A solution of 0.1 mol/L to 1.0 mol/L H2SO4 can dissolve alkali metals and alkaline earth metals which weaken an active site of SCR catalyst. The waste catalyst washed with 0.5 mol/L H2SO4 regained the best catalytic a...A solution of 0.1 mol/L to 1.0 mol/L H2SO4 can dissolve alkali metals and alkaline earth metals which weaken an active site of SCR catalyst. The waste catalyst washed with 0.5 mol/L H2SO4 regained the best catalytic activity. When a concentration of the sulfuric acid is less than 0.5 mol/L, sufficient cleaning effects cannot be obtained. In contrast, when the concentration is greater than 1.0 tool/L, the active components, vanadium and tungsten are undesirably eluted. The total BET surface of the catalyst regenerated by air lift loop reactor showed almost the same as that of fresh catalyst due to the removal of insoluble compounds which may be penetrated into pores of catalyst. The addition of a solution of 0.075 mol/L ammonium vanadate （NHnVO3） and 0.075 mol/L ammonium paratungstate （5（NH4）20· 12WO3-5H20） to 0.1 mol/L H2SO4 significantly increases the activity of the waste catalyst.展开更多
To study the gas-solid flow characteristics in a chemical looping combustion system integrated with a moving bed air reactor,a 3D full-loop numerical model was established using the Eulerian-Eulerian approach integrat...To study the gas-solid flow characteristics in a chemical looping combustion system integrated with a moving bed air reactor,a 3D full-loop numerical model was established using the Eulerian-Eulerian approach integrated with the kinetic theory of granular flow.The solid circulation mechanism and gas leakage performance were studied in detail.The simulation results showed that in the start-up process,the solid circulation rate first increased to approximately 5 kg/s and then dropped to approximately 1.2 kg/s;this observation was related to the dynamic control of the pressure distribution.In this system,the gas leakage between the inertial separator,upper air reactor,and lower air reactor was restrained by adjusting the pressure difference,thus obtaining optimal gas flow paths.When the pressures at the outlets of the inertial separator,upper air reactor,and lower air were 7.4,11.0,and 14.6 kPa,respectively,the gas leakage ratio was less than 1%in the system.展开更多
基金Project(2009T100100602) supported by the Korea Institute of Energy Technology Evaluation and Planning,Korea
文摘A solution of 0.1 mol/L to 1.0 mol/L H2SO4 can dissolve alkali metals and alkaline earth metals which weaken an active site of SCR catalyst. The waste catalyst washed with 0.5 mol/L H2SO4 regained the best catalytic activity. When a concentration of the sulfuric acid is less than 0.5 mol/L, sufficient cleaning effects cannot be obtained. In contrast, when the concentration is greater than 1.0 tool/L, the active components, vanadium and tungsten are undesirably eluted. The total BET surface of the catalyst regenerated by air lift loop reactor showed almost the same as that of fresh catalyst due to the removal of insoluble compounds which may be penetrated into pores of catalyst. The addition of a solution of 0.075 mol/L ammonium vanadate （NHnVO3） and 0.075 mol/L ammonium paratungstate （5（NH4）20· 12WO3-5H20） to 0.1 mol/L H2SO4 significantly increases the activity of the waste catalyst.
基金The National Natural Science Foundation of China(No.51976034)China Postdoctoral Science Foundation(No.2020M681455)+2 种基金the National Key R&D Program of China(No.2018YFC1901200)Jiangsu Planned Projects for Postdoctoral Research Fundsthe Fundamental Research Funds for the Central Universities.
文摘To study the gas-solid flow characteristics in a chemical looping combustion system integrated with a moving bed air reactor,a 3D full-loop numerical model was established using the Eulerian-Eulerian approach integrated with the kinetic theory of granular flow.The solid circulation mechanism and gas leakage performance were studied in detail.The simulation results showed that in the start-up process,the solid circulation rate first increased to approximately 5 kg/s and then dropped to approximately 1.2 kg/s;this observation was related to the dynamic control of the pressure distribution.In this system,the gas leakage between the inertial separator,upper air reactor,and lower air reactor was restrained by adjusting the pressure difference,thus obtaining optimal gas flow paths.When the pressures at the outlets of the inertial separator,upper air reactor,and lower air were 7.4,11.0,and 14.6 kPa,respectively,the gas leakage ratio was less than 1%in the system.
