In this study, the mechanical properties of aluminum-5%magnesium doped with rare earth metal neodymium were evaluated. Fuzzy logic (FL) and artificial neural network (ANN) were used to model the mechanical properties ...In this study, the mechanical properties of aluminum-5%magnesium doped with rare earth metal neodymium were evaluated. Fuzzy logic (FL) and artificial neural network (ANN) were used to model the mechanical properties of aluminum-5%magnesium (0-0.9 wt%) neodymium. The single input (SI) to the fuzzy logic and artificial neural network models was the percentage weight of neodymium, while the multiple outputs (MO) were average grain size, ultimate tensile strength, yield strength elongation and hardness. The fuzzy logic-based model showed more accurate prediction than the artificial neutral network-based model in terms of the correlation coefficient values (R).展开更多
The effect of Hf on the grain refinement of as-cast aluminum was investigated using optical microscopy, electron microscopy and X-ray diffraction. The result shows that the grain size of studied alloy decreases effect...The effect of Hf on the grain refinement of as-cast aluminum was investigated using optical microscopy, electron microscopy and X-ray diffraction. The result shows that the grain size of studied alloy decreases effectively with the addition of Hf,Hf can react with Al to form Al3Hf particles during the solidification, the primary Al3Hf particles are highly potent nucleants for Al and the nanoscale coherent Al3Hf particles can inhibit the grain growth by pinning effect. The grain refinement mechanism of studied alloys was verified by the solute theory and the crystallography study, and it can be divided into two distinct types: At low Hf contents, there are no primary Al3Hf phases to form, the acquired grain refinement is primarily attributed to the constitutional undercooling induced by the Hf solute. At medium and high Hf contents, both Hf solute and Al3Hf particles contribute to the refinement.展开更多
The mechanism of grain fracturing in a zirconia metering nozzle used in the continuous casting process was studied. The phase composition, microstructure, and chemical composition of the residual samples were studied ...The mechanism of grain fracturing in a zirconia metering nozzle used in the continuous casting process was studied. The phase composition, microstructure, and chemical composition of the residual samples were studied using an X-ray fluorescence analyzer, scanning electron microscope, and electron probe. Results revealed that the composition, structure, and mineral phase of the original layer, transition layer, and affected layer of the metering nozzle differed because of stabilizer precipitation and steel slag permeation. The stabilizer MgO formed low-melting phases with steel slag and impure SiO2 on the boundaries(pores) of zirconia grains; consequently, grain fracturing occurred and accelerated damage to the metering nozzle was observed.展开更多
Dense B;C material was fabricated using spark plasma sintering(SPS), and the densification mechanisms and grain growth kinetics were revealed. The density, hardness, transverse flexure strength and toughness of sample...Dense B;C material was fabricated using spark plasma sintering(SPS), and the densification mechanisms and grain growth kinetics were revealed. The density, hardness, transverse flexure strength and toughness of samples were investigated and the model predictions were confirmed by SEM and TEM experimental observations. Results show that SPSed B;C exhibits two sintering periods: a densification period(1800-2000 °C) and a grain growth period(2100-2200 °C). Based on steady-state creep model, densification proceeds by grain boundary sliding and then dislocation-climb-controlled mechanism. Grain growth mechanism is controlled by grain boundary diffusion at 2100 °C,and then governed by volume or liquid-phase diffusion at 2200 °C.展开更多
this paper based on the food security, the food the macroeconomic regulation and control of the operation mechanism of the general theory, focus on the China's grain macroeconomic regulation and control mechanism, th...this paper based on the food security, the food the macroeconomic regulation and control of the operation mechanism of the general theory, focus on the China's grain macroeconomic regulation and control mechanism, the concept of grain macroeconomic regulation and control mechanism, the grain circulation macroeconomic regulation and control tool application, grain circulation macroeconomic regulation and control system, the problem of grain circulation system, food price formation mechanism. Through the research set up grain control of the operation mechanism of general theory.展开更多
this article through to the national food security problems, and puts forward China's grain macro-control mechanism is to follow the food economic law, with the national food security as the foundation, the food econ...this article through to the national food security problems, and puts forward China's grain macro-control mechanism is to follow the food economic law, with the national food security as the foundation, the food economy structure adjustment as power, based on production and supply balance, trade and consumption balance, price and social grain total cost balance, grain reserves and the retaining rate balance four as the key point, establish and perfect the food security is the core of the production, processing, trade, reserve, consumption for control system, perfect the government macroeconomic regulation and control of the market, protect the food producers and consumers' vital interests, early warning and solving the international and domestic food crisis and risk, maintain food markets continue to stability and promote national economic security of food.展开更多
A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards a...A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards and distribute randomly inside the Al melt, which induces more nucleation sites resulting in grain refinement. At the same time, the effect of nuclei size on the nuclei distribution and refinement employing electric current pulse (ECP) was also investigated. The smaller nuclei migrate a short distance with the Al melt at lower speed. But for the larger nuclei, the migration downwards with higher speed benefits the refinement of interior grains of the melt. The research results help to better understand the refinement process and provide a more reasonable explanation of the grain refinement mechanism using ECP.展开更多
Effects of welding speed on the microstructure evolution in the stir zone(SZ)and mechanical properties of the friction stir welding(FSW)joints were studied by OM,XRD,SEM,TEM,EBSD and tensile testing.Compared with the ...Effects of welding speed on the microstructure evolution in the stir zone(SZ)and mechanical properties of the friction stir welding(FSW)joints were studied by OM,XRD,SEM,TEM,EBSD and tensile testing.Compared with the base metal(BM),an obviously fine dynamic recrystallization(DRX)microstructure occurs in the SZ and the DRX grain size decreases from 5.6 to 4.4μm with the increasing of welding speed.Fine DRX microstructure is mainly achieved by continuous dynamic recrystallization(CDRX)mechanism,strain induced boundary migration(SIBM)mechanism and particle stimulated nucleation(PSN)mechanism.Meanwhile,the geometric coalescence and the Burke−Turnbull mechanism are the main DRX grain growth mechanisms.Among all the welding speeds,the joint welded at rotation speed of 1500 r/min and welding speed of 75 mm/min has the greatest tensile properties,i.e.ultimate tensile strength(UTS)of(509±2)MPa,yield strength(YS)of(282±4)MPa,elongation(El)of(23±1)%,and the joint efficiency of 73%.展开更多
By means of supersonic fine particles bombarding (SFPB),a nanostructured surface layer up to 15 μm was fabricated on a 45 steel plate with ferrite and pearlite phases. To reveal the grain refinement mechanism of SF...By means of supersonic fine particles bombarding (SFPB),a nanostructured surface layer up to 15 μm was fabricated on a 45 steel plate with ferrite and pearlite phases. To reveal the grain refinement mechanism of SFPB-treated 45 steel,microstructure features of various sections in the treated surface were systematically characterized by X-ray diffraction (XRD),scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Grain size increases with an increase of depth from the treated surface. Plastic deformation and grain refinement processes are accompanied by an increase in strain. Plastic deformation in the proeutectoid ferrite phases has precedence over the pearlite phases. Grain refinement in the ferrite phases involves: the onset of dislocation lines (Dls),dislocation tangles (DTs) and dense dislocation walls (DDWs) in the original grains; the formation of fine lamellar and roughly equiaxed cells separated by DDWs; by dislocation annihilation and rearrangement,the transformation of DDWS into subboundaries and boundaries and the formation of submicron grains or subgrains; the successive subdivision of grains to finer and finer scale,resulting in the formation of highly misoriented nano-grains. By contrast,eutectoid cementite phase accommodated strain in a sequence as follows: onset of elongated,bended and shear deformation under deformation stress of ferrites,short and thin cementites with a width of about 20-50 nm and discontinuous length were formed. Shorter and thinner cementites were developed into ultra-fine pieces under the action of high density dislocation and strains. At the top surface,some cementites were decomposed under severe plastic deformation. Experimental evidences and analysis indicate that surface nanocrystallization of 45 steel results from dislocation activities,high strains and high strain rate are necessary for the formation of nanocrystallites.展开更多
A high grain breakage rate is the main problem that occurs during mechanical maize harvest in China.The breakage sensitivity of different varieties was significantly different,and the breakage resistance is heritable....A high grain breakage rate is the main problem that occurs during mechanical maize harvest in China.The breakage sensitivity of different varieties was significantly different,and the breakage resistance is heritable.Therefore,breakage resistant variety screening can help improve the field production efficiency and provide references for breeding work.In this study,42 varieties of maize were harvested with the same mechanical parameters and the same manipulator on a range of harvest dates at experimental stations in Xinxiang,Henan Province,in 2017 and Changji,Xinjiang Province,in 2018 to determine the sensitivity of grain moisture content on grain breakage rate during machine harvest for different varieties.The integral value of the grain breakage rate curve corresponding to the range of 15%to 30%grain moisture content was used as an index that expressed the sensitivity of maize grains to breakage depending on grain moisture content(BSW).Forty-two varieties were categorized as having weak,intermediate,or strong BSW.Among the same four varieties in the two stations,Lianchuang 825 and Lianchuang 808 were classified as sensitive and fragile varieties,Shandan 650 was classified as an intermediate variety,Zeyu 8911 was divided into weak sensitive and breakage-resistance varieties in Xinxiang and intermediate varieties in Changji.The BSW classification results at the two experimental sites were generally consistent,indicating that breakage sensitivity due to moisture content may be a relatively stable genetic characteristic.This study suggested that the integral method for determining BSW can be used to assess the resistance of different maize varieties to grain breakage during mechanical harvesting.The integral method was used to identify twelve breakage-resistant varieties in Xinxiang Station,and six breakage-resistant varieties in Changji Station.This study provides a method for screening maize varieties that are suited to mechanical grain harvesting and for studying the mechanisms of grain breakage resistance.展开更多
In this study, the ultrafine grained (UFG) 6061 Al alloys fabricated by cold rolling were friction stir welded (FSW) with different rotation rates under both air cooling and rapid cooling in water. Low-heat-input ...In this study, the ultrafine grained (UFG) 6061 Al alloys fabricated by cold rolling were friction stir welded (FSW) with different rotation rates under both air cooling and rapid cooling in water. Low-heat-input parameters of 400 rpm rotation rate in water (400-Water) could effectively inhibit the coarsening of recrystallized grains, reduce the precipitation rate, and retain more dislocations of the UFG 6061 Al parent metal. 400-Water joint showed high lowest-hardness value, narrow low-hardness zone, and high tensile strength, attributing to the effect of dislocation, grain boundary, solid-solution, and precipitation hardening. This work provides an effective strategy to fabricate large-sized bulk UFG AI alloy by cold rolling with large deformation and low-heat-input FSW.展开更多
The design of high irradiation-resistant materials is very important for the development of next-generation nuclear reactors. Grain boundaries acting as effective defect sinks are thought to be able to moderate the de...The design of high irradiation-resistant materials is very important for the development of next-generation nuclear reactors. Grain boundaries acting as effective defect sinks are thought to be able to moderate the deterioration of mechanical behaviors of irradiated materials, and have drawn increasing attention in recent years. The study of the effect of grain boundaries on the mechanical behaviors of irradiated materials is a multi-scale problem. At the atomic level, grain boundaries can effectively affect the production and formation of irradiation-induced point defects in grain interiors, which leads to the change of density, size distribution and evolution of defect clusters at grain level. The change of microstructure would influence the macroscopic mechanical properties of the irradiated polycrystal. Here we give a brief review about the effect of grain boundaries on the mechanical behaviors of irradiated metals from three scales: microscopic scale, mesoscopic scale and macroscopic scale.展开更多
Sintering kinetics have been found to be effective in judging the evolution of ceramics.By using magnesium oxide-partially stabilized zirconia(Mg-PSZ)powder prepared by co-precipitation as raw materials,the evolution ...Sintering kinetics have been found to be effective in judging the evolution of ceramics.By using magnesium oxide-partially stabilized zirconia(Mg-PSZ)powder prepared by co-precipitation as raw materials,the evolution of densification and grain growth for Mg-PSZ ceramics were investigated.The results indicated that the densification of samples was mainly controlled by grain boundary diffusion in intermediate sintering stage.During the sintering process,the grain growth mechanisms included normal grain growth,abnormal grain growth and solid solution drag-controlled grain growth.Interestingly,the apparent activation energy for grain growth of Mg-PSZ ceramics is lower than that of ZrO_(2)–Y_(2)O_(3)ceramics in the solid solution drag-controlled grain grow process,which will cause grain to grow easily.The sintering kinetics and microstructure of Mg-PSZ ceramics were studied,and the kinetic equation of grain growth at different temperatures was established.The results show that the strength difference between Mg-PSZ and yttrium oxide-stabilized zirconia is closely related to the easy grain growth of Mg-PSZ ceramics.展开更多
A novel hard material with various (W0.5Al0.5)C grain shapes was successfully prepared through mechanical alloying and in-situ high-pressure sintering process. X-ray diffraction apparatus and scanning electron micro...A novel hard material with various (W0.5Al0.5)C grain shapes was successfully prepared through mechanical alloying and in-situ high-pressure sintering process. X-ray diffraction apparatus and scanning electron microscopy were used to characterize the phase and the microstructures of the samples. The novel hard materials with "fibrous", "rounded" and "plate-like" grains, which do not contain sharp edges, have the improved mechanical properties. The bulk boundless (W0.5Al0.5)C hard material with various (W0.5Al0.5)C grain shapes possesses good mechanical properties and light weight. The formation mechanism for the non-equilibrium (W0.5Al0.5)C grains during in-situ high-pressure sintering is also discussed.展开更多
Maize is a bulk commodity in international agricultural product trading,and unified and standardized quality inspection standards are the basis of purchase and sales and other trading behaviors.China and the United St...Maize is a bulk commodity in international agricultural product trading,and unified and standardized quality inspection standards are the basis of purchase and sales and other trading behaviors.China and the United States are the largest maize producers and consumers in the world,jointly accounting for more than 60%of the world's total production.In this research,the used data were from annual maize harvest quality reports released by the U.S.Grains Council in 2011-2019 and 2987 groups of mechanical grain harvest sample data collected by the Crop Cultivation and Physiology Innovation Team of the Chinese Academy of Agricultural Sciences in 2012-2019,this study compares the quality standards of commercial maize grain in China and the United States,the mechanical harvest quality(which affects the quality of the maize grain commodity),and the status quo of harvesting and storage processes in the two countries.Additionally,this study analyzes the differences in the formulation of mechanical harvest quality standards between China and the United States,as well as the reasons behind these differences,and recommends requirements for the formulation of quality standards for maize production technology and commodities that are in line with the economic conditions and maize-production conditions in China and in line with international standards in order to provide support for the industrialization of modern maize production in China.展开更多
A new Al-5Ti-0.75B-0.2C master alloy was successfully prepared by self-propagating high-temperature(SHS)reaction from an Al-Ti-B_4C system with molten Al.Microstructure and phase characterization of the prepared Al-...A new Al-5Ti-0.75B-0.2C master alloy was successfully prepared by self-propagating high-temperature(SHS)reaction from an Al-Ti-B_4C system with molten Al.Microstructure and phase characterization of the prepared Al-5Ti-0.75B-0.2C master alloy show that the nearly spherical TiC particles,hexagonal or rectangular TiB_2 particles,and blocklike TiAl_3 particles distribute uniformly in the aluminum matrix.Grain refining test on commercial pure aluminum indicates that Al-5Ti-0.75B-0.2C master alloy exhibits a better grain refining performance than Al-5Ti-lB master alloy.By addition of 0.2 wt%Al-5Ti-0.75B-0.2C master alloy,the average grain size of a-Al can be effectively refined to160 ± 5 μm from about 3000 μm,and the tensile strength and elongation are increased by about 20%and 14.1%due to the grain refinement.展开更多
Through molecular dynamics(MD) simulation, the dependencies of temperature, grain size and strain rate on the mechanical properties were studied. The simulation results demonstrated that the strain rate from 0.05 to...Through molecular dynamics(MD) simulation, the dependencies of temperature, grain size and strain rate on the mechanical properties were studied. The simulation results demonstrated that the strain rate from 0.05 to 2 ns–1 affected the Young's modulus of nickel nanowires slightly, whereas the yield stress increased. The Young's modulus decreased approximately linearly; however, the yield stress firstly increased and subsequently dropped as the temperature increased. The Young's modulus and yield stress increased as the mean grain size increased from 2.66 to 6.72 nm. Moreover, certain efforts have been made in the microstructure evolution with mechanical properties association under uniaxial tension. Certain phenomena such as the formation of twin structures, which were found in nanowires with larger grain size at higher strain rate and lower temperature, as well as the movement of grain boundaries and dislocation, were detected and discussed in detail. The results demonstrated that the plastic deformation was mainly accommodated by the motion of grain boundaries for smaller grain size. However, for larger grain size, the formations of stacking faults and twins were the main mechanisms of plastic deformation in the polycrystalline nickel nanowire.展开更多
Additive manufacturing is believed to open up a new era in precise microfabrication,and the dynamic microstructure evolution during the process as well as the experiment-simulation correlated study is conducted on a p...Additive manufacturing is believed to open up a new era in precise microfabrication,and the dynamic microstructure evolution during the process as well as the experiment-simulation correlated study is conducted on a prototype multi-principal-element alloys FeCrNi fabricated using selective laser melting(SLM).Experimental results reveal that columnar crystals grow across the cladding layers and the dense cellular structures develop in the filled crystal.At the micron scale,all constituent elements are evenly distributed,while at the near-atomic scale,Cr element is obviously segregated.Simulation results at the atomic scale illustrate that i)the solid-liquid interface during the grain growth changes from horizontal to arc due to the radial temperature gradient;ii)the precipitates,microscale voids,and stacking faults also form dynamically as a result of the thermal gradient,leading to the residual stress in the SLMed structure.In addition,we established a microstructure-based physical model based on atomic simulation,which indicates that strong interface strengthening exists in the tensile deformation.The present work provides an atomic-scale understanding of the microstructural evolution in the SLM process through the combination of experiment and simulation.展开更多
Effects of Nd on microstructure and mechanical properties of as-cast Mg-8Li-3Al alloy were investigated by OM,X-ray diffraction(XRD),EPMA,scanning electron microscopy(SEM) and energy dispersive spectroscopy(EDS)...Effects of Nd on microstructure and mechanical properties of as-cast Mg-8Li-3Al alloy were investigated by OM,X-ray diffraction(XRD),EPMA,scanning electron microscopy(SEM) and energy dispersive spectroscopy(EDS).The results showed that the dendrites sizes of α phase were decreased by the Nd addition.When the amount of addition Nd was 1.6 wt.%,the alloy with the smallest α phase was obtained.The refining mechanism mainly owed to the increasing constitutional supercooling at the solidification front.Furthermore,the compound Al 2 Nd generated by the reaction of Al and Nd,which distributed at the phase boundary and inside β phase,could also restrain the growth of α phase.Nd could improve the tensile strength and elongation of Mg-8Li-3Al alloy,however,excessive Al 2 Nd might also become crack source and decrease the elongation.展开更多
The effect of solution annealing on the microstructure and mechanical properties of a Ni-Cr-W-Fe alloy developed for advanced 700?C ultra-supercritical power plants was investigated. Test samples in this study were s...The effect of solution annealing on the microstructure and mechanical properties of a Ni-Cr-W-Fe alloy developed for advanced 700?C ultra-supercritical power plants was investigated. Test samples in this study were subjected to different solution treatments and the same aging treatment(at 760?C for 1 h).When solution annealing temperature was elevated from 1020?C to 1150?C, the stress-rupture life at750?C/320 MPa was increased from 60 h to 300 h, the stress-rupture elongation was enhanced from12% to 17%, and the elongation of the tensile at 750?C was improved from 11% to 24%. All tensile and stress-rupture samples displayed an intergranular dimple mixed fracture. Intergranular micro-cracks had a great relationship with the morphology of grain boundary carbides. Most carbides retained the morphology of globular shape and continuous thin plate. After tensile and stress-rupture tests, a few carbides were converted into lamellar. The results showed that intergranular micro-cracks were easier to form at continuous thin plate carbides than at globular shape carbides. Lamellar carbides hardly caused the nucleation of micro-cracks. Besides, grain boundaries sliding and elements diffusion during stressrupture tests led to the formation of precipitate free zones, which accelerated the extension of microcracks and influenced the stress-rupture life.展开更多
文摘In this study, the mechanical properties of aluminum-5%magnesium doped with rare earth metal neodymium were evaluated. Fuzzy logic (FL) and artificial neural network (ANN) were used to model the mechanical properties of aluminum-5%magnesium (0-0.9 wt%) neodymium. The single input (SI) to the fuzzy logic and artificial neural network models was the percentage weight of neodymium, while the multiple outputs (MO) were average grain size, ultimate tensile strength, yield strength elongation and hardness. The fuzzy logic-based model showed more accurate prediction than the artificial neutral network-based model in terms of the correlation coefficient values (R).
基金Project(SGRI-WD-71-13-001) supported by the Scientific and Technological Project of State Grid Corporation of China
文摘The effect of Hf on the grain refinement of as-cast aluminum was investigated using optical microscopy, electron microscopy and X-ray diffraction. The result shows that the grain size of studied alloy decreases effectively with the addition of Hf,Hf can react with Al to form Al3Hf particles during the solidification, the primary Al3Hf particles are highly potent nucleants for Al and the nanoscale coherent Al3Hf particles can inhibit the grain growth by pinning effect. The grain refinement mechanism of studied alloys was verified by the solute theory and the crystallography study, and it can be divided into two distinct types: At low Hf contents, there are no primary Al3Hf phases to form, the acquired grain refinement is primarily attributed to the constitutional undercooling induced by the Hf solute. At medium and high Hf contents, both Hf solute and Al3Hf particles contribute to the refinement.
基金funded by the National Natural Science Foundation of China(51372193)the Natural Science Basic Research Plan in the Shaanxi Province of China(2014JM6224)
文摘The mechanism of grain fracturing in a zirconia metering nozzle used in the continuous casting process was studied. The phase composition, microstructure, and chemical composition of the residual samples were studied using an X-ray fluorescence analyzer, scanning electron microscope, and electron probe. Results revealed that the composition, structure, and mineral phase of the original layer, transition layer, and affected layer of the metering nozzle differed because of stabilizer precipitation and steel slag permeation. The stabilizer MgO formed low-melting phases with steel slag and impure SiO2 on the boundaries(pores) of zirconia grains; consequently, grain fracturing occurred and accelerated damage to the metering nozzle was observed.
基金the financial supports from the National Natural Science Foundation of China (No. 51874369)Hunan Provincial Natural Science Foundation, China (No. 2021JJ30856)+1 种基金the China Scholarship Council for financial supports (No. CSC201906370123)the Fundamental Research Funds for the Central Universities of Central South University, China (No. 2020zzts084)。
文摘Dense B;C material was fabricated using spark plasma sintering(SPS), and the densification mechanisms and grain growth kinetics were revealed. The density, hardness, transverse flexure strength and toughness of samples were investigated and the model predictions were confirmed by SEM and TEM experimental observations. Results show that SPSed B;C exhibits two sintering periods: a densification period(1800-2000 °C) and a grain growth period(2100-2200 °C). Based on steady-state creep model, densification proceeds by grain boundary sliding and then dislocation-climb-controlled mechanism. Grain growth mechanism is controlled by grain boundary diffusion at 2100 °C,and then governed by volume or liquid-phase diffusion at 2200 °C.
文摘this paper based on the food security, the food the macroeconomic regulation and control of the operation mechanism of the general theory, focus on the China's grain macroeconomic regulation and control mechanism, the concept of grain macroeconomic regulation and control mechanism, the grain circulation macroeconomic regulation and control tool application, grain circulation macroeconomic regulation and control system, the problem of grain circulation system, food price formation mechanism. Through the research set up grain control of the operation mechanism of general theory.
文摘this article through to the national food security problems, and puts forward China's grain macro-control mechanism is to follow the food economic law, with the national food security as the foundation, the food economy structure adjustment as power, based on production and supply balance, trade and consumption balance, price and social grain total cost balance, grain reserves and the retaining rate balance four as the key point, establish and perfect the food security is the core of the production, processing, trade, reserve, consumption for control system, perfect the government macroeconomic regulation and control of the market, protect the food producers and consumers' vital interests, early warning and solving the international and domestic food crisis and risk, maintain food markets continue to stability and promote national economic security of food.
基金Project(SELF-2011-01)supported by the Open Project of Shanghai Key Laboratory of Modern Metallurgy and Materials Processing,ChinaProjects(51204109,51035004)supported by the National Natural Science Foundation of China
文摘A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards and distribute randomly inside the Al melt, which induces more nucleation sites resulting in grain refinement. At the same time, the effect of nuclei size on the nuclei distribution and refinement employing electric current pulse (ECP) was also investigated. The smaller nuclei migrate a short distance with the Al melt at lower speed. But for the larger nuclei, the migration downwards with higher speed benefits the refinement of interior grains of the melt. The research results help to better understand the refinement process and provide a more reasonable explanation of the grain refinement mechanism using ECP.
文摘Effects of welding speed on the microstructure evolution in the stir zone(SZ)and mechanical properties of the friction stir welding(FSW)joints were studied by OM,XRD,SEM,TEM,EBSD and tensile testing.Compared with the base metal(BM),an obviously fine dynamic recrystallization(DRX)microstructure occurs in the SZ and the DRX grain size decreases from 5.6 to 4.4μm with the increasing of welding speed.Fine DRX microstructure is mainly achieved by continuous dynamic recrystallization(CDRX)mechanism,strain induced boundary migration(SIBM)mechanism and particle stimulated nucleation(PSN)mechanism.Meanwhile,the geometric coalescence and the Burke−Turnbull mechanism are the main DRX grain growth mechanisms.Among all the welding speeds,the joint welded at rotation speed of 1500 r/min and welding speed of 75 mm/min has the greatest tensile properties,i.e.ultimate tensile strength(UTS)of(509±2)MPa,yield strength(YS)of(282±4)MPa,elongation(El)of(23±1)%,and the joint efficiency of 73%.
文摘By means of supersonic fine particles bombarding (SFPB),a nanostructured surface layer up to 15 μm was fabricated on a 45 steel plate with ferrite and pearlite phases. To reveal the grain refinement mechanism of SFPB-treated 45 steel,microstructure features of various sections in the treated surface were systematically characterized by X-ray diffraction (XRD),scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Grain size increases with an increase of depth from the treated surface. Plastic deformation and grain refinement processes are accompanied by an increase in strain. Plastic deformation in the proeutectoid ferrite phases has precedence over the pearlite phases. Grain refinement in the ferrite phases involves: the onset of dislocation lines (Dls),dislocation tangles (DTs) and dense dislocation walls (DDWs) in the original grains; the formation of fine lamellar and roughly equiaxed cells separated by DDWs; by dislocation annihilation and rearrangement,the transformation of DDWS into subboundaries and boundaries and the formation of submicron grains or subgrains; the successive subdivision of grains to finer and finer scale,resulting in the formation of highly misoriented nano-grains. By contrast,eutectoid cementite phase accommodated strain in a sequence as follows: onset of elongated,bended and shear deformation under deformation stress of ferrites,short and thin cementites with a width of about 20-50 nm and discontinuous length were formed. Shorter and thinner cementites were developed into ultra-fine pieces under the action of high density dislocation and strains. At the top surface,some cementites were decomposed under severe plastic deformation. Experimental evidences and analysis indicate that surface nanocrystallization of 45 steel results from dislocation activities,high strains and high strain rate are necessary for the formation of nanocrystallites.
基金This work was financially supported by the National Key Research and Development Program of China(2016YFD0300110,2016YFD0300101)the National Natural Science Foundation of China(31371575)+1 种基金the China Agriculture Research System(CARS-02-25)the Agricultural Science and Technology Innovation Project of the Chinese Academy of Agricultural Science.
文摘A high grain breakage rate is the main problem that occurs during mechanical maize harvest in China.The breakage sensitivity of different varieties was significantly different,and the breakage resistance is heritable.Therefore,breakage resistant variety screening can help improve the field production efficiency and provide references for breeding work.In this study,42 varieties of maize were harvested with the same mechanical parameters and the same manipulator on a range of harvest dates at experimental stations in Xinxiang,Henan Province,in 2017 and Changji,Xinjiang Province,in 2018 to determine the sensitivity of grain moisture content on grain breakage rate during machine harvest for different varieties.The integral value of the grain breakage rate curve corresponding to the range of 15%to 30%grain moisture content was used as an index that expressed the sensitivity of maize grains to breakage depending on grain moisture content(BSW).Forty-two varieties were categorized as having weak,intermediate,or strong BSW.Among the same four varieties in the two stations,Lianchuang 825 and Lianchuang 808 were classified as sensitive and fragile varieties,Shandan 650 was classified as an intermediate variety,Zeyu 8911 was divided into weak sensitive and breakage-resistance varieties in Xinxiang and intermediate varieties in Changji.The BSW classification results at the two experimental sites were generally consistent,indicating that breakage sensitivity due to moisture content may be a relatively stable genetic characteristic.This study suggested that the integral method for determining BSW can be used to assess the resistance of different maize varieties to grain breakage during mechanical harvesting.The integral method was used to identify twelve breakage-resistant varieties in Xinxiang Station,and six breakage-resistant varieties in Changji Station.This study provides a method for screening maize varieties that are suited to mechanical grain harvesting and for studying the mechanisms of grain breakage resistance.
基金funded by the National Natural Science Foundation of China(No.51601045)the Guangxi Natural Science Foundation(No.2015GXNSFBA139238)+2 种基金the Guangxi ‘Bagui’ Teams for Innovation and Researchthe National Basic Research Program of China(No.2013CB733000)the Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi
文摘In this study, the ultrafine grained (UFG) 6061 Al alloys fabricated by cold rolling were friction stir welded (FSW) with different rotation rates under both air cooling and rapid cooling in water. Low-heat-input parameters of 400 rpm rotation rate in water (400-Water) could effectively inhibit the coarsening of recrystallized grains, reduce the precipitation rate, and retain more dislocations of the UFG 6061 Al parent metal. 400-Water joint showed high lowest-hardness value, narrow low-hardness zone, and high tensile strength, attributing to the effect of dislocation, grain boundary, solid-solution, and precipitation hardening. This work provides an effective strategy to fabricate large-sized bulk UFG AI alloy by cold rolling with large deformation and low-heat-input FSW.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11225208 and 11521202)
文摘The design of high irradiation-resistant materials is very important for the development of next-generation nuclear reactors. Grain boundaries acting as effective defect sinks are thought to be able to moderate the deterioration of mechanical behaviors of irradiated materials, and have drawn increasing attention in recent years. The study of the effect of grain boundaries on the mechanical behaviors of irradiated materials is a multi-scale problem. At the atomic level, grain boundaries can effectively affect the production and formation of irradiation-induced point defects in grain interiors, which leads to the change of density, size distribution and evolution of defect clusters at grain level. The change of microstructure would influence the macroscopic mechanical properties of the irradiated polycrystal. Here we give a brief review about the effect of grain boundaries on the mechanical behaviors of irradiated metals from three scales: microscopic scale, mesoscopic scale and macroscopic scale.
基金The work has been supported by the National Key Research and Development Program of China(No.2017YFB0310401)National Natural Science Foundation of China(Nos.U1908227 and U20A20239).
文摘Sintering kinetics have been found to be effective in judging the evolution of ceramics.By using magnesium oxide-partially stabilized zirconia(Mg-PSZ)powder prepared by co-precipitation as raw materials,the evolution of densification and grain growth for Mg-PSZ ceramics were investigated.The results indicated that the densification of samples was mainly controlled by grain boundary diffusion in intermediate sintering stage.During the sintering process,the grain growth mechanisms included normal grain growth,abnormal grain growth and solid solution drag-controlled grain growth.Interestingly,the apparent activation energy for grain growth of Mg-PSZ ceramics is lower than that of ZrO_(2)–Y_(2)O_(3)ceramics in the solid solution drag-controlled grain grow process,which will cause grain to grow easily.The sintering kinetics and microstructure of Mg-PSZ ceramics were studied,and the kinetic equation of grain growth at different temperatures was established.The results show that the strength difference between Mg-PSZ and yttrium oxide-stabilized zirconia is closely related to the easy grain growth of Mg-PSZ ceramics.
基金supported by the National Natural Science Foundation of China(No.50371080)the Project of Science and Technology Development Program(No.20030508) of Jilin Province, Chinathe financial support from the Alexander von Humboldt Foundation
文摘A novel hard material with various (W0.5Al0.5)C grain shapes was successfully prepared through mechanical alloying and in-situ high-pressure sintering process. X-ray diffraction apparatus and scanning electron microscopy were used to characterize the phase and the microstructures of the samples. The novel hard materials with "fibrous", "rounded" and "plate-like" grains, which do not contain sharp edges, have the improved mechanical properties. The bulk boundless (W0.5Al0.5)C hard material with various (W0.5Al0.5)C grain shapes possesses good mechanical properties and light weight. The formation mechanism for the non-equilibrium (W0.5Al0.5)C grains during in-situ high-pressure sintering is also discussed.
基金the National Key Research and Development Program of China(Grant No.2016YFD0300101,2016YFD0300110)the National Natural Science Foundation of China(Grant No.31371575)+1 种基金the China Agriculture Research System(CARS-02-25)the Agricultural Science and Technology Innovation Project of the Chinese Academy of Agricultural Sciences.
文摘Maize is a bulk commodity in international agricultural product trading,and unified and standardized quality inspection standards are the basis of purchase and sales and other trading behaviors.China and the United States are the largest maize producers and consumers in the world,jointly accounting for more than 60%of the world's total production.In this research,the used data were from annual maize harvest quality reports released by the U.S.Grains Council in 2011-2019 and 2987 groups of mechanical grain harvest sample data collected by the Crop Cultivation and Physiology Innovation Team of the Chinese Academy of Agricultural Sciences in 2012-2019,this study compares the quality standards of commercial maize grain in China and the United States,the mechanical harvest quality(which affects the quality of the maize grain commodity),and the status quo of harvesting and storage processes in the two countries.Additionally,this study analyzes the differences in the formulation of mechanical harvest quality standards between China and the United States,as well as the reasons behind these differences,and recommends requirements for the formulation of quality standards for maize production technology and commodities that are in line with the economic conditions and maize-production conditions in China and in line with international standards in order to provide support for the industrialization of modern maize production in China.
基金supported by the Scientific and Technical Project of Sichuan Province(Nos.13CGZHZX0200,2014GZX0064,2015GZ0057)
文摘A new Al-5Ti-0.75B-0.2C master alloy was successfully prepared by self-propagating high-temperature(SHS)reaction from an Al-Ti-B_4C system with molten Al.Microstructure and phase characterization of the prepared Al-5Ti-0.75B-0.2C master alloy show that the nearly spherical TiC particles,hexagonal or rectangular TiB_2 particles,and blocklike TiAl_3 particles distribute uniformly in the aluminum matrix.Grain refining test on commercial pure aluminum indicates that Al-5Ti-0.75B-0.2C master alloy exhibits a better grain refining performance than Al-5Ti-lB master alloy.By addition of 0.2 wt%Al-5Ti-0.75B-0.2C master alloy,the average grain size of a-Al can be effectively refined to160 ± 5 μm from about 3000 μm,and the tensile strength and elongation are increased by about 20%and 14.1%due to the grain refinement.
基金Supported by the National Natural Science Foundation of China(11102139,11472195)the Natural Science Foundation of Hubei Province of China(2014CFB713)
文摘Through molecular dynamics(MD) simulation, the dependencies of temperature, grain size and strain rate on the mechanical properties were studied. The simulation results demonstrated that the strain rate from 0.05 to 2 ns–1 affected the Young's modulus of nickel nanowires slightly, whereas the yield stress increased. The Young's modulus decreased approximately linearly; however, the yield stress firstly increased and subsequently dropped as the temperature increased. The Young's modulus and yield stress increased as the mean grain size increased from 2.66 to 6.72 nm. Moreover, certain efforts have been made in the microstructure evolution with mechanical properties association under uniaxial tension. Certain phenomena such as the formation of twin structures, which were found in nanowires with larger grain size at higher strain rate and lower temperature, as well as the movement of grain boundaries and dislocation, were detected and discussed in detail. The results demonstrated that the plastic deformation was mainly accommodated by the motion of grain boundaries for smaller grain size. However, for larger grain size, the formations of stacking faults and twins were the main mechanisms of plastic deformation in the polycrystalline nickel nanowire.
基金supported by the National Natural Science Foundation of China(Nos.52020105013,51871092,and 11902113)the Natural Science Foundation of Hunan Province(Nos.2019JJ50068 and 2021JJ40032)+1 种基金the Changsha Municipal Natu-ral Science Foundation(No.kq2014126)support from the National Science Foundation(Nos.DMR-1611180 and 1809640).
文摘Additive manufacturing is believed to open up a new era in precise microfabrication,and the dynamic microstructure evolution during the process as well as the experiment-simulation correlated study is conducted on a prototype multi-principal-element alloys FeCrNi fabricated using selective laser melting(SLM).Experimental results reveal that columnar crystals grow across the cladding layers and the dense cellular structures develop in the filled crystal.At the micron scale,all constituent elements are evenly distributed,while at the near-atomic scale,Cr element is obviously segregated.Simulation results at the atomic scale illustrate that i)the solid-liquid interface during the grain growth changes from horizontal to arc due to the radial temperature gradient;ii)the precipitates,microscale voids,and stacking faults also form dynamically as a result of the thermal gradient,leading to the residual stress in the SLMed structure.In addition,we established a microstructure-based physical model based on atomic simulation,which indicates that strong interface strengthening exists in the tensile deformation.The present work provides an atomic-scale understanding of the microstructural evolution in the SLM process through the combination of experiment and simulation.
基金supported by the National High Technology Research and Development Program ("863" Program) of China (2009AA03Z525)the Program of New Century Excellent Talents of the Ministry of Education of China (NCET-08-0080)+1 种基金the Science and Technology Fund of Dalian City (2009J21DW003)the Fundamental Research Funds for the Central Universities (DUT11ZD115)
文摘Effects of Nd on microstructure and mechanical properties of as-cast Mg-8Li-3Al alloy were investigated by OM,X-ray diffraction(XRD),EPMA,scanning electron microscopy(SEM) and energy dispersive spectroscopy(EDS).The results showed that the dendrites sizes of α phase were decreased by the Nd addition.When the amount of addition Nd was 1.6 wt.%,the alloy with the smallest α phase was obtained.The refining mechanism mainly owed to the increasing constitutional supercooling at the solidification front.Furthermore,the compound Al 2 Nd generated by the reaction of Al and Nd,which distributed at the phase boundary and inside β phase,could also restrain the growth of α phase.Nd could improve the tensile strength and elongation of Mg-8Li-3Al alloy,however,excessive Al 2 Nd might also become crack source and decrease the elongation.
文摘The effect of solution annealing on the microstructure and mechanical properties of a Ni-Cr-W-Fe alloy developed for advanced 700?C ultra-supercritical power plants was investigated. Test samples in this study were subjected to different solution treatments and the same aging treatment(at 760?C for 1 h).When solution annealing temperature was elevated from 1020?C to 1150?C, the stress-rupture life at750?C/320 MPa was increased from 60 h to 300 h, the stress-rupture elongation was enhanced from12% to 17%, and the elongation of the tensile at 750?C was improved from 11% to 24%. All tensile and stress-rupture samples displayed an intergranular dimple mixed fracture. Intergranular micro-cracks had a great relationship with the morphology of grain boundary carbides. Most carbides retained the morphology of globular shape and continuous thin plate. After tensile and stress-rupture tests, a few carbides were converted into lamellar. The results showed that intergranular micro-cracks were easier to form at continuous thin plate carbides than at globular shape carbides. Lamellar carbides hardly caused the nucleation of micro-cracks. Besides, grain boundaries sliding and elements diffusion during stressrupture tests led to the formation of precipitate free zones, which accelerated the extension of microcracks and influenced the stress-rupture life.