Study on impact factors of tracer gas method in investigations of gaseous pollutant transport and building ventilation

Building ventilation is essential to discharge indoor pollutants and improve indoor air quality for occupant health.Tracer gas method is an efficient way in the field of building ventilation to measure ventilation rate and to evaluate the ventilation performance.Literature shows notable deviation of measured ventilation rate using different tracer gases.In the present study,CFD simulations are carried out to analyze He-,CO_(2)-and SF_(6)-based tracer gas methods.The effects of tracer gas density and release rate on the concentration distribution and ventilation effectiveness are studied.Various application scenarios of different ventilation rates and airflow distribution forms are compared.The results show that the deviation of ventilation effectiveness evaluated by different tracer gases can be above 2-4 times,and the error is introduced by non-passive dispersion.Whether tracer gas dispersion is passive or not depends on the relative importance of density difference driven mass transfer to forced convection mass transfer,which is due to the combined effects of density difference,release rate,and indoor airflow velocity,and can be judged by a dimensionless number θ.Under the geometry and ventilation settings in the present study,the critical value of θ is 1.0 for the error range of 5%,and 2.0 for the error range of 10%.When θ is below the critical value,the gas transport is passive and dominated by the indoor ventilation airflow.A release of tracer gas with smaller release rate and smaller density difference into a stronger indoor airflow behaves more passive.Heavier tracer gas tends to significantly overestimate the performance of upper supply and lower exhaust ventilation,and lighter tracer gas aggravates the overestimation of the performance for lower supply and upper exhaust ventilation.In mechanical ventilation rooms with air change rate of 3.0-6.0 h^(−1),a continuous release of tracer gas SF_(6),CO_(2) or He with release rate above 8 mg/s or source concentration above 8-75 ppm should not be considered as passive.This work clarified the passive and non-passive transport characteristics and mechanisms of various tracer gases,which is helpful for the engineering applications of tracer gas method in building ventilation studies.

Determination of Vapor Pressure of Liquid Copper by Carrier Gas Method

The relationship between the vapor pressure of liquid copper and the flow rate of carrier gas argon was discussed, when the carrier gas method was used to determine the vapor pressure of liquid copper at 1892 K. The proper argon flow rate range obtained was 150-500 mL/min and enough evidence was provided to verify the vapor pressure-flow rate of carrier gas relationship at the target temperature. Based on the proper flow rate range, the vapor pressure of liquid copper was measured at 1609-1892 K. The relationship of vapor pressure-temperature obtained by the method of regression analysis can be expressed as： In（p/Pa） = （25.470 -I- 0.903） - （39099.8 -4- 1574.5）/T, Further, the thermodynamic properties including the heat of vaporization and the Gibbs free energy of the Cu （I） = Cu （g） reaction were calculated by the vapor pressiJre obtained over the temperature range covered.

Hybrid Dissolved Gas-in-Oil Analysis Methods

Dissolved gas analysis is the most widely used diagnostic test in power transformers. The aim of this paper is to introduce the dissolved gas analysis (DGA) methods able to diagnose the transformer conditions. The faults cause the transformer oil, pressboard, and other insulating materials to decompose and generate gases, some of which dissolve in the oil. The results of DGA must be accurate if faults are to be diagnosed reliably. There are different established methods used in industry for interpreting DGA results. We will compare the result of IEEE Key Gas Methods and Rogers’ Ratios. The transformer conditions are evaluated by the Key Gas Method with total combustible gas method (TCGM) and then verified by the Rogers’ Ratios. As result, the aging pattern and trend of the power transformer deterioration can be determined. The 30 sample data from IEEE with known faults and dissolved gas concentrations were used as the basis of comparison.

Partitioning characteristics of gas channel of coal-rock mass in mining space and gas orientation method

In order to research the influence of coal-rock mass morphology of mining space on the flow law of gas,the laboratory physical model and numerical computation methods were adopted to simulate coal mining activities.The simulation results indicate that,after coal seam mining,the loose rock accumulation body of free caving,ordered rock arrangement body of plate damage rich in longitudinal and transverse fractures and horizontal fissure body formed by rock mass deformation imbalance are formed from bottom to top in the mining space.For these three types of accumulation bodies,there are essential differences in the accumulation state,rock size and gas breakover characteristics.According to this,the coal-rock mass in the mining space is classified into gas turbulence channel area,gas transitional flow channel area and gas seepage channel area.In the turbulence channel area,the gas is distributed transversely and longitudinally and gas diffuses in the form of convection with Reynolds number R_e more than100;in the transitional flow channel area,one-way or two-way gas channels are crisscross and gas is of transitional flow regime with R,.between 10 and 100.In the seepage channel area,there are a few vertical gas channels with R,.less than 10.In this paper,the researches on the gas orientation method in different partitions were further carried out,gas orientation methods of low-level pipe burying,middle-level interception and high-level extraction were determined and an on-site industrial test was conducted,achieving the effective diversion of gas and verifying the reasonableness of gas channel partition.

STUDY ON NANOMETER ZINC PARTICLES FABRICATED BY GAS EVAPORATION METHOD

Nanometer Zn particles with mean diameters 12-100nm made by evaporating its powders in argon gas were studied mainly by X-ray diffraction and electron microscopy. They are collected at various distances and those factors influencing the mean particle size were studied. The optimal synthetic conditions were obtained, i.e., evaporation temperature is 1200℃; argon flow rate is 0.4m3/h; amount of powder charged is 3g; distance from evaporation source is 10cm. It was found that the size of particles was governed by argon flow rate, evaporation temperature, amount of metal charged and distance from the source. The size increases remarkably with distance in the space where no metal vapor exists. This implies that the crystallites grow by coalescence. Electron micrographs and diffraction patterns are reproduced to show the size, shape and state of oxidations. Nanoparticles with definite crystal habits were sometimes observed among those with irregular ones.

Reliability of gas holdup measurements using the differential pressure method in a cyclone-static micro-bubble flotation column

Gas holdup is one of the key parameters in flotation process. Gas holdup as measured by a differential pressure method was investigated and the relative errors compared to the average gas holdup from the volume expansion method. The errors were used to establish optimum measurement positions. The results show that the measurement position should be in the middle of the column and in the region half way from the center to the wall (the half-radius). The gas holdup along the axial direction is lower at the bottom and higher at the top of the floatation column. The gas holdup along the radial direction is lower near the wall and higher near the center of the flotation column. The average gas holdup measure- ment can be replaced by regional gas holdup values.

INVESTIGATION OF THE PALEOGEOTHERMAL TECTONIC HISTORY ON DONGPU DEPRESSION AND OIL/GAS FORMATION BY FISSION-TRACK METHOD

Dongpu depression is a fault basin at residual-mobility period of Diwa stage, it developed on the strata of the Mesozoie and Pre-Mesozoie. It is one of the important oil/gas- bearing basin during Cenozoie era along the East China. The strueture in Dongpu geodepression is very complex. There exists a strueture pattern with east- and west-depression belts and one central swell belt, it is divided into the southern- and northern-division by Gaopingji (orMeng Ju ) -Xieheng fault.

Experimental study on gas uniformity at the inlets of six cyclones in a CFB with multi-tracer gas method

To investigate the non-uniform distribution of different gases passing through the parallel cyclones,experiments were conducted on a circulating fluidized bed(CFB)equipped with six asymmetrical cyclones.A multi-tracer gas method was used,with CO,O_(2),and CO_(2) chosen to represent gases with different properties in the flue gas at the inlets of the cyclones.The uniformity of multi-gas distribution was evaluated by measuring the concentration deviations of each tracer gas passing through individual cyclones.The results indicate that the concentrations of multi-tracer gases are higher in the middle cyclone among the three,which are located on the tracer gas injection side during the test of single-side secondary air(SA)tracing.The maximum concentration deviation of tracer gases is for CO_(2),while the minimum is for CO.At the three cyclone inlets on the opposite side,the tracer gas with higher density exhibits a more uniform distribution,and the gas uniformity decreases as the density decreases.The effects of superficial velocity,SA ratio,bed inventory,and tracer gas injection region on the uniformity of gas distribution were studied.The results show that superficial velocity and SA ratio primarily affect the uniformity of higher density gases,while bed inventory has a greater influence on lower density gases.The gas distributions are most non-uniform,especially for CO_(2),when the tracer gas injection region is near the rear wall closer to the induced draft fan during the test of regional SA tracing.

Initial estimation of hydrate formation temperature of sweet natural gases based on new empirical correlation

Production,processing and transportation of natural gases can be significantly affected by clathrate hydrates.Knowing the gas analysis is crucial to predict the right conditions for hydrate formation.Nevertheless,Katz gas gravity method can be used for initial estimation of hydrate formation temperature （HFT） under the circumstances of indeterminate gas composition.So far several correlations have been proposed for gas gravity method,in which the most accurate and reliable one has belonged to Bahadori and Vuthaluru.The main objective of this study is to present a simple and yet accurate correlation for fast prediction of sweet natural gases HFT based on the fit to Katz gravity chart.By reviewing the error analysis results,one can discover that the new proposed correlation has the best estimation capability among the widely accepted existing correlations within the investigated range.

The coalbed methane production potential method for optimization of wells location selection

A gas production potential method for optimization of gas wellsite locations selection is proposed in terms of the coalbed gas resources volume and the recoverability. The method uses the actual data about reservoirs in a coalbed gas field in central China to optimize wellsite locations in the studied area in combination with the dynamic data about actual production in the coalbed gas field, selects a favorable subarea for gas wells deployment. The method is established based on the basic properties of coal reservoirs, in combination with the coalbed thickness and the gas content to make an analysis of the gas storage potential of a coal reservoir, as well as resources volume and the permeability of a coal reservoir. This method can be popularized for optimization of wellsite locations in other methane gas development areas or blocks.

Numerical simulation of flow in Hartmann resonance tube and flow in ultrasonic gas atomizer

The gas flow in the Hartmann resonance tube is numerically investigated by the finite volume method based on the Roe solver. The oscillation of the flow is studied with the presence of a needle actuator set along the nozzle axis. Numerical results agree well with the theoretical and experimental results available. Numerical results indicate that the resonance mode of the resonance tube will switch by means of removing or adding the actuator. The gas flow in the ultrasonic gas atomization （USGA） nozzle is also studied by the same numerical methods. Oscillation caused by the Hartmann resonance tube structure, coupled with a secondary resonator, in the USGA nozzle is investigated. Effects of the variation of parameters on the oscillation are studied. The mechanism of the transition of subsonic flow to supersonic flow in the USGA nozzle is also discussed based on numerical results.

Molecular Simulations of FCC Dry Gas Components Adsorption in Zeolite Y

Adsorption of FCC dry gas components, hydrogen(H_2), nitrogen(N_2), methane(CH_4), ethane(C_2H_6) and ethylene(C_2H_4) in zeolite Y was studied by performing the Grant Canonical Monte Carlo(GCMC) simulations at 298K and 823K and under a pressure range up to 10 MPa. Simulation results were analyzed using the Langmuir model, which presented fitting of dry gas components adsorption to be suggested as the monolayer adsorption. C_2H_4 presented most single adsorption amount, which reached 7.63 mol/kg at 298K under a pressure of 200kPa. Thermodynamic parameters of the Gibbs free energy change, enthalpy change and entropy change were analyzed based on adsorption equilibrium constant obtained from the GCMC simulations. The results suggested that it was more favorable for C_2H_4 to be adsorbed in zeolite Y. Adsorption molecules were in ordered arrangement in the zeolite, and C_2H_4 exhibited a more orderly arrangement than other components. Additionally, a competition in the adsorption of a mixture of dry gas components was found, and supercages were the priority adsorption space. The competition was favorable to CH_4 and C_2H_6, and the competitive power was affected by temperature.

A statistical method for assessment of the existing correlations of hydrate forming conditions

Hydrate formation in the oil and gas industries has been a serious problem for a long time. It may cause many difficulties for instance in gas pipelines blockages. In order to determine the hydrate forming condition, gas gravity method has been used. Several correlations have been proposed based on gas gravity method. Checking the accuracy of the applied correlations is important. In this paper, the leverage approach is used for this purpose. Leverage approach is a statistical method for detection outliers which identifies the applicability domain （AD） of hydrate data predicting correlations and the quality of the existing data. Moreover, the Williams plot is sketched, which is a graphical depiction for determination of the doubtful points. The obtained results showed the existing correlations are all statistically correct and valid to predict hydrate formation temperature, just one data point is out of the applicability domains, and none of the experimental data can be chosen as outliers.

EFFECT OF OXYGEN CONTENTS ON OXYGEN POTENTIALS OF H_2O-H_2 AND H_2O-H_2-INERTS GAS MIXTURES

By taking the effect of oxygen contents into account,a new set of formulae which represents the oxygen potentials of H_2O-H_2 and H_2O-H_2-inerts gas mixtures has been derived.Classi- cal representation is only a particular case of it.Some of the variables affecting equilibrium atmosphere when trace oxygen is present and optimum preparation of the gas mixtures to min- imize errors have been discussed.The reliability of some of previous equilibrium experiments under the oxygen potentials controlled by H_2O-H_2 or H_2O-H_2-inerts gas mixtures has also been criticized.

Technique and experiment of active direct gas pressure measurement in coal roadway

An active measurement method and its principle was introduced consideringthe low success rate,special difficulty,and long measurement time of the direct gas pressuremeasurement currently used in coal roadways.The technology of drilling,boreholesealing depth,borehole sealing length,sealing control of the measuring process,compensatorycomputation of gas loss quantity and other key techniques were discussed.Finally,based on the latest instrument the authors developed,a series of experiments of directgas pressure measurement in the coal roadways of the Jincheng and Tongchuanmine district,were carried out.The experimental results show that active gas pressuremeasurement technique has advantages as follows:(1) the application scope of direct gaspressure measurement technique is wide and it does not have the restriction of coalhardness,coal seam fissure and other conditions;(2) the measured results are credible,which can be tested by the same gas pressure value acquired from a different borehole inthe same place;(3) the measurement process is convenient and quick,it takes about 2 to3 days to acquire the gas pressure value in a coal seam.

Monte Carlo study of the universal area distribution of clusters in the honeycomb O(n) loop model

We investigate the area distribution of clusters （loops） in the honeycomb O（n） loop model by means of the worm algorithm with n = 0.5, 1, 1.5, and 2. At the critical point, the number of clusters, whose enclosed area is greater than A, is proportional to A-1 with a proportionality constant C. We confirm numerically that C is universal, and its value agrees well with the predictions based on the Coulomb gas method.

The mass and heat transfer process through the door seal of refrigeration

As one of the main reasons causing leakage heat load in a refrigerator,mass and heat transfer through refrigerator door seal is of great importance to be studied.In this paper,a model is presented for numerical simulation of mass and heat transfer process through refrigerator door seal,and an experiment apparatus is designed and set up as well for comparison.A two-dimensional model and tracer gas method are used in simulation and experiment,respectively.It can be found that the relative deviations of air infiltration rate between the simulated results and experimental results were less than 1%,and the temperature difference errors at two special points of the door seal were less than 2.03℃.In conclusion,the simulated results are in good agreement with the experimental results.This paper initially sets up a model that can accurately simulate the heat and mass transfer through the refrigerator door seal,and the model can be used in refrigerator door seal optimization research in the follow-up study.

Overload type and optimization of meadow carrying capacity in Maqin County in the Three-River Source Region,China

Alpine meadows,comprising the main ecosystem of the Three-River Source Region,play an important role in the economic development of western pastoral areas.To determine whether the grazing level was too intense or the nutrient-carrying capacity of the meadows was overloaded,and to offer solutions in Maqin County,Qinghai Province,China,the meadows carrying capacity was determined by combining grass-yield and nutrients data for different seasons across different meadows.The results showed that the levels of crude protein(CP),ether extract(EE),ash,soluble sugars(SS),gas production,and energy value of forage in the summer–autumn grazing meadows were higher than those of the winter–spring meadows.Neutral detergent fiber(NDF)and acid detergent fiber(ADF)of forage in the summer–autumn grazing meadows were lower than those of the winter–spring meadows.We found that no pastures were overloaded with metabolizable energy(ME)for the whole year but digestible crude protein(DCP)was overloaded in winter–spring.And there were differences in the amount carrying capacity(forage yield)of seasonal grazing meadows for the different herds,the overload types were annual overloading(herd A),overloaded in summer–autumn(herd B),overloaded in winter–spring(herd C),and not overloaded(herd D).Compared with the previous grazing mode,theoretical carrying capacity,DCP carrying capacity,and ME carrying capacity of herd A increased by 20,19,and 27 sheep units,respectively,after optimization;herd B:36,31,and 45 sheep units,respectively;herd C:28,23,and 44 sheep units,respectively;and herd D:43,40,and 61 sheep units,respectively.In the Three-River Source Region and similar alpine pastoral areas,the grassland-livestock structure should be optimized to improve grassland vegetation status and increase the theoretical carrying capacity.

Analysis of gas-solid flow and shaft-injected gas distribution in an oxygen blast furnace using a discrete element method and computational fluid dynamics coupled model

lronmaking using an oxygen blast furnace is an attractive approach for reducing energy consumption in the iron and steel industry. This paper presents a numerical study of gas-solid flow in an oxygen blast fur- nace by coupling the discrete element method with computational fluid dynamics. The model reliability was verified by previous experimental results. The influences of particle diameter, shaft tuyere size, and specific ratio （X） of shaft-injected gas （51G） flowrate to total gas flowrate on the SIC penetration behavior and pressure field in the furnace were investigated. The results showed that gas penetration capacity in the furnace gradually decreased as the particle diameter decreased from 100 to 40 mm. Decreasing particle diameter and increasing shaft tuyere size both slightly increased the SIG concentration near the furnace wall but decreased it at the furnace center. The value of X has a significant impact on the SIG distribution. According to the pressure fields obtained under different conditions, the key factor affecting SIG penetration depth is the pressure difference between the upper and lower levels of the shaft tuyere. If the pressure difference is small, the SIG can easily penetrate to the furnace center.

Impacts of climate change on seasonal extreme waves in the Northwest Atlantic using a Spatial Neural Gas clustering method

Having estimates of wave climate parameters and extreme values play important roles for a variety of different societal activities,such as coastal management,design of inshore and offshore structures,marine transport,coastal recreational activities,fisheries,etc.This study investigates the efficiency of a state-of-the-art spatial neutral gas clustering method in the classification of wind/wave data and the evaluation of extreme values of significant wave heights(Hs),mean wave direction(MWD)and mean wave periods(T0)for two 39-year time periods;from 1979 to 2017 for the present climate,and from 2060 to 2098,for a future climate change scenario in the Northwest Atlantic.These data were constructed by application of a numerical model,WAVEWATCHIII TM(hereafter,WW3),to simulate the wave climate for the study area for both present and future climates.Data from the model was extracted for the wave climate,in terms of the wave parameters,specifically Hs,MWD and T0,which were analyzed and compared for winter and summer seasons,for present and future climates.In order to estimate extreme values in the study area,a Natural Gas(hereafter,NG)clustering method was applied,separate clusters were identified,and corresponding centroid points were determined.To analyze data at each centroid point,time series of wave parameters were extracted,and using standard stochastic models,such as Gumbel,exponential and Weibull distribution functions,the extreme values for 50 and 100-year return periods were estimated.Thus,the impacts of climate change on wave regimes and extreme values can be specified.