In order to contribute for a better understanding of mass transfer in drying of shrinking particles, in this study shrinkage and drying characteristics of sorghum seeds encapsulated into gel-based polymeric matrix wer...In order to contribute for a better understanding of mass transfer in drying of shrinking particles, in this study shrinkage and drying characteristics of sorghum seeds encapsulated into gel-based polymeric matrix were experimentally determined by using infrared (IR) radiation. IR drying of gel coated seeds was carried out at three different temperatures (65℃, 80℃ and 93℃). The shrinkage of the individual particles during drying was quantified by means of the volume and surface area changes evaluated from geometric measurements. The product quality was evaluated in terms of the changes of particle density and percent of cracks in gel coating incurred during drying. Surface area and volume of the gel-seed system decreased about 65% and 80% until the end of the process, respectively, stressing the need to take into account the surface area changes to calculate water flux density as function of moisture content and obtain an accurate interpretation of the drying mechanisms well as to include the volume shrinkage in mass transfer models to determine reliable values of moisture diffusivity. The IR drying behavior of gel-coated seeds was then characterized by the presence of three drying periods: heating up, constant moisture flux and falling moisture flux. Accelerated drying of gel coated seeds was obtained by applying higher IR radiation intensities. The effect of IR source temperature on the particle shrinkage was more pronounced at the constant moisture flux period and practically negligible at the decreasing moisture flux period. Neglecting shrinkage of individual coated-seeds during IR drying led to an erroneous absence of constant flux period and overestimation of the mass transfer by diffusion. Apparent density of the particles was greater at low-temperature IR drying than at high-temperature IR drying. Coated particles keep their original geometry, but a significant cracking of gel coating was observed at rapid drying rate conditions.展开更多
Tactile sensing provides robots the ability of object recognition,fine operation,natural interaction,etc.However,in the actual scenario,robotic tactile recognition of similar objects still faces difficulties such as l...Tactile sensing provides robots the ability of object recognition,fine operation,natural interaction,etc.However,in the actual scenario,robotic tactile recognition of similar objects still faces difficulties such as low efficiency and accuracy,resulting from a lack of high-performance sensors and intelligent recognition algorithms.In this paper,a flexible sensor combining a pyramidal microstructure with a gradient conformal ionic gel coating was demonstrated,exhibiting excellent signal-to-noise ratio(48 dB),low detection limit(1 Pa),high sensitivity(92.96 kPa^(-1)),fast response time(55 ms),and outstanding stability over 15,000 compression-release cycles.Furthermore,a Pressure-Slip Dual-Branch Convolutional Neural Network(PSNet)architecture was proposed to separately extract hardness and texture features and perform feature fusion.In tactile experiments on different kinds of leaves,a recognition rate of 97.16%was achieved,and surpassed that of human hands recognition(72.5%).These researches showed the great potential in a broad application in bionic robots,intelligent prostheses,and precise human–computer interaction.展开更多
We have prepared silica,SiO2coated NiO and NiO coated SiO2by sol-gel method.The physicochemical properties of the desired materials were investigated by surface charge properties,scanning electron microscopy(SEM),en...We have prepared silica,SiO2coated NiO and NiO coated SiO2by sol-gel method.The physicochemical properties of the desired materials were investigated by surface charge properties,scanning electron microscopy(SEM),energy dispersive X-ray(EDX) spectroscopy,surface area measurements and X-ray diffraction(XRD) analyses.The point of zero charge(PZC) of the solid was determined by the salt addition method.In coated materials,two PZC values were noted representing the surface charge of their counterparts.The SEM image of SiO2coated NiO displays a uniform coating of silica on the surface of NiO whereas in case of NiO coated SiO2,a honeycomb like appearance was observed with highly porous structures.In the diffractograms of NiO,the characteristic peaks were suppressed in NiO coated silica however,no diffraction peak could be seen in SiO2coated NiO.Batch adsorption technique was applied for the removal of Pb2+ions from aqueous solution.The sorption trend for Pb2+ions was observed in the order of NiO coated SiO2〉 SiO2coated NiO 〉 NiO 〉 SiO2.This trend confirms that the coated materials have more sorption capacities than their parent counterparts.展开更多
基金The authors are grateful to CNPq(National Council for Research)and FAPITEC(Foundation for Research Support of Sergipe State)for the financial support received.
文摘In order to contribute for a better understanding of mass transfer in drying of shrinking particles, in this study shrinkage and drying characteristics of sorghum seeds encapsulated into gel-based polymeric matrix were experimentally determined by using infrared (IR) radiation. IR drying of gel coated seeds was carried out at three different temperatures (65℃, 80℃ and 93℃). The shrinkage of the individual particles during drying was quantified by means of the volume and surface area changes evaluated from geometric measurements. The product quality was evaluated in terms of the changes of particle density and percent of cracks in gel coating incurred during drying. Surface area and volume of the gel-seed system decreased about 65% and 80% until the end of the process, respectively, stressing the need to take into account the surface area changes to calculate water flux density as function of moisture content and obtain an accurate interpretation of the drying mechanisms well as to include the volume shrinkage in mass transfer models to determine reliable values of moisture diffusivity. The IR drying behavior of gel-coated seeds was then characterized by the presence of three drying periods: heating up, constant moisture flux and falling moisture flux. Accelerated drying of gel coated seeds was obtained by applying higher IR radiation intensities. The effect of IR source temperature on the particle shrinkage was more pronounced at the constant moisture flux period and practically negligible at the decreasing moisture flux period. Neglecting shrinkage of individual coated-seeds during IR drying led to an erroneous absence of constant flux period and overestimation of the mass transfer by diffusion. Apparent density of the particles was greater at low-temperature IR drying than at high-temperature IR drying. Coated particles keep their original geometry, but a significant cracking of gel coating was observed at rapid drying rate conditions.
基金supported by the Open Project of the State Key Laboratory of Trauma and Chemical Poisoning(SKL202102)the Key R&D and Transformation of Science and Technology Projects in Tibet Autonomous Region(XZ2022RH001)+3 种基金Chongqing Talents Program(CQYC2020030146)the Project of Chongqing Science and Technology Bureau(cstc2021ycjh-bgzxm0345)Chongqing Bayu Scholar Program(DP2020036)Chongqing Entrepreneurship and Innovation Support Program for Overseas Students Returning to China.
文摘Tactile sensing provides robots the ability of object recognition,fine operation,natural interaction,etc.However,in the actual scenario,robotic tactile recognition of similar objects still faces difficulties such as low efficiency and accuracy,resulting from a lack of high-performance sensors and intelligent recognition algorithms.In this paper,a flexible sensor combining a pyramidal microstructure with a gradient conformal ionic gel coating was demonstrated,exhibiting excellent signal-to-noise ratio(48 dB),low detection limit(1 Pa),high sensitivity(92.96 kPa^(-1)),fast response time(55 ms),and outstanding stability over 15,000 compression-release cycles.Furthermore,a Pressure-Slip Dual-Branch Convolutional Neural Network(PSNet)architecture was proposed to separately extract hardness and texture features and perform feature fusion.In tactile experiments on different kinds of leaves,a recognition rate of 97.16%was achieved,and surpassed that of human hands recognition(72.5%).These researches showed the great potential in a broad application in bionic robots,intelligent prostheses,and precise human–computer interaction.
文摘We have prepared silica,SiO2coated NiO and NiO coated SiO2by sol-gel method.The physicochemical properties of the desired materials were investigated by surface charge properties,scanning electron microscopy(SEM),energy dispersive X-ray(EDX) spectroscopy,surface area measurements and X-ray diffraction(XRD) analyses.The point of zero charge(PZC) of the solid was determined by the salt addition method.In coated materials,two PZC values were noted representing the surface charge of their counterparts.The SEM image of SiO2coated NiO displays a uniform coating of silica on the surface of NiO whereas in case of NiO coated SiO2,a honeycomb like appearance was observed with highly porous structures.In the diffractograms of NiO,the characteristic peaks were suppressed in NiO coated silica however,no diffraction peak could be seen in SiO2coated NiO.Batch adsorption technique was applied for the removal of Pb2+ions from aqueous solution.The sorption trend for Pb2+ions was observed in the order of NiO coated SiO2〉 SiO2coated NiO 〉 NiO 〉 SiO2.This trend confirms that the coated materials have more sorption capacities than their parent counterparts.