[ Manuscript received October 8, 2003, in revised form March 2, 2004]Corrosion behaviors of X70 steel were studied by means of electrochemical experiments and morphology observation. First, through potentiodynamic pol...[ Manuscript received October 8, 2003, in revised form March 2, 2004]Corrosion behaviors of X70 steel were studied by means of electrochemical experiments and morphology observation. First, through potentiodynamic polarization in solution of various Cl- ions concentration, it was found that Epit began to appear in solution of Cl- concentration above 0.1 mol/L, and there was a critical point of Cl- concentration between 0.05 mol/L and 0.1 mol/L, below which the extent of pitting and general corrosion were trivial, while in solution of Cl- concentration above 0.1 mol/L, general and pitting corrosion became greater as the increasing of Cl- concentration. All of them were confirmed by the SEM observations after anodic polarization. Second, via the potentiodynamic polarization curves of X70 steel in 0.5 mol/L Cl- solution with 0, 0.05, 0.5 and 1 mol/L SO42-ions, it was found SO42- ions were able to inhibit corrosion aroused from Cl- ions, accordingly a model was set up to describe the process. In addition, to further explore the inhibited effect of SO42- ions, EIS was used in solutions of different Cl- and SO42- concentrations, the results revealed that the electrochemical resistance has a relation with the [SO42-]/[Cl-], that was, the bigger the value of [SO42-]/[CI-], the greater the electrochemical resistance.展开更多
The effect of Sn on corrosion behavior of ferritic stainless steels in 20mass% H2SO4 was investigated by alternating current and direct current electrochemical methods and gravimetric tests at 25 ℃.The results show t...The effect of Sn on corrosion behavior of ferritic stainless steels in 20mass% H2SO4 was investigated by alternating current and direct current electrochemical methods and gravimetric tests at 25 ℃.The results show that Sn can effectively improve general corrosion resistance of ferritic stainless steels in H2SO4,mainly due to highly raised hydrogen evolution overpotential which is in favour of strong suppression of hydrogen evolution reaction,and inhibitive effect of dissolved Sn^2＋ on elementary anodic reactions.With increasing Sn content,the better corrosion resistance can be reached.The Electrochemical Impedance Spectroscopy（EIS）includes four time constants and can be perfectly fitted by equivalent circuit：Rs（CdlRct）（QadsRads（RL1（L1（RL2L2））））.展开更多
Traditional researches on metal corrosion under salt solutions deposit conditions are usually carried out by visual, electron microscopic observations and simple electrochemical measurement via a traditional one-piece...Traditional researches on metal corrosion under salt solutions deposit conditions are usually carried out by visual, electron microscopic observations and simple electrochemical measurement via a traditional one-piece electrode. These techniques have difficulties in measuring localized corrosion that frequently occur in inhomogeneous media. This paper reports the results from the experiments using specially shaped coupons and a relatively new method of measuring heterogeneous electrochemical processes, namely, the wire beam electrode（WBE）. Preliminary results from copper and aluminum corrosion in highly concentrated sodium chloride solutions with and without solid deposits show that the method is useful in simulating and studying corrosion especially localized corrosion in pipelines.展开更多
文摘[ Manuscript received October 8, 2003, in revised form March 2, 2004]Corrosion behaviors of X70 steel were studied by means of electrochemical experiments and morphology observation. First, through potentiodynamic polarization in solution of various Cl- ions concentration, it was found that Epit began to appear in solution of Cl- concentration above 0.1 mol/L, and there was a critical point of Cl- concentration between 0.05 mol/L and 0.1 mol/L, below which the extent of pitting and general corrosion were trivial, while in solution of Cl- concentration above 0.1 mol/L, general and pitting corrosion became greater as the increasing of Cl- concentration. All of them were confirmed by the SEM observations after anodic polarization. Second, via the potentiodynamic polarization curves of X70 steel in 0.5 mol/L Cl- solution with 0, 0.05, 0.5 and 1 mol/L SO42-ions, it was found SO42- ions were able to inhibit corrosion aroused from Cl- ions, accordingly a model was set up to describe the process. In addition, to further explore the inhibited effect of SO42- ions, EIS was used in solutions of different Cl- and SO42- concentrations, the results revealed that the electrochemical resistance has a relation with the [SO42-]/[Cl-], that was, the bigger the value of [SO42-]/[CI-], the greater the electrochemical resistance.
基金Item Sponsored by National Science-technology Support Plan Project of China(2012BAE04B02)National Natural Science Foundation of China(51271050)+1 种基金China Postdoctoral Science Foundation(2015M581346)Foundamental Research Funds for the Central Universities of China(N150203002)
文摘The effect of Sn on corrosion behavior of ferritic stainless steels in 20mass% H2SO4 was investigated by alternating current and direct current electrochemical methods and gravimetric tests at 25 ℃.The results show that Sn can effectively improve general corrosion resistance of ferritic stainless steels in H2SO4,mainly due to highly raised hydrogen evolution overpotential which is in favour of strong suppression of hydrogen evolution reaction,and inhibitive effect of dissolved Sn^2＋ on elementary anodic reactions.With increasing Sn content,the better corrosion resistance can be reached.The Electrochemical Impedance Spectroscopy（EIS）includes four time constants and can be perfectly fitted by equivalent circuit：Rs（CdlRct）（QadsRads（RL1（L1（RL2L2））））.
文摘Traditional researches on metal corrosion under salt solutions deposit conditions are usually carried out by visual, electron microscopic observations and simple electrochemical measurement via a traditional one-piece electrode. These techniques have difficulties in measuring localized corrosion that frequently occur in inhomogeneous media. This paper reports the results from the experiments using specially shaped coupons and a relatively new method of measuring heterogeneous electrochemical processes, namely, the wire beam electrode（WBE）. Preliminary results from copper and aluminum corrosion in highly concentrated sodium chloride solutions with and without solid deposits show that the method is useful in simulating and studying corrosion especially localized corrosion in pipelines.
