Flexural behavior of in-plane bending glass structures for design method

Experimental study was carried out on the in-plane bending behavior of glass plates without lateral supports, and the effects of the factors, such as height-to-span ratio, on the stability of glass panels were studied. Results show that the in-plane bending glass plates with both ends simply supported and their upper edge free lose overall stability under loads, which belongs to the limit-point type of instability. It is found that the buckling load increases linearly with the increase of height-to-span ratio of the glass plates. The lateral stress of in-plane bending glass plates without lateral supports increases linearly under loads; while the large-area stress increases nonlinearly and the lateral stress is not the controlling factor of instability. In finite element analysis, the first buckling mode is regarded as the initial imperfection and imposed on the model as 1/1000 of the span of the components. The numerical buckling load according to the theory of large deflection is less than the experiment result, which is more conservative and can provide some reference for design. For the design method, when the in-plane load is imposed on the glass plate, its lateral strength and the deflection should be verified. Considering the stability of the in-plane bending glass plate without reliable lateral support, buckling is another possible failure mode and calls for verification.

The Effect of Na_(2)O/B_(2)O_(3)Composition Ratio on the Structure and Properties of Cu^(+)Doped Luminescent Glass

Cu^(+)-doped alkali borosilicate glasses with different Na_(2)O contents were prepared by the melting method,and the effects of different R values(R=Na_(2)O/B_(2)O_(3))on the structure,ion presence state and luminescence properties of Cu^(+)-doped alkali borosilicate glasses were investigated.The analysis by FT-IR and Raman spectroscopy shows that,with the increase of R value of the glass,the[BO_(3)]in the structure of Cu^(+)-doped alkali borosilicate glass transforms into[BO_(4)]and the number of non-bridging oxygen in the glass network appears to be slightly increased.The absorption spectra and EPR analysis reveal that the Cu^(+)content in the glass gradually decreases and the Cu^(2+)content gradually increases as the R value of the glass increases.XPS and PL tests further indicate that the transformation of the octahedral coordination structure of Cu^(+)to the octahedral coordination structure of Cu^(2+)and the cubic coordination structure of Cu^(+)occurs in the glass as the R value of the glass increases.This transformation can effectively reduce the concentration quenching phenomenon of Cu^(+)and improve the fluorescence luminescence intensity of the glass samples.Meanwhile,the samples were found to have luminescence tunability as well as good thermal stability.

NMR Study on Structural Characteristics of Rare Earth Doped Boro-Alumino-Silicate Glasses

The structural characteristics of Re2O3 doped B2O3-Al2O3-SiO2 glasses and factors such as the component and heat-treating conditions affecting the glass structure were investigated by magic angle spin nuclear magnetic resonance （MAS NMR） spectroscopy and differential thermal analysis （DTA）. It is found that, in B2O3-Al2O3-SiO2 glass, the boron （4）, and Al（5）, Al（6） changes to Al（4）. On the other hand, compared with Ba^2＋ , RE^3＋ can accumulate the boron network because of its higher field strength, which results in a large network structure. With the increase of samarium oxide, the silicate coordination Qa（3T） will have predominance gradually. Heat-treatment has little effect on the boron and aluminum coordination sites in the glass structure.

Dynamic performance of cable net facade with consideration of glass panels under earthquake

Shaking table tests and theoretical analysis were conducted to study the dynamic performance of cable net facade with consideration of glass panels under earthquake. Firstly,the dynamic response of cable net faade under earthquake was investigated with shaking table test. Then the working mechanism of glass panels in coordination with cable net was proposed. Accordingly,a numerical simulation model of glass panel's working in coordination with cable net was built for the dynamic analysis.And then the seismic response was analyzed with this model theoretically. The study indicates that the seismic response of the cable net with glass panels on most occasions is mainly decided by the symmetric modes,and the first vibration mode is dominant. The damping of cable net facade is mainly decided by glass panels. And it is very good for cable net faade to restrain its dynamic response under earthquake.

Effect of^3B Group in Rings on Special Dispersion of B2O3-SiO2-ZrO2-Ta2O5-Na2O System Glass

Borosilicate glasses,with x B2O3-（60-x）SiO2-8ZrO2-8Ta2O5-24Na2O（7≤x≤59 mol%）composition,were fabricated by melt-quenching technique.NMR,UV-Vis,Raman and IR spectroscopic studies were utilized to investigate the structure of fabricated glasses.The NMR spectrum was deconvoluted into five Gaussian bands,assigned to ^4B（0B,4Si）,^4B（1B,3Si）,^4B（2B,2Si）,^3B（rings）and ^3B（loose）,to get their quantitative information.The relative dispersion deviation？P（g,F） was attributed to the relative quantity of ^3B（rings）but not all ^3B groups,and B2O3 existed mainly as[BO3]in rings firstly,and then as[BO3]in loose condition.The UV-Vis spectra revealed that the quantity of non-bridging oxygen increased firstly and then decreased with increasing concentration of B2O3.Acting as complementary techniques,Raman and IR measurements revealed that four-coordinated boron and silica mainly existed as ^4B-O-B,and Si-O-Si in Q^2,respectively,as chain structure but not framework structure,and[B？4]units prefered connections with borate rather than with silicate entities of the glass network in these studied glasses.In addition,the conclusion also certified that ^3B in＂loose＂condition located in lower wavenumbers between 1 200-1 600 cm^-1 in Raman spectra.

Structure and Nonlinear Refractive Index of Bismuth Borate Glass

The method of conventional glass melting is used to study the glass formation region of Bi2O3-B2O3-TiO2-La2O3 system. The instrument of Differential Scanning Calorimeter （DSC） is used to research the glass stability. Raman spectra and IR spectra are used to speculate on the structure of glasses. The refractive index of glass is measured by prism coupler. With increase of Bi2O3, the glass stability, the amount of [BiO3] group and boron-oxygen loops decrease, while the content of B-O- bond, refractive index and nonlinear refractive index increase.

Formation, Structure and Properties of Bulk Metallic Glasses

Bulk metallic glasses with up to 72 mm critical section thickness have been obtained by conventional casting techniques and the properties of these materials, particularly the mechanical and magnetic properties have been studied. These materials have been demonstrated to have novel properties which are fundamentally different from their crystalline counterparts. The recent status of research and development in formation, structure and properties of bulk metallic glasses is reviewed. The techniques to produce such bulk glasses are summarized and the glass forming ability and the critical cooling rate of these materials are discussed. Further consideration of the development and application of this new class of materiaIs will be proposed.

Effect of Ga_2O_3 on Structure and Properties of Calcium Aluminate Glasses

The effect of Ga_2O_3 on the structure and properties of calcium aluminate glasses fabricated by vacuum melting process was investigated by Raman spectrum, differential scanning calorimeter（DSC）, and infrared spectrum methods. The results show that calcium aluminate glass network only consists of [AlO_4] tetrahedral units. With the gradual addition of Ga_2O_3, the quantity of [GaO_4] tetrahedral units increases. Substitution of Ga_2O_3 for Al_2O_3 results in a decrease in Tg, Tx, and Tp, and an increase in the thermal stable index ΔT. Similarly, the absorption band around 3.0 μm obviously reduces and the transparency in 4.0-6.0 μm rapidly increases with increasing Ga_2O_3 content. However, the chemical stability of calcium aluminate glasses decreases if Ga_2O_3 is introduced due to the increasing of [GaO_4] units in the glass network.

Defect feature recognition method of glass fibre-reinforced structure based on visual image analysis

Glass fibre-reinforced(GFR)structure is extensively used in radome,spoiler and some other equipment.In engineering practice,due to the influence of wear,aging,impact,chemical corrosion of surface structure and other factors,the internal structure of this kind of structure gradually evolves into a defect state and expands to form defects such as bubbles,scratches,shorts,cracks,cavitation erosion,stains and other defects.These defects have posed a serious threat to the quality and performance of GFR structure.From the propagation process of GFR structure defects,its duration is random and may be very short.Therefore,designing a scientific micro defect intelligent detection system for GFR structure to enhance the maintainability of GFR structure will not only help to reduce emergencies,but also have positive theoretical significance and application value to ensure safe production and operation.Firstly,the defect detection mechanism of GFR structure is discussed,and the defect detection principle and defect area identification method are analyzed.Secondly,the processing process of defect edge signal is discussed,a classifier based on MLP is established,and the algorithm of the classifier is designed.Finally,the effectiveness of this method is proved by real-time monitoring and defect diagnosis of a typical GFR structure.The experimental results show that this method improves the efficiency of defect detection and has high defect feature recognition accuracy,which provides a new idea for the on-line detection of GFR structure defects.

Structure Evolution of Bulk Metallic Glass Zr_(52.5)Ni_(14.6)Al_10Cu_(17.9)Ti_5 during Annealing

Bulk metallic glass Zr_52.5Ni_14.6Al_10Cu_17.9Ti_5 was prepared by melt injection casting method. Its glass transition and crystallization temperatures were determined by differential scanning calorimetry (DSC) to be 631 K and 710 K respectively. By analysis of X-ray diffractometry (XRD) and transmission electron microscopy (TEM ), the predominant crystallized phase of Zr_2Ni0.67O0.33 distributed on glass state matrix was detected after annealing at 673 K for 600 s. The transformation to Zr_2Ni_0.67O_0.33 and a small amount of ZrAl and Zr_2Cu took place after annealing for 600 s at temperature from 703 K to 723 K. With increasing annealing temperature from 753 K to 823 K, the amounts of ZrAl and Zr_2Cu increased, but the size of the crystals did not significantly change. The transformation to Zr_2Ni_0.67O_0.33 is interface-controlled, but is diffusion-controlled to Zr_2Cu and ZrAl. With increasing annealing temperature up to 200 K above T_x, the nanometer grains became very fine because of the increase of nucleation rate for Zr_2Cu and ZrAl.

Effect of Electron Beam on the Structure and Crystallization Features of BaO-SrO-TiO_2-SiO_2 Glass

Glasses of BaO-SrO-TiO2-SiO2 after electronic radiation treatment of 50 - 1000 kgy were studied by means of IR spectra, DTA and visible light absorption method. The result shows that the glass structure is changed due to the formation of structure defect from oxygen vacancy and E’ color center, which resultsd in the crystallization process and new precursors, and decreasement of Tg temperature and crystallization peaks by 20 -50℃.

STUDY ON THE STRUCTURE OF IONIC CONDUCTOR FOR LiH-LiF-P_2O_5 GLASS SYSTEM

The system of LiH-LiF-P_2O_5 ionic conductor glass is prepared in neutral atmosphere and glass -forming region is given. The structure and coor- dination of glass are analyzed by IR spectra. Raman spectra and RDF(r). The result indicates that the (PO_4), (PO_3F) and (LiF_4) tetrahedra are basical structure units of glass network and the coordina- tion number of Li is 4. The coordination number of P is 4. The glass random network structure model is given. The study on structure shows that Li^+, H^- and partial F^- are charge carriers in glass system.

Interaction mechanism between arsenate and fayalite-type copper slag at high temperatures

The interaction mechanism between sodium arsenate and fayalite-type copper slag at 1200℃was investigated through XRD,XPS,HRTEM,TCLP and other technical means and methods.The results indicated that the proportions of sodium arsenate in the slag and flue gas phases were approximately 30%and 70%,respectively.The addition of sodium arsenate depolymerized the fayalite structure and changed it from a crystalline state to an amorphous state.The fayalite structural changes indicated that the[AsO_(4)]tetrahedron in sodium arsenate combined with the[SiO_(4)]tetrahedron and[FeO_(4)]tetrahedron through bridging oxygen to form a silicate glass structure.The TCLP test results of the samples before and after the high temperature reaction of fayalite and sodium arsenate showed that after high temperature reaction,fayalite could effectively reduce the leaching toxicity of sodium arsenate,reducing the leaching concentration of arsenic from 3025.52 to 12.8 mg/L before and after reaction,respectively.

COLOUR-CHANGING MECHANISM IN P_2O_5-Nb_2O_5-Li_2O NONCRYSTALLINE SYSTEM

Raman, IR spectra, RDF and visible spectrum were used to study the glass structure and the valence states of niobium ions in P_2O_5-Nb_2O_5-Li_2O noncrystalling system. The colour-changing mechanism was studied. For 10Nb_2O_5xP_2O_5(90-x)Li_2O (x=40,45,50,55) system glasses, it was known that the glass colout changing from light gold-yellow to blue with increasing is aroused by the Nb^(3+) ion increasing, not by the change of niobium ion coordination.

Cooling rate calibration and mapping of ultra-short pulsed laser modifications in fused silica by Raman and Brillouin spectroscopy

This paper focuses on the preparation of a new extended set of calibrations of cooling rate(fictive temperature)in fused silica determined by inelastic light scattering and its subsequent use to characterize the local cooling rate distribution in ultra-short pulsed(USP)laser modification.In order to determine the thermal history(e.g.cooling rate and fictive temperature)of fused silica,high-resolution inelastic light-scattering experiments(Raman and Brillouin spectroscopy)were investigated.Calibrations were performed and compared to the existing literature to quantify structural changes due to a change of fictive temperature.Compared to existing calibrations,this paper provides an extension to lower and higher cooling rates.Using this new set of calibrations,we characterized a USP laser modification in fused silica and calculated the local fictive temperature distribution.An equation relating the fictive temperature(Tf)to cooling rates is given.A maximum cooling rate of 3000 K min-1 in the glass transition region around 1200℃ was deduced from the Raman analysis.The Brillouin observations are sensitive to both the thermal history and the residual stress.By comparing the Raman and Brillouin observations,we extracted the local residual stress distribution with high spatial resolution.For the first time,combined Raman and Brillouin inelastic light scattering experiments show the local distribution of cooling rates and residual stresses(detailed behavior of the glass structure)in the interior and the surrounding of an USP laser modified zone.

Deformation Measurement of Glass Structure Using FBG Sensor

Glass has been widely used as an important component in structures such as reflection glass curtainwalls,high speed trains,and landscape glass bridges with advantages of transparent and easy to clean,which are exposed to extreme weather conditions and external loads.Over time,these factors can lead to a damage of glass.So the health status of glass structure is critical,which should be routinely monitored to improve safety and provide reliable maintenance strategy.In this paper,fiber Bragg grating(FBG)sensors are used to monitor glass damage based on the fact that the main components of both the optical fiber and the glass are silica,which hints that both optical fiber and glass have the similar mechanical properties.Furthermore,the diameter of FBG installed on the glass structure is small,which has little effect on the beauty of glass.In order to validate the feasibility of the damage monitoring method,one common glass panel model with two-side fixations is loaded impact and static loads respectively,on the upper and lower surfaces of which four FBG sensors and two resistance strain gages are installed.A comparison study among the measured strains from the FBG sensors,those from the resistance strain gages,and those calculated from finite element model(FEM)analysis is conducted and the result obtained with experiments agrees with the element result.Test results show that the FBG sensors can effectively measure the glass deformation or damage under the impact and static load.

Thermal and structural properties of Nd2O3-doped calcium boroaluminate glasses

Nd^3＋ doped CaO-Al2O-B2O3-CaF2 glasses were prepared by conventional melt-quenching technique,and their structural and thermal properties were studied.The amorphous nature of these samples was confirmed by X-ray diffraction（XRD）.The measured density showed an increase with Nd2O3 doping,at the expense of CaO.Raman spectra presented changes with addition of Nd2O3,which indicated that the network structure of the glasses studied presented various borate groups,such as tetraborates,metaborates,ortho-borates and pyroborates units.The N4 values calculated from FTIR spectra revealed that incorporation of Nd2O3 into glass network converted the structural units from BO4 to BO3.From the analysis of DTA curves,we verified that Tg increased with the addition of Nd2O3;it was similar to the behavior caused by modifier oxides in the structure of borate glasses.Besides that,the calculated glass stability Tx–Tg for doped samples presented a decrease if compared to the undoped glass.Specific heat and thermal conductivity did not present significant changes with Nd2O3 concentration,up to 2.30 mol.%.The results of density,DTA,Raman and FTIR reinforced the idea that Nd2O3 acted as network modifier.

Amorphization of Ni_(61)Nb_(39) Alloy by Laser Surface Treatment

The surface of Ni_（61）Nb_（39） crystalline ingot was treated by laser surface melting with different processing parameters.A fully amorphous layer with a thickness of approximately 10μm could be produced on the top surface under optimal parameters.An amorphous-crystalline composite layer with the depth from 10 to 50μm,consisting of amorphous matrix and intermetallic phases of Ni_3 Nb and Ni_6Nb_7,could be formed.The micro-hardness（about 831HV）of the treated surface was remarkably improved by nearly 100% compared with the value of the crystalline substrate caused by the formation of the fully amorphous structure.A finite volume simulation was adopted to evaluate the temperature distribution in the laser-affected zone of Ni_（61）Nb_（39） alloys and to reveal the mechanism of glass formation in the laser-affected zone.