The pilot performance of the combined GAC-MF membrane process for drinking water advanced treatment was described. In the process of GAC adsorption, under the conditions of 20 min HRT and 6 m/h filtration rate, the re...The pilot performance of the combined GAC-MF membrane process for drinking water advanced treatment was described. In the process of GAC adsorption, under the conditions of 20 min HRT and 6 m/h filtration rate, the removal efficiencies of UV_(254) and trichloromethane could reach 40% and 50% respectively and the UV_(254) and trichloromethane in system effluent was less than 0.015 cm^(-1) and 5μg/L respectively. In the post MF membrane process, MF membrane effectively retained the particles and bacteria in raw water. The effluent turbidity was less than 0.2 NTU and no bacteria were detected at all in permeate. A computer-controlled system was employed to control this system. The membrane operating parameters of backwash interval, duration and flux were studied. The backwash interval of 10-min, 20-min and 60-min was researched respectively, and the variation of trans-membrane pressure was also analyzed. Consequently short backwash interval was recommended under the same water consume.展开更多
In order to reduce the microfauna leakage risk from a granular biological activated carbon （GBAC） reactor which employs granular activated carbon （GAC） as adsorption media in drinking water advanced treatment, a n...In order to reduce the microfauna leakage risk from a granular biological activated carbon （GBAC） reactor which employs granular activated carbon （GAC） as adsorption media in drinking water advanced treatment, a novel fiber and granular biological activated carbon （FGBAC） reactor which employs both GAC and activated carbon fiber （ACF） as adsorption media, was developed. The results showed that the species composition of microfauna leaking from FGBAC reactor is almost similar to that leaking from GBAC reactor, however the densities of microfauna leaking from FGBAC reactor is reduced by 26%-81% compared to those leaking from GBAC reactor. In addition, compared to GBAC reactor, FGBAC reactor can increase the removal efflciencies of chemical oxygen demand （COD） and turbidity by 7% and 10%, respectively, during the stable operation period of reactor.展开更多
The study was conducted to characterize and perform laboratory-scale treatment of municipal drainage wastewater of Khulna, Bangladesh. Wastewater samples were collected from three different points of existing urban dr...The study was conducted to characterize and perform laboratory-scale treatment of municipal drainage wastewater of Khulna, Bangladesh. Wastewater samples were collected from three different points of existing urban drain outlets into the Mayur River around Khulna. Laboratory testing shows the BOD5 and COD concentration of wastewater samples varied from 57 - 226 mg/l and 320 - 435 mg/l, respectively, and the total dissolved solids ranged from 1800 - 2525 mg/l. Therefore, a laboratory-scale treatment technology was developed to treat this wastewater. Treatment technologies adopted were primary sedimentation, followed by aeration, chemical precipitation and filtration. In treated wastewater, BOD5, COD and TDS were found to be in the range of 40 - 115 mg/l, 160 - 256 mg/l and 1356 - 1500 mg/l, respectively. These test results suggest that the performance of laboratory-scale treatment plant was not adequate to fulfil the acceptable limit (ECR’97) for safe disposal into surface water bodies. Due to poor quality of effluents, modification of laboratory-scale treatment plant was made by an activated sludge process followed by granular media filtration. The final BOD5, COD TDS and TSS concentration of effluents was found to be 1.38 - 9.8 mg/l, 32 - 192 mg/l, 590 - 1667 mg/l, and 35 - 95 mg/l respectively, which satisfy ECR’97 standard limits for safe disposal into inland water bodies.展开更多
Heterogeneous advanced oxidation processes(AOPs)based on non-radical reactive species are considered as a powerful technology for wastewater purification due to their long half-lives and high adaptation in a wide pH r...Heterogeneous advanced oxidation processes(AOPs)based on non-radical reactive species are considered as a powerful technology for wastewater purification due to their long half-lives and high adaptation in a wide pH range.Herein,we fabricate surface Co defect-rich spinel ZnCo_(2)O_(4)porous nanosheets,which can generate≡CoIV=O and ^(1)O_(2) over a wide pH range of 3.81-10.96 by the formation of amphoteric≡Zn(OH)2 in peroxymonosulfate(PMS)activation process.Density functional theory(DFT)calculations show Co defect-rich ZnCo_(2)O_(4)possesses much stronger adsorption ability and more electron transfer to PMS.Moreover,the adsorption mode changes from terminal oxygen Co-O-Co to Co-O,accelerating the polarization of adjacent oxygen,which is beneficial to the generation of≡CoIV=O and Generating ^(1)O_(2) .Co defect-rich ZnCo_(2)O_(4)porous nanosheets exhibit highly active PMS activation activity and stability in p-nitrophenol(PNP)degradation,whose toxicity of degradation intermediates is significant reduction.The Co defect-rich ZnCo_(2)O_(4)nanosheet catalyst sponge/PMS system achieved stable and efficient removal of PNP with a removal efficiency higher than 93%over 10 h.This work highlights the development of functional catalyst and provides an atomic-level understanding into non-radical PMS activation process in wastewater treatment.展开更多
基金Sponsored by Fok Ying Tung Education Foundation (No. 94004)
文摘The pilot performance of the combined GAC-MF membrane process for drinking water advanced treatment was described. In the process of GAC adsorption, under the conditions of 20 min HRT and 6 m/h filtration rate, the removal efficiencies of UV_(254) and trichloromethane could reach 40% and 50% respectively and the UV_(254) and trichloromethane in system effluent was less than 0.015 cm^(-1) and 5μg/L respectively. In the post MF membrane process, MF membrane effectively retained the particles and bacteria in raw water. The effluent turbidity was less than 0.2 NTU and no bacteria were detected at all in permeate. A computer-controlled system was employed to control this system. The membrane operating parameters of backwash interval, duration and flux were studied. The backwash interval of 10-min, 20-min and 60-min was researched respectively, and the variation of trans-membrane pressure was also analyzed. Consequently short backwash interval was recommended under the same water consume.
基金Project supported by the Key Special Program on the Science&Technology for the Pollution Control and Treatment of Water Bodies(Grant No.2008ZX07421-004)the Specific Project for Shanghai World Expo 2010(Grant No.07DZ05804)the Shanghai Leading Academic Discipline Project(Grant No.S30109)
文摘In order to reduce the microfauna leakage risk from a granular biological activated carbon （GBAC） reactor which employs granular activated carbon （GAC） as adsorption media in drinking water advanced treatment, a novel fiber and granular biological activated carbon （FGBAC） reactor which employs both GAC and activated carbon fiber （ACF） as adsorption media, was developed. The results showed that the species composition of microfauna leaking from FGBAC reactor is almost similar to that leaking from GBAC reactor, however the densities of microfauna leaking from FGBAC reactor is reduced by 26%-81% compared to those leaking from GBAC reactor. In addition, compared to GBAC reactor, FGBAC reactor can increase the removal efflciencies of chemical oxygen demand （COD） and turbidity by 7% and 10%, respectively, during the stable operation period of reactor.
文摘The study was conducted to characterize and perform laboratory-scale treatment of municipal drainage wastewater of Khulna, Bangladesh. Wastewater samples were collected from three different points of existing urban drain outlets into the Mayur River around Khulna. Laboratory testing shows the BOD5 and COD concentration of wastewater samples varied from 57 - 226 mg/l and 320 - 435 mg/l, respectively, and the total dissolved solids ranged from 1800 - 2525 mg/l. Therefore, a laboratory-scale treatment technology was developed to treat this wastewater. Treatment technologies adopted were primary sedimentation, followed by aeration, chemical precipitation and filtration. In treated wastewater, BOD5, COD and TDS were found to be in the range of 40 - 115 mg/l, 160 - 256 mg/l and 1356 - 1500 mg/l, respectively. These test results suggest that the performance of laboratory-scale treatment plant was not adequate to fulfil the acceptable limit (ECR’97) for safe disposal into surface water bodies. Due to poor quality of effluents, modification of laboratory-scale treatment plant was made by an activated sludge process followed by granular media filtration. The final BOD5, COD TDS and TSS concentration of effluents was found to be 1.38 - 9.8 mg/l, 32 - 192 mg/l, 590 - 1667 mg/l, and 35 - 95 mg/l respectively, which satisfy ECR’97 standard limits for safe disposal into inland water bodies.
基金supported by the National Natural Science Foundation of China(NSFC)(No.22308336).
文摘Heterogeneous advanced oxidation processes(AOPs)based on non-radical reactive species are considered as a powerful technology for wastewater purification due to their long half-lives and high adaptation in a wide pH range.Herein,we fabricate surface Co defect-rich spinel ZnCo_(2)O_(4)porous nanosheets,which can generate≡CoIV=O and ^(1)O_(2) over a wide pH range of 3.81-10.96 by the formation of amphoteric≡Zn(OH)2 in peroxymonosulfate(PMS)activation process.Density functional theory(DFT)calculations show Co defect-rich ZnCo_(2)O_(4)possesses much stronger adsorption ability and more electron transfer to PMS.Moreover,the adsorption mode changes from terminal oxygen Co-O-Co to Co-O,accelerating the polarization of adjacent oxygen,which is beneficial to the generation of≡CoIV=O and Generating ^(1)O_(2) .Co defect-rich ZnCo_(2)O_(4)porous nanosheets exhibit highly active PMS activation activity and stability in p-nitrophenol(PNP)degradation,whose toxicity of degradation intermediates is significant reduction.The Co defect-rich ZnCo_(2)O_(4)nanosheet catalyst sponge/PMS system achieved stable and efficient removal of PNP with a removal efficiency higher than 93%over 10 h.This work highlights the development of functional catalyst and provides an atomic-level understanding into non-radical PMS activation process in wastewater treatment.
