the explosion flame dynamic characteristics.The experimental results show that the SiO_2 fine powders suppressed evidently the gas explosion flame,and reduced the peak value of pressure and flame speed by more than 40%.The ion current result shows that the SiO_2 super fine powders were easy to contact with and absorb free radicals near the combustion reaction region,which greatly reduced the combustion reaction intensity,and in turn influenced the flame propagation and pressure rising.
基金Supported by the National Natural Science Foundation of China （50974055, 50476033） the Doctor Foundation Project from the Henan Polytechnic University （B2011 - 101）
文摘In order to study the gas explosion suppression performance based on ferrocene, the self-constructed experimental facility was used to accomplish the experiment of gas explosion suppression. By means of thermogravimetric analysis, the thermal characteristics of ferrocene have been gotten and the gas explosion suppression mechanism of ferrocene has been analyzed. The results show that ferrocene had good effects on gas explosion suppression, and the explosion pressure and flame propagation speed declined obviously. When ferrocene concentration is 0.08 g/L and methane volume concentration is 9.5%, the maximum explosion overpressure and maximum flame propagation speed of methane-air respectively decreased by about 59.5% and 19.6%, respectively. TG and DSC curves showed that the mass loss of ferrocene consists of two processes, which are sublimation and lattice fracture. The temperature of mass loss ranged from 128 ℃ to 230 ℃. The results showed profoundly theoretical significance to gas explosion suppression by ferrocene in coal mines.
基金financial supports of the National Key Research and Development Program of China(2018YFC0808103)the National Natural Science Foundation of China (51774115, 51604095)。
文摘Combined effects of obstacles and fine water mist on a methane-air explosion of a semi-closed pipe were investigated experimentally.In this study,the diameter of the water mist,the location,and the number of obstacles was considered.The results demonstrated that 5 μm water mist present a significant suppression affected while 45 μm shows a slight promotion effected on a gas explosion of the condition without obstacles.In the presence of an obstacle,however,the inhibitory effect of 5 μm water veils of mist dropped significantly during flame propagation,and the effect of 45 μm water veils of mist changed from the enhancement of inhibition,and its inhibitory effect was significant.The inhibitory effect of 45 μm water veils of mist on gas explosion weakened firstly and then enhanced with the increasing distance between obstacle location from the ignition location as well as in several obstacles.
基金Supported by the Natural Science Foundation of China （50904049） the Development Fund Project of Xi＇an University of Science and Technology （2010047） the Shaanxi Provincial Scientific and Technological Fund （2010KJXX-08）
文摘Using a 20 L spherical explosion suppressing test system, the largest gas explosion pressure and maximum pressure rising rate with additives of ultra-fine ABC dry powder and diatomite powder were tested and compared, and the explosion suppression effect of the two kinds of powder was analyzed. Experimental results show that both powders can suppress gas ex- plosion and ABC dry powder is superior to diatomite powder. Adding two powders under the same experimental conditions, when methane concentration is 7.0%, the maximum explosion pressure decreased 39% and 4%, respectively, while the rising rate of the maximum pressure decreased 80% and 53%, respectively. When methane concentration is 9.5%, the maximum ex- plosion pressure decreased 14% and 12%, respectively, the rising rate of maximum pressure decreased 62% and 27%, respec- tively, the maximum explosion pressure decreased 23% and 18%, respectively, while the rising rate of the maximum pressure decreased 77% and 70%, respectively. When methane concentration is 12.0%, the explosion suppression effect of ultra-fine ABC dry powder is not affected by the methane concentration, and the explosion suppression effect of diatomite powder under high methane concentrations is more obvious.
基金the Research Fund for Coal and Steel(Project MINFIREX No RFCR-CT-2010-0005).
文摘Potentially explosive atmosphere can occur not only in the production systems of the food,energy,chemical and petrochemical industries but also in the production processes of the mining industry.Gases,vapours,mists and dusts arise can escape in an uncontrolled way during production,processing,transportation and storage of flammable substances.In combination with oxygen,they create explosive atmospheres that,if ignited,lead to an explosion causing catastrophic damage to peopled lives and property.To protect against the results of hazardous dust-gas mixtures explosions in a confined work space,where employees can stay,various control and protection mechanisms are used in the form of an active explosion-proof system.The article presents the results of tests on an active system for limiting the effects of ignition of gas and/or dust based on a highly efficient explosion suppression system-equipped with an ignition detection system,high-pressure fire extinguisher and a power supply and trigger system.Smokeless powder was used as the explosive charge and sodium bicarbonate as the suppressive material.Tests of the effectiveness of the active explosion suppression system were carried out on two devices:a small-size dry dust collector and a zone extinguishing system adapted for direct explosion suppression in closed working spaces.In both cases,the explosion suppression process took place through the action of extinguishing powder blown out of the fire extinguisher after membrane perforation by compressed combustion products.
文摘采用van der Waals等效单组分流体模型和Ross硬球微扰理论软球修正模型,计算了爆轰气相产物的状态方程;用石墨相、金刚石相、类石墨液相和类金刚石液相4种相态描述凝聚成分,由Gibbs自由能最小确定了不同状态下的凝聚产物相态。对爆轰产物混合系统采用自由能最小原理,通过化学平衡方程组求解了炸药爆轰产物系统的平衡组分。使用该理论计算了高含碳炸药PBX9502 Chapman-Jouguet(CJ)点的爆轰参数,计算值与实验值符合很好;同时计算了3条等温线,并与Sesame库比较,发现温度超过1000℃时,计算值与Sesame库的计算结果比较接近。在计算的5 802K等温线上发现了一个拐点,分析发现是由于在此处游离态的碳发生了相变。
文摘The water-based materials for mine gas absorption and explosion suppression were prepared, in which the mixed organic aggregate of Span80 and alkaline salt can be used as methane absorbent. Methane was used as a model of mine gas, and the absorptions of methane with different complex materials were studied using head space gas chromatography. Then the state of aqueous material was characterized with laser light scattering instrument and the effects of different complex materials on explosion suppression were preliminarily studied in explosion chamber which can simulate mine gas explosion. The research results showed that complex material could absorb methane and there was some corre- lation between the mean diameter of organic aggregate in aqueous material and the absorption effect. Additionally, the aqueous material could suppress the methane explosion to some degree. The material can absorb mine gas in atomization condition, therefore, degrease mine gas concentration and influence the distribution of mine gas in the space, and then suppress the mine gas explosion to some extent.
