Photomineralization of methane in air(10.0-1,000 ppm(mass/volume)of C)at 100%relative humidity(dioxygen as oxygen donor),was systematically studied at 318±3 K,in an annular laboratory-scale reactor,by photocataly...Photomineralization of methane in air(10.0-1,000 ppm(mass/volume)of C)at 100%relative humidity(dioxygen as oxygen donor),was systematically studied at 318±3 K,in an annular laboratory-scale reactor,by photocatalytic membranes immobilising titanium dioxide and tungsten trioxide as co-photocatalysts.Kinetics of both substrate disappearance,to yield intermediates,and total organic carbon(TOC)disappearance,to yield carbon dioxide,were followed.A kinetic model was employed,from which,by a set of differential equations,four final optimised parameters,k1 and K1,k2 and K2,were calculated,able to fit the whole kinetic profile adequately.Modelling of quantum yields,as a function of substrate concentration and irradiance,as well as of concentration of photocatalysts,was carried out very satisfactorily.Kinetics of hydroxyl radicals reacting between themselves,leading to hydrogen peroxide,other than with substrate or intermediates leading to mineralization,were considered,paralleled by second competition kinetics involving superoxide radical anion.When using appropriate blends of the two photocatalysts,limiting quantum yieldsF∞values increase considerably and approach the maximum allowable value for the investigated molecule,in a much wider range of irradiances than that shown by the single catalysts mainly at low irradiances.This may be interpreted by strong competition kinetics of superoxide radicals generated by the catalyst defects,in the corresponding range of high irradiances.By this way,operation at high irradiance values is possible,without losing any efficiency for the mineralization process.展开更多
The Anninghe fault is a large left-lateral strike-slip fault in southwestern China. It has controlled deposition and magmatic activities since the Proterozoic, and seismic activity occurs frequently. The Mianning-Xich...The Anninghe fault is a large left-lateral strike-slip fault in southwestern China. It has controlled deposition and magmatic activities since the Proterozoic, and seismic activity occurs frequently. The Mianning-Xichang segment of the Anninghe fault is a seismic gap that has been locked by high stress. Many studies suggest that this segment has great potential for large earthquakes(magnitude >7). We obtained three vertical velocity profiles of the Anninghe fault(between Mianning and Xichang) based on the inversion of P-wave first arrival times. The travel time data were picked from seismograms generated by methane gaseous sources and recorded by three linearly distributed across-fault dense arrays. The inversion results show that the P-wave velocity structures at depths of 0-2 km corresponds well with the local lithology. The Quaternary sediments have low seismic velocities, whereas the igneous rocks,metamorphic rocks, and bedrock have high seismic velocities. We then further discuss the fault activities of the two fault branches of the Anninghe fault in the study region based on small earthquakes(magnitudes between ML 0.5 and ML 2.5) detected by the Xichang array.The eastern fault branch is more active than the western branch and that the fault activities in the eastern branch are different in the northern and southern segments at the border of 28°21′N. The high-resolution models obtained are essential for future earthquake rupture simulations and hazard assessments of the Anninghe fault zone. Future studies of velocity models at greater depths may further explain the complex fault activities in the study region.展开更多
基金The present paper is the 91st in a series of papers,authored by Ignazio Renato Bellobono and his collaborators over the past 35 years,which is collectively referred to as the“Photosynthetic Membranes”series.
文摘Photomineralization of methane in air(10.0-1,000 ppm(mass/volume)of C)at 100%relative humidity(dioxygen as oxygen donor),was systematically studied at 318±3 K,in an annular laboratory-scale reactor,by photocatalytic membranes immobilising titanium dioxide and tungsten trioxide as co-photocatalysts.Kinetics of both substrate disappearance,to yield intermediates,and total organic carbon(TOC)disappearance,to yield carbon dioxide,were followed.A kinetic model was employed,from which,by a set of differential equations,four final optimised parameters,k1 and K1,k2 and K2,were calculated,able to fit the whole kinetic profile adequately.Modelling of quantum yields,as a function of substrate concentration and irradiance,as well as of concentration of photocatalysts,was carried out very satisfactorily.Kinetics of hydroxyl radicals reacting between themselves,leading to hydrogen peroxide,other than with substrate or intermediates leading to mineralization,were considered,paralleled by second competition kinetics involving superoxide radical anion.When using appropriate blends of the two photocatalysts,limiting quantum yieldsF∞values increase considerably and approach the maximum allowable value for the investigated molecule,in a much wider range of irradiances than that shown by the single catalysts mainly at low irradiances.This may be interpreted by strong competition kinetics of superoxide radicals generated by the catalyst defects,in the corresponding range of high irradiances.By this way,operation at high irradiance values is possible,without losing any efficiency for the mineralization process.
基金supported by the Key Research and Development Project of the Ministry of Science and Technology(Grant No.2018YFC1503400)。
文摘The Anninghe fault is a large left-lateral strike-slip fault in southwestern China. It has controlled deposition and magmatic activities since the Proterozoic, and seismic activity occurs frequently. The Mianning-Xichang segment of the Anninghe fault is a seismic gap that has been locked by high stress. Many studies suggest that this segment has great potential for large earthquakes(magnitude >7). We obtained three vertical velocity profiles of the Anninghe fault(between Mianning and Xichang) based on the inversion of P-wave first arrival times. The travel time data were picked from seismograms generated by methane gaseous sources and recorded by three linearly distributed across-fault dense arrays. The inversion results show that the P-wave velocity structures at depths of 0-2 km corresponds well with the local lithology. The Quaternary sediments have low seismic velocities, whereas the igneous rocks,metamorphic rocks, and bedrock have high seismic velocities. We then further discuss the fault activities of the two fault branches of the Anninghe fault in the study region based on small earthquakes(magnitudes between ML 0.5 and ML 2.5) detected by the Xichang array.The eastern fault branch is more active than the western branch and that the fault activities in the eastern branch are different in the northern and southern segments at the border of 28°21′N. The high-resolution models obtained are essential for future earthquake rupture simulations and hazard assessments of the Anninghe fault zone. Future studies of velocity models at greater depths may further explain the complex fault activities in the study region.
