Microbial geoengineering technology,as a new eco-friendly rock and soil improvement and reinforcement technology,has a wide application prospect.However,this technology still has many deficiencies and is difficult to ...Microbial geoengineering technology,as a new eco-friendly rock and soil improvement and reinforcement technology,has a wide application prospect.However,this technology still has many deficiencies and is difficult to achieve efficient curing,which has become the bottleneck of large-scale field application.This paper reviews the research status,hot spots,difficulties and future development direction microbial induced calcium carbonate precipitation(MICP)technology.The principle of solidification and the physical and mechanical properties of improved rock and soil are systematically summarized.The solidification efficiency is mainly affected by the reactant itself and the external environment.At present,the MICP technology has been preliminarily applied in the fields of soil solidification,crack repair,anti-seepage treatment,pollution repair and microbial cement.However,the technology is currently mainly limited to the laboratory level due to the difficulty of homogeneous mineralization,uneconomical reactants,short microbial activity period and large environmental interference,incidental toxicity of metabolites and poor field application.Future directions include improving the uniformity of mineralization by improving grouting methods,improving urease persistence by improving urease activity,and improving the adaptability of bacteria to the environment by optimizing bacterial species.Finally,the authors point out the economic advantages of combining soybean peptone,soybean meal and cottonseed as carbon source with phosphogypsum as calcium source to induce CaCO3.展开更多
On 2019-03-04,the largest induced earthquake(ML4.18)occurred in the East Shale Basin,Alberta,and the underlying physical mechanisms have not been fully understood.This paper proposes a synthetical geoengineering metho...On 2019-03-04,the largest induced earthquake(ML4.18)occurred in the East Shale Basin,Alberta,and the underlying physical mechanisms have not been fully understood.This paper proposes a synthetical geoengineering methodology to comprehensively characterize this earthquake caused by hydraulic fracturing.Based on 3D structural,petrophysical,and geomechanical models,an unconventional fracture model is constructed by considering the stress shadow between adjacent hydraulic fractures and the interactions between hydraulic and natural fractures.Coupled poroelastic simulations are conducted to reveal the triggering mechanisms of induced seismicity.It is found that four vertical basement-rooted faults were identified via focal mechanisms analysis.The brittleness index(BI)along two horizontal wells has a high magnitude(BI>0.5),indicating the potential susceptibility of rock brittleness.Due to the presence of overpressure,pre-existing faults in the Duvernay Formation are highly susceptible to fault reactivation.The occurrence of the earthquake clusters has been attributed to the fracturing fluid injection during the west 38^(th)-39^(th) stage and east 38^(th) stage completions.Rock brittleness,formation overpressure,and large fracturing job size account for the nucleation of earthquake clusters,and unconventional natural-hydraulic fracture networks provide fluid flow pathways to cause fault reactivation.This workflow can be used to mitigate potential seismic risks in unconventional reservoirs in other fields.展开更多
The effect of deposition temperature on the morphology and optoelectronic performance of Ge/Si QDs grown by magnetron sputtering under low Ge deposition(~4 nm)was investigated by atomic force microscopy,Raman spectros...The effect of deposition temperature on the morphology and optoelectronic performance of Ge/Si QDs grown by magnetron sputtering under low Ge deposition(~4 nm)was investigated by atomic force microscopy,Raman spectroscopy,and photoluminescence(PL)tests.The experimental results indicate that temperatures higher than 750℃effectively increase the crystallization rate and surface smoothness of the Si buffer layer,and temperatures higher than 600℃significantly enhance the migration ability of Ge atoms,thus increasing the probability of Ge atoms meeting and nucleating to form QDs on Si buffer layer,but an excessively high temperature will cause the QDs to undergo an Ostwald ripening process and thus develop into super large islands.In addition,some PL peaks were observed in samples containing small-sized,high-density Ge QDs,the photoelectric properties reflected by these peaks were in good agreement with the corresponding structural characteristics of the grown QDs.Our results demonstrate the viability of preparing high-quality QDs by magnetron sputtering at high deposition rate,and the temperature effect is expected to work in conjunction with other controllable factors to further regulate QD growth,which paves an effective way for the industrial production of QDs that can be used in future devices.展开更多
基金This work was financed by the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(Grant No.2019QZKK0904)the Key Research and Development Plan of Yunnan Province(Grant No.202103AA080013).
文摘Microbial geoengineering technology,as a new eco-friendly rock and soil improvement and reinforcement technology,has a wide application prospect.However,this technology still has many deficiencies and is difficult to achieve efficient curing,which has become the bottleneck of large-scale field application.This paper reviews the research status,hot spots,difficulties and future development direction microbial induced calcium carbonate precipitation(MICP)technology.The principle of solidification and the physical and mechanical properties of improved rock and soil are systematically summarized.The solidification efficiency is mainly affected by the reactant itself and the external environment.At present,the MICP technology has been preliminarily applied in the fields of soil solidification,crack repair,anti-seepage treatment,pollution repair and microbial cement.However,the technology is currently mainly limited to the laboratory level due to the difficulty of homogeneous mineralization,uneconomical reactants,short microbial activity period and large environmental interference,incidental toxicity of metabolites and poor field application.Future directions include improving the uniformity of mineralization by improving grouting methods,improving urease persistence by improving urease activity,and improving the adaptability of bacteria to the environment by optimizing bacterial species.Finally,the authors point out the economic advantages of combining soybean peptone,soybean meal and cottonseed as carbon source with phosphogypsum as calcium source to induce CaCO3.
基金This research was supported by Science Foundation of China University of Petroleum,Beijing(No.2462023BJRC001)National Natural Science Foundation of China Project(No.52204039).
文摘On 2019-03-04,the largest induced earthquake(ML4.18)occurred in the East Shale Basin,Alberta,and the underlying physical mechanisms have not been fully understood.This paper proposes a synthetical geoengineering methodology to comprehensively characterize this earthquake caused by hydraulic fracturing.Based on 3D structural,petrophysical,and geomechanical models,an unconventional fracture model is constructed by considering the stress shadow between adjacent hydraulic fractures and the interactions between hydraulic and natural fractures.Coupled poroelastic simulations are conducted to reveal the triggering mechanisms of induced seismicity.It is found that four vertical basement-rooted faults were identified via focal mechanisms analysis.The brittleness index(BI)along two horizontal wells has a high magnitude(BI>0.5),indicating the potential susceptibility of rock brittleness.Due to the presence of overpressure,pre-existing faults in the Duvernay Formation are highly susceptible to fault reactivation.The occurrence of the earthquake clusters has been attributed to the fracturing fluid injection during the west 38^(th)-39^(th) stage and east 38^(th) stage completions.Rock brittleness,formation overpressure,and large fracturing job size account for the nucleation of earthquake clusters,and unconventional natural-hydraulic fracture networks provide fluid flow pathways to cause fault reactivation.This workflow can be used to mitigate potential seismic risks in unconventional reservoirs in other fields.
基金Founded by the National Key Research and Development Program(No.2021YFB3802400)the National Natural Science Foundation of China(No.52161037)the Basic Research Project of Yunnan Province(No.202001AU070112)。
文摘The effect of deposition temperature on the morphology and optoelectronic performance of Ge/Si QDs grown by magnetron sputtering under low Ge deposition(~4 nm)was investigated by atomic force microscopy,Raman spectroscopy,and photoluminescence(PL)tests.The experimental results indicate that temperatures higher than 750℃effectively increase the crystallization rate and surface smoothness of the Si buffer layer,and temperatures higher than 600℃significantly enhance the migration ability of Ge atoms,thus increasing the probability of Ge atoms meeting and nucleating to form QDs on Si buffer layer,but an excessively high temperature will cause the QDs to undergo an Ostwald ripening process and thus develop into super large islands.In addition,some PL peaks were observed in samples containing small-sized,high-density Ge QDs,the photoelectric properties reflected by these peaks were in good agreement with the corresponding structural characteristics of the grown QDs.Our results demonstrate the viability of preparing high-quality QDs by magnetron sputtering at high deposition rate,and the temperature effect is expected to work in conjunction with other controllable factors to further regulate QD growth,which paves an effective way for the industrial production of QDs that can be used in future devices.
