Study on multi-component combustible gas explosive characteristics of high gas mine

Studied on multi-component combustible gas,methane mainly,explosion char- acteristics of high gas mine,obtained the rules of gas explosive limit that influenced by environment temperature,pressure,concentration of oxygen,other combustible gas,coal dust,energy of fire source,and the inert gas,proposed a new method of divide gas explo- sive triangle partition,and gave new partition linear equations.The gas explosive triangle and its new partition has important directive significance in distinguishing if the fire area has a gas explosion when sealing or opening fire area,or fire extinguishing in sealed fire area,and judging if there will be a gas explosion or other trend while fire extinguishing with inert gas.

Experimental study of polyurea-coated fiber-reinforced cement boards under gas explosions

Five types of polyurea elastomers were synthesized by changing the isocyanate component and the mechanical properties of polyurea materials were measured. Fiber-reinforced cement boards(FRCB)strengthened by polyurea with different formulations were processed, and a series of experiments were carried out on the specimens with gas explosion devices. The results showed that the conventional mechanical properties of different types of polyureas had their own advantages. Based on the gas explosion overpressure criterion, the blast resistances of reinforced plates were quantitatively evaluated,and the best polyurea was selected to guide the formulation design. The three typical failure modes of polyurea-reinforced FRCBs were flexural, shear, and flexural-shear failure. Dynamic thermodynamics and shock wave spectral analysis revealed that the polyurea did not undergo a glass transition in the gas explosion tests but retained its elastic properties, allowing it to effectively wrap the fragments formed by the brittle substrates.

Calibrated explosive triangle for determining capacity of explosion of gas mixtures

Determination of the capacity for explosion of gas mixtures in a sealed area is very important for mining engineers.If this capacity is high,it would be very dangerous for rescue workers to proceed with their rescue operations.A number of methods have been developed to determine the capacity for explosion of gas mixtures in sealed areas.One of the more popular methods is the Coward explosive triangle,published by Coward.He presented a fast and easy way to determine the capacity for explosion of gas mixtures,which has proved to be a very useful tool for mining engineers and members of rescue teams.However,due to few drawbacks in this method;potential errors would be introduced when it is applied.In a brief introduction we first describe the Coward method and then,we propose and discuss new calibrated explosive triangles.We demonstrate the method in two case studies where we compare our results with those of the old model.The results indicate that the calibrated method have improved accuracy and reliability.Therefore,assessments can be made more accurately.

Understanding the boundary and mechanism of gas-induced explosion for lithium-ion cells:Experimental and theoretical analysis

Thermal runaway(TR)of lithium-ion(Li-ion)batteries(LIBs)involves multiple forms of hazards,such as gas venting/jetting,fire,or even explosion.Explosion,as the most extreme case,is caused by the generated flammable gases,and a deflagration to detonation transition(DDT)may occur in this process.Here,overheat-to-TR tests and the corresponding outgas-induced explosion tests were conducted on 42 Ah Li-ion cells with Li[Ni_(1/3)Co_(1/3)Mn_(1/3)]O2cathode.The sum of CO_(2),H_(2),C_(2)H_(4),CO,and CH4accounted for more than 90%of the gases.Lower/upper explosion limits(LEL/UEL),laminar flame speed,and ideal stable detonation pressure were calculated to interpret the explosion characteristics and boundary.It turned out that shockwave was easily to be compressed and accelerated under higher state of charge(SOC)conditions.Thus,Li-ion cells explosion may evolve into unstable detonation in encapsulated battery pack and its evolution mechanism was explained,which provides a new idea for explosion-proof design of LIBs system.Additionally,a comprehensive assessment method was developed to intuitively characterize TR hazards.Severity of explosion presented an upward trend with the increase of SOC while the sensitivity was not the same.This study provides a further anatomy of TR,which is instructive to the safety of power battery systems.

Study on Gas Explosion Characteristics in Urban Utility Tunnels

In order to study the effects of three factors,namely,premixed gas concentration,number of pressure relief ports and number of obstacles,on the overpressure characteristics of gas explosion and flame structure of gas chambers in utility tunnels,in this paper,a small and narrow experimental platform for gas explosion was constructed to study the evolution mechanism and law of the kinetic characteristics and flame behavior of gas explosion in utility tunnels,with a view to revealing the special influencing mechanism of the overpressure characteristics and flame behavior of gas explosion in utility tunnels.The results show that in the methane concentration of 9.5%when the explosion overpressure reaches its peak,and at the same time by the utility tunnel long and narrow restricted space,the explosion generated by the precursor shock wave along with the flame compression wave were superimposed on both ends of the pipeline back and forth for many times so that the overpressure waveforms are cyclic oscillatory trend,increasing the explosion hazards;compared with the closed conditions,the relief port on the overpressure characteristics of the significant impact of the maximum decrease of 57.7%,when the frequency of overpressure oscillation is reduced,the gas explosion generated by the overpressure damage is reduced;the presence of obstacles significantly affects the flow field,accelerates the flame propagation and leads to greater overpressure peaks and overpressure oscillations.The conclusions of the study can provide a basis for the safety of natural gas in utility tunnels.

Experimental study on gas explosion to kill and injury mouse

The killing and injury effects of gas explosion shock wave on mouse in an open space pipeline is tested experimentally. When the methane volume fraction is 10M, the maximum explosion pressure is 0. 264 MPa and the injury is the most serious. Specially, some designed obstacles put in the open space pipeline are conducive to producing more stronger gas explosion shock wave. Accordingly, the injury effect of methane explosion on mouse is enhanced under obstacles condition. When the methane volume fraction is 10%, the maximum explosion pressure can reach 0. 298 MPa under obstacles conditiorL It can be concluded that to reduce explosive accident impact, the obstacles in coal mine should be avoided. With the explosions increasing, the death pressure of mouse decreases.

Numerical simulation to determine the gas explosion risk in longwall goaf areas:A case study of Xutuan Colliery

Underground gassy longwall mining goafs may suffer potential gas explosions during the mining process because of the irregularity of gas emissions in the goaf and poor ventilation of the working face,which are risks difficult to control.In this work,the 3235 working face of the Xutuan Colliery in Suzhou City,China,was researched as a case study.The effects of air quantity and gas emission on the three-dimensional distribution of oxygen and methane concentration in the longwall goaf were studied.Based on the revised Coward’s triangle and linear coupling region formula,the coupled methane-oxygen explosive hazard zones(CEHZs)were drawn.Furthermore,a simple practical index was proposed to quantitatively determine the gas explosion risk in the longwall goaf.The results showed that the CEHZs mainly focus on the intake side where the risk of gas explosion is greatest.The CEHZ is reduced with increasing air quantity.Moreover,the higher the gas emission,the larger the CEHZ,which moves towards the intake side at low goaf heights and shifts to the deeper parts of the goaf at high heights.In addition,the risk of gas explosion is reduced as air quantities increase,but when gas emissions increase to a higher level(greater than 50 m3/min),the volume of the CEHZ does not decrease with the increase of air quantity,and the risk of gas explosion no longer shows a linear downward trend.This study is of significance as it seeks to reduce gas explosion accidents and improve mine production safety.

Practice of Fighting Fire and Suppressing Explosion for a Super-Large and Highly Gassy Mine

The Baijigou Mine fire in Ningxia Province,which broke out on October 24,2003,affected more than 108 m3 of the mine and was probably the largest underground fire in China in recent years. In addition to its size,the fire was also characterized by excessive air leakage and the potential for violent methane explosions. A series of new measures were taken to fight the fire,including sealing intake tunnels with water,injecting three-phase foam through boreholes,and flushing with a large volume of nitrogen. The fire was successfully extinguished and production re-sumed soon afterwards; not one single methane explosion occurred during fire-fighting and afterwards.

Destruction mechanism of gas explosion to ventilation facilities and automatic recovery technology

In order to overcome the heavy casualties caused by gas explosion, we verified the propagation law of shock wave in pipeline and the overpressure distribution of gas explosion by similar experiments according to the analyses of reasons for casualty and ventilation system model destroyed by gas explosion in the mining face. We summarized the gas composition after the explosion and its danger, analyzed the effects of the gas explosion shock wave to ventilation system and facilities and the laws of toxic gas spread and diffusion in the ventilation network after the explosion. We presented a technical proposal to control the smoke and recover the ventilation system after a gas explosion and developed a reserve air door and control system that were embed in the lane, and could close automatically in conditions of no pressure and electricity. The results showed that the reserve air door normally opened and could close automatically controlling the smoke flow and resuming the ventilation system when the gas explosion shock wave destroyed the original shutting air door which resulted in the air short circuit.

Mechanical Model of Domestic Gas Explosion Load

With the increase of domestic gas consumption in cities and towns in China,gas explo-sion accidents happened rather frequently,and many structures were damaged greatly.Rational physical design could protect structures from being destroyed,but the character of explosion load must be learned firstly by establishing a correct mechanical model to simulate vented gas explo-sions.The explosion process has been studied for many years towards the safety of chemical in-dustry equipments.The key problem of these studies was the equations usually involved some ad-justable parameters that must be evaluated by experimental data,and the procedure of calculation was extremely complicated,so the reliability of these studies was seriously limited.Based on these studies,a simple mathematical model was established in this paper by using energy conservation,mass conservation,gas state equation,adiabatic compression equation and gas venting equation.Explosion load must be estimated by considering the room layout; the rate of pressure rise was then corrected by using a turbulence factor,so the pressure-time curve could be obtained.By using this method,complicated calculation was avoided,while experimental and calculated results fitted fairly well.Some pressure-time curves in a typical rectangular room were calculated to inves-tigate the influences of different ignition locations,gas thickness,concentration,room size and venting area on the explosion pressure.The results indicated that: it was the most dangerous con-dition when being ignited in the geometry centre of the room; the greater the burning velocity,the worse the venting effect; the larger the venting pressure,the higher the peak pressure; the larger the venting area,the lower the peak pressure.

Colonic gas explosion during therapeutic colonoscopy with electrocautery

Therapeutic colonoscopy with electrocautery is widely used around the world. Adequate colonic cleansing is considered a crucial factor for the safety of this procedure. Colonic gas explosion, although rare, is one of the most frightening iatrogenic complications during colonoscopy with electrocautery. This complication is the result of an accumulation of colonic gases to explosive concentrations, but may be prevented by meticulous bowel preparation. The purpose of.this review is to discuss the indications and the types of bowel preparations for therapeutic colonoscopy, and to contribute recommendations for the adequate bowel preparation for colonoscopy with electrocautery.

Experimental investigation on micro-dynamic behavior of gas explosion suppression with SiO_2 fine powders

To study the effect of inert dust on gas explosion suppression mechanism,SiO_2 fine powders were sprayed to suppress premixed CH_4-Air gas explosion in a 20 L spherical experimental system.In the experiment,high speed schlieren image system was adopted to record explosion flame propagation behaviors,meanwhile,pressure transducers and ion current probes were used to clearly record the explosion flame dynamic characteristics.The experimental results show that the SiO_2 fine powders suppressed evidently the gas explosion flame,and reduced the peak value of pressure and flame speed by more than 40%.The ion current result shows that the SiO_2 super fine powders were easy to contact with and absorb free radicals near the combustion reaction region,which greatly reduced the combustion reaction intensity,and in turn influenced the flame propagation and pressure rising.

Effects of Obstacles on Flame Propagation Behavior and Explosion Overpressure Development During Gas Explosions in a Large Closed Tube

AutoReaGas was used for the simulations of premixed gas/air mixtures explosion characteristics in obstacle-filled tubes with a cross-section of 0.2 m×0.2 m and the length of 28 m. Numerical analyses provide a quantitative description of dependence of flame propagation speed and explosion overpressure on obstacles number, blockage ratio and interval distance. Computational results indicate that the obstacles play a significant role in determining the flame transmission speed and explosion overpressure in gas explosions. With the increase of blockage ratio, the explosion overpressure gradually rises. Nevertheless, the flame speed does not always increase along with increasing blockage ratio, but subsequently begins to decrease as the blockage ratio increases to some extend. Also, the interval distance between obstacles strongly influences flame behavior and explosion overpressure. When the obstacle interval distance is equal to inner diameter of the tube, the average flame speed in the obstacle zone and the peak overpressure in tube all reach maximum values.

Combined effects of obstacle and fine water mist on gas explosion characteristics

Combined effects of obstacles and fine water mist on a methane-air explosion of a semi-closed pipe were investigated experimentally.In this study,the diameter of the water mist,the location,and the number of obstacles was considered.The results demonstrated that 5 μm water mist present a significant suppression affected while 45 μm shows a slight promotion effected on a gas explosion of the condition without obstacles.In the presence of an obstacle,however,the inhibitory effect of 5 μm water veils of mist dropped significantly during flame propagation,and the effect of 45 μm water veils of mist changed from the enhancement of inhibition,and its inhibitory effect was significant.The inhibitory effect of 45 μm water veils of mist on gas explosion weakened firstly and then enhanced with the increasing distance between obstacle location from the ignition location as well as in several obstacles.

Analysis of vacuum chamber suppressing gas explosion

In order to suppress the harm of gas explosion,the current study researched on the body of vacuum chamber.The previous studies verifed that it could obviously lower the explosion overpressure by reasonably arranging vacuum chamber on pipe.That is to say,the vacuum chamber has the effect of absorbing wave and energy.To further deeply analyze the vacuum chamber suppressing gas explosion,this research designed the L-type pipe of gas explosion,and compared the experimental results of gas explosion with vacuum chamber and without vacuum chamber.Besides,using the gas chromatograph,this study also investigated the gas compositions in the pipe before and after explosion.The results show that:(1)without vacuum chamber,the maximum value of explosion overpressure is 0.22 MPa,with60 ms duration,and after explosion,the concentration of oxygen drops to 12.07%,but the concentration of carbon monoxide increases to 4392.3 10à6,and the concentration of carbon dioxide goes up to7.848%,which can make the persons in danger suffocate and die;(2)with vacuum chamber,explosion overpressure drops to 0.18 MPa,with 20 ms duration or less,and after explosion,the concentration of oxygen still remains 12.07%,but the concentration of methane is 7.83%,however the concentration of carbon monoxide is only 727.24 10à6,and the concentration of carbon dioxide is only 1.219%,at the this moment the concentration ratio of toxic gas drops by more than 83%in comparison to be that without vacuum chamber.Consequently,the vacuum chamber can guarantee that most methane does not take part in chemical reaction,and timely quenches the deflagration reaction of gas and oxygen.Because of the two points mentioned above,it reduces the explosion energy,and lowers that the overpressure of blast wave impacts and damages on the persons and facilities,and also decreases the consumption of oxygen and the production of the toxic gas.Therefore,it is safe to conclude that the vacuum chamber not only absorbs wave and energy,but also prevents and suppresses explosion.

Simulation Analysis of Indoor Gas Explosion Damage

The influence factors and process of indoor gas explosion are studied with AutoReaGas explosion simulator. The result shows that venting pressure has great influence on the indoor gas explosion damage. The higher the venting pressure is, the more serious the hazard consequence will be. The ignition location has also evident effect on the gas explosion damage. The explosion static overpressure would not cause major injury to person and serious damage to structure in the case of low venting pressure (lower than 2 kPa). The high temperature combustion after the explosion is the major factor to person injury in indoor gas explosion accidents.

Experimental study on gas explosion suppression based on ferrocene

In order to study the gas explosion suppression performance based on ferrocene, the self-constructed experimental facility was used to accomplish the experiment of gas explosion suppression. By means of thermogravimetric analysis, the thermal characteristics of ferrocene have been gotten and the gas explosion suppression mechanism of ferrocene has been analyzed. The results show that ferrocene had good effects on gas explosion suppression, and the explosion pressure and flame propagation speed declined obviously. When ferrocene concentration is 0.08 g/L and methane volume concentration is 9.5%, the maximum explosion overpressure and maximum flame propagation speed of methane-air respectively decreased by about 59.5% and 19.6%, respectively. TG and DSC curves showed that the mass loss of ferrocene consists of two processes, which are sublimation and lattice fracture. The temperature of mass loss ranged from 128 ℃ to 230 ℃. The results showed profoundly theoretical significance to gas explosion suppression by ferrocene in coal mines.

Comparative experimental study on inhibiting gas explosion using ABC dry powder and diatomite powder

Using a 20 L spherical explosion suppressing test system, the largest gas explosion pressure and maximum pressure rising rate with additives of ultra-fine ABC dry powder and diatomite powder were tested and compared, and the explosion suppression effect of the two kinds of powder was analyzed. Experimental results show that both powders can suppress gas ex- plosion and ABC dry powder is superior to diatomite powder. Adding two powders under the same experimental conditions, when methane concentration is 7.0%, the maximum explosion pressure decreased 39% and 4%, respectively, while the rising rate of the maximum pressure decreased 80% and 53%, respectively. When methane concentration is 9.5%, the maximum ex- plosion pressure decreased 14% and 12%, respectively, the rising rate of maximum pressure decreased 62% and 27%, respec- tively, the maximum explosion pressure decreased 23% and 18%, respectively, while the rising rate of the maximum pressure decreased 77% and 70%, respectively. When methane concentration is 12.0%, the explosion suppression effect of ultra-fine ABC dry powder is not affected by the methane concentration, and the explosion suppression effect of diatomite powder under high methane concentrations is more obvious.

Forecast correct model of overpressure attenuation during gas explosion in excavation roadway

Through analyzing experimental data of gas explosions in excavation roadwaysand the forecast models of the literature, Found that there is no direct proportional linearcorrelation between overpressure and the square root of the accumulated volume of gas,the square root of the propagation distance multiplicative inverse.Also, attenuation speedof the forecast model calculation is faster than that of experimental data.Based on theoriginal forecast models and experimental data, deduced the relation of factors by introducinga correlation coefficient with concrete volume and distance, which had been verifiedby the roadway experiment data.The results show that it is closer to the roadway experimentaldata and the overpressure amount increases first then decreases with thepropagation distance.

Experimental and Numerical Study on the Gas Explosion in Urban Regulator Station

Regulator station is an important part in the urban gas transmission and distribution system.Once gas explosion occurs,the real explosion process and consequences of methane gas explosion in the regulator station were not revealed systematically.In this study,a full-scale experiment was carried out to simulate the regulator station explosion process,and some numerical simulations with a commercial CFD software called FLACS were conducted to analyze the effect of ignition and vent conditions on the blast overpressure and flame propagation.The experimental results demonstrated that the peak overpressure increased as the distance from the vent increased within a certain distance.And the maximum overpressure appeared 3 m away from the door,which was about 36.6 kPa.It was found that the pressure-time rising curves obtained from the simulation are basically the same as the ones from the experiment,however,the time of reaching the peak pressure was much shorter.The numerical simulation results show that the peak overpressures show an increase trend as the ignition height decreased and the vent relief pressure increased.It indicates that the damage and peak overpressure of gas explosion could be well predicted by FLACS in different styles of regulator station.In addition,the results help us to understand the internal mechanism and development process of gas explosion better.It also offers technical support for the safety protection of the urban regulator station.