Dense pre-hydrated geosynthetic clay liners(DPH GCLs)were manufactured as innovative materials accompanied by the advantage of lower hydraulic conductivity(k).The k of DPH GCLs permeated with de-ionized water(DIW)was ...Dense pre-hydrated geosynthetic clay liners(DPH GCLs)were manufactured as innovative materials accompanied by the advantage of lower hydraulic conductivity(k).The k of DPH GCLs permeated with de-ionized water(DIW)was 9.8×10^(−12) m/s.The effect of Cu^(2+)synthetic solution on DPH GCLs was discussed.Furthermore,the effect mechanism was studied on the basis of test technologies.A significant adverse impact on hydraulic performance of DPH GCLs is found when the concentration of Cu^(2+)is greater than 1 g/L.SEM,XRD,XRF,FTIR,and XPS analyses show that the effect of Cu^(2+)on DPH GCLs includes two steps.Firstly,Cu^(2+)interacts with hydrophobic organic matter(HOM),and the adhesion of bentonite is destroyed,and some holes appear.The Cu^(2+)contacts with bentonite directly,and Cu^(2+)interacts with bentonite through ion exchange.Passivated phenomenon occurs on the surface of the bentonite,and swelling ability of bentonite is reduced,which causes permeable DPH GCLs.展开更多
The geosynthetic clay liner （GCL） is a kind of waterproofing material used widely in engineering. The waterproof mechanism is understood in terms of bentonite particles becoming water-obstruct colloid layers after t...The geosynthetic clay liner （GCL） is a kind of waterproofing material used widely in engineering. The waterproof mechanism is understood in terms of bentonite particles becoming water-obstruct colloid layers after they sorb water and swell. The swell pressure stress, however, has not been determined directly till now. In our experiment, swell pressure stress of the GCL under saturated water-sorbing condition was measured directly using a custom-made instrument. The results show that （1） the instrument designed by the authors performs satisfactorily and the test results are reproducible; and （2） the trend line of swell pressure stress variation with time can be divided into three segments. The first segment is characterized by a quick increase of the swell force in the first 0-50 hours. The swell pressure stress increases by 7.00×10^-4-1.00×10^-3 MPa/h. The second segment shows a slow increase of the swell pressure stress from the 50th to 1730th hour. The swell force increases by 7.54×10^-6-2.02×10^-5 MPa/h. The third segment is characterized by a little variation in swell pressure stress after 1730 hours. In this segment, the average value of the swell pressure stress measurements is 0.0719 MPa and the maximum value is 0.0729 MPa. It is suggested that the swell pressure stress is mainly raised by water entering pores among montmorillonite particles and interstitial layers in individual montmorillonite crystals, leading to an increase of volume.展开更多
基金National Key Research and Development Project of China(No.2017FB0310902)。
文摘Dense pre-hydrated geosynthetic clay liners(DPH GCLs)were manufactured as innovative materials accompanied by the advantage of lower hydraulic conductivity(k).The k of DPH GCLs permeated with de-ionized water(DIW)was 9.8×10^(−12) m/s.The effect of Cu^(2+)synthetic solution on DPH GCLs was discussed.Furthermore,the effect mechanism was studied on the basis of test technologies.A significant adverse impact on hydraulic performance of DPH GCLs is found when the concentration of Cu^(2+)is greater than 1 g/L.SEM,XRD,XRF,FTIR,and XPS analyses show that the effect of Cu^(2+)on DPH GCLs includes two steps.Firstly,Cu^(2+)interacts with hydrophobic organic matter(HOM),and the adhesion of bentonite is destroyed,and some holes appear.The Cu^(2+)contacts with bentonite directly,and Cu^(2+)interacts with bentonite through ion exchange.Passivated phenomenon occurs on the surface of the bentonite,and swelling ability of bentonite is reduced,which causes permeable DPH GCLs.
文摘The geosynthetic clay liner （GCL） is a kind of waterproofing material used widely in engineering. The waterproof mechanism is understood in terms of bentonite particles becoming water-obstruct colloid layers after they sorb water and swell. The swell pressure stress, however, has not been determined directly till now. In our experiment, swell pressure stress of the GCL under saturated water-sorbing condition was measured directly using a custom-made instrument. The results show that （1） the instrument designed by the authors performs satisfactorily and the test results are reproducible; and （2） the trend line of swell pressure stress variation with time can be divided into three segments. The first segment is characterized by a quick increase of the swell force in the first 0-50 hours. The swell pressure stress increases by 7.00×10^-4-1.00×10^-3 MPa/h. The second segment shows a slow increase of the swell pressure stress from the 50th to 1730th hour. The swell force increases by 7.54×10^-6-2.02×10^-5 MPa/h. The third segment is characterized by a little variation in swell pressure stress after 1730 hours. In this segment, the average value of the swell pressure stress measurements is 0.0719 MPa and the maximum value is 0.0729 MPa. It is suggested that the swell pressure stress is mainly raised by water entering pores among montmorillonite particles and interstitial layers in individual montmorillonite crystals, leading to an increase of volume.
