Toxic Cu(Ⅱ) and Ni(Ⅱ) ions in aqueous solutions were adsorbed by microporous activated carbon(AC). The adsorption isotherm and kinetics correlation coefficients indicate that the adsorption of Cu(Ⅱ) and Ni(Ⅱ) ions...Toxic Cu(Ⅱ) and Ni(Ⅱ) ions in aqueous solutions were adsorbed by microporous activated carbon(AC). The adsorption isotherm and kinetics correlation coefficients indicate that the adsorption of Cu(Ⅱ) and Ni(Ⅱ) ions on the AC fits the pseudo second-order rate model and Langmuir adsorption model. The used AC adsorbents containing the adsorbed Cu and Ni ions were used as colorant in glass preparation. The coloration effect of Cu ions was influenced by the carbon absorbent included in the glass batch due to the reduction phenomenon, while the coloration of Ni ions was not affected.展开更多
The composition design and melting technique of colored glasses based on wollastonite was studied. The density, expansion coefficient, thermostability, durability and some optical properties of glasses were measured. ...The composition design and melting technique of colored glasses based on wollastonite was studied. The density, expansion coefficient, thermostability, durability and some optical properties of glasses were measured. The results show: These glasses have low melting temperature and short clarifying time. Their physicochemical properties were improved res- pectively to a certain degree.展开更多
Color conversion glass ceramics are prepared by cosintering borosilicate glass frits and green 0.06Ce:Y2.94(Al1-xGax)5O12 phosphors. The crystal structures, the influence of Ga concentration on the photoluminescen...Color conversion glass ceramics are prepared by cosintering borosilicate glass frits and green 0.06Ce:Y2.94(Al1-xGax)5O12 phosphors. The crystal structures, the influence of Ga concentration on the photoluminescence (PL), and reliability properties of the color conversion glass ceramics are investigated. The PL emission wavelengths of 0.06Ce:Y2.94(Al1-xGax)5O12 glass ceramics show blue shift from 545 nm to 525 nm with increasing Ga content (x value) under excited at 460 nm. Reliability test results show that the quantum yield (QY) of 0.06Ce:Y2.94(Al1-xGax)5O12 glass ceramics decreases from 70.60% to 59.06% with x value increasing from 0.15 to 0.35 under the ambient condition of 85℃/RH85% for the exposure time of 168 h. And the quantum yield (QY) of 0.06Ce:Y2.94(Al1-xGax)5O12 glass ceramics decreases from 65.13% to 52.23% after being soaked into boiled water for 4 h. The finding reveals that the addition of Ga can deteriorate the reliability of the color conversion glass ceramics.展开更多
We calculate the exclusive charmonium photo-production in the framework of color glass condensate.To obtain a good description of the vector meson production experimental data at HERA,we introduce a vector meson mass ...We calculate the exclusive charmonium photo-production in the framework of color glass condensate.To obtain a good description of the vector meson production experimental data at HERA,we introduce a vector meson mass dependent skewness factor into the skewness effect.Then we extend the skewness improved model to the LHC energies.The numerical results of our model are in good agreement with theΨ/Ψ and Ψ(2S)data in ultraperipheral proton-proton collisions at LHC,which show the significance of the vector meson mass-dependent skewness factor.A prediction of the exclusive charmonium photo-production in ultra-peripheral nucleus-nucleus collisions is performed since it can provide a good way to test the effectiveness of the color glass condensate.展开更多
Color is an important tool for glass industry to let the product gain additional aesthetic and functional properties forced by the market demands. In this context, it is necessary to understand the color forming mecha...Color is an important tool for glass industry to let the product gain additional aesthetic and functional properties forced by the market demands. In this context, it is necessary to understand the color forming mechanism better in order to get target color and improve the yield. A detailed experimental study to investigate the relationship between the manganese content on color formation and the redox condition was carried out. All experiments were carried out at different level of iron and manganese oxides. Color parameters (dominant wavelength, brightness (%), purity (%) and L-a-b values) were examined for large interval of batch redoxes. In this paper, the results of above mentioned experimental studies were discussed together.展开更多
The color conversion glass ceramics which were made of borosilicate matrix co-doped(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence propert...The color conversion glass ceramics which were made of borosilicate matrix co-doped(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence properties and the drift of chromaticity coordinates(CIE) of the(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors and the color conversion glass ceramics were studied in the sintering temperature range from 600℃ to 800℃. The luminous intensity and internal quantum yield(QY) of the blue-green phosphors and glass ceramics decreased with the sintering temperature increasing. When the sintering temperature increased beyond 750℃, the phosphors and the color conversion glass ceramics almost had no peak in photoluminescence(PL) and excitation(PLE) spectra. The results showed that the blue-green phosphors had poor thermal stability at higher temperature. The lattice structure of the phosphors was destroyed by the glass matrix and the Ce^3+ in the phosphors was oxidized to Ce^4+, which further caused a decrease in luminescent properties of the color conversion glass ceramics.展开更多
The lead glass used in an X-ray examination room is indispensable for watching a subject being tested or a situation of operation of an X-ray generator, but because it is some structure equipment of an X-ray examinati...The lead glass used in an X-ray examination room is indispensable for watching a subject being tested or a situation of operation of an X-ray generator, but because it is some structure equipment of an X-ray examination room, it must obey legal restrictions. Although the standard for lead glass is determined by the International Electrotechnical Commission (IEC), there are few reports about the characteristics related to interaction with radiation. We performed a comparison of three lead glass products, which are principally used in world. As for three products, differences are not looked by physics and chemical characteristics features. Simply the difference was looked by the coloring characteristic for an interaction with radiation. Furthermore, we checked that temporal decolorization of coloring had two half-lives. The short half-life is about 28 hours and the long half-life is about 107 days.展开更多
The effect of single coloring agent Nd(NO3)3 on the crystallization, microstructure and colorization of Li2O-Al2O3-SiO2 (LAS) glass ceramics were investigated by differential thermal analysis (DTA), X-ray diffractomet...The effect of single coloring agent Nd(NO3)3 on the crystallization, microstructure and colorization of Li2O-Al2O3-SiO2 (LAS) glass ceramics were investigated by differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The introduction of little neodymium has no effect on the crystallization manner and the formation of main crystallization phase, but more neodymium will weaken the crystallization of LAS glass. Little neodymium can increase the glossiness of LAS glass ceramic, while more neodymium can color LAS glass with light purple or red purple. The colorability of neodymium for LAS glass ceramic decreases with the increase of crystallization temperature.展开更多
A simulation of the stress analysis for a vacuum glass bulb of 35 inch (V) 120° Color Picture Tube(CPT) has been developed. It is shown that extra large deflection angle Color Picture Tube is viable. Increase ...A simulation of the stress analysis for a vacuum glass bulb of 35 inch (V) 120° Color Picture Tube(CPT) has been developed. It is shown that extra large deflection angle Color Picture Tube is viable. Increase in the deflection angle will shorten the de展开更多
We report a unique red light-emitting Eu-doped borosilicate glass to convert color for warm white light-emitting diodes. This glass can be excited from 394 nm-peaked near ultraviolet light, 466 nm-peaked blue light, t...We report a unique red light-emitting Eu-doped borosilicate glass to convert color for warm white light-emitting diodes. This glass can be excited from 394 nm-peaked near ultraviolet light, 466 nm-peaked blue light, to 534 nm- peaked green light to emit the desired red light with an excellent transmission in the wavelength range of 400-700 nm which makes this glass suitable for color conversion without a great cost of luminous power loss. In particular, when assembling this glass for commercial white light-emitting diodes, the tested results show that the color rendering index is improved to 84 with a loss of luminous power by 12 percent at average, making this variety of glass promising for inorganic "remote-phosphor" color conversion.展开更多
In this paper, the influences of catch-color agent content on glass-ceramic decorated material in the system of CaO-Al2O3-SiO2 were studied. By ladder temperature furnace and sintering shrinkage curve measurement . th...In this paper, the influences of catch-color agent content on glass-ceramic decorated material in the system of CaO-Al2O3-SiO2 were studied. By ladder temperature furnace and sintering shrinkage curve measurement . the influence of catch-color agent content on sintering and crystallization temperature was discussed. By means of XRD, three point bending strength and density measurement, the properties of the decorated material were investigated.展开更多
Taking R2-RO-BiOSiO2 system glasses as base,cadmi-um sulfide(CdS) and selenium (Se) powders as colorants, the author has succeeded in producing ruby selenium-cadmium iron-sealing glass-es with suitable coefficient of ...Taking R2-RO-BiOSiO2 system glasses as base,cadmi-um sulfide(CdS) and selenium (Se) powders as colorants, the author has succeeded in producing ruby selenium-cadmium iron-sealing glass-es with suitable coefficient of thermal expansion and other relevant properties necessary for iron-seeling.展开更多
Glasses of BaO-SrO-TiO2-SiO2 after electronic radiation treatment of 50 - 1000 kgy were studied by means of IR spectra, DTA and visible light absorption method. The result shows that the glass structure is changed due...Glasses of BaO-SrO-TiO2-SiO2 after electronic radiation treatment of 50 - 1000 kgy were studied by means of IR spectra, DTA and visible light absorption method. The result shows that the glass structure is changed due to the formation of structure defect from oxygen vacancy and E’ color center, which resultsd in the crystallization process and new precursors, and decreasement of Tg temperature and crystallization peaks by 20 -50℃.展开更多
基金Funded by the National Natural Science Foundation of China(No.51372102)
文摘Toxic Cu(Ⅱ) and Ni(Ⅱ) ions in aqueous solutions were adsorbed by microporous activated carbon(AC). The adsorption isotherm and kinetics correlation coefficients indicate that the adsorption of Cu(Ⅱ) and Ni(Ⅱ) ions on the AC fits the pseudo second-order rate model and Langmuir adsorption model. The used AC adsorbents containing the adsorbed Cu and Ni ions were used as colorant in glass preparation. The coloration effect of Cu ions was influenced by the carbon absorbent included in the glass batch due to the reduction phenomenon, while the coloration of Ni ions was not affected.
文摘The composition design and melting technique of colored glasses based on wollastonite was studied. The density, expansion coefficient, thermostability, durability and some optical properties of glasses were measured. The results show: These glasses have low melting temperature and short clarifying time. Their physicochemical properties were improved res- pectively to a certain degree.
基金Project supported by the National Natural Science Foundation of China(Grant No.51302171)the Science and Technology Commission of Shanghai Municipality,China(Grant No.14500503300)the Natural Science Foundation of Shanghai,China(Grant No.12ZR1430900)
文摘Color conversion glass ceramics are prepared by cosintering borosilicate glass frits and green 0.06Ce:Y2.94(Al1-xGax)5O12 phosphors. The crystal structures, the influence of Ga concentration on the photoluminescence (PL), and reliability properties of the color conversion glass ceramics are investigated. The PL emission wavelengths of 0.06Ce:Y2.94(Al1-xGax)5O12 glass ceramics show blue shift from 545 nm to 525 nm with increasing Ga content (x value) under excited at 460 nm. Reliability test results show that the quantum yield (QY) of 0.06Ce:Y2.94(Al1-xGax)5O12 glass ceramics decreases from 70.60% to 59.06% with x value increasing from 0.15 to 0.35 under the ambient condition of 85℃/RH85% for the exposure time of 168 h. And the quantum yield (QY) of 0.06Ce:Y2.94(Al1-xGax)5O12 glass ceramics decreases from 65.13% to 52.23% after being soaked into boiled water for 4 h. The finding reveals that the addition of Ga can deteriorate the reliability of the color conversion glass ceramics.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11765005,11305040,IRG11521064,11775097 and 11465021the Fund of Science and Technology Department of Guizhou Province under Grant No[2015]2114the Education Department of Guizhou Province under Grant No.KY[2017]004
文摘We calculate the exclusive charmonium photo-production in the framework of color glass condensate.To obtain a good description of the vector meson production experimental data at HERA,we introduce a vector meson mass dependent skewness factor into the skewness effect.Then we extend the skewness improved model to the LHC energies.The numerical results of our model are in good agreement with theΨ/Ψ and Ψ(2S)data in ultraperipheral proton-proton collisions at LHC,which show the significance of the vector meson mass-dependent skewness factor.A prediction of the exclusive charmonium photo-production in ultra-peripheral nucleus-nucleus collisions is performed since it can provide a good way to test the effectiveness of the color glass condensate.
文摘Color is an important tool for glass industry to let the product gain additional aesthetic and functional properties forced by the market demands. In this context, it is necessary to understand the color forming mechanism better in order to get target color and improve the yield. A detailed experimental study to investigate the relationship between the manganese content on color formation and the redox condition was carried out. All experiments were carried out at different level of iron and manganese oxides. Color parameters (dominant wavelength, brightness (%), purity (%) and L-a-b values) were examined for large interval of batch redoxes. In this paper, the results of above mentioned experimental studies were discussed together.
基金Project supported by the Science and Technology Planning Project of Zhejiang Province,China(Grant No.2018C01046)Enterprise-funded Latitudinal Research Projects,China(Grant Nos.J2016-141,J2017-171,J2017-293,and J2017-243)
文摘The color conversion glass ceramics which were made of borosilicate matrix co-doped(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence properties and the drift of chromaticity coordinates(CIE) of the(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors and the color conversion glass ceramics were studied in the sintering temperature range from 600℃ to 800℃. The luminous intensity and internal quantum yield(QY) of the blue-green phosphors and glass ceramics decreased with the sintering temperature increasing. When the sintering temperature increased beyond 750℃, the phosphors and the color conversion glass ceramics almost had no peak in photoluminescence(PL) and excitation(PLE) spectra. The results showed that the blue-green phosphors had poor thermal stability at higher temperature. The lattice structure of the phosphors was destroyed by the glass matrix and the Ce^3+ in the phosphors was oxidized to Ce^4+, which further caused a decrease in luminescent properties of the color conversion glass ceramics.
文摘The lead glass used in an X-ray examination room is indispensable for watching a subject being tested or a situation of operation of an X-ray generator, but because it is some structure equipment of an X-ray examination room, it must obey legal restrictions. Although the standard for lead glass is determined by the International Electrotechnical Commission (IEC), there are few reports about the characteristics related to interaction with radiation. We performed a comparison of three lead glass products, which are principally used in world. As for three products, differences are not looked by physics and chemical characteristics features. Simply the difference was looked by the coloring characteristic for an interaction with radiation. Furthermore, we checked that temporal decolorization of coloring had two half-lives. The short half-life is about 28 hours and the long half-life is about 107 days.
文摘The effect of single coloring agent Nd(NO3)3 on the crystallization, microstructure and colorization of Li2O-Al2O3-SiO2 (LAS) glass ceramics were investigated by differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The introduction of little neodymium has no effect on the crystallization manner and the formation of main crystallization phase, but more neodymium will weaken the crystallization of LAS glass. Little neodymium can increase the glossiness of LAS glass ceramic, while more neodymium can color LAS glass with light purple or red purple. The colorability of neodymium for LAS glass ceramic decreases with the increase of crystallization temperature.
文摘A simulation of the stress analysis for a vacuum glass bulb of 35 inch (V) 120° Color Picture Tube(CPT) has been developed. It is shown that extra large deflection angle Color Picture Tube is viable. Increase in the deflection angle will shorten the de
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 50872091 and 21076161)the Tianjin Municipal Sci/Tech. Commission, China (Grant Nos. 10SYSYJC28100 and 2006ZD30)the Tianjin Municipal Higher Education Commission, China (Grant No. 20110304)
文摘We report a unique red light-emitting Eu-doped borosilicate glass to convert color for warm white light-emitting diodes. This glass can be excited from 394 nm-peaked near ultraviolet light, 466 nm-peaked blue light, to 534 nm- peaked green light to emit the desired red light with an excellent transmission in the wavelength range of 400-700 nm which makes this glass suitable for color conversion without a great cost of luminous power loss. In particular, when assembling this glass for commercial white light-emitting diodes, the tested results show that the color rendering index is improved to 84 with a loss of luminous power by 12 percent at average, making this variety of glass promising for inorganic "remote-phosphor" color conversion.
文摘In this paper, the influences of catch-color agent content on glass-ceramic decorated material in the system of CaO-Al2O3-SiO2 were studied. By ladder temperature furnace and sintering shrinkage curve measurement . the influence of catch-color agent content on sintering and crystallization temperature was discussed. By means of XRD, three point bending strength and density measurement, the properties of the decorated material were investigated.
文摘Taking R2-RO-BiOSiO2 system glasses as base,cadmi-um sulfide(CdS) and selenium (Se) powders as colorants, the author has succeeded in producing ruby selenium-cadmium iron-sealing glass-es with suitable coefficient of thermal expansion and other relevant properties necessary for iron-seeling.
基金Funded by Natural Science Foundation of China ( No. E020201-59972028)
文摘Glasses of BaO-SrO-TiO2-SiO2 after electronic radiation treatment of 50 - 1000 kgy were studied by means of IR spectra, DTA and visible light absorption method. The result shows that the glass structure is changed due to the formation of structure defect from oxygen vacancy and E’ color center, which resultsd in the crystallization process and new precursors, and decreasement of Tg temperature and crystallization peaks by 20 -50℃.