The glass formability of NiBSimelt and the thermostability of this metallic glass formedfrom the the melt can be enhanced by eliminating the heterogeneous catalystg. The purificationwas done by cyclical superheating m...The glass formability of NiBSimelt and the thermostability of this metallic glass formedfrom the the melt can be enhanced by eliminating the heterogeneous catalystg. The purificationwas done by cyclical superheating melt in special glasses and subsequently cyclicallysuperheating it in an electromagnetic levitation apparatus. The purified NiBSiamorphoussample sized up to 20 ~ I0 x 0.5 mm was prepared as four times the thickness of unpurifiedones.展开更多
The effectsof melt overheating degree on the undercooling degree and resultant solidification structures of Nd9Fe85-xTi4C2Bx(x=10, 12) glass-forming alloyswerestudied by differential thermal analysis combining with ...The effectsof melt overheating degree on the undercooling degree and resultant solidification structures of Nd9Fe85-xTi4C2Bx(x=10, 12) glass-forming alloyswerestudied by differential thermal analysis combining with solidification structure analysis. The results indicate that the undercooling degree of Nd9Fe85-xTi4C2Bx(x=10, 12) alloys significantly increaseswith the rise of melt overheating degree, and two overheating degree thresholds corresponding to the drastic increase of the mean undercooling degree are found for each of the alloys. The existence of two turning points of the mean undercooling degreescan be linked to the structure transitions inside the overheated melts, which result in the evident increase of volume fraction of amorphous phasein the solidified structures.展开更多
文摘The glass formability of NiBSimelt and the thermostability of this metallic glass formedfrom the the melt can be enhanced by eliminating the heterogeneous catalystg. The purificationwas done by cyclical superheating melt in special glasses and subsequently cyclicallysuperheating it in an electromagnetic levitation apparatus. The purified NiBSiamorphoussample sized up to 20 ~ I0 x 0.5 mm was prepared as four times the thickness of unpurifiedones.
基金Projects(51174121,51274125)supported by the National Natural Science Foundation of ChinaProject(2010R50016-30)supported by Zhejiang Province Science and Technology Innovation Team of Key Projects,ChinaProject supported by the K.C.Wong Magna Fund of Ningbo University,China
文摘The effectsof melt overheating degree on the undercooling degree and resultant solidification structures of Nd9Fe85-xTi4C2Bx(x=10, 12) glass-forming alloyswerestudied by differential thermal analysis combining with solidification structure analysis. The results indicate that the undercooling degree of Nd9Fe85-xTi4C2Bx(x=10, 12) alloys significantly increaseswith the rise of melt overheating degree, and two overheating degree thresholds corresponding to the drastic increase of the mean undercooling degree are found for each of the alloys. The existence of two turning points of the mean undercooling degreescan be linked to the structure transitions inside the overheated melts, which result in the evident increase of volume fraction of amorphous phasein the solidified structures.