Aqueous zinc-ion batteries(AZIBs)are one of the most compelling alternatives of lithium-ion batteries due to their inherent safety and economics viability.In response to the growing demand for green and sustainable en...Aqueous zinc-ion batteries(AZIBs)are one of the most compelling alternatives of lithium-ion batteries due to their inherent safety and economics viability.In response to the growing demand for green and sustainable energy storage solutions,organic electrodes with the scalability from inexpensive starting materials and potential for biodegradation after use have become a prominent choice for AZIBs.Despite gratifying progresses of organic molecules with electrochemical performance in AZIBs,the research is still in infancy and hampered by certain issues due to the underlying complex electrochemistry.Strategies for designing organic electrode materials for AZIBs with high specific capacity and long cycling life are discussed in detail in this review.Specifically,we put emphasis on the unique electrochemistry of different redox-active structures to provide in-depth understanding of their working mechanisms.In addition,we highlight the importance of molecular size/dimension regarding their profound impact on electrochemical performances.Finally,challenges and perspectives are discussed from the developing point of view for future AZIBs.We hope to provide a valuable evaluation on organic electrode materials for AZIBs in our context and give inspiration for the rational design of high-performance AZIBs.展开更多
In this paper, we propose a parametric modeling method to reconstruct the Hui-Style and solve the problem that the user can't effectively reconstruct the Hui-Style three dimensional models because of the various styl...In this paper, we propose a parametric modeling method to reconstruct the Hui-Style and solve the problem that the user can't effectively reconstruct the Hui-Style three dimensional models because of the various style and complicated structure of Hui-Style components. This model includes summarizing and defining a variety of Hui-Style components parameter types. Determine the relationship between the parameter according to building formulas and design the parametric modeling process. First, set the depth of platform as the given user value. Then, calculate the component properties and the corresponding size according to the style of the Hui-Style architecture components and the constraint relation between Hui-Style architecture components. This needs only one parameter that is needed as the basic parameter in this method and the entire modeling process can be achieved based on it. The experimental result shows that the proposed method can well solve the complex parameters relationship of the Hui-Style architecture components and help the general users to construct the Hui-Style architecture components more effective.展开更多
基金supported in part by the National Natural Science Foundation of China(Nos.22075027,52003030)Starting Grant from Beijing Institute of Technology and financial support from the State Key Laboratory of Explosion Science and Technology(YBKT21-06,YKBT23-05).
文摘Aqueous zinc-ion batteries(AZIBs)are one of the most compelling alternatives of lithium-ion batteries due to their inherent safety and economics viability.In response to the growing demand for green and sustainable energy storage solutions,organic electrodes with the scalability from inexpensive starting materials and potential for biodegradation after use have become a prominent choice for AZIBs.Despite gratifying progresses of organic molecules with electrochemical performance in AZIBs,the research is still in infancy and hampered by certain issues due to the underlying complex electrochemistry.Strategies for designing organic electrode materials for AZIBs with high specific capacity and long cycling life are discussed in detail in this review.Specifically,we put emphasis on the unique electrochemistry of different redox-active structures to provide in-depth understanding of their working mechanisms.In addition,we highlight the importance of molecular size/dimension regarding their profound impact on electrochemical performances.Finally,challenges and perspectives are discussed from the developing point of view for future AZIBs.We hope to provide a valuable evaluation on organic electrode materials for AZIBs in our context and give inspiration for the rational design of high-performance AZIBs.
基金Supported by Chinese National Natural Science Foundation(61370167)National Key Technology Support Program(2012BAJ08B01)and the Natural Science Foundation of Anhui Province(1608085QF148)
文摘In this paper, we propose a parametric modeling method to reconstruct the Hui-Style and solve the problem that the user can't effectively reconstruct the Hui-Style three dimensional models because of the various style and complicated structure of Hui-Style components. This model includes summarizing and defining a variety of Hui-Style components parameter types. Determine the relationship between the parameter according to building formulas and design the parametric modeling process. First, set the depth of platform as the given user value. Then, calculate the component properties and the corresponding size according to the style of the Hui-Style architecture components and the constraint relation between Hui-Style architecture components. This needs only one parameter that is needed as the basic parameter in this method and the entire modeling process can be achieved based on it. The experimental result shows that the proposed method can well solve the complex parameters relationship of the Hui-Style architecture components and help the general users to construct the Hui-Style architecture components more effective.