Temporary plugging agent(TPA)is widely used in many fields of petroleum reservoir drilling and production,such as temporary plugging while drilling and petroleum well stimulation by diverting in acidizing or fracturin...Temporary plugging agent(TPA)is widely used in many fields of petroleum reservoir drilling and production,such as temporary plugging while drilling and petroleum well stimulation by diverting in acidizing or fracturing operations.The commonly used TPA mainly includes hard particles,fibers,gels,and composite systems.However,current particles have many limitations in applications,such as insufficient plugging strength and slow degradation rate.In this paper,a degradable pre-formed particle gel(DPPG)was developed.Experimental results show that the DPPG has an excellent static swelling effect and self-degradation performance.With a decrease in the concentration of total monomers or cross-linker,the swelling volume of the synthesized DPPG gradually increases.However,the entire self-degradation time gradually decreases.The increase in 2-acrylamide-2-methylpropanesulfonic acid(AMPS)in the DPPG composition can significantly increase its swelling ratio and shorten the self-degradation time.Moreover,DPPG has excellent high-temperature resistance(150°C)and high-salinity resistance(200,000 mg/L NaCl).Core displacement results show that the DPPG has a perfect plugging effect in the porous media(the plugging pressure gradient was as high as 21.12 MPa),and the damage to the formation after degradation is incredibly minor.Therefore,the DPPG can be used as an up-and-coming TPA in oil fields.展开更多
Inspired by the viscoelastic displacement theory,a product called preformed particle gel(PPG)is developed as conformance control agent to enhance oil recovery and control excess water production.The migration law of P...Inspired by the viscoelastic displacement theory,a product called preformed particle gel(PPG)is developed as conformance control agent to enhance oil recovery and control excess water production.The migration law of PPG suspension in porous media is related to its deep profile control and displacement capability.Laboratory experiments indicate that PPG suspension has good viscosity increasing,and the apparent viscosity decreases with the increase of shear rate.PPG suspension is mainly elastic,and its network structure makes it have certain shear stability.PPG particles realize migration in porous media in the way of“accumulation and blockage/pressure increase/deformation and migration”.When the ratio of the PPG particle size to the pore throat diameter d ranges from 35.52 to 53.38,the particles can match through the porous medium.When the permeability difference of the parallel model is 5,PPG suspension has the highest profile improvement rate,69.10%.PPG suspension can adjust the planar heterogeneity,and increase the oil recovery rate by 20.75%.The PPG suspension can effectively start“cluster"、“film”and“blind end residual oil”,and has a high oil washing efficiency.The core NMR T2 spectrum shows that PPG suspension mainly reduces oil saturation in mesopores and macropores.After PPG flooding,the EOR capacity of small pores is the highest,39.11%.展开更多
基金This work was supported by the Research Foundation of China University of Petroleum-Beijing at Karamay(No.XQZX20200010)the Natural Science Foundation of Xinjiang Uygur Autonomous Region(No.2019D01B57)+3 种基金the University Scientific Research Project of Xinjiang Uygur Autonomous Region(No.XJEDU2019Y067)the Xinjiang Uygur Autonomous Region Innovation Environment Construction Project(No.2019Q025)the Sichuan Province Regional Innovation Cooperation Project(No.2020YFQ0036)the CNPC Strategic Cooperation Science and Technology Project(ZLZX2020-01-04-04)。
文摘Temporary plugging agent(TPA)is widely used in many fields of petroleum reservoir drilling and production,such as temporary plugging while drilling and petroleum well stimulation by diverting in acidizing or fracturing operations.The commonly used TPA mainly includes hard particles,fibers,gels,and composite systems.However,current particles have many limitations in applications,such as insufficient plugging strength and slow degradation rate.In this paper,a degradable pre-formed particle gel(DPPG)was developed.Experimental results show that the DPPG has an excellent static swelling effect and self-degradation performance.With a decrease in the concentration of total monomers or cross-linker,the swelling volume of the synthesized DPPG gradually increases.However,the entire self-degradation time gradually decreases.The increase in 2-acrylamide-2-methylpropanesulfonic acid(AMPS)in the DPPG composition can significantly increase its swelling ratio and shorten the self-degradation time.Moreover,DPPG has excellent high-temperature resistance(150°C)and high-salinity resistance(200,000 mg/L NaCl).Core displacement results show that the DPPG has a perfect plugging effect in the porous media(the plugging pressure gradient was as high as 21.12 MPa),and the damage to the formation after degradation is incredibly minor.Therefore,the DPPG can be used as an up-and-coming TPA in oil fields.
基金The work was supported by the National Natural Science Foundation of China(No.51674208)Sichuan Provincial Key Labo-ratory of Applied Chemistry for Oil and Gas Field Open Fund(YQKF202010)Southwest Petroleum University College Students Open Experimental Fund(2020KSZ33001,2020KSZ04047).
文摘Inspired by the viscoelastic displacement theory,a product called preformed particle gel(PPG)is developed as conformance control agent to enhance oil recovery and control excess water production.The migration law of PPG suspension in porous media is related to its deep profile control and displacement capability.Laboratory experiments indicate that PPG suspension has good viscosity increasing,and the apparent viscosity decreases with the increase of shear rate.PPG suspension is mainly elastic,and its network structure makes it have certain shear stability.PPG particles realize migration in porous media in the way of“accumulation and blockage/pressure increase/deformation and migration”.When the ratio of the PPG particle size to the pore throat diameter d ranges from 35.52 to 53.38,the particles can match through the porous medium.When the permeability difference of the parallel model is 5,PPG suspension has the highest profile improvement rate,69.10%.PPG suspension can adjust the planar heterogeneity,and increase the oil recovery rate by 20.75%.The PPG suspension can effectively start“cluster"、“film”and“blind end residual oil”,and has a high oil washing efficiency.The core NMR T2 spectrum shows that PPG suspension mainly reduces oil saturation in mesopores and macropores.After PPG flooding,the EOR capacity of small pores is the highest,39.11%.
