Various factors controlling the accumulation of natural gas hydrates(NGHs)form various enrichment and accumulation modes through organic combination.This study mainly analyzes the geological and geophysical characteri...Various factors controlling the accumulation of natural gas hydrates(NGHs)form various enrichment and accumulation modes through organic combination.This study mainly analyzes the geological and geophysical characteristics of the NGHs occurrence in the uplifts and their slope zones within the deep-water area in the Qiongdongnan(QDN)Basin(also referred to as the study area).Furthermore,it investigates the dominant governing factors and models of NGHs migration and accumulation in the study area.The results are as follows.(1)The uplifts and their slope zones in the study area lie in the dominant pressure-relief direction of fluids in central hydrocarbon-rich sags in the area,which provide sufficient gas sources for the NGHs accumulation and enrichment through pathways such as gas chimneys and faults.(2)The top and flanks of gas chimneys below the bottom simulating reflectors(BSRs)show high-amplitude seismic reflections and pronounced transverse charging of free gas,indicating the occurrence of a large amount of gas accumulation at the heights of the uplifts.(3)Chimneys,faults,and high-porosity and high-permeability strata,which connect the gas hydrate temperature-pressure stability zones(GHSZs)with thermogenic gas and biogenic gas,form the main hydrate migration system.(4)The reservoir system in the study area comprises sedimentary interlayers consisting of mass transport deposits(MTDs)and turbidites.In addition,the reservoir system has developed fissure-and pore-filling types of hydrates in the pathways.The above well-matched controlling factors of hydrate accumulation enable the uplifts and their slope zones in the study area to become the favorable targets of NGHs exploration.展开更多
Natural gas hydrate(NGH)is generally produced and accumulated together with the underlying conventional gas.Therefore,optimizing the production technology of these two gases should be seen as a relevant way to effecti...Natural gas hydrate(NGH)is generally produced and accumulated together with the underlying conventional gas.Therefore,optimizing the production technology of these two gases should be seen as a relevant way to effectively reduce the exploitation cost of the gas hydrate.In this study,three types of models accounting for the coexistence of these gases are considered.Type A considers the upper hydrate-bearing layer(HBL)adjacent to the lower conventional gas layer(CGL);with the Type B a permeable interlayer exists between the upper HBL and the lower CGL;with the type C there is an impermeable interlayer between the upper HBL and the lower CGL.The production performances associated with the above three models are calculated under different conditions,including only a depressurized HBL(only HBL DP);only a depressurized CGL(only CGL DP);and both the HBL and the CGL being depressurized(HBL+CGL DP).The results show that for Type A and Type B coexistence accumulation models,when only HBL or CGL is depressurized,the gas from the other layer will flow into the production layer due to the pressure difference between the two layers.In the coexistence accumulation model of type C,the cumulative gas production is much lower than that of Type A and Type B,regardless of whether only HBL DP,only CGL DP,or HBL+CGL DP are considered.This indicates that the impermeable interlayer restricts the cross-flow of gas between HBL and CGL.For three different coexistence accumulation models,CGL DP has the largest gas-to-water ratio.展开更多
A detailed understanding of the distribution and potential of natural gas hydrate(NGHs)resources is crucial to fostering the industrialization of those resources in the South China Sea,where NGHs are abundant.In this ...A detailed understanding of the distribution and potential of natural gas hydrate(NGHs)resources is crucial to fostering the industrialization of those resources in the South China Sea,where NGHs are abundant.In this study,this study analyzed the applicability of resource evaluation methods,including the volumetric,genesis,and analogy methods,and estimated NGHs resource potential in the South China Sea by using scientific resource evaluation methods based on the factors controlling the geological accumulation and the reservoir characteristics of NGHs.Furthermore,this study compared the evaluation results of NGHs resource evaluations in representative worldwise sea areas via rational analysis.The results of this study are as follows:(1)The gas hydrate accumulation in the South China Sea is characterized by multiple sources of gas supply,multi-channel migration,and extensive accumulation,which are significantly different from those of oil and gas and other unconventional resources.(2)The evaluation of gas hydrate resources in the South China Sea is a highly targeted,stratified,and multidisciplinary evaluation of geological resources under the framework of a multi-type gas hydrate resource evaluation system and focuses on the comprehensive utilization of multi-source heterogeneous data.(3)Global NGHs resources is n×10^(15)m^(3),while the NGHs resources in the South China Sea are estimated to be 10^(13)m^(3),which is comparable to the abundance of typical marine NGHs deposits in other parts of the world.In the South China Sea,the NGHs resources have a broad prospect and provide a substantial resource base for production tests and industrialization of NGHs.展开更多
In order to investigate the migration and accumulation efficiency of hydrocarbon natural gas in the Xujiaweizi fault depression, and to provide new evidence for the classification of its genesis, a source rock pyrolys...In order to investigate the migration and accumulation efficiency of hydrocarbon natural gas in the Xujiaweizi fault depression, and to provide new evidence for the classification of its genesis, a source rock pyrolysis experiment in a closed system was designed and carried out. Based on this, kinetic models for describing gas generation from organic matter and carbon isotope fractionation during this process were established, calibrated and then extrapolated to geologic conditions by combining the thermal history data of the Xushen-1 Well. The results indicate that the coal measures in the Xujiaweizi fault depression are typical "high-efficiency gas sources", the natural gas generated from them has a high migration and accumulation efficiency, and consequently a large-scale natural gas accumulation occurred in the area. The highly/over matured coal measures in the Xujiaweizi fault depression generate coaliferous gas with a high δ^13C1 value (〉 -20‰) at the late stage, making the carbon isotope composition of organic alkane gases abnormally heavy. In addition, the mixing and dissipation through the caprock of natural gas can result in the negative carbon isotope sequence (δ^13C1 〉δ^13C2 〉δ^13C3 〉δ^13C4) of organic alkane gases, and the dissipation can also lead to the abnormally heavy carbon isotope composition of organic alkane gases. As for the discovery of inorganic nonhydrocarbon gas reservoirs, it can only serve as an accessorial evidence rather than a direct evidence that the hydrocarbon gas is inorganic. As a result, it needs stronger evidence to classify the hydrocarbon natural gas in the Xujiaweizi fault depression as inorganic gas.展开更多
Sand production is one of the main obstacles restricting gas extraction efficiency and safety from marine natural gas hydrate(NGH)reservoirs.Particle migration within the NGH reservoir dominates sand production behavi...Sand production is one of the main obstacles restricting gas extraction efficiency and safety from marine natural gas hydrate(NGH)reservoirs.Particle migration within the NGH reservoir dominates sand production behaviors,while their relationships were rarely reported,severely constrains quantitative evaluation of sand production risks.This paper reports the optical observations of solid particle migration and production from micrometer to mesoscopic scales conditioned to gravel packing during depressurization-induced NGH dissociation for the first time.Theoretical evolutionary modes of sand migration are established based on experimental observations,and its implications on field NGH are comprehensively discussed.Five particle migration regimes of local borehole failure,continuous collapse,wormhole expansion,extensive slow deformation,and pore-wall fluidization are proved to occur during depressurization.The types of particle migration regimes and their transmission modes during depressurization are predominantly determined by initial hydrate saturation.In contrast,the depressurization mainly dominates the transmission rate of the particle migration regimes.Furthermore,both the cumulative mass and the medium grain size of the produced sand decrease linearly with increasing initial methane hydrate(MH)saturation.Discontinuous gas bubble emission,expansion,and explosion during MH dissociation delay sand migration into the wellbore.At the same time,continuous water flow is a requirement for sand production during hydrate dissociation by depressurization.The experiments enlighten us that a constitutive model that can illustrate visible particle migration regimes and their transmission modes is urgently needed to bridge numerical simulation and field applications.Optimizing wellbore layout positions or special reservoir treatment shall be important for mitigating sand production tendency during NGH exploitation.展开更多
Many evidences for gas hydrate bearing sediments had been found in the continental slope of the East China Sea,such as bottom simulating reflections(BSRs),undersea gas springs,pyrite associated with methane leakage,mu...Many evidences for gas hydrate bearing sediments had been found in the continental slope of the East China Sea,such as bottom simulating reflections(BSRs),undersea gas springs,pyrite associated with methane leakage,mud diapirs/mud volcanos,bottom-water methane anomalies and so on.In this study,six key stratigraphic interfaces including T_0(seafloor),T_1(LGM,23 kyr B.P.),T_2(2.58 Myr),T_3(5.33 Myr),T_4(11.02 Myr)and T_5(16.12 Myr)were identified,and then five third-order sequences of SQIII1 to SQIII5 were divided.However,T5 in southern continental slope is not found,which shows that the middle-northern Okinawa Trough had begun to rift in the early Miocene,earlier than the southern segment.Four system tracts including lowstand systems tract(LST),transgressive systems tract(TST),highstand systems tract(HST)and falling stage systems tract(FSST)are further divided.The marine erosion interface of 11.02 Myr and regressive unconformity interface of 23 kyr B.P.indicate two large-scale sea level drop events in the research area.Seven typical seismic facies identified in the continental slope are continental shelf-edge deltas,littoral fluvial-delta plains,incised channels or submarine canyons,slope fans,submarine fans or coastal sandbars,littoral-neritic finegrained sediments,mud volcanos and some other geological bodies respectively.The minimum water depth for hydrate occurrence in the Okinawa Trough is 630 m,and the thickness of gas hydrate stability zone in continental slope is between 0 and 590 m.The calculated bottom boundary of hydrate stability zone is slightly deeper than BSRs on the seismic sections.The re-depositional turbidite sand bodies,such as canyon channels,slope fans and submarine fans developed in Quaternary strata,are the predominant hydrate reservoirs.According to developing process,the dynamic accumulation of hydrate systems can be divided into three evolutionary stages including canyon erosion and hydrate stability zone migration stage,sediments destabilizing and methane leakage stage,and channel filling and hydrate re-occurrence stage.展开更多
The Mohe permafrost in northeast China possesses favorable subsurface ambient temperature, salinity, Eh values and pH levels of groundwater for the formation of microbial gas, and the Mohe Basin contains rich organic ...The Mohe permafrost in northeast China possesses favorable subsurface ambient temperature, salinity, Eh values and pH levels of groundwater for the formation of microbial gas, and the Mohe Basin contains rich organic matter in the Middle Jurassic dark mudstones. This work conducted gas chromatography and isotope mass spectrometry analyses of nearly 90 core gas samples from the Mk-2 well in the Mohe Basin. The results show that the dryness coefficient(C1/C1–5) of core hydrocarbon gas from approximately 900 m intervals below the surface is larger than 98%, over 70% of the δ13 C values of methane are smaller than-55‰, and almost all δD values of methane are smaller than-250‰, indicative of a microbial origin of the gas from almost 900 m of the upper intervals in the Mohe permafrost. Moreover, the biomarker analyses of 72 mudstone samples from the Mohe area indicate that all of them contain 25-norhopane series compounds, thereby suggesting widely distributed microbial activities in the permafrost. This work has confirmed the prevailing existence of microbial gas in the Mohe area, which may be a potential gas source of gas hydrate formation in the Mohe permafrost. This result is of great significance to gas hydrate accumulation in the permafrost across China.展开更多
Migration and accumulation simulation of oil and gas in carrier systems has always been a difficult subject in the quantitative study of petroleum geology. In view of the fact that the traditional geological modeling ...Migration and accumulation simulation of oil and gas in carrier systems has always been a difficult subject in the quantitative study of petroleum geology. In view of the fact that the traditional geological modeling technology can not establish the interrelation of carriers in three dimensional space, we have proposed a hybrid-dimensional mesh modeling technology consisting of body(stratum), surfaces(faults and unconformities), lines and points, which provides an important research method for the description of geometry of sand bodies, faults and unconformities, the 3 D geological modeling of complex tectonic areas, and the simulation of hydrocarbon migration and accumulation. Furthermore, we have advanced a 3 D hydrocarbon migration pathway tracking method based on the hybrid-dimensional mesh of the carrier system. The application of this technology in western Luliang Uplift of Junggar Basin shows that the technology can effectively characterize the transport effect of fault planes, unconformities and sand bodies, indicate the hydrocarbon migration pathways, simulate the process of oil accumulation, reservoir adjustment and secondary reservoir formation, predict the hydrocarbon distribution. It is found through the simulation that the areas around the paleo-oil reservoir and covered by migration pathways are favorable sites for oil and gas distribution.展开更多
The Shenhu gas hydrate drilling area is located in the central Baiyun sag, Zhu I! depression, Pearl River Mouth basin, northern South China Sea. The gas compositions contained in the hydrate-bearing zones is dominated...The Shenhu gas hydrate drilling area is located in the central Baiyun sag, Zhu I! depression, Pearl River Mouth basin, northern South China Sea. The gas compositions contained in the hydrate-bearing zones is dominated by methane with content up to 99.89% and 99.91%. The carbon isotope of the methane (δ^13C1) are -56.7%0. and -60.9%0, and its hydrogen isotope (δD) are -199%0 and -180%0, respectively, indicating the methane from the microbial reduction of CO2. Based on the data of measured seafloor temperature and geothermal gradient, the gas formed hydrate reservoirs are from depths 24-1699 m below the seafloor, and main gas-generation zone is present at the depth interval of 416-1165 m. Gas-bearing zones include the Hanjiang Formation, Yuehai Formation, Wanshan Formation and Quaternary sediments. We infer that the microbial gas migrated laterally or vertically along faults (especially interlayer faults), slump structures, small-scale diapiric structures, regional sand beds and sedimentary boundaries to the hydrate stability zone, and formed natural gas hydrates in the upper Yuehai Formation and lower Wanshan Formation, probably with contribution of a little thermogenic gas from the deep sedments during this process.展开更多
Solid bitumens were found throughout the carbonate reservoirs in the Puguang gas field, the largest gas field so far found in marine carbonates in China, confirming that the Puguang gas field evolved from a paleo-oil ...Solid bitumens were found throughout the carbonate reservoirs in the Puguang gas field, the largest gas field so far found in marine carbonates in China, confirming that the Puguang gas field evolved from a paleo-oil reservoir. The fluid conduit system at the time of intensive oil accumulation in the field was reconstructed, and petroleum migration pathways were modeled using a 3-D model and traced by geochemical parameters. The forward modeling and inversion tracing coincided with each other and both indicated that oils accumulated in the Puguang-Dongyuezhai structure originated from a generative kitchen to the northwest of the Puguang gas field. The deposition of organic-rich Upper Permian source rocks dominated by sapropelic organic matter in the Northeast Sichuan Basin, the development of fluid conduit system that was vertically near-source rock and laterally near-generative kitchen, and the focusing of oils originated from a large area of the generative kitchen, were the three requirements for the formation of the giant paleo-oil reservoir from which the giant Puguang gas field evolved. The Puguang gas field had experienced a three-stage evolution. The post-accumulation processes, especially the organic-inorganic interaction in the hydrocarbon-water-rock system, had not only profoundly altered the composition and characteristics of the petroleum fluids, but also obviously changed the physicochemical conditions in the reservoir and resulted in complicated precipitation and solution of carbonate minerals.展开更多
The prediction of continental tight sandstone gas sweet spots is an obstacle during tight sandstone gas exploration. In this work, the classic physical fluid charging experimental equipment is improved, the combinatio...The prediction of continental tight sandstone gas sweet spots is an obstacle during tight sandstone gas exploration. In this work, the classic physical fluid charging experimental equipment is improved, the combination of the gas migration and accumulation process with the pore network numerical simulation method is investigated, and application of the permeability/porosity ratio is proposed to predict the gas saturation and sweet spots of continental formations. The results show that (1) as the charging pressure increases, the permeability of the reservoir increases because more narrow pore throats are displaced in the percolation process;and (2) based on pore network numerical simulation and theoretical analysis, the natural gas migration and accumulation mechanisms are revealed. The gas saturation of tight sandstone rock is controlled by the gas charging pressure and dynamic percolation characteristics. (3) The ratio of permeability/porosity and fluid charging pressure is proposed to predict the gas saturation of the formation. The ratio is verified in a pilot and proven to be applicable and practical. This work highlights the tight sandstone gas migration and accumulation mechanisms and narrows the gap among microscale physical experiments, numerical simulation research, and field applications.展开更多
Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloo...Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloor topographic highs. Many gas hydrate exploration examples abroad also indicate that the saturation of gas hydrates was higher at seafloor topographic highs. This work aims to understand why gas hydrates accumulated at topographic highs and why their saturation is higher.展开更多
The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T cond...The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T conditions, geophysical anomalies and saturation calculations of these gas hydrates, but has not documented in detail the migration of gas-bearing fluids in the study area. Based on the interpretations of 2D/3D seismic data, this work identified two types of migration pathways for gas-bearing fluids in the Shenhu area, i.e., vertical and lateral pathways. The vertical pathways(largescale faults, gas chimneys and mud diapirs) presented as steep seismic reflection anomalies, which could be traced downward to the Eocene source rocks and may penetrate into the Late Miocene strata. The deeper gases/fluids might be allowed migrating into the shallower strata through these vertical conduits. However, the distributions showed distinct differences between these pathways. Large-scale faults developed only in the north and northeast of the Shenhu area, while in the drilling area gas chimneys were the sole vertical migration pathways. Since the Pliocene, normal faults, detachment faults and favorable sediments have constituted the lateral pathways in the Shenhu gas hydrate drilling area. Although these lateral pathways were connected with gas chimneys, they exerted different effects on hydrate formation and accumulation. Gas-bearing fluids migrated upward along gas chimneys might further migrate laterally because of the normal faults, thereby enlarging the range of the chimneys. Linking gas chimneys with the seafloor, the detachment faults might act as conduits for escaping gases/fluids. Re-deposited sediments developed at the early stage of the Quaternary were located within the gas hydrate stability zone, so hydrates would be enriched in these favorable sediments. Compared with the migration pathways(large-scale faults and mud diapirs) in the LW3-1 deep-sea oil/gas field, the migration efficiency of the vertical pathways(composed of gas chimneys) in the gas hydrate drilling area might be relatively low. Description and qualitative discrimination of migration pathways in the Shenhu gas hydrate drilling area are helpful to further understand the relationship between good-quality deep source rocks and shallow, mainly biogenicallyproduced, hydrates. As the main source rocks of the Baiyun sag, lacustrine mudstones in the Wenchang and Enping Formations may provide thermogenic methane. Gas chimneys with relatively low migration efficiency created the vertical pathways. Caused by the Dongsha tectonic movement, the release of overpressured fluids might reduce the vertical migration rates of the thermogenic methane. The thick bathyal/abyssal fine-grained sediments since the Late Miocene provided migration media with low permeability. These preconditions may cause carbon isotopic fractionation ofthermogenic methane during long-distance vertical migrations. Therefore, although geochemical analyses indicate that the methane forming gas hydrate in the Shenhu area was mainly produced biogenically, or was mixed methane primarily of microbial origin, thermogenic methane still contribute significantly.展开更多
The Kuqa foreland basin is an important petroliferous basin where gas predominates. The Kela-2 large natural gas reservoir and the Yinan-2, Dabei-1, Tuzi and Dina-11 gas reservoirs have been discovered in the basin up...The Kuqa foreland basin is an important petroliferous basin where gas predominates. The Kela-2 large natural gas reservoir and the Yinan-2, Dabei-1, Tuzi and Dina-11 gas reservoirs have been discovered in the basin up to the present. Natural gases in the Kelasu district and the Yinan district are generated from different source rocks indicated by methane and ethane carbon isotopes. The former is derived from both Jurassic and Triassic source rocks, while the latter is mainly from the Jurassic. Based on its multistage evolution and superposition and the intense tectonic transformation in the basin, the hydrocarbon charging history can be divided into the early and middle Himalayan hydrocarbon accumulation and the late Himalayan redistribution and re-enrichment. The heavier carbon isotope composition and the high natural gas ratio of C1/C1-4 indicate that the accumulated natural gas in the early Himalayan stage is destroyed and the present trapped natural gas was charged mainly in the middle and late Himalayan stages. Comparison and contrast of the oils produced in the Kelasu and Yinan regions indicate the hydrocarbon charging histories in the above two regions are complex and should be characterized by multistage hydrocarbon migration and accumulation.展开更多
Gas and water migration through the hydrate-bearing sediment are characteristic features in marine gas hydrate reservoirs worldwide.However,there are few experimental investigations on the effect of water-gas flow on ...Gas and water migration through the hydrate-bearing sediment are characteristic features in marine gas hydrate reservoirs worldwide.However,there are few experimental investigations on the effect of water-gas flow on the gas hydrate reservoir.In this study,gas-water migration in gas hydrate stability zone(GHSZ)was investigated visually employing a high-resolution magnetic resonance imaging(MRI)apparatus,and the formation of hydrate seal was experimentally investigated.Results revealed that normal flow of gas-water at the low flow rate of 1–0.25 mL/min will induce the hydrate reformation.Conversely,higher gas-water flow rates(at 2–0.5 and 4–1 mL/min)need higher reservoir pressure to induce the hydrate reformation.In addition,the hydrate reformation during the gas-water flow process produced the hydrate seal,which can withstand an over 9.0 MPa overpressure.This high overpressure provides the development condition for the underlying gas and/or water reservoir.A composite MRI image of the whole hydrate seal was obtained through the MRI.The pore difference between hydrate zone and coexistence zone produces a capillary sealing effect for hydrate seal.The hydrate saturation of hydrate seal was more than 51.6%,and the water saturation was more than 19.3%.However,the hydrate seal can be broken through when the overpressure exceeded the capillary pressure of the hydrate seal,which induced the sudden drop of reservoir pressure.This study provides a scientific explanation for the existence of high-pressure underlying gas below the hydrate layer and is significant for the safe exploitation of these common typical marine hydrate reservoirs.展开更多
Laboratory visual detection on the hydrate accumulation process provides an effective and low-cost method to uncover hydrate accumulation mechanisms in nature.However,the spatial hydrate distribution and its dynamic e...Laboratory visual detection on the hydrate accumulation process provides an effective and low-cost method to uncover hydrate accumulation mechanisms in nature.However,the spatial hydrate distribution and its dynamic evolutionary behaviors are still not fully understood due to the lack of methods and experimental systems.Toward this goal,we built a two-dimensional electrical resistivity tomography(ERT)apparatus capable of measuring spatial and temporal characteristics of hydrate-bearing porous media.Beach sand(0.05–0.85 mm)was used to form artificial methane hydrate-bearing sediment.The experiments were conducted at 1°C under excess water conditions and the ERT data were acquired and analyzed.This study demonstrates the utility of the ERT method for hydrate mapping in laboratory-scale.The results indicate that the average electrical conductivity decreases nonlinearly with the formation of the hydrate.At some special time-intervals,the average conductivity fluctuates within a certain scope.The plane conductivity fields evolve heterogeneously and the local preferential hydrate-forming positions alternate throughout the experimental duration.We speculate that the combination of hydrate formation itself and salt-removal effect plays a dominant role in the spatial and temporal hydrate distribution,as well as geophysical parameters changing behaviors during hydrate accumulation.展开更多
A type of authigenic pyrites that fully fill or semi-fill the rock fractures of drillholes with gas hydrate anomalies are found in the Qilian Mountain permafrost; this type of pyrite is known as "fracture-filling" p...A type of authigenic pyrites that fully fill or semi-fill the rock fractures of drillholes with gas hydrate anomalies are found in the Qilian Mountain permafrost; this type of pyrite is known as "fracture-filling" pyrite. The occurrence of "fracture-filling" pyrite has a certain similarity with that of the hydrate found in this region, and the pyrite is generally concentrated in the lower part of the hydrate layer or the hydrate anomaly layer. The morphology, trace elements, rare earth elements, and sulfur isotope analyses of samples from drillhole DK-6 indicate that the "fracture-filling" pyrites are dominated by cubic ones mainly aligned in a step-like fashion along the surfaces of rock fractures and are associated with a circular structure, lower Co/Ni and Sr/Ba, lower ZREE, higher LREE, significant Eu negative anomalies, and 634ScDT positive bias. In terms of the pyrites' unique crys- tal morphology and geochemical characteristics and their relationship with the hydrate layers or abnormal layers, they are closely related with the accumulation system of the gas hydrate in the Qilian Mountain permafrost. As climate change is an important factor in affecting the stability of the gas hydrate, formation of fracture-filling pyrites is most likely closely related to the secondary change of the metastable gas hydrate under the regional climate warming. The distribution intensity of these py- rites indicates that when the gas hydrate stability zone (GHSZ) is narrowing, the hydrate decomposition at the bottom of the GHSZ is stronger than that at the top of the GHSZ, whereas the hydrate decomposition within the GHSZ is relatively weak. Thus, the zone between the shallowest and the deepest distribution of the fracture-filling pyrite recorded the largest possible original GHSZ.展开更多
With the guidance of petroleum system theory,the dynamic filling history of natural gas in the Kela-2 gasfield is analyzed by using a large suite of oil and gas geo-chemistry evidence in combination with the tectonic ...With the guidance of petroleum system theory,the dynamic filling history of natural gas in the Kela-2 gasfield is analyzed by using a large suite of oil and gas geo-chemistry evidence in combination with the tectonic evolu-tion history and reservoir evolution history. It concludes thatthe Kela-2 gas field was formed by capturing the gas gener-ated during the main gas generation period, while the latekerogen cracking gas contributed a little to the gas field. Itsuggests that the gas generated during the main gas genera-tion accumulated in the early-formed wide-gentle anticline,which is the necessary condition for natural gas to re-migrateand enrich late to form the large-scale gas reservoir. Thenewest research shows that the filling history of gas in theDabei-1, Yinan-2, Tuziluoke and Dina-2 gas fields was re-lated with the natural gas accumulation in the early wide-gentle anticline as well as late re-migration and enrichmentof natural gas.展开更多
Seepage-type gas hydrate accumulation in subsea shallow formations involves complicated thermohydro-solid coupling processes and matching problem between various accumulation elements.Theformation physical properties ...Seepage-type gas hydrate accumulation in subsea shallow formations involves complicated thermohydro-solid coupling processes and matching problem between various accumulation elements.Theformation physical properties control local natural gas migration pathway and thus the final reservoircharacteristics of hydrates.In this paper,a novel mixed-flux model for gas hydrate accumulation isestablished and then used to simulate the process of methane gas migration into the shallow stratum toform a hydrate reservoir.The effects of reservoir heterogeneity and gas source conditions on the distribution of pore fluid and hydrate accumulation are examined.The simulation results show thatreservoir heterogeneity is conducive to the retention and lateral migration of CH4 in a hydrate stabilityzone.CH4 can contact more pore water to form a large hydrate reserve,but the formed hydrate is oftendispersed.Low-permeability layers enhance the trapping of CH4 and form a uniform and large hydratesaturation.Besides,gas source conditions have an important impact on the hydrate accumulation inreservoirs.Large gas flux,small pore water flux,continuous gas supply,high content of heavy components in natural gas,and numerous gas source points contribute to large amounts of hydrates generationin a certain time period.The presented work will deepen our understanding of the controls of natural gashydrate systems in subea shallow formations.展开更多
基金funded by the projects initiated by the China Geological Survey(DD20190217 and DD20190230)the key special project for introduced talent team of Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)(GML2019ZD0102)Guangdong Major project of Basic and Applied Basic Research(2020B0301030003).
文摘Various factors controlling the accumulation of natural gas hydrates(NGHs)form various enrichment and accumulation modes through organic combination.This study mainly analyzes the geological and geophysical characteristics of the NGHs occurrence in the uplifts and their slope zones within the deep-water area in the Qiongdongnan(QDN)Basin(also referred to as the study area).Furthermore,it investigates the dominant governing factors and models of NGHs migration and accumulation in the study area.The results are as follows.(1)The uplifts and their slope zones in the study area lie in the dominant pressure-relief direction of fluids in central hydrocarbon-rich sags in the area,which provide sufficient gas sources for the NGHs accumulation and enrichment through pathways such as gas chimneys and faults.(2)The top and flanks of gas chimneys below the bottom simulating reflectors(BSRs)show high-amplitude seismic reflections and pronounced transverse charging of free gas,indicating the occurrence of a large amount of gas accumulation at the heights of the uplifts.(3)Chimneys,faults,and high-porosity and high-permeability strata,which connect the gas hydrate temperature-pressure stability zones(GHSZs)with thermogenic gas and biogenic gas,form the main hydrate migration system.(4)The reservoir system in the study area comprises sedimentary interlayers consisting of mass transport deposits(MTDs)and turbidites.In addition,the reservoir system has developed fissure-and pore-filling types of hydrates in the pathways.The above well-matched controlling factors of hydrate accumulation enable the uplifts and their slope zones in the study area to become the favorable targets of NGHs exploration.
基金supported by the National Natural Science Foundation of China (Nos.52074334,51991365)the National Key R&D Program of China (2021YFC2800903),which are gratefully acknowledged.
文摘Natural gas hydrate(NGH)is generally produced and accumulated together with the underlying conventional gas.Therefore,optimizing the production technology of these two gases should be seen as a relevant way to effectively reduce the exploitation cost of the gas hydrate.In this study,three types of models accounting for the coexistence of these gases are considered.Type A considers the upper hydrate-bearing layer(HBL)adjacent to the lower conventional gas layer(CGL);with the Type B a permeable interlayer exists between the upper HBL and the lower CGL;with the type C there is an impermeable interlayer between the upper HBL and the lower CGL.The production performances associated with the above three models are calculated under different conditions,including only a depressurized HBL(only HBL DP);only a depressurized CGL(only CGL DP);and both the HBL and the CGL being depressurized(HBL+CGL DP).The results show that for Type A and Type B coexistence accumulation models,when only HBL or CGL is depressurized,the gas from the other layer will flow into the production layer due to the pressure difference between the two layers.In the coexistence accumulation model of type C,the cumulative gas production is much lower than that of Type A and Type B,regardless of whether only HBL DP,only CGL DP,or HBL+CGL DP are considered.This indicates that the impermeable interlayer restricts the cross-flow of gas between HBL and CGL.For three different coexistence accumulation models,CGL DP has the largest gas-to-water ratio.
基金jointly supported by the National Natural Science Foundation of China(42376222,U22A20581,and 42076069)Key Research and Development Program of Hainan Province(ZDYF2024GXJS002)China Geological Survey(DD20230402)。
文摘A detailed understanding of the distribution and potential of natural gas hydrate(NGHs)resources is crucial to fostering the industrialization of those resources in the South China Sea,where NGHs are abundant.In this study,this study analyzed the applicability of resource evaluation methods,including the volumetric,genesis,and analogy methods,and estimated NGHs resource potential in the South China Sea by using scientific resource evaluation methods based on the factors controlling the geological accumulation and the reservoir characteristics of NGHs.Furthermore,this study compared the evaluation results of NGHs resource evaluations in representative worldwise sea areas via rational analysis.The results of this study are as follows:(1)The gas hydrate accumulation in the South China Sea is characterized by multiple sources of gas supply,multi-channel migration,and extensive accumulation,which are significantly different from those of oil and gas and other unconventional resources.(2)The evaluation of gas hydrate resources in the South China Sea is a highly targeted,stratified,and multidisciplinary evaluation of geological resources under the framework of a multi-type gas hydrate resource evaluation system and focuses on the comprehensive utilization of multi-source heterogeneous data.(3)Global NGHs resources is n×10^(15)m^(3),while the NGHs resources in the South China Sea are estimated to be 10^(13)m^(3),which is comparable to the abundance of typical marine NGHs deposits in other parts of the world.In the South China Sea,the NGHs resources have a broad prospect and provide a substantial resource base for production tests and industrialization of NGHs.
基金the National Natural Science Foundation of China (No. 40572079); the Program for New Century Excellent Talents in University (No. NCET-04-0345); the Venture Capital Foundation of PetroChina (No. 2005-01-02).
文摘In order to investigate the migration and accumulation efficiency of hydrocarbon natural gas in the Xujiaweizi fault depression, and to provide new evidence for the classification of its genesis, a source rock pyrolysis experiment in a closed system was designed and carried out. Based on this, kinetic models for describing gas generation from organic matter and carbon isotope fractionation during this process were established, calibrated and then extrapolated to geologic conditions by combining the thermal history data of the Xushen-1 Well. The results indicate that the coal measures in the Xujiaweizi fault depression are typical "high-efficiency gas sources", the natural gas generated from them has a high migration and accumulation efficiency, and consequently a large-scale natural gas accumulation occurred in the area. The highly/over matured coal measures in the Xujiaweizi fault depression generate coaliferous gas with a high δ^13C1 value (〉 -20‰) at the late stage, making the carbon isotope composition of organic alkane gases abnormally heavy. In addition, the mixing and dissipation through the caprock of natural gas can result in the negative carbon isotope sequence (δ^13C1 〉δ^13C2 〉δ^13C3 〉δ^13C4) of organic alkane gases, and the dissipation can also lead to the abnormally heavy carbon isotope composition of organic alkane gases. As for the discovery of inorganic nonhydrocarbon gas reservoirs, it can only serve as an accessorial evidence rather than a direct evidence that the hydrocarbon gas is inorganic. As a result, it needs stronger evidence to classify the hydrocarbon natural gas in the Xujiaweizi fault depression as inorganic gas.
基金supported by the Laoshan Laboratory(No.LSKJ LSKJ202203506)the Taishan Scholars Program,and the National Natural Science Foundation of China(Grant No.41976074).
文摘Sand production is one of the main obstacles restricting gas extraction efficiency and safety from marine natural gas hydrate(NGH)reservoirs.Particle migration within the NGH reservoir dominates sand production behaviors,while their relationships were rarely reported,severely constrains quantitative evaluation of sand production risks.This paper reports the optical observations of solid particle migration and production from micrometer to mesoscopic scales conditioned to gravel packing during depressurization-induced NGH dissociation for the first time.Theoretical evolutionary modes of sand migration are established based on experimental observations,and its implications on field NGH are comprehensively discussed.Five particle migration regimes of local borehole failure,continuous collapse,wormhole expansion,extensive slow deformation,and pore-wall fluidization are proved to occur during depressurization.The types of particle migration regimes and their transmission modes during depressurization are predominantly determined by initial hydrate saturation.In contrast,the depressurization mainly dominates the transmission rate of the particle migration regimes.Furthermore,both the cumulative mass and the medium grain size of the produced sand decrease linearly with increasing initial methane hydrate(MH)saturation.Discontinuous gas bubble emission,expansion,and explosion during MH dissociation delay sand migration into the wellbore.At the same time,continuous water flow is a requirement for sand production during hydrate dissociation by depressurization.The experiments enlighten us that a constitutive model that can illustrate visible particle migration regimes and their transmission modes is urgently needed to bridge numerical simulation and field applications.Optimizing wellbore layout positions or special reservoir treatment shall be important for mitigating sand production tendency during NGH exploitation.
基金supported by the National Natural Science Foundation of China (Nos. 41806073, 41530963)the Natural Science Foundation of Shandong Province (No. ZR 2017BD014)+1 种基金the Shandong Provincial Key Laboratory of Depositional Mineralization & Sedimentary Minerals, Shandong University of Science and Technology (No. DMSM 2017042)the Fundamental Research Funds for the Central Universities (Nos. 201964016, 201851023)
文摘Many evidences for gas hydrate bearing sediments had been found in the continental slope of the East China Sea,such as bottom simulating reflections(BSRs),undersea gas springs,pyrite associated with methane leakage,mud diapirs/mud volcanos,bottom-water methane anomalies and so on.In this study,six key stratigraphic interfaces including T_0(seafloor),T_1(LGM,23 kyr B.P.),T_2(2.58 Myr),T_3(5.33 Myr),T_4(11.02 Myr)and T_5(16.12 Myr)were identified,and then five third-order sequences of SQIII1 to SQIII5 were divided.However,T5 in southern continental slope is not found,which shows that the middle-northern Okinawa Trough had begun to rift in the early Miocene,earlier than the southern segment.Four system tracts including lowstand systems tract(LST),transgressive systems tract(TST),highstand systems tract(HST)and falling stage systems tract(FSST)are further divided.The marine erosion interface of 11.02 Myr and regressive unconformity interface of 23 kyr B.P.indicate two large-scale sea level drop events in the research area.Seven typical seismic facies identified in the continental slope are continental shelf-edge deltas,littoral fluvial-delta plains,incised channels or submarine canyons,slope fans,submarine fans or coastal sandbars,littoral-neritic finegrained sediments,mud volcanos and some other geological bodies respectively.The minimum water depth for hydrate occurrence in the Okinawa Trough is 630 m,and the thickness of gas hydrate stability zone in continental slope is between 0 and 590 m.The calculated bottom boundary of hydrate stability zone is slightly deeper than BSRs on the seismic sections.The re-depositional turbidite sand bodies,such as canyon channels,slope fans and submarine fans developed in Quaternary strata,are the predominant hydrate reservoirs.According to developing process,the dynamic accumulation of hydrate systems can be divided into three evolutionary stages including canyon erosion and hydrate stability zone migration stage,sediments destabilizing and methane leakage stage,and channel filling and hydrate re-occurrence stage.
基金supported by Prospecting and Testing Production Project of Gas Hydrate resources, Ministry of Land and Resources of China (grants No. GZHL20110317, GZHL20110320, GZHL20110322)
文摘The Mohe permafrost in northeast China possesses favorable subsurface ambient temperature, salinity, Eh values and pH levels of groundwater for the formation of microbial gas, and the Mohe Basin contains rich organic matter in the Middle Jurassic dark mudstones. This work conducted gas chromatography and isotope mass spectrometry analyses of nearly 90 core gas samples from the Mk-2 well in the Mohe Basin. The results show that the dryness coefficient(C1/C1–5) of core hydrocarbon gas from approximately 900 m intervals below the surface is larger than 98%, over 70% of the δ13 C values of methane are smaller than-55‰, and almost all δD values of methane are smaller than-250‰, indicative of a microbial origin of the gas from almost 900 m of the upper intervals in the Mohe permafrost. Moreover, the biomarker analyses of 72 mudstone samples from the Mohe area indicate that all of them contain 25-norhopane series compounds, thereby suggesting widely distributed microbial activities in the permafrost. This work has confirmed the prevailing existence of microbial gas in the Mohe area, which may be a potential gas source of gas hydrate formation in the Mohe permafrost. This result is of great significance to gas hydrate accumulation in the permafrost across China.
基金Supported by the China National Science and Technology Major Project(2017ZX05008-006)
文摘Migration and accumulation simulation of oil and gas in carrier systems has always been a difficult subject in the quantitative study of petroleum geology. In view of the fact that the traditional geological modeling technology can not establish the interrelation of carriers in three dimensional space, we have proposed a hybrid-dimensional mesh modeling technology consisting of body(stratum), surfaces(faults and unconformities), lines and points, which provides an important research method for the description of geometry of sand bodies, faults and unconformities, the 3 D geological modeling of complex tectonic areas, and the simulation of hydrocarbon migration and accumulation. Furthermore, we have advanced a 3 D hydrocarbon migration pathway tracking method based on the hybrid-dimensional mesh of the carrier system. The application of this technology in western Luliang Uplift of Junggar Basin shows that the technology can effectively characterize the transport effect of fault planes, unconformities and sand bodies, indicate the hydrocarbon migration pathways, simulate the process of oil accumulation, reservoir adjustment and secondary reservoir formation, predict the hydrocarbon distribution. It is found through the simulation that the areas around the paleo-oil reservoir and covered by migration pathways are favorable sites for oil and gas distribution.
基金supported by the National Major Fundamental and Development Project of China (No. 2009CB219501)the National Natural Science Foundation of China (No. 41202099)
文摘The Shenhu gas hydrate drilling area is located in the central Baiyun sag, Zhu I! depression, Pearl River Mouth basin, northern South China Sea. The gas compositions contained in the hydrate-bearing zones is dominated by methane with content up to 99.89% and 99.91%. The carbon isotope of the methane (δ^13C1) are -56.7%0. and -60.9%0, and its hydrogen isotope (δD) are -199%0 and -180%0, respectively, indicating the methane from the microbial reduction of CO2. Based on the data of measured seafloor temperature and geothermal gradient, the gas formed hydrate reservoirs are from depths 24-1699 m below the seafloor, and main gas-generation zone is present at the depth interval of 416-1165 m. Gas-bearing zones include the Hanjiang Formation, Yuehai Formation, Wanshan Formation and Quaternary sediments. We infer that the microbial gas migrated laterally or vertically along faults (especially interlayer faults), slump structures, small-scale diapiric structures, regional sand beds and sedimentary boundaries to the hydrate stability zone, and formed natural gas hydrates in the upper Yuehai Formation and lower Wanshan Formation, probably with contribution of a little thermogenic gas from the deep sedments during this process.
基金supported by the"973"Project (2005CB422105)the Program for Changjiang Scholars and Innovative Research Team at the University (PCSIRT IRT0658).
文摘Solid bitumens were found throughout the carbonate reservoirs in the Puguang gas field, the largest gas field so far found in marine carbonates in China, confirming that the Puguang gas field evolved from a paleo-oil reservoir. The fluid conduit system at the time of intensive oil accumulation in the field was reconstructed, and petroleum migration pathways were modeled using a 3-D model and traced by geochemical parameters. The forward modeling and inversion tracing coincided with each other and both indicated that oils accumulated in the Puguang-Dongyuezhai structure originated from a generative kitchen to the northwest of the Puguang gas field. The deposition of organic-rich Upper Permian source rocks dominated by sapropelic organic matter in the Northeast Sichuan Basin, the development of fluid conduit system that was vertically near-source rock and laterally near-generative kitchen, and the focusing of oils originated from a large area of the generative kitchen, were the three requirements for the formation of the giant paleo-oil reservoir from which the giant Puguang gas field evolved. The Puguang gas field had experienced a three-stage evolution. The post-accumulation processes, especially the organic-inorganic interaction in the hydrocarbon-water-rock system, had not only profoundly altered the composition and characteristics of the petroleum fluids, but also obviously changed the physicochemical conditions in the reservoir and resulted in complicated precipitation and solution of carbonate minerals.
基金supported by CNPC Scientific Research and Technology Development Project“Whole petroleum system theory and unconventional hydrocarbon accumulation mechanism”(2021DJ0101).
文摘The prediction of continental tight sandstone gas sweet spots is an obstacle during tight sandstone gas exploration. In this work, the classic physical fluid charging experimental equipment is improved, the combination of the gas migration and accumulation process with the pore network numerical simulation method is investigated, and application of the permeability/porosity ratio is proposed to predict the gas saturation and sweet spots of continental formations. The results show that (1) as the charging pressure increases, the permeability of the reservoir increases because more narrow pore throats are displaced in the percolation process;and (2) based on pore network numerical simulation and theoretical analysis, the natural gas migration and accumulation mechanisms are revealed. The gas saturation of tight sandstone rock is controlled by the gas charging pressure and dynamic percolation characteristics. (3) The ratio of permeability/porosity and fluid charging pressure is proposed to predict the gas saturation of the formation. The ratio is verified in a pilot and proven to be applicable and practical. This work highlights the tight sandstone gas migration and accumulation mechanisms and narrows the gap among microscale physical experiments, numerical simulation research, and field applications.
基金funded by the National Natural Science Foundation of China(grants No.41406080,41273066 and 41106060)
文摘Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloor topographic highs. Many gas hydrate exploration examples abroad also indicate that the saturation of gas hydrates was higher at seafloor topographic highs. This work aims to understand why gas hydrates accumulated at topographic highs and why their saturation is higher.
基金supported by the National Natural Science Foundation of China (grants No.41576048,41202080 and 41176052)the Open Fund of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Chengdu University of Technology) (grant No.PLC201402)+1 种基金the Youth Innovation Promotion Association CAS (2016312)the Scientific Cooperative Project by CNPC and CAS (2015A-4813)
文摘The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T conditions, geophysical anomalies and saturation calculations of these gas hydrates, but has not documented in detail the migration of gas-bearing fluids in the study area. Based on the interpretations of 2D/3D seismic data, this work identified two types of migration pathways for gas-bearing fluids in the Shenhu area, i.e., vertical and lateral pathways. The vertical pathways(largescale faults, gas chimneys and mud diapirs) presented as steep seismic reflection anomalies, which could be traced downward to the Eocene source rocks and may penetrate into the Late Miocene strata. The deeper gases/fluids might be allowed migrating into the shallower strata through these vertical conduits. However, the distributions showed distinct differences between these pathways. Large-scale faults developed only in the north and northeast of the Shenhu area, while in the drilling area gas chimneys were the sole vertical migration pathways. Since the Pliocene, normal faults, detachment faults and favorable sediments have constituted the lateral pathways in the Shenhu gas hydrate drilling area. Although these lateral pathways were connected with gas chimneys, they exerted different effects on hydrate formation and accumulation. Gas-bearing fluids migrated upward along gas chimneys might further migrate laterally because of the normal faults, thereby enlarging the range of the chimneys. Linking gas chimneys with the seafloor, the detachment faults might act as conduits for escaping gases/fluids. Re-deposited sediments developed at the early stage of the Quaternary were located within the gas hydrate stability zone, so hydrates would be enriched in these favorable sediments. Compared with the migration pathways(large-scale faults and mud diapirs) in the LW3-1 deep-sea oil/gas field, the migration efficiency of the vertical pathways(composed of gas chimneys) in the gas hydrate drilling area might be relatively low. Description and qualitative discrimination of migration pathways in the Shenhu gas hydrate drilling area are helpful to further understand the relationship between good-quality deep source rocks and shallow, mainly biogenicallyproduced, hydrates. As the main source rocks of the Baiyun sag, lacustrine mudstones in the Wenchang and Enping Formations may provide thermogenic methane. Gas chimneys with relatively low migration efficiency created the vertical pathways. Caused by the Dongsha tectonic movement, the release of overpressured fluids might reduce the vertical migration rates of the thermogenic methane. The thick bathyal/abyssal fine-grained sediments since the Late Miocene provided migration media with low permeability. These preconditions may cause carbon isotopic fractionation ofthermogenic methane during long-distance vertical migrations. Therefore, although geochemical analyses indicate that the methane forming gas hydrate in the Shenhu area was mainly produced biogenically, or was mixed methane primarily of microbial origin, thermogenic methane still contribute significantly.
基金supported by the National 973 Basic Research Program(Grant No.2006CB202308)the Major National Science and Technology Program (2008ZX05008-004-012)
文摘The Kuqa foreland basin is an important petroliferous basin where gas predominates. The Kela-2 large natural gas reservoir and the Yinan-2, Dabei-1, Tuzi and Dina-11 gas reservoirs have been discovered in the basin up to the present. Natural gases in the Kelasu district and the Yinan district are generated from different source rocks indicated by methane and ethane carbon isotopes. The former is derived from both Jurassic and Triassic source rocks, while the latter is mainly from the Jurassic. Based on its multistage evolution and superposition and the intense tectonic transformation in the basin, the hydrocarbon charging history can be divided into the early and middle Himalayan hydrocarbon accumulation and the late Himalayan redistribution and re-enrichment. The heavier carbon isotope composition and the high natural gas ratio of C1/C1-4 indicate that the accumulated natural gas in the early Himalayan stage is destroyed and the present trapped natural gas was charged mainly in the middle and late Himalayan stages. Comparison and contrast of the oils produced in the Kelasu and Yinan regions indicate the hydrocarbon charging histories in the above two regions are complex and should be characterized by multistage hydrocarbon migration and accumulation.
基金supported by the National Key Research and Development Plan of China(2021YFC2800902)the National Natural Science Foundation of China(52206076,U19B2005)+1 种基金the Fundamental Research Funds for the Central Universities of China(DUT21ZD103)the Opening Fund of MOE Key Laboratory of Ocean Energy Utilization and Energy Conservation(LOEC-202204).
文摘Gas and water migration through the hydrate-bearing sediment are characteristic features in marine gas hydrate reservoirs worldwide.However,there are few experimental investigations on the effect of water-gas flow on the gas hydrate reservoir.In this study,gas-water migration in gas hydrate stability zone(GHSZ)was investigated visually employing a high-resolution magnetic resonance imaging(MRI)apparatus,and the formation of hydrate seal was experimentally investigated.Results revealed that normal flow of gas-water at the low flow rate of 1–0.25 mL/min will induce the hydrate reformation.Conversely,higher gas-water flow rates(at 2–0.5 and 4–1 mL/min)need higher reservoir pressure to induce the hydrate reformation.In addition,the hydrate reformation during the gas-water flow process produced the hydrate seal,which can withstand an over 9.0 MPa overpressure.This high overpressure provides the development condition for the underlying gas and/or water reservoir.A composite MRI image of the whole hydrate seal was obtained through the MRI.The pore difference between hydrate zone and coexistence zone produces a capillary sealing effect for hydrate seal.The hydrate saturation of hydrate seal was more than 51.6%,and the water saturation was more than 19.3%.However,the hydrate seal can be broken through when the overpressure exceeded the capillary pressure of the hydrate seal,which induced the sudden drop of reservoir pressure.This study provides a scientific explanation for the existence of high-pressure underlying gas below the hydrate layer and is significant for the safe exploitation of these common typical marine hydrate reservoirs.
基金The Taishan Scholar Special Experts Project of Shandong Province under contract No.ts201712079the National Natural Science Foundation of China under contract No.41976074the National Key Research and Development Program of China under contract No.2018YFE0126400。
文摘Laboratory visual detection on the hydrate accumulation process provides an effective and low-cost method to uncover hydrate accumulation mechanisms in nature.However,the spatial hydrate distribution and its dynamic evolutionary behaviors are still not fully understood due to the lack of methods and experimental systems.Toward this goal,we built a two-dimensional electrical resistivity tomography(ERT)apparatus capable of measuring spatial and temporal characteristics of hydrate-bearing porous media.Beach sand(0.05–0.85 mm)was used to form artificial methane hydrate-bearing sediment.The experiments were conducted at 1°C under excess water conditions and the ERT data were acquired and analyzed.This study demonstrates the utility of the ERT method for hydrate mapping in laboratory-scale.The results indicate that the average electrical conductivity decreases nonlinearly with the formation of the hydrate.At some special time-intervals,the average conductivity fluctuates within a certain scope.The plane conductivity fields evolve heterogeneously and the local preferential hydrate-forming positions alternate throughout the experimental duration.We speculate that the combination of hydrate formation itself and salt-removal effect plays a dominant role in the spatial and temporal hydrate distribution,as well as geophysical parameters changing behaviors during hydrate accumulation.
基金supported by National Natural Science Foundation of China(Grant Nos.41102021,41202099)National Special Research Fund(Grant No.GZHL20110308)
文摘A type of authigenic pyrites that fully fill or semi-fill the rock fractures of drillholes with gas hydrate anomalies are found in the Qilian Mountain permafrost; this type of pyrite is known as "fracture-filling" pyrite. The occurrence of "fracture-filling" pyrite has a certain similarity with that of the hydrate found in this region, and the pyrite is generally concentrated in the lower part of the hydrate layer or the hydrate anomaly layer. The morphology, trace elements, rare earth elements, and sulfur isotope analyses of samples from drillhole DK-6 indicate that the "fracture-filling" pyrites are dominated by cubic ones mainly aligned in a step-like fashion along the surfaces of rock fractures and are associated with a circular structure, lower Co/Ni and Sr/Ba, lower ZREE, higher LREE, significant Eu negative anomalies, and 634ScDT positive bias. In terms of the pyrites' unique crys- tal morphology and geochemical characteristics and their relationship with the hydrate layers or abnormal layers, they are closely related with the accumulation system of the gas hydrate in the Qilian Mountain permafrost. As climate change is an important factor in affecting the stability of the gas hydrate, formation of fracture-filling pyrites is most likely closely related to the secondary change of the metastable gas hydrate under the regional climate warming. The distribution intensity of these py- rites indicates that when the gas hydrate stability zone (GHSZ) is narrowing, the hydrate decomposition at the bottom of the GHSZ is stronger than that at the top of the GHSZ, whereas the hydrate decomposition within the GHSZ is relatively weak. Thus, the zone between the shallowest and the deepest distribution of the fracture-filling pyrite recorded the largest possible original GHSZ.
文摘With the guidance of petroleum system theory,the dynamic filling history of natural gas in the Kela-2 gasfield is analyzed by using a large suite of oil and gas geo-chemistry evidence in combination with the tectonic evolu-tion history and reservoir evolution history. It concludes thatthe Kela-2 gas field was formed by capturing the gas gener-ated during the main gas generation period, while the latekerogen cracking gas contributed a little to the gas field. Itsuggests that the gas generated during the main gas genera-tion accumulated in the early-formed wide-gentle anticline,which is the necessary condition for natural gas to re-migrateand enrich late to form the large-scale gas reservoir. Thenewest research shows that the filling history of gas in theDabei-1, Yinan-2, Tuziluoke and Dina-2 gas fields was re-lated with the natural gas accumulation in the early wide-gentle anticline as well as late re-migration and enrichmentof natural gas.
基金This research is supported by the Fundamental Research Funds for the Central Universities(No.15CX05036A,18CX05009A)the National Key Basic Research Program 973 project(No.2015CB251201)+2 种基金It is also partially financed by the National Major S&T Project(No.2016ZX05056004-003)the General Project of Shandong Natural Science Foundation(ZR2020ME090)the National Natural Science Foundation of China(No.51974347)。
文摘Seepage-type gas hydrate accumulation in subsea shallow formations involves complicated thermohydro-solid coupling processes and matching problem between various accumulation elements.Theformation physical properties control local natural gas migration pathway and thus the final reservoircharacteristics of hydrates.In this paper,a novel mixed-flux model for gas hydrate accumulation isestablished and then used to simulate the process of methane gas migration into the shallow stratum toform a hydrate reservoir.The effects of reservoir heterogeneity and gas source conditions on the distribution of pore fluid and hydrate accumulation are examined.The simulation results show thatreservoir heterogeneity is conducive to the retention and lateral migration of CH4 in a hydrate stabilityzone.CH4 can contact more pore water to form a large hydrate reserve,but the formed hydrate is oftendispersed.Low-permeability layers enhance the trapping of CH4 and form a uniform and large hydratesaturation.Besides,gas source conditions have an important impact on the hydrate accumulation inreservoirs.Large gas flux,small pore water flux,continuous gas supply,high content of heavy components in natural gas,and numerous gas source points contribute to large amounts of hydrates generationin a certain time period.The presented work will deepen our understanding of the controls of natural gashydrate systems in subea shallow formations.