The study was conducted to determine the applicability of gravity separation method on the Ashashire gold ore deposit Benishangul gumuz region, western Ethiopia. The Ashashire composite was produced to provide suffici...The study was conducted to determine the applicability of gravity separation method on the Ashashire gold ore deposit Benishangul gumuz region, western Ethiopia. The Ashashire composite was produced to provide sufficient mass for this study and experiment, including sample preparation, mineralogical analysis of gold and associated elements, gravity concentration, and data interpretation and analysis. During the study, a grind optimization was conducted on the composites sample with varying grind size to evaluate the effect of grind size on gold recovery. The ore was moderately ground to the standard grind size of 80%, passing 106 µm, 75 µm, 53 µm and this nominal size was selected for the preliminary assessment for concentration optimization for this deposit. The gravity testing comprised three-stage concentration using Knelson concentrator. High recovery of gold from the gravity concentrates was achieved from the second gravity concentration. Based on the laboratory experimental result analysis, a grind size of P80 75 µm is selected as optimal size for the Ashashire gold deposit. Increasing the grind size from P80 of 75 µm to 106 µm decreases the recovery rate from 75% to 54%, or decreasing the grind size from P80 of 75 µm to 53 µm decreases the gold recovery rate to 37%. The native gold grain in the ores is mostly associated with quartz and fine gold is closely associated with pyrite. According to analysis of the fire assay, chemical, and mineralogical data, only gold and telluride is commercially valuable elements in the ores. Predominantly gold was occurred in the native form of Au-Te. The sample subjected to gravity separation assayed about 2.6 g/t Au.展开更多
X-ray fluorescence(XRF)sensor-based ore sorting enables efficient beneficiation of heterogeneous ores,while intraparticle heterogeneity can cause significant grade detection errors,leading to misclassifications and hi...X-ray fluorescence(XRF)sensor-based ore sorting enables efficient beneficiation of heterogeneous ores,while intraparticle heterogeneity can cause significant grade detection errors,leading to misclassifications and hindering widespread technology adoption.Accurate classification models are crucial to determine if actual grade exceeds the sorting threshold using localized XRF signals.Previous studies mainly used linear regression(LR)algorithms including simple linear regression(SLR),multivariable linear regression(MLR),and multivariable linear regression with interaction(MLRI)but often fell short attaining satisfactory results.This study employed the particle swarm optimization support vector machine(PSO-SVM)algorithm for sorting porphyritic copper ore pebble.Lab-scale results showed PSO-SVM out-performed LR and raw data(RD)models and the significant interaction effects among input features was observed.Despite poor input data quality,PSO-SVM demonstrated exceptional capabilities.Lab-scale sorting achieved 93.0%accuracy,0.24%grade increase,84.94%recovery rate,57.02%discard rate,and a remarkable 39.62 yuan/t net smelter return(NSR)increase compared to no sorting.These improvements were achieved by the PSO-SVM model with optimized input combinations and highest data quality(T=10,T is XRF testing times).The unsuitability of LR methods for XRF sensor-based sorting of investigated sample is illustrated.Input element selection and mineral association analysis elucidate element importance and influence mechanisms.展开更多
The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurre...The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurrences. Those deposits are mainly clustered(from west to east) within the Tongguanshan, Shizishan, Xinqiao, Fenghuangshan, and Shatanjiao orefields. Until recently, the majority of these deposits were thought to be skarn-or porphyry–skarn-type deposits; however there have been recent discoveries of numerous vein-type Au, Ag, and Pb-Zn deposits that do not fall into either of these categories. This indicates that there is some uncertainty over this classification. Here, we present the results of several systematic geological studies of representative deposits in the Tongling ore district. From investigation of the ore-controlling structures, lithology of the host rock, mineral assemblages, and the characteristics of the mineralization and alteration within these deposits, three genetic types of deposits(skarn-, porphyry-, and vein-type deposits) have been identified. The spatial and temporal relationships between the orebodies and Yanshanian intrusions combined with the sources of the ore-forming fluids and metals, as well as the geodynamic setting of this ore district, indicate that all three deposit types are genetically related each other and constitute a magmatic–hydrothermal system. This study outlines a model that relates the polymetallic copper–gold porphyry-, skarn-, and vein-type deposits within the Tongling ore district. This model provides a theoretical basis to guide exploration for deep-seated and concealed porphyry-type Cu(–Mo, –Au) deposits as well as shallow vein-type Au, Ag, and Pb–Zn deposits in this area and elsewhere.展开更多
The Naruo porphyry copper-gold deposit (hereinafter referred to as the Naruo deposit) in Tibet is a potentially ultra-large, typical gold-rich porphyry copper deposit, which was recently discovered in the Bangongco-...The Naruo porphyry copper-gold deposit (hereinafter referred to as the Naruo deposit) in Tibet is a potentially ultra-large, typical gold-rich porphyry copper deposit, which was recently discovered in the Bangongco-Nujiang metallogenic belt. This study analyzed U-Ph chronology and Hf isotopes of the ore-bearing granodiorite porphyry in the Naruo deposit using the LA-ICPMS dating technique. The results show that the weighted average age is 124.03±0.94Ma (MSWD=1.7, n=20), and 2±6pb/23SU isocbron age is 126.2±2.7 Ma (MSWD=1.02, n=20), both of which are within the error. The weighted average age represents the crystallization age of the granodiorite porphyry, which indicates that the ore-bearing porphyry in the Naruo deposit area was formed in the Early Cretaceous and further implies that the Neo-tethys Ocean had not been closed before 124 Ma under a typical island-arc subduction environment. The εGr(t) of zircons from the granodiorite porphyry varies from 2.14 to 9.07, with an average of 5.18, and all zircons have εRf(t) values greater than 0; 176Hf/177Hf ratio is relatively high (0.282725-0.282986). Combined with the zircon age--Hf isotope correlation diagram, the aforementioned data indicate that the source reservoir might be a region that is mixed with depleted mantle and ancient crust, which possibly contains more materials sourced from depleted mantle. Rock-forming ages and ore-forming ages of the Duolong ore concentrate area are 120-124 Ma and 118-119 Ma, respectively, which indicate 124-118 Ma represents the main rockforming and ore-forming stage within the area. The Naruo deposit is located in the north of the Bangongco-Nujiang suture, and it yielded a zircon LA-ICPMS age of 124.03 Ma. This indicates the Bangongco-Nujiang oceanic basin subducted towards the north at about 124 Ma, and the Neo-tethys Ocean had not been closed before the middle Early Cretaceous. It is possible that the crust-mantle mixing formed the series of large and giant porphyry copper-gold deposits in the Bangongco.展开更多
The refractory gold ores associated with rich copper and trapped in pyrite and quartz were studied. With conventional technique (all-sliming cyanidation), the gold recovery rate is only 51.78%. To eliminate the nega...The refractory gold ores associated with rich copper and trapped in pyrite and quartz were studied. With conventional technique (all-sliming cyanidation), the gold recovery rate is only 51.78%. To eliminate the negative effects of copper and pyrite on cyanidation and increase the gold recovery rate, the investigation on bio-heap leaching pretreatment was made, by which Cu would be dissolved and gold would be liberated from pyrite. The experiment adopted mixed bacteria, mainly ThiobaciUus ferrooxidan (named T.fl ), as the bacterial catalyst for bio-preconditioning and was carried out in a PVC column with a diameter of 20 cm and a height of 1.3 m loaded with gold ores. The temperature was controlled between 28 and 30℃, the pH value was kept between 2.0-2.5, and the flux of sprinkling bacterial liquid was maintained 0.80 L/h. After 45-day's bio-oxidization, among the samples sizing from 0 to 5 mm, the oxidation rates of Cu, Fe and S were respectively 44.62%, 28.16% and 25.46%, and the gold recovery rate by cyaniding increased to 80.35%. The bio-heap leaching pretreatment can therefore effectively dissolve Cu and liberate gold from pyrite and lead to the increase of gold extraction.展开更多
Shizishan ore-field is a nonferrous and noble metal ore-field which is most rich in copper and gold.There are many types of fluid inclusions in minerals of the deposits.The homogeneous temperatures and the salinities ...Shizishan ore-field is a nonferrous and noble metal ore-field which is most rich in copper and gold.There are many types of fluid inclusions in minerals of the deposits.The homogeneous temperatures and the salinities of the fluid inclusions in main mineralization stages have wide ranges,while the different types of the fluid inclusions existed together and their homogeneous temperatures are almost identical in the same mineralization stage,which indicates that the ore-forming process has great relation with the fluid boiling.The gas and liquid chemical compositions and the carbon,hydrogen and oxygen isotopic compositions of the fluid inclusions show that the ore-forming fluids of copper-gold deposits have the same characteristics and evolution tendency,which reflects that the ore-forming material mainly came from the magmatism.The stratigraphic component and the meteoric water may mix in ore- forming fluids in the later mineralization stages.Furthermore,with the fall of the ore-forming temperature the ratios of water and rock decreased.The characteristics of chemical composition and carbon isotopic composition of fluid inclusions indicate that CH4 may play an important role for separating copper and gold in the ore-forming process.展开更多
Gold concentration usually consists of gravity separation, flotation, cyanidation, or the combination of these processes. The choice among these processes depends on the mineralogical characterization and gold content...Gold concentration usually consists of gravity separation, flotation, cyanidation, or the combination of these processes. The choice among these processes depends on the mineralogical characterization and gold content of the ore. Recently, the recovery of gold using gravity methods has gained attention because of low cost and environmentally friendly operations. In this study, gold pre-concentrates were produced by the stepwise gravity separation and flotation techniques. The Knelson concentrator and conventional flotation were employed for the recovery of gold. Gold bearing ore samples were taken from Gümüshane Region, northern east part of Turkey. As a result of stepwise Knelson concentration experiments, a gold concentrate assaying around 620 g/t is produced with 41.4wt% recovery. On the other hand, a gold concentrate about 82 g/t is obtained with 89.9wt% recovery from a gold ore assaying 6 g/t Au by direct flotation.展开更多
On the basis of results of the studies of primary fluid inclusions, and the hydrogen and oxygen isotope data, the authors concluded that the early-stage ore-forming fluid from the Jinchangqing gold (copper) ore deposi...On the basis of results of the studies of primary fluid inclusions, and the hydrogen and oxygen isotope data, the authors concluded that the early-stage ore-forming fluid from the Jinchangqing gold (copper) ore deposit is a kind of sulfate type hot brine characterized by medium temperature and salinity, genetically related to the late-stage ore-forming fluid derived from an acidic and more reductive environment. However, the late-stage ore-forming fluid is a sort of low temperature and low salinity chloride-type hot brine which originated from a lower pressure, acidic and more oxidative environment. In general, the ore fluids were derived from the late-stage, or largely from the early-stage groundwater-derived meteoric water, which has a 12‰-17‰ heavier oxygen isotopic composition than the original rain water (δ{}+{18}O={-15.3‰}), and were formed during gold mineralization as a product of oxygen isotope exchange during the reaction between ore-forming fluid and wall rocks under a lower water/rock ratio condition.展开更多
The present work investigated microbial leaching of zinc from ore using Acidithiobacillus ferrooxidans (ATCC 14859). The ore samples, consisted of 13wt% zinc, were obtained from a gold mine in north-eastern Thailand...The present work investigated microbial leaching of zinc from ore using Acidithiobacillus ferrooxidans (ATCC 14859). The ore samples, consisted of 13wt% zinc, were obtained from a gold mine in north-eastern Thailand. A shake flask study was performed on the ore samples using a rotary shaker under the following fixed conditions (250 r·min^-1, 30℃ for 16 d). The influence of various conditions, namely medium type (with and without iron), particle ore size (〈20, 20-40, 40-60, 60-100, and 〉100 mesh), ore density (20 kg·m^-3, 50 kg·m^-3, and 100 kg·m^-3), and pH of the medium (2, 2.5, 2.8, and 3), were investigated. The microbial leaching was assessed by determining the concentration of zinc in the medium and compared with the initial sample concentration. The results show that Acidithiobacillus ferrooxidans can successfully leach zinc by as much as 6 times compared with the control experiment (without Acidithiobacillus ferrooxidans ferrooxidans). The maximum efficiency (92.3%) for microbial leaching is obtained in iron-containing medium, 20-40 mesh ore sizes, 20 kg·m^-3 ore density at pH 2.8, and the zinc content is found in the medium at about 120 mg·m^-1.展开更多
The Liziyuan gold deposit, situated on the south side of the Shangdan suture zone, West Qinling Orogen, occurs in metamorphic volcanic rocks(greenschist facies) of the early Paleozoic Liziyuan Group and in Indosinian ...The Liziyuan gold deposit, situated on the south side of the Shangdan suture zone, West Qinling Orogen, occurs in metamorphic volcanic rocks(greenschist facies) of the early Paleozoic Liziyuan Group and in Indosinian Tianzishan monzogranite. Orebodies in the Liziyuan gold field are controlled by the ductile-brittle shear zone, and by thrusting nappe faults related to the Indosinian orogeny. In detail, this paper analyzed the geological characteristics of the Liziyuan gold field, and the Pb isotopes of the Lziyuan host rocks, granitoids(Tianzishan monzogranite and Jiancaowan syenite porphyry), sulfides, and auriferous quartz veins by multiple-collector inductively coupled plasma mass spectrometry(MC-ICPMS). In addition, previous data on the sulfur, hydrogen, and oxygen isotopes were employed to discuss the possible sources of the ore-forming fluids and materials, and to further understand the tectonic setting of the Liziyuan gold deposit. The sulfides and their host rocks(Lziyuan Group), Tianzishan monzogranite and Jiancaowan syenite porphyry, and auriferous quartz veins have similar Pb isotopic compositions.Zartman’s plumbotectonic model diagram shows that most of the data for the deposit fall near the orogenic Pb evolutionary curve or within the area between the orogenic and mantle Pb evolutionary curves. In the△β-△γ diagram, which genetically classifies the lead isotopes, most of the data fall within the range of the subduction-zone lead mixed with upper crust and mantle. This indicates that a complex source of the ore lead formed in the orogenic environment. The δ34S values of the sulfides range from 3.90 to 8.50‰(average6.80‰), with a pronounced mode at 5.00‰-8.00‰. These values are consistent with that of orogenic gold deposits worldwide, indicating that the sulfur sourced mainly from reduced metamorphic fluids. The isotopic hydrogen and oxygen compositions support a predominantly metamorphic origin of the oreforming fluids, with possible mixing of minor magmatic fluids, but the late stage was dominated by meteoric water. The characteristics of the Liziyuan gold deposit formed in the Indosinian orogenic environment of the Qinling Orogen are consistent with those of orogenic gold deposits found worldwide.展开更多
The extraction process of gold and silver from the gold clay ore containing arsenic and manganese was investigated.With the conventional technique,the leaching rates of gold and silver are 78.23%and 49.02%,respectivel...The extraction process of gold and silver from the gold clay ore containing arsenic and manganese was investigated.With the conventional technique,the leaching rates of gold and silver are 78.23%and 49.02%,respectively.To eliminate the negative effects of arsenic and manganese on cyanidation and increase the gold and silver leaching rates,a novel catalyst was added.The content of the catalyst used in the process was 8 g per 500 g org sample,the sample size was 60μm and the pH value was kept between 10 and 11.Leaching with the catalyst for 3-5 h under certain conditions,the gold leaching rate increased to over 90%and the silver leaching rate increased to 80%-90%.The catalyst can effectively liberate gold and silver from the enclosure of arsenic and manganese and the industrial experiment has great significance to the development and utilization of the gold clay ore containing arsenic and manganese.展开更多
Three major types of Ordovician intrusive-related gold-copper deposits are recognized in central-west New South Wales, Australia: porphyry, skarn and high sulphidation epithermal deposits. These deposits are mainly di...Three major types of Ordovician intrusive-related gold-copper deposits are recognized in central-west New South Wales, Australia: porphyry, skarn and high sulphidation epithermal deposits. These deposits are mainly distributed within two Ordovician volcano-intrusive belts of the Lachlan Fold Belt: the Orange-Wellington Belt and the Parkes-Narromine Belt. Available isotopic age data suggest that mineralization of the three types of deposits is essentially coeval with the Ordovician intrusive rocks (480-430 Ma).Porphyry gold-copper deposits can be further divided into two groups. The first group is associated with monzonite showing shoshonitic features, represented by Cadia and Goonumbla. The second group is associated with diorite and dacite, including the Copper Hill and Cargo gold-copper deposits. Gold skarn is associated with Late Ordovician (430-439 Ma) monzonitic intrusive complexes in the Junction Reefs area (Sheahan-Grants, Frenchmans, and Cor-nishmens), Endeavour 6, 7 and 44, Big and Little Cadia. The epithermal gold deposits with high sulphidation including Gidginbung (Temora) and Peak Hill mainly occur within Ordovician andesite and volcaniclastic rocks, and are associated with advanced argillic alteration. Available isotopic age data indicate that both alteration and mineralization of the porphyry, skarn and epithermal gold-copper deposits are broadly coeval with the Late Ordovician shoshonitic magmatism, which is thought to result from the melting of sub-continental lithosphere caused by Palaeozoic subduction events.The Ordovician intrusive-related gold-copper deposits are restricted to two longitudinal parallel volcano-intrusive belts, rarely extending outside them. Diagonal intra-belt trends of mineralization are common, particularly at the intersections of longitudinal and transverse (oblique) fault/fracture zones based on the authors' review of available geological data. The locations of these gold-copper deposits are obviously influenced by transverse (oblique) fault/fracture zones that are oriented northwest, eastwest and northeast. The conjunctions of these fault/fractures zones are thought to be zones of structural weakness, and appear to be the favourable locus for the Ordovician intrusive-related gold-copper deposits. Differences in structural patterns, intrusive, wall rock types, and depths of ore formation may contribute to the differences among the deposits.展开更多
Underground prospecting within the L ubin- Sieroszowice mining area which took place during last5 years,led to a discovery of a new type of Au,Pt and Pd mineralisation located 0 - 0 .5 m below the copper- silver orebo...Underground prospecting within the L ubin- Sieroszowice mining area which took place during last5 years,led to a discovery of a new type of Au,Pt and Pd mineralisation located 0 - 0 .5 m below the copper- silver orebody in the south- western part of the Polish Permian Basin.The gold- bearing zone lies mainly in the Weissliegendessandstone (L ower Permian) , butlocally transgresses the stratigraphic sequence into the overlying kupferschieferand Wer- ra limestone(Zechstein) .Gold deposit lies in a secondary red- coloured variety of the above mentioned sedimentary strata.The oxidation in the underlying sandstone is reflected by red spots and dots containing fine grains of hematite dispersed in a carbonate- clay matrix.The secondary oxidation is peneconcordant in relation to the reducing facies which contains cop- per sulphides and to the Rote Faule,thatis early diagenetic.Between redbeds(gold bearing zone) and black,reduced sediments (Kupferschiefer) ,a transition zone has been recognized. This transition zone is characterized by the low grade of copper mineralisation.Thickness of the gold depositvaries from few centimetresto1.5 metres with an average of about0 .2 5 me- tres.The highestthickness of Au- depositis observed in placeswhere oxide fronttransgress- es the copper- silver deposit.Gold content ranges from 0 .5 up to 10 6 ppm with an average grade of(0 .717- 3.491)× 10 -6depending on the counting block.Gold- bearing horizon is peneconcordantand is characterized by the presence of high fineness native gold,electrum, hematite,and minor pyrite,chalcopyrite,digenite,chalcocite,covellite,rammelsbergite, clausthalite and展开更多
Microwave radiation was employed as a pretreating technology to oxidise a refractory gold ore. Heating characteristics showed that, in an identical microwave field, the bulk temperature of the sample increased with mi...Microwave radiation was employed as a pretreating technology to oxidise a refractory gold ore. Heating characteristics showed that, in an identical microwave field, the bulk temperature of the sample increased with microwave power, microwave radiation time and particle size. The rate of sulphur removal increased with microwave radiation time. Particle size also had a significant effect on the oxidation rate. Pyrite and marcasite could be oxidised into Fe 2O 3 with a high porous structure. When microwave radiation was carried out in a rotary bed, the oxidation was more uniformly developed, in comparison with in a fixed bed. Gold extraction by cyanidation could be remarkably improved after the ore was subjected to microwave radiation. The results showed that gold recovery could be improved from 37% to 69%~ 81.2 %.展开更多
The Shaxi porphyry copper (gold) deposits are a typical example of porphyry copper deposits associated with diorite in eastern China. Quartz diorite, which hosts the deposits, has a Rb-Sr isochron age of 127.9 ± ...The Shaxi porphyry copper (gold) deposits are a typical example of porphyry copper deposits associated with diorite in eastern China. Quartz diorite, which hosts the deposits, has a Rb-Sr isochron age of 127.9 ± 1.6 Ma. Geochemically, the rock is rich in alkalis (especially sodium), light rare earth elements (LREE) and large-ion lithophile elements (LILE), and has a relatively low initial strontium isotopic ratio (Isr=0.7058); thus it is the product of differentiation of crust-mantle mixing source magma. The model of alteration and mineralization zoning is similar to the Hollister (1974) diorite model. The ore fluids have a relatively high salinity and contain significant amounts of CO2, Ca2+, Na+ and ***CI?. The homogenization temperatures of fluid inclusions for the main mineralization stage range from 280 to 420°C, the δ18O values of the ore fluids vary from 3.51 to 5.52 %, the δD values are in the range between ?82.4 and ?59.8 %, the δ34S values of sulphides vary from ?0.3 to 2.49 %, and the δ13C values of CO2 in inclusions range between ?2.66 and ?6.53 %. Isotope data indicate that the hydrothermal ore fluids and ore substances of the Shaxi porphyry copper (gold) deposits were mainly derived from magmatic systems.展开更多
Mechanochemical sulfidization of a mixed sulfide/oxide copper ore by co-grinding with sulfur and additives including Mg(NO3)2 and Fe(NO3)3 salts and iron,aluminum and magnesium powders was investigated for the first t...Mechanochemical sulfidization of a mixed sulfide/oxide copper ore by co-grinding with sulfur and additives including Mg(NO3)2 and Fe(NO3)3 salts and iron,aluminum and magnesium powders was investigated for the first time.Also,the influence of sulfidization during the wet-milling process was examined on the separation efficiency and recovery of copper in detail.The results demonstrated that co-grinding with sulfur solely had the best flotation performance at the value of 0.5 wt.%and it was attributed to the possible existence of S\\O bonding on copper oxides surfaces.In addition,adding magnesium nitrate salt,magnesium powder,iron nitrate salt and aluminum powder as additive associated with 0.5 wt%sulfur into ball milling caused the flotation improvement at the amounts of 0.2 wt%,0.2 wt%,0.5 wt%and 0.5 wt%,respectively.Also,the effect of grinding time and sulfidization pH with 0.5 wt%sulfur solely was determined and pH s of 7.5 to 8.5 gave the best results.The highest recovery(75.76%)and separation efficiency(63.44%)were achieved at pH of 7.5 and 8.5,respectively.展开更多
While roasting has been widely applied to reduce the negative effect of carbonaceous matters on gold extraction from fine-grained carbonaceous gold ores, the phase and structure changes of minerals during roasting and...While roasting has been widely applied to reduce the negative effect of carbonaceous matters on gold extraction from fine-grained carbonaceous gold ores, the phase and structure changes of minerals during roasting and their in fluences on the leachi ng rate of gold have not been fully understood. This limits the extraction of carbonaceous gold deposits. The current work examines the oxidation process of a fine-grained carbonaceous gold ore during roasting using a range of techniques including X-ray diffraction (XRD), seanning electron microscopy (SEM), Energy Dispersive Spectrometer (EDS) analysis and pore structure analysis together with gold leaching tests. The results show that during the process of oxidative roasting, the carbonaceous matters (organic carbon and graphitic carbon) and pyrite were completely decomposed at 600 ℃ with the carbonaceous components burned and pyrite oxidized into hematite. At 650 ℃, while dolomite was decomposed into calcia, magnesia, calcium sulfate etc., the calcine structure became loose and porous, leading to a high gold leaching rate from the roasted product. Above 750 ℃, the porous calcite structure started to collapse along with the agglomeration, leading to the secondary encapsulation of gold particles, which contributed to the sharp drop in the gold leaching rate of the roasted product. This study suggests optimum phase and structure changes of minerals during roasting to achieve maximum gold extraction from fine-grained carbonaceous gold deposits.展开更多
The resources of refractory gold ores are abundant, and their effective treatment can bring good economic benefits. This paper investigated the kinetics of leaching gold from refractory gold ores by ultrasonic-assiste...The resources of refractory gold ores are abundant, and their effective treatment can bring good economic benefits. This paper investigated the kinetics of leaching gold from refractory gold ores by ultrasonic-assisted electro-chlorination. The effects of ultrasound time ratio, initial hydrochloric acid concentration and leaching temperature on the kinetic parameters were discussed. It is found that the leaching ratio goes up with all the factors increasing. The reaction kinetics is controlled by diffusion. When ultrasound improves the diffusion by reducing the diffusion resistance, the activation energy increases to 37.1 kJ/mol.展开更多
Platinum-group elements (PGE) in PGE-rich porphyry copper (gold) deposits are mainly Pt and Pd, whereas the concentrations of other PGE (Ru, Rh, Os, Ir) are significantly low. Moreover, Pt and Pd mainly exist in...Platinum-group elements (PGE) in PGE-rich porphyry copper (gold) deposits are mainly Pt and Pd, whereas the concentrations of other PGE (Ru, Rh, Os, Ir) are significantly low. Moreover, Pt and Pd mainly exist in sulfides in the forms of crystal lattice or tiny platinum-group mineral (PGM) inclusions. The present data show that there is a positive relationship between Pt and Pd concentrations and Cu (Au) in porphyry copper (gold) deposits. The comparison of chondrite-normalized PGE distribution patterns between the ore-bearing porphyry intrusions and ore-barren porphyry intrusions in arc setting, 187^Os/188^Os, 87^Sr/86^Sr and S isotopes for porphyry copper (gold) deposits shows that PGEs were mainly derived from the mantle, and fluids from subduction zones devoted trivial PGE to the magma. The porphyry copper (gold) deposits associated with subducted events are most probably enriched in PGE, whereas those related to crustal thickening, lithospheric delamination or underplating rarely concentrate PGE. The osmium isotopic compositions in porphyry copper (gold) deposits reveal that (187^Os/188^Os)i values are highly variable and not lower than those of primitive upper mantle (PUM) and mantle peridotite, however, osmium concentrations are commonly lower than mantle peridotite, suggesting that parental magmas of some porphyry intrusions had experienced crustal contamination during magma evolution. Experimental investigations have proved that PGE exist in the forms of Cl^- and HS^- complexes during transportation and migration of the oreforming fluids. This paper summarizes previous studies including crucial controlling factors and mechanisms for PGE enrichment, and points out that the mantle-derived magmas parental to porphyry intrusions are the prerequisite for PGE enrichment in porphyry copper (gold) deposits. Favorable physical and chemical conditions (including salinity, temperature, pressure, pH, and oxygen fugacity) in hydrothermal fluids crucially control the PGE enrichment, and sulfur concentrations of melts play important roles in this process as well.展开更多
文摘The study was conducted to determine the applicability of gravity separation method on the Ashashire gold ore deposit Benishangul gumuz region, western Ethiopia. The Ashashire composite was produced to provide sufficient mass for this study and experiment, including sample preparation, mineralogical analysis of gold and associated elements, gravity concentration, and data interpretation and analysis. During the study, a grind optimization was conducted on the composites sample with varying grind size to evaluate the effect of grind size on gold recovery. The ore was moderately ground to the standard grind size of 80%, passing 106 µm, 75 µm, 53 µm and this nominal size was selected for the preliminary assessment for concentration optimization for this deposit. The gravity testing comprised three-stage concentration using Knelson concentrator. High recovery of gold from the gravity concentrates was achieved from the second gravity concentration. Based on the laboratory experimental result analysis, a grind size of P80 75 µm is selected as optimal size for the Ashashire gold deposit. Increasing the grind size from P80 of 75 µm to 106 µm decreases the recovery rate from 75% to 54%, or decreasing the grind size from P80 of 75 µm to 53 µm decreases the gold recovery rate to 37%. The native gold grain in the ores is mostly associated with quartz and fine gold is closely associated with pyrite. According to analysis of the fire assay, chemical, and mineralogical data, only gold and telluride is commercially valuable elements in the ores. Predominantly gold was occurred in the native form of Au-Te. The sample subjected to gravity separation assayed about 2.6 g/t Au.
基金supported by State Key Laboratory of Mineral Processing (No.BGRIMM-KJSKL-2022-16)China Postdoctoral Science Foundation (No.2021M700387)+1 种基金National Natural Science Foundation of China (No.G2021105015L)Ministry of Science and Technology of the People’s Republic of China (No.2022YFC2904502)。
文摘X-ray fluorescence(XRF)sensor-based ore sorting enables efficient beneficiation of heterogeneous ores,while intraparticle heterogeneity can cause significant grade detection errors,leading to misclassifications and hindering widespread technology adoption.Accurate classification models are crucial to determine if actual grade exceeds the sorting threshold using localized XRF signals.Previous studies mainly used linear regression(LR)algorithms including simple linear regression(SLR),multivariable linear regression(MLR),and multivariable linear regression with interaction(MLRI)but often fell short attaining satisfactory results.This study employed the particle swarm optimization support vector machine(PSO-SVM)algorithm for sorting porphyritic copper ore pebble.Lab-scale results showed PSO-SVM out-performed LR and raw data(RD)models and the significant interaction effects among input features was observed.Despite poor input data quality,PSO-SVM demonstrated exceptional capabilities.Lab-scale sorting achieved 93.0%accuracy,0.24%grade increase,84.94%recovery rate,57.02%discard rate,and a remarkable 39.62 yuan/t net smelter return(NSR)increase compared to no sorting.These improvements were achieved by the PSO-SVM model with optimized input combinations and highest data quality(T=10,T is XRF testing times).The unsuitability of LR methods for XRF sensor-based sorting of investigated sample is illustrated.Input element selection and mineral association analysis elucidate element importance and influence mechanisms.
基金funded by the National Natural Science Foundation of China(NSFC)(grant numbers 41472066,40972063 and 41672038)the Program of the Deep Exploration in China(SinoProb-03-05)+1 种基金the National KeyR&S Program of China(2016 YFC0600209)the Land and Resources Science and Techonolgy Foundation of Anhui Province(2016-K-03 and No.2014-K-03)
文摘The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurrences. Those deposits are mainly clustered(from west to east) within the Tongguanshan, Shizishan, Xinqiao, Fenghuangshan, and Shatanjiao orefields. Until recently, the majority of these deposits were thought to be skarn-or porphyry–skarn-type deposits; however there have been recent discoveries of numerous vein-type Au, Ag, and Pb-Zn deposits that do not fall into either of these categories. This indicates that there is some uncertainty over this classification. Here, we present the results of several systematic geological studies of representative deposits in the Tongling ore district. From investigation of the ore-controlling structures, lithology of the host rock, mineral assemblages, and the characteristics of the mineralization and alteration within these deposits, three genetic types of deposits(skarn-, porphyry-, and vein-type deposits) have been identified. The spatial and temporal relationships between the orebodies and Yanshanian intrusions combined with the sources of the ore-forming fluids and metals, as well as the geodynamic setting of this ore district, indicate that all three deposit types are genetically related each other and constitute a magmatic–hydrothermal system. This study outlines a model that relates the polymetallic copper–gold porphyry-, skarn-, and vein-type deposits within the Tongling ore district. This model provides a theoretical basis to guide exploration for deep-seated and concealed porphyry-type Cu(–Mo, –Au) deposits as well as shallow vein-type Au, Ag, and Pb–Zn deposits in this area and elsewhere.
基金financially supported by the Study on mineralization background and conditions of copper-gold in the western part of Bangongco-Nujiang metallogenic belt of Ministry of land and resources of Public industry research and special projects(201011013)Opening Foundation of Key Laboratory of Tectonic Controls on Mineralization and Hydrocarbon Accumulation,Ministry of Land and Resources(gzck2013006)Tectonic metallogeny theory development and practice team fund of Sichuan Province(13TD0008)
文摘The Naruo porphyry copper-gold deposit (hereinafter referred to as the Naruo deposit) in Tibet is a potentially ultra-large, typical gold-rich porphyry copper deposit, which was recently discovered in the Bangongco-Nujiang metallogenic belt. This study analyzed U-Ph chronology and Hf isotopes of the ore-bearing granodiorite porphyry in the Naruo deposit using the LA-ICPMS dating technique. The results show that the weighted average age is 124.03±0.94Ma (MSWD=1.7, n=20), and 2±6pb/23SU isocbron age is 126.2±2.7 Ma (MSWD=1.02, n=20), both of which are within the error. The weighted average age represents the crystallization age of the granodiorite porphyry, which indicates that the ore-bearing porphyry in the Naruo deposit area was formed in the Early Cretaceous and further implies that the Neo-tethys Ocean had not been closed before 124 Ma under a typical island-arc subduction environment. The εGr(t) of zircons from the granodiorite porphyry varies from 2.14 to 9.07, with an average of 5.18, and all zircons have εRf(t) values greater than 0; 176Hf/177Hf ratio is relatively high (0.282725-0.282986). Combined with the zircon age--Hf isotope correlation diagram, the aforementioned data indicate that the source reservoir might be a region that is mixed with depleted mantle and ancient crust, which possibly contains more materials sourced from depleted mantle. Rock-forming ages and ore-forming ages of the Duolong ore concentrate area are 120-124 Ma and 118-119 Ma, respectively, which indicate 124-118 Ma represents the main rockforming and ore-forming stage within the area. The Naruo deposit is located in the north of the Bangongco-Nujiang suture, and it yielded a zircon LA-ICPMS age of 124.03 Ma. This indicates the Bangongco-Nujiang oceanic basin subducted towards the north at about 124 Ma, and the Neo-tethys Ocean had not been closed before the middle Early Cretaceous. It is possible that the crust-mantle mixing formed the series of large and giant porphyry copper-gold deposits in the Bangongco.
文摘The refractory gold ores associated with rich copper and trapped in pyrite and quartz were studied. With conventional technique (all-sliming cyanidation), the gold recovery rate is only 51.78%. To eliminate the negative effects of copper and pyrite on cyanidation and increase the gold recovery rate, the investigation on bio-heap leaching pretreatment was made, by which Cu would be dissolved and gold would be liberated from pyrite. The experiment adopted mixed bacteria, mainly ThiobaciUus ferrooxidan (named T.fl ), as the bacterial catalyst for bio-preconditioning and was carried out in a PVC column with a diameter of 20 cm and a height of 1.3 m loaded with gold ores. The temperature was controlled between 28 and 30℃, the pH value was kept between 2.0-2.5, and the flux of sprinkling bacterial liquid was maintained 0.80 L/h. After 45-day's bio-oxidization, among the samples sizing from 0 to 5 mm, the oxidation rates of Cu, Fe and S were respectively 44.62%, 28.16% and 25.46%, and the gold recovery rate by cyaniding increased to 80.35%. The bio-heap leaching pretreatment can therefore effectively dissolve Cu and liberate gold from pyrite and lead to the increase of gold extraction.
基金the National Natural Science Foundation of China ( No. 40472052) is sincerely acknowledged.
文摘Shizishan ore-field is a nonferrous and noble metal ore-field which is most rich in copper and gold.There are many types of fluid inclusions in minerals of the deposits.The homogeneous temperatures and the salinities of the fluid inclusions in main mineralization stages have wide ranges,while the different types of the fluid inclusions existed together and their homogeneous temperatures are almost identical in the same mineralization stage,which indicates that the ore-forming process has great relation with the fluid boiling.The gas and liquid chemical compositions and the carbon,hydrogen and oxygen isotopic compositions of the fluid inclusions show that the ore-forming fluids of copper-gold deposits have the same characteristics and evolution tendency,which reflects that the ore-forming material mainly came from the magmatism.The stratigraphic component and the meteoric water may mix in ore- forming fluids in the later mineralization stages.Furthermore,with the fall of the ore-forming temperature the ratios of water and rock decreased.The characteristics of chemical composition and carbon isotopic composition of fluid inclusions indicate that CH4 may play an important role for separating copper and gold in the ore-forming process.
文摘Gold concentration usually consists of gravity separation, flotation, cyanidation, or the combination of these processes. The choice among these processes depends on the mineralogical characterization and gold content of the ore. Recently, the recovery of gold using gravity methods has gained attention because of low cost and environmentally friendly operations. In this study, gold pre-concentrates were produced by the stepwise gravity separation and flotation techniques. The Knelson concentrator and conventional flotation were employed for the recovery of gold. Gold bearing ore samples were taken from Gümüshane Region, northern east part of Turkey. As a result of stepwise Knelson concentration experiments, a gold concentrate assaying around 620 g/t is produced with 41.4wt% recovery. On the other hand, a gold concentrate about 82 g/t is obtained with 89.9wt% recovery from a gold ore assaying 6 g/t Au by direct flotation.
基金Thisresearchprojectwasgrantedjointlybythe95’StateKeyScienceandTechnologyProjects(96 914 03 04),ResearchProjectsin95’KeyRegionsandZonessponsoredbytheoriginalNon ferrousMetalIndustry GeneralCompany(96 D 42),theStateKeyBasicResearch,Develop mentandPlanningProgram(G1999043208)andtheFoundationProjects ofYunnanProvincialEducationDepartment(0142104).
文摘On the basis of results of the studies of primary fluid inclusions, and the hydrogen and oxygen isotope data, the authors concluded that the early-stage ore-forming fluid from the Jinchangqing gold (copper) ore deposit is a kind of sulfate type hot brine characterized by medium temperature and salinity, genetically related to the late-stage ore-forming fluid derived from an acidic and more reductive environment. However, the late-stage ore-forming fluid is a sort of low temperature and low salinity chloride-type hot brine which originated from a lower pressure, acidic and more oxidative environment. In general, the ore fluids were derived from the late-stage, or largely from the early-stage groundwater-derived meteoric water, which has a 12‰-17‰ heavier oxygen isotopic composition than the original rain water (δ{}+{18}O={-15.3‰}), and were formed during gold mineralization as a product of oxygen isotope exchange during the reaction between ore-forming fluid and wall rocks under a lower water/rock ratio condition.
文摘The present work investigated microbial leaching of zinc from ore using Acidithiobacillus ferrooxidans (ATCC 14859). The ore samples, consisted of 13wt% zinc, were obtained from a gold mine in north-eastern Thailand. A shake flask study was performed on the ore samples using a rotary shaker under the following fixed conditions (250 r·min^-1, 30℃ for 16 d). The influence of various conditions, namely medium type (with and without iron), particle ore size (〈20, 20-40, 40-60, 60-100, and 〉100 mesh), ore density (20 kg·m^-3, 50 kg·m^-3, and 100 kg·m^-3), and pH of the medium (2, 2.5, 2.8, and 3), were investigated. The microbial leaching was assessed by determining the concentration of zinc in the medium and compared with the initial sample concentration. The results show that Acidithiobacillus ferrooxidans can successfully leach zinc by as much as 6 times compared with the control experiment (without Acidithiobacillus ferrooxidans ferrooxidans). The maximum efficiency (92.3%) for microbial leaching is obtained in iron-containing medium, 20-40 mesh ore sizes, 20 kg·m^-3 ore density at pH 2.8, and the zinc content is found in the medium at about 120 mg·m^-1.
基金jointly provided by the National Natural Science Foundation of China (Grant Nos. 41421002, 41730426, 41272092, and 41030423)MOST Special Fund from the State Key Laboratory of Continental Dynamics, Northwest UniversityNorthwest University Graduate Innovation and Creativity Fund (YZZ17190)
文摘The Liziyuan gold deposit, situated on the south side of the Shangdan suture zone, West Qinling Orogen, occurs in metamorphic volcanic rocks(greenschist facies) of the early Paleozoic Liziyuan Group and in Indosinian Tianzishan monzogranite. Orebodies in the Liziyuan gold field are controlled by the ductile-brittle shear zone, and by thrusting nappe faults related to the Indosinian orogeny. In detail, this paper analyzed the geological characteristics of the Liziyuan gold field, and the Pb isotopes of the Lziyuan host rocks, granitoids(Tianzishan monzogranite and Jiancaowan syenite porphyry), sulfides, and auriferous quartz veins by multiple-collector inductively coupled plasma mass spectrometry(MC-ICPMS). In addition, previous data on the sulfur, hydrogen, and oxygen isotopes were employed to discuss the possible sources of the ore-forming fluids and materials, and to further understand the tectonic setting of the Liziyuan gold deposit. The sulfides and their host rocks(Lziyuan Group), Tianzishan monzogranite and Jiancaowan syenite porphyry, and auriferous quartz veins have similar Pb isotopic compositions.Zartman’s plumbotectonic model diagram shows that most of the data for the deposit fall near the orogenic Pb evolutionary curve or within the area between the orogenic and mantle Pb evolutionary curves. In the△β-△γ diagram, which genetically classifies the lead isotopes, most of the data fall within the range of the subduction-zone lead mixed with upper crust and mantle. This indicates that a complex source of the ore lead formed in the orogenic environment. The δ34S values of the sulfides range from 3.90 to 8.50‰(average6.80‰), with a pronounced mode at 5.00‰-8.00‰. These values are consistent with that of orogenic gold deposits worldwide, indicating that the sulfur sourced mainly from reduced metamorphic fluids. The isotopic hydrogen and oxygen compositions support a predominantly metamorphic origin of the oreforming fluids, with possible mixing of minor magmatic fluids, but the late stage was dominated by meteoric water. The characteristics of the Liziyuan gold deposit formed in the Indosinian orogenic environment of the Qinling Orogen are consistent with those of orogenic gold deposits found worldwide.
基金supported by the National Natural Science Foundation of China(No.20877036) the Natural Science Foundation of Shaanxi Province,China(No.2006Z06)
文摘The extraction process of gold and silver from the gold clay ore containing arsenic and manganese was investigated.With the conventional technique,the leaching rates of gold and silver are 78.23%and 49.02%,respectively.To eliminate the negative effects of arsenic and manganese on cyanidation and increase the gold and silver leaching rates,a novel catalyst was added.The content of the catalyst used in the process was 8 g per 500 g org sample,the sample size was 60μm and the pH value was kept between 10 and 11.Leaching with the catalyst for 3-5 h under certain conditions,the gold leaching rate increased to over 90%and the silver leaching rate increased to 80%-90%.The catalyst can effectively liberate gold and silver from the enclosure of arsenic and manganese and the industrial experiment has great significance to the development and utilization of the gold clay ore containing arsenic and manganese.
文摘Three major types of Ordovician intrusive-related gold-copper deposits are recognized in central-west New South Wales, Australia: porphyry, skarn and high sulphidation epithermal deposits. These deposits are mainly distributed within two Ordovician volcano-intrusive belts of the Lachlan Fold Belt: the Orange-Wellington Belt and the Parkes-Narromine Belt. Available isotopic age data suggest that mineralization of the three types of deposits is essentially coeval with the Ordovician intrusive rocks (480-430 Ma).Porphyry gold-copper deposits can be further divided into two groups. The first group is associated with monzonite showing shoshonitic features, represented by Cadia and Goonumbla. The second group is associated with diorite and dacite, including the Copper Hill and Cargo gold-copper deposits. Gold skarn is associated with Late Ordovician (430-439 Ma) monzonitic intrusive complexes in the Junction Reefs area (Sheahan-Grants, Frenchmans, and Cor-nishmens), Endeavour 6, 7 and 44, Big and Little Cadia. The epithermal gold deposits with high sulphidation including Gidginbung (Temora) and Peak Hill mainly occur within Ordovician andesite and volcaniclastic rocks, and are associated with advanced argillic alteration. Available isotopic age data indicate that both alteration and mineralization of the porphyry, skarn and epithermal gold-copper deposits are broadly coeval with the Late Ordovician shoshonitic magmatism, which is thought to result from the melting of sub-continental lithosphere caused by Palaeozoic subduction events.The Ordovician intrusive-related gold-copper deposits are restricted to two longitudinal parallel volcano-intrusive belts, rarely extending outside them. Diagonal intra-belt trends of mineralization are common, particularly at the intersections of longitudinal and transverse (oblique) fault/fracture zones based on the authors' review of available geological data. The locations of these gold-copper deposits are obviously influenced by transverse (oblique) fault/fracture zones that are oriented northwest, eastwest and northeast. The conjunctions of these fault/fractures zones are thought to be zones of structural weakness, and appear to be the favourable locus for the Ordovician intrusive-related gold-copper deposits. Differences in structural patterns, intrusive, wall rock types, and depths of ore formation may contribute to the differences among the deposits.
文摘Underground prospecting within the L ubin- Sieroszowice mining area which took place during last5 years,led to a discovery of a new type of Au,Pt and Pd mineralisation located 0 - 0 .5 m below the copper- silver orebody in the south- western part of the Polish Permian Basin.The gold- bearing zone lies mainly in the Weissliegendessandstone (L ower Permian) , butlocally transgresses the stratigraphic sequence into the overlying kupferschieferand Wer- ra limestone(Zechstein) .Gold deposit lies in a secondary red- coloured variety of the above mentioned sedimentary strata.The oxidation in the underlying sandstone is reflected by red spots and dots containing fine grains of hematite dispersed in a carbonate- clay matrix.The secondary oxidation is peneconcordant in relation to the reducing facies which contains cop- per sulphides and to the Rote Faule,thatis early diagenetic.Between redbeds(gold bearing zone) and black,reduced sediments (Kupferschiefer) ,a transition zone has been recognized. This transition zone is characterized by the low grade of copper mineralisation.Thickness of the gold depositvaries from few centimetresto1.5 metres with an average of about0 .2 5 me- tres.The highestthickness of Au- depositis observed in placeswhere oxide fronttransgress- es the copper- silver deposit.Gold content ranges from 0 .5 up to 10 6 ppm with an average grade of(0 .717- 3.491)× 10 -6depending on the counting block.Gold- bearing horizon is peneconcordantand is characterized by the presence of high fineness native gold,electrum, hematite,and minor pyrite,chalcopyrite,digenite,chalcocite,covellite,rammelsbergite, clausthalite and
文摘Microwave radiation was employed as a pretreating technology to oxidise a refractory gold ore. Heating characteristics showed that, in an identical microwave field, the bulk temperature of the sample increased with microwave power, microwave radiation time and particle size. The rate of sulphur removal increased with microwave radiation time. Particle size also had a significant effect on the oxidation rate. Pyrite and marcasite could be oxidised into Fe 2O 3 with a high porous structure. When microwave radiation was carried out in a rotary bed, the oxidation was more uniformly developed, in comparison with in a fixed bed. Gold extraction by cyanidation could be remarkably improved after the ore was subjected to microwave radiation. The results showed that gold recovery could be improved from 37% to 69%~ 81.2 %.
文摘The Shaxi porphyry copper (gold) deposits are a typical example of porphyry copper deposits associated with diorite in eastern China. Quartz diorite, which hosts the deposits, has a Rb-Sr isochron age of 127.9 ± 1.6 Ma. Geochemically, the rock is rich in alkalis (especially sodium), light rare earth elements (LREE) and large-ion lithophile elements (LILE), and has a relatively low initial strontium isotopic ratio (Isr=0.7058); thus it is the product of differentiation of crust-mantle mixing source magma. The model of alteration and mineralization zoning is similar to the Hollister (1974) diorite model. The ore fluids have a relatively high salinity and contain significant amounts of CO2, Ca2+, Na+ and ***CI?. The homogenization temperatures of fluid inclusions for the main mineralization stage range from 280 to 420°C, the δ18O values of the ore fluids vary from 3.51 to 5.52 %, the δD values are in the range between ?82.4 and ?59.8 %, the δ34S values of sulphides vary from ?0.3 to 2.49 %, and the δ13C values of CO2 in inclusions range between ?2.66 and ?6.53 %. Isotope data indicate that the hydrothermal ore fluids and ore substances of the Shaxi porphyry copper (gold) deposits were mainly derived from magmatic systems.
基金the AbbasAbad copper mineShahrood University of Technology for their financial support during this research。
文摘Mechanochemical sulfidization of a mixed sulfide/oxide copper ore by co-grinding with sulfur and additives including Mg(NO3)2 and Fe(NO3)3 salts and iron,aluminum and magnesium powders was investigated for the first time.Also,the influence of sulfidization during the wet-milling process was examined on the separation efficiency and recovery of copper in detail.The results demonstrated that co-grinding with sulfur solely had the best flotation performance at the value of 0.5 wt.%and it was attributed to the possible existence of S\\O bonding on copper oxides surfaces.In addition,adding magnesium nitrate salt,magnesium powder,iron nitrate salt and aluminum powder as additive associated with 0.5 wt%sulfur into ball milling caused the flotation improvement at the amounts of 0.2 wt%,0.2 wt%,0.5 wt%and 0.5 wt%,respectively.Also,the effect of grinding time and sulfidization pH with 0.5 wt%sulfur solely was determined and pH s of 7.5 to 8.5 gave the best results.The highest recovery(75.76%)and separation efficiency(63.44%)were achieved at pH of 7.5 and 8.5,respectively.
基金Supported by the National Natural Science Foundation of China(51704059,51474169)
文摘While roasting has been widely applied to reduce the negative effect of carbonaceous matters on gold extraction from fine-grained carbonaceous gold ores, the phase and structure changes of minerals during roasting and their in fluences on the leachi ng rate of gold have not been fully understood. This limits the extraction of carbonaceous gold deposits. The current work examines the oxidation process of a fine-grained carbonaceous gold ore during roasting using a range of techniques including X-ray diffraction (XRD), seanning electron microscopy (SEM), Energy Dispersive Spectrometer (EDS) analysis and pore structure analysis together with gold leaching tests. The results show that during the process of oxidative roasting, the carbonaceous matters (organic carbon and graphitic carbon) and pyrite were completely decomposed at 600 ℃ with the carbonaceous components burned and pyrite oxidized into hematite. At 650 ℃, while dolomite was decomposed into calcia, magnesia, calcium sulfate etc., the calcine structure became loose and porous, leading to a high gold leaching rate from the roasted product. Above 750 ℃, the porous calcite structure started to collapse along with the agglomeration, leading to the secondary encapsulation of gold particles, which contributed to the sharp drop in the gold leaching rate of the roasted product. This study suggests optimum phase and structure changes of minerals during roasting to achieve maximum gold extraction from fine-grained carbonaceous gold deposits.
基金supported by the Key Subject of Shanghai Municipality (No.S30109)Shanghai Science and Technology Commission (No.10dz1205302)
文摘The resources of refractory gold ores are abundant, and their effective treatment can bring good economic benefits. This paper investigated the kinetics of leaching gold from refractory gold ores by ultrasonic-assisted electro-chlorination. The effects of ultrasound time ratio, initial hydrochloric acid concentration and leaching temperature on the kinetic parameters were discussed. It is found that the leaching ratio goes up with all the factors increasing. The reaction kinetics is controlled by diffusion. When ultrasound improves the diffusion by reducing the diffusion resistance, the activation energy increases to 37.1 kJ/mol.
基金supported by the 12th Five-Year Plan project of State Key Laboratory of Ore Deposit Geochemistry,Chinese Academy of Sciences(SKLOG-ZY125-06)the Knowledge Innovation Project,Chinese Academic Sciences(KZCX2-YW-136-1)
文摘Platinum-group elements (PGE) in PGE-rich porphyry copper (gold) deposits are mainly Pt and Pd, whereas the concentrations of other PGE (Ru, Rh, Os, Ir) are significantly low. Moreover, Pt and Pd mainly exist in sulfides in the forms of crystal lattice or tiny platinum-group mineral (PGM) inclusions. The present data show that there is a positive relationship between Pt and Pd concentrations and Cu (Au) in porphyry copper (gold) deposits. The comparison of chondrite-normalized PGE distribution patterns between the ore-bearing porphyry intrusions and ore-barren porphyry intrusions in arc setting, 187^Os/188^Os, 87^Sr/86^Sr and S isotopes for porphyry copper (gold) deposits shows that PGEs were mainly derived from the mantle, and fluids from subduction zones devoted trivial PGE to the magma. The porphyry copper (gold) deposits associated with subducted events are most probably enriched in PGE, whereas those related to crustal thickening, lithospheric delamination or underplating rarely concentrate PGE. The osmium isotopic compositions in porphyry copper (gold) deposits reveal that (187^Os/188^Os)i values are highly variable and not lower than those of primitive upper mantle (PUM) and mantle peridotite, however, osmium concentrations are commonly lower than mantle peridotite, suggesting that parental magmas of some porphyry intrusions had experienced crustal contamination during magma evolution. Experimental investigations have proved that PGE exist in the forms of Cl^- and HS^- complexes during transportation and migration of the oreforming fluids. This paper summarizes previous studies including crucial controlling factors and mechanisms for PGE enrichment, and points out that the mantle-derived magmas parental to porphyry intrusions are the prerequisite for PGE enrichment in porphyry copper (gold) deposits. Favorable physical and chemical conditions (including salinity, temperature, pressure, pH, and oxygen fugacity) in hydrothermal fluids crucially control the PGE enrichment, and sulfur concentrations of melts play important roles in this process as well.