Analysis of the Molecules Structure and Vertical Electron Affinity of Organic Gas Impact on Electric Strength

It is necessary to find an efficient selection method to pre-analyze the gas electric strength from the perspective of molecule structure and the properties for finding the alternative gases to sulphur hexafluoride （SF6）. As the properties of gas are determined by the gas molecule structure, the research on the relationship between the gas molecule structure and the electric strength can contribute to the gas pre-screening and new gas development. In this paper, we calculated the vertical electron affinity, molecule orbits distribution and orbits energy of gas molecules by the means of density functional theory （DFT） for the typical structures of organic gases and compared their electric strengths. By this method, we find part of the key properties of the molecule which are related to the electric strength, including the vertical electron affinity, the lowest unoccupied molecule orbit （LUMO） energy, molecule orbits distribution and negativeion system energy. We also listed some molecule groups such as unsaturated carbons double bonds （C=C） and carbonitrile bonds （C=N） which have high electric strength theoretically by this method.

THE STUDY ON MEASURING TECHNIQUE OF PARTIAL DISCHARGE IN GAS INSULATED SWITCHGEAR USING ULTRA HIGH FREQUENCY METHOD WITH EXTERNAL SENSORS

Objective In order to find early latent faults and prevent catastrophic failures, diagnosis of insulation condition by measuring technique of partial discharge(PD) in gas insulated switchgear (GIS) is applied in this paper, which is one of the most basic ways for diagnosis of insulation condition. Methods Ultra high frequency(UHF) PD detection method by using internal sensors has been proved efficient, because it may avoid the disturbance of corona, but the sensor installation of this method will be limited by the structure and operation condition of GIS. There are some of electromagnetic (E-M) waves leak from the place of insulation spacer, therefore, the external sensors UHF measuring PD technique is applied, which isn't limited by the operation condition of GIS. Results This paper analyzes propagated electromagnetic (E-M) waves of partial discharge pulse excited by using the finite-difference time-domain (FDTD) method. The signal collected at the outer point is more complex than that of the inner point, and the signals' amplitude of outer is about half of the inner, because it propagates through spacer and insulation slot. Set up UHF PD measuring system. The typical PD in 252kV GIS bus bar was measured using PD detection UHF technique with external sensors. Finally, compare the results of UHF measuring technique using external sensors with the results of FDTD method simulation and the traditional IEC60270 method detection. Conclusion The results of experiment shows that the UHF technique can realize the diagnosis of insulation condition, the results of FDTD method simulation and the result UHF method detection can demonstrate each other, which gives references to further researches and application for UHF PD measuring technique.

The effective ionization coefficients and electron drift velocities in gas mixtures of CF_3I with N_2 and CO_2 obtained from Boltzmann equation analysis

The electron swarm parameters including the density-normalized effective ionization coefficients（α-η）/N and the electron drift velocities V e are calculated for a gas mixture of CF3I with N2 and CO2 by solving the Boltzmann equation in the condition of a steady-state Townsend（SST） experiment.The overall density-reduced electric field strength is from 100 Td to 1000 Td（1 Td = 10-17V·cm2）,while the CF3I content k in the gas mixture can be varied over the range from 0% to 100%.From the variation of（αη）/N with the CF3I mixture ratio k,the limiting field strength（E/N） lim for each CF3I concentration is derived.It is found that for the mixtures with 70% CF3I,the values of（E/N） lim are essentially the same as that for pure SF 6.Additionally,the global warming potential（GWP） and the liquefaction temperature of the gas mixtures are also taken into account to evaluate the possibility of application in the gas insulation of power equipment.

Arcing Model of a Disconnector and its Effect on VFTO

In the computational process of very fast transient over-voltage （VFTO）, it is essen-tial to find an accurate model for a gas insulated substation. The arcing model of the disconnector is particularly important. The general arcing model is not able to give a good description of the arc development process. In this paper, based on the physical process of arcing and existing arc models （the exponential time-varying resistance model and the segmental arcing models）, a dy- namic arcing model is proposed, which is divided into two stages before and after the zero crossing. The dynamic arcing model combines hyperbola time-varying resistance and the Mayr model to describe the dynamic process of arcing. The present paper creates an arc model blockset upon the Matlab/Simulink software platform. Moreover for a specific 1100 kV station, VFTO is simulated in detail based on different arcing models. It is demonstrated that the dynamic arcing model can describe the physical arc process precisely and is useful for improving the accuracy of VFTO simulations.

GIS用超高频传感器的校准:不同校准方法的比较及一种采用锥形天线的校准系统测试(英文)

Different methods of calibrating ultra high frequency(UHF) sensors for gas-insulated substations(GIS) were investigated in the past.The first approach was to use strip lines,triplates and TEM calibration cells.These cells had already been in use for years for example to test the electromagnetic compatibility of electronic devices.The smaller the size of the cell,the higher its bandwidth-but the cell should be large enough to not disturb the electric field with the installed sensor under test.To overcome this problem,a calibration procedure using a gigahertz transverse electromagnetic (GTEM) test cell and a pulsed signal source were introduced in 1997.Although this procedure has many advantages and is easy to understand,measurements show several shortcomings of this calibration method.To overcome the disadvantages of the known systems,a calibration cell using a monopole cone antenna and a metallic ground plane were developed and tested.The UHF sensor was placed in a region with minimum distortion of the electric field due to its installation.Experience shows that the new method for calibrating UHF sensors is necessary in order to overcome the limits in the calibration of large sensors and to suppress the propagation of higher order modes and reflections.Due to its surprisingly simple structure,its low price and low overall measurement uncertainty,it is the preferred method for calibrating UHF sensors for GIS applications.

单壁碳纳米管气体传感器在GIS局部放电检测中的应用(英文)

This paper describes a realizable fabrication method to manufacture chemical gas sensors by using singlewalled carbon nanotubes(SWCNTs).The sensors were tested for the monitoring of SF_6 decomposition gas produced by partial discharge(PD) in GIS tank.The results showed a superior sensitivity,favorable reliability and good reproducibility. For further clarifying the relativity between sensor response and partial discharge activity,the discharge in GIS tank was monitored simultaneously through conventional pulse current method and a SWCNTs gas sensor,and the measurement results were put together for comparative analysis in this paper.The sensor response showed a great dependence on partial discharge characteristics.The sensor response increased nearly linearly with limits when the energy of discharge was persistently accumulated.Partial discharge power had a great influence on the response rate and the time delay.With the increase of partial discharge power,the response rate augmented almost in proportion while the time delay gradually becomes shorter with limits.The results were quite favorable to assess the partial discharge intensity and duration to some extent.Compared with pulse current method,the sensor was predominant to detect partial discharge exposed to constantly high levels of noise.It was capable of detecting partial discharge which was too weak to be detected with pulse current method.However,the sensor response didn't show much dependency on the apparent discharge of partial discharge.

佛山地区500kV变电站设备运行缺陷分析

对广东佛山地区500kV变电站运行设备从缺陷类别、发现方法、设备种类、出现原因、电压等级等方面进行了统计分析和总结,并提出了针对性较强的消缺和预防措施,对500kV变电站的运行管理、维护、建设有一定的指导意义。

浅论六氟化硫组合开关安装的管理

随着国民经济的发展需要,高压配电SF6的装置广泛应用于水电站、城区变电站。做好SF6的安装、维护,能保证电力系统的安全运行。

Discharge Characteristics of Long SF6 Gas Gap with and Without Insulator in GIS Under VFTO and LI

Gas insulator switchgears(GISs),widely used in electric power systems for decades,have many advantages due to their compactness,minimal environmental impact,and long maintenance cycles.However,very fast transient overvoltage(VFTO)increases caused by a rise in voltage levels can lead to GIS insulation failures.In this paper,a generating system of VFTO and standard lightning impulse(LI)is established.The insulation characteristics of SF6 gas with and without insulators under VFTO and standard LI are investigated.Experimental results show that the 50%breakdown voltages of the inhomogeneous electric field rod-plane gap under positive VFTO and standard LI are higher than that under negative VFTO and standard LI.The research shows that the 50%breakdown voltage under VFTO could be lower than that under standard LI at 0.5 MPa for the negative polarity.Moreover,the polarity effect of the insulator without defect is different from that with defect.Similarly,the breakdown voltage of the defective insulator under VFTO could be lower than that under standard LI by 8%.The flashover channel under VFTO is seen as more than that under standard LI.Based on the analysis of discharge images and experimental results,it is concluded that the polarity effect is related to the distortion effect of ion clusters formed by SF6 on the electric field.Additionally,the steepness and front time of impulse plays an important role in the initiation and further development of discharge on insulator surface.Finally,the research shows that different discharge characteristics between VFTO and standard LI may be caused by different wave fronts and oscillation on the tails of the impulses.

Estimation of the Type of Low Energy Discharge in GIS Adopting Characteristic Gas

In order to guarantee safe operations, low energy discharge within gas insulated switchgear （GIS） should be detected as soon as possible before they develop severely and cause final breakdown failures. This paper aims to present a GIS discharge diagnosis technique adopting gaseous decompositions. To reach this aim, needle-plate electrode and the sphere-plate electrode with metallic particles on the plate are designed to simulate two kinds of low energy discharge, namely, corona discharge and spark discharge, respectively. After sampling and analyzing the gases, different yields of gaseous by-products under different types of low energy discharge are obtained. Based on the decomposition mechanisms reported by previous researches and the experiment results, it can be concluded that S2OF10, SO2F2 , and SO2 can be used as the characteristic gas to identify low energy discharge; the increment of S2OF10 can indicate the occurrence of low energy discharges while the volume ratio between SO2F2 and SO2 can define the type of low energy discharge.

Review of Charge Accumulation on Spacers of Gas Insulated Equipment at DC Stress

Charge accumulation on the spacer surface in gas insulated equipment is very severe in the DC field,leading to easy flashover,which restricts the application of DC GIS/GIL.Therefore,knowledge about the charge accumulation characteristics of gas insulated equipment at DC stress is essential.In this paper,we reviewed the research methods and the characteristics of charge accumulation on spacers.A summary of charge measurement methods and setups are presented.And the surface charge inversion algorithms are introduced.Then the simulation model for charge accumulation in the DC field is reviewed.Subsequently,the charge accumulation mechanisms and phenomenon,the influence factor of surface charge accumulation and the influence of accumulated charge on spacer insulation characteristics are summarized.In addition,some suppression methods of surface charge accumulation are discussed.Finally,based on the understanding of charge accumulation on spacers,some suggestions on further studies are presented to aid in the design of a better spacer free from surface charges.

Environment-friendly Insulating Gases for HVDC Gas-insulated Transmission Lines

Environment-friendly gas insulating mediums adapted to a DC gas-insulated transmission line(GIL)electric field condition is the key to the next generation of Environment-friendly HVDC GILs.In this paper,we review the literature on sulfur hexafluoride(SF6)alternatives including the scientific understanding,control,and implementation of gas-solid systems in this type of power transmission.First,the structure-activity relationship between the molecular structure and physico-chemical properties of Environment-friendly insulating gases is presented.Then,the search and prediction of important physicochemical properties of gases are summarized.Subsequently,in view of the potential of environmental friendly insulating gases,the swarm parameters of gas discharge and breakdown properties in a quasi-uniform field,inhomogeneous field,and at the gas-solid interface,that need to be taken into account with industrialized DC GILs are discussed.The latest research progress on insulation characteristics,especially the polarity effect in DC gas-solid insulation systems,the sensitivity to the electrode surface state,and the non-uniformity of the electric field,and the influence of metal particles and their variation with air pressure,is highlighted.In addition,the heat transfer characteristics of insulating gases,related to DC GIL transmission with a large current-carrying capacity and the influence of alternative gases on the heat transfer characteristics are described.Finally,aiming at solving the contradiction of low environmental impact,high dielectric strength and low liquefaction temperatures in the selection of alternative gases,an coordinated regulation model for Environment-friendly gases in DC GILs is established.Considerations for future work on this topic are also presented.

A novel algorithm for frequency dependent modeling of ferrite ring and its optimum design to study VFTO behaviors within GIS

One of the fundamental issues in gas insulated substations （GIS） which has destructive effects on GIS equipment is the very fast transient over-voltages （VFTOs）. This paper models a 400/230 kV substation in order to study the effects of VFTO extensively implemen- ted on EMTP-RV. In addition, the application of ferrite rings for suppressing VFTOs is assessed thoroughly. The main advantage of this paper is its new proposed algorithm according to the ferrite ring frequency dependent modeling that is validated with experimental results. This paper examines the effects of three compositions of the ferrite ring on VFTO suppression. Moreover, it estimates the dimension of the ferrite ring based on the SF6 gas insulation withstand and the maximum effect of ferrite rings on VFTO suppression constraint with the COMSOL multiphysics software. Furthermore, it gains VFTO attenuated percentages due to the installation of the ferrite ring in different GIS nodes. Finally, it analyzes the offered VFTO amendment technique in various GIS switching scenarios.