Warm and humid climate and gentle hilly topography have provided favourable conditions for the devel-opment of the weathering crust of the granite intrusions in the Longnan area, Jiangxi Province. REE is mostlyconcent...Warm and humid climate and gentle hilly topography have provided favourable conditions for the devel-opment of the weathering crust of the granite intrusions in the Longnan area, Jiangxi Province. REE is mostlyconcentrated in an adsorption state in clay in the wholly weathered zone. The rare-earth minerals enriched inthe parent rocks provided the source material for the REE enrichment. Exchangeable REE accounts for48-86%. Extraction experiments and stable isotopic study of clay minerals suggest that the downward infiltra-tion of meteoric water and increasing gradient of pH values have played an important role in the enrichment ofREE during the progressive weathering. Slight fractionation of individual REE can not change their distribu-tion patterns in the profiles. which are inherited from the parent rocks.展开更多
As we know there is a famous East Qinling-Dabie molybdenum belt in china,where many molybdenum deposits located such as super giant Jinduicheng,Sandaozhuang,Shangfanggou and Nannihu molybdenum deposits(Li,2008) ;The m...As we know there is a famous East Qinling-Dabie molybdenum belt in china,where many molybdenum deposits located such as super giant Jinduicheng,Sandaozhuang,Shangfanggou and Nannihu molybdenum deposits(Li,2008) ;The molybdenum mineralization in the East Qinling-Dabie belt clusters into three groups or mineralization pulses:233-221,148-138 and 131-112 Ma(Mao et al,2008).展开更多
The Zudong and Guanxi granites are original rocks of the ion adsorption-type HREE and LREE deposits in weathering crust of granites. The ΣREE value and LREE/HREE ratio of the Zudong granite are 264 ppm and 0.81-0.24 ...The Zudong and Guanxi granites are original rocks of the ion adsorption-type HREE and LREE deposits in weathering crust of granites. The ΣREE value and LREE/HREE ratio of the Zudong granite are 264 ppm and 0.81-0.24 respectively, and the average Y/ΣREE ratio is 35.8-54.5%. This is mainly due to magmatic crystallization and evolution and deuteric metasomatism (albitization, muscovitization and fluorite-doveritization). These alterations resulted in endogenic mineralizations of yttrium-group REE fluorine carbonates, silicates and arsenates. The Guanxi granite is characterized by LREE enrichment (the average LREE/HREE ratio is 2.43).展开更多
Controlled by E-W-trending faults, a Proterozoic (1.4-1.8 Ga old) rapakivi granite suite was intruded inBeijing and the area to its east (within Hebei Province), forming three parallel belts of igneous rocks. Theisoto...Controlled by E-W-trending faults, a Proterozoic (1.4-1.8 Ga old) rapakivi granite suite was intruded inBeijing and the area to its east (within Hebei Province), forming three parallel belts of igneous rocks. Theisotopic, trace element and rare earth element geochemical data of a bimodal rock association made up ofanorthosite, gabbro and alkali basalt and olivine-bearing quartz-syenite, rapakivi granite and trachyte as wellas potassic A-type granites and anorogenic granites—— all suggest that there exists an incipient rift in thestudy area. Fractional crystallization of a mixed magma formed by the magma derived from the upper mantleand the magma derived by small degrees of fusion of the lower crust produced anorthosite cumulates. Thewater-deficient granitic magma was differentiated into a subalkaline series. When the fractional crystallizationwas incomplete, rhythmic eruptions took place.展开更多
The granitic dykes in the Badu Group, Zhejiang Province, South China provide important insights on tectonic setting and crustal evolution of the South China Block (SCB) and the Indochina Block during Triassic. Here ...The granitic dykes in the Badu Group, Zhejiang Province, South China provide important insights on tectonic setting and crustal evolution of the South China Block (SCB) and the Indochina Block during Triassic. Here we report LA-ICP-MS U-Pb data of granitic rocks from the Hucun and Kengkou which show early Triassic ages of 242 ± 2 and 232 ± 3 Ma, respectively, representing their timing of emplacement. The dyke rocks are enriched in K, AI, LREE, Rb, Th, U, and Pb, and are depleted in Nb, Ta, St, and Ti. The rocks are characterized by highly fractionated REE patterns with (La/Yb)N ratios of 28.46 -38.07 with strong negative Eu anomalies (Eu/Eu* = 0,65-0.73). In situ Hf isotopic analyses of zircons from the Hucun granite yielded CHf(t) values of -13.9 to -6.4 and two-stage depleted mantle Hf model ages of 1.68-2.15 Ga, which indicate that the magma was formed by partial melting of the Paleo- proterozoic metasedimentary protoliths in the Cathaysia Block. The zircons from the Kengkou granite have eHf(t) values ranging from -40.7 to 31.5 and yield two-stage depleted mantle Hf model ages of 0.99 -2.49 Ga, indicating magma origin from a mixed source. The Hucun and Kengkou dykes, together with the Triassic A-type granites in SE China were probably generated during magmatism associated with crust-mantle decoupling along the convergent plate boundary between SCB and the Indochina Block.展开更多
Selected geological data on Early Cretaceous strata, structures, magmatic plutons and volcanic rocks from the Kunlun to Himalaya Mountains reveal a new view of the Early Cretaceous paleo-tectonics and the related geod...Selected geological data on Early Cretaceous strata, structures, magmatic plutons and volcanic rocks from the Kunlun to Himalaya Mountains reveal a new view of the Early Cretaceous paleo-tectonics and the related geodynamic movement of the Tibetan Plateau. Two major paleo- oceans, the Mid-Tethys Ocean between the Qiangtang and Lhasa blocks, and the Neo-Tethys Ocean between the Lhasa and Himalayan blocks, existed in the Tibetan region in the Early Cretaceous. The Himalayan Marginal and South Lhasa Seas formed in the southern and northern margins of the Neo- Tethys Ocean, the Central Tibet Sea and the Qiangtang Marginal Sea formed in the southern and northern margins of the Mid-Tethys Ocean, respectively. An arm of the sea extended into the southwestern Tarim basin in the Early Cretaceous. Early Cretaceous intensive thrusting, magmatic emplacement and volcanic eruptions occurred in the central and northern Lhasa Block, while strike- slip formed along the Hoh-Xil and South Kunlun Faults in the northern Tibetan region. Early Cretaceous tectonics together with magmatic K20 geochemistry indicate an Early Cretaceous southward subduction of the Mid-Tethys Oceanic Plate along the Bangoin-Nujiang Suture which was thrust ~87 km southward during the Late Cretaceous-Early Cenozoic. No intensive thrust and magmatic emplacement occurred in the Early Cretaceous in the Himalayan and southern Lhasa Blocks, indicating that the spreading Neo-Tethys Oceanic Plate had not been subducted in the Early Cretaceous. To the north, terrestrial basins of red-beds formed in the Hoh-Xil, Kunlun, Qilian and the northeastern Tarim blocks in Early Cretaceous, and the Qiangtang Marginal Sea disappeared after the Qiangtang Block uplifted in the late Early Cretaceous.展开更多
Geochemical characteristics of the Chagande'ersi molybdenum deposit in Inner Mongolia and its genesis were analyzed in this study using rock mineralography and rock geochemical testing. The mineralized country rocks ...Geochemical characteristics of the Chagande'ersi molybdenum deposit in Inner Mongolia and its genesis were analyzed in this study using rock mineralography and rock geochemical testing. The mineralized country rocks of the Chagande'ersi molybdenum deposit consist mainly of medium- to fine-grained monzogranite, medium-to fine-grained rich-K granite, with minor fine-grained K- feldspar granite veins and quartz veins. The rocks are characterized by high silica, rich alkali, high potassium, which are favorable factors for molybdenum mineralization. The rocks have the Rittmann index ranging from 1.329 to 1.961, an average Na20+K20 value of 7.41, and AI2Oa/(CaO+Na20+K^O) 〉1, suggesting that the rocks belong to the high-K calc-alkaline peraluminous granite. The typical rock samples are enriched in Rb, Th, K and light rare earth elements, depleted in Sr, Ba, Nb, P and Ti, and these features are similar to that of the melt granite resulting from collision of plate margins. The JEu of the rocks falls the zone between the crust granite and crust-mantle granite, and are close to that of the crust granite; (La/LU)N indicates the formation environment of granite is a continental margin setting. The Nb/Ta ratios are close to that of the average crust (10); the Zr/Hf ratios of monzogranite are partly below the mean mantle (34-60), while the Zr/Hf ratio of K-feldspar granite are close to the mean value in the crust. Comprehensive analyses show that the granite in this area formed during the transition period between tectonic collision and post-collision. During the plate collision and orogeny, the crust and mantle material were mixed physically, remelting into lava and then crystal fractionation, finally gave rise to the formation of the rock body in this area. This has close spatial and temporal relation with the molybdenum mineralization.展开更多
文摘Warm and humid climate and gentle hilly topography have provided favourable conditions for the devel-opment of the weathering crust of the granite intrusions in the Longnan area, Jiangxi Province. REE is mostlyconcentrated in an adsorption state in clay in the wholly weathered zone. The rare-earth minerals enriched inthe parent rocks provided the source material for the REE enrichment. Exchangeable REE accounts for48-86%. Extraction experiments and stable isotopic study of clay minerals suggest that the downward infiltra-tion of meteoric water and increasing gradient of pH values have played an important role in the enrichment ofREE during the progressive weathering. Slight fractionation of individual REE can not change their distribu-tion patterns in the profiles. which are inherited from the parent rocks.
文摘As we know there is a famous East Qinling-Dabie molybdenum belt in china,where many molybdenum deposits located such as super giant Jinduicheng,Sandaozhuang,Shangfanggou and Nannihu molybdenum deposits(Li,2008) ;The molybdenum mineralization in the East Qinling-Dabie belt clusters into three groups or mineralization pulses:233-221,148-138 and 131-112 Ma(Mao et al,2008).
文摘The Zudong and Guanxi granites are original rocks of the ion adsorption-type HREE and LREE deposits in weathering crust of granites. The ΣREE value and LREE/HREE ratio of the Zudong granite are 264 ppm and 0.81-0.24 respectively, and the average Y/ΣREE ratio is 35.8-54.5%. This is mainly due to magmatic crystallization and evolution and deuteric metasomatism (albitization, muscovitization and fluorite-doveritization). These alterations resulted in endogenic mineralizations of yttrium-group REE fluorine carbonates, silicates and arsenates. The Guanxi granite is characterized by LREE enrichment (the average LREE/HREE ratio is 2.43).
文摘Controlled by E-W-trending faults, a Proterozoic (1.4-1.8 Ga old) rapakivi granite suite was intruded inBeijing and the area to its east (within Hebei Province), forming three parallel belts of igneous rocks. Theisotopic, trace element and rare earth element geochemical data of a bimodal rock association made up ofanorthosite, gabbro and alkali basalt and olivine-bearing quartz-syenite, rapakivi granite and trachyte as wellas potassic A-type granites and anorogenic granites—— all suggest that there exists an incipient rift in thestudy area. Fractional crystallization of a mixed magma formed by the magma derived from the upper mantleand the magma derived by small degrees of fusion of the lower crust produced anorthosite cumulates. Thewater-deficient granitic magma was differentiated into a subalkaline series. When the fractional crystallizationwas incomplete, rhythmic eruptions took place.
基金supported by the Central Fundamental Research(Grant No.DZLXJK201504)
文摘The granitic dykes in the Badu Group, Zhejiang Province, South China provide important insights on tectonic setting and crustal evolution of the South China Block (SCB) and the Indochina Block during Triassic. Here we report LA-ICP-MS U-Pb data of granitic rocks from the Hucun and Kengkou which show early Triassic ages of 242 ± 2 and 232 ± 3 Ma, respectively, representing their timing of emplacement. The dyke rocks are enriched in K, AI, LREE, Rb, Th, U, and Pb, and are depleted in Nb, Ta, St, and Ti. The rocks are characterized by highly fractionated REE patterns with (La/Yb)N ratios of 28.46 -38.07 with strong negative Eu anomalies (Eu/Eu* = 0,65-0.73). In situ Hf isotopic analyses of zircons from the Hucun granite yielded CHf(t) values of -13.9 to -6.4 and two-stage depleted mantle Hf model ages of 1.68-2.15 Ga, which indicate that the magma was formed by partial melting of the Paleo- proterozoic metasedimentary protoliths in the Cathaysia Block. The zircons from the Kengkou granite have eHf(t) values ranging from -40.7 to 31.5 and yield two-stage depleted mantle Hf model ages of 0.99 -2.49 Ga, indicating magma origin from a mixed source. The Hucun and Kengkou dykes, together with the Triassic A-type granites in SE China were probably generated during magmatism associated with crust-mantle decoupling along the convergent plate boundary between SCB and the Indochina Block.
基金supported by the China Geological Survey under grants No.1212011120185 and 1212011221111the Ministry of Land and Resources of China under a grant Sinoprobe-02the Ministry of Science and Technology of China under a grant 2006DFB21330
文摘Selected geological data on Early Cretaceous strata, structures, magmatic plutons and volcanic rocks from the Kunlun to Himalaya Mountains reveal a new view of the Early Cretaceous paleo-tectonics and the related geodynamic movement of the Tibetan Plateau. Two major paleo- oceans, the Mid-Tethys Ocean between the Qiangtang and Lhasa blocks, and the Neo-Tethys Ocean between the Lhasa and Himalayan blocks, existed in the Tibetan region in the Early Cretaceous. The Himalayan Marginal and South Lhasa Seas formed in the southern and northern margins of the Neo- Tethys Ocean, the Central Tibet Sea and the Qiangtang Marginal Sea formed in the southern and northern margins of the Mid-Tethys Ocean, respectively. An arm of the sea extended into the southwestern Tarim basin in the Early Cretaceous. Early Cretaceous intensive thrusting, magmatic emplacement and volcanic eruptions occurred in the central and northern Lhasa Block, while strike- slip formed along the Hoh-Xil and South Kunlun Faults in the northern Tibetan region. Early Cretaceous tectonics together with magmatic K20 geochemistry indicate an Early Cretaceous southward subduction of the Mid-Tethys Oceanic Plate along the Bangoin-Nujiang Suture which was thrust ~87 km southward during the Late Cretaceous-Early Cenozoic. No intensive thrust and magmatic emplacement occurred in the Early Cretaceous in the Himalayan and southern Lhasa Blocks, indicating that the spreading Neo-Tethys Oceanic Plate had not been subducted in the Early Cretaceous. To the north, terrestrial basins of red-beds formed in the Hoh-Xil, Kunlun, Qilian and the northeastern Tarim blocks in Early Cretaceous, and the Qiangtang Marginal Sea disappeared after the Qiangtang Block uplifted in the late Early Cretaceous.
基金supported by the National Natural Science Foundation,40073013
文摘Geochemical characteristics of the Chagande'ersi molybdenum deposit in Inner Mongolia and its genesis were analyzed in this study using rock mineralography and rock geochemical testing. The mineralized country rocks of the Chagande'ersi molybdenum deposit consist mainly of medium- to fine-grained monzogranite, medium-to fine-grained rich-K granite, with minor fine-grained K- feldspar granite veins and quartz veins. The rocks are characterized by high silica, rich alkali, high potassium, which are favorable factors for molybdenum mineralization. The rocks have the Rittmann index ranging from 1.329 to 1.961, an average Na20+K20 value of 7.41, and AI2Oa/(CaO+Na20+K^O) 〉1, suggesting that the rocks belong to the high-K calc-alkaline peraluminous granite. The typical rock samples are enriched in Rb, Th, K and light rare earth elements, depleted in Sr, Ba, Nb, P and Ti, and these features are similar to that of the melt granite resulting from collision of plate margins. The JEu of the rocks falls the zone between the crust granite and crust-mantle granite, and are close to that of the crust granite; (La/LU)N indicates the formation environment of granite is a continental margin setting. The Nb/Ta ratios are close to that of the average crust (10); the Zr/Hf ratios of monzogranite are partly below the mean mantle (34-60), while the Zr/Hf ratio of K-feldspar granite are close to the mean value in the crust. Comprehensive analyses show that the granite in this area formed during the transition period between tectonic collision and post-collision. During the plate collision and orogeny, the crust and mantle material were mixed physically, remelting into lava and then crystal fractionation, finally gave rise to the formation of the rock body in this area. This has close spatial and temporal relation with the molybdenum mineralization.