The sol-gel method was used to prepare the nanocrystalline Gd_（1–x）Ca_xFeO_3 （x=0–0.4） powders. The XRD results showed that all the Gd_（1–x）Ca_xFeO_3 （x=0–0.4） compounds crystallized as perovskite phase wi...The sol-gel method was used to prepare the nanocrystalline Gd_（1–x）Ca_xFeO_3 （x=0–0.4） powders. The XRD results showed that all the Gd_（1–x）Ca_xFeO_3 （x=0–0.4） compounds crystallized as perovskite phase with orthorhombic structure. The doping of Ca in GdFeO_3 not only reduced the resistance, but also enhanced the response to methanol. The Gd_（0.9）Ca_（0.1）FeO_3 showed the best response to methanol among Gd_（1–x）Ca_xFeO_3 sensors. Besides, it showed good selectivity to methanol among methanol, ethanol, CO and formaldehyde gases. The responses at 260 oC for Gd_（0.9）Ca_（0.1）FeO_3-based sensor to 600 ppm methanol, ethanol and CO gases were 117.7, 72.7 and 31.9, respectively. Even at quite low gas concentrations, Gd_（0.9）Ca_（0.1）FeO_3-based sensor had an obvious response. At 260 °C, the response of 1.54 was obtained to be 45 ppm methanol. The experimental results showed that nanocrystalline Gd_（0.9）Ca_（0.1）FeO_3 based sensor can be used to detect methanol gas.展开更多
基金Project supported by National Natural Science Foundation of China(51602035,51472145,51272133)the Fundamental Research Funds for the Central Universities(DUT16RC(4)69)
文摘The sol-gel method was used to prepare the nanocrystalline Gd_（1–x）Ca_xFeO_3 （x=0–0.4） powders. The XRD results showed that all the Gd_（1–x）Ca_xFeO_3 （x=0–0.4） compounds crystallized as perovskite phase with orthorhombic structure. The doping of Ca in GdFeO_3 not only reduced the resistance, but also enhanced the response to methanol. The Gd_（0.9）Ca_（0.1）FeO_3 showed the best response to methanol among Gd_（1–x）Ca_xFeO_3 sensors. Besides, it showed good selectivity to methanol among methanol, ethanol, CO and formaldehyde gases. The responses at 260 oC for Gd_（0.9）Ca_（0.1）FeO_3-based sensor to 600 ppm methanol, ethanol and CO gases were 117.7, 72.7 and 31.9, respectively. Even at quite low gas concentrations, Gd_（0.9）Ca_（0.1）FeO_3-based sensor had an obvious response. At 260 °C, the response of 1.54 was obtained to be 45 ppm methanol. The experimental results showed that nanocrystalline Gd_（0.9）Ca_（0.1）FeO_3 based sensor can be used to detect methanol gas.
