Near the metal-insulator transition, the Hall coefficient R of metal-insulator composites (M-I composite) can be up to 104 times larger than that in the pure metal called Giant Hall effect. Applying the physical model...Near the metal-insulator transition, the Hall coefficient R of metal-insulator composites (M-I composite) can be up to 104 times larger than that in the pure metal called Giant Hall effect. Applying the physical model for alloys with phase separation developed in [1] [2], we conclude that the Giant Hall effect is caused by an electron transfer away from the metallic phase to the insulating phase occupying surface states. These surface states are the reason for the granular structure typical for M-I composites. This electron transfer can be described by [1] [2], provided that long-range diffusion does not happen during film production (n is the electron density in the phase A. u<sub>A </sub>and u<sub>B</sub> are the volume fractions of the phase A (metallic phase) and phase B (insulator phase). β is a measure for the average potential difference between the phases A and B). A formula for calculation of R of composites is derived and applied to experimental data of granular Cu<sub>1-y</sub>(SiO<sub>2</sub>)<sub>y</sub> and Ni<sub>1-y</sub>(SiO<sub>2</sub>)<sub>y</sub> films.展开更多
As a special biofilm structure,microbial attachment is believed to play an important role in the granulation of aerobic granular activated sludge（AGAS）.This experiment was to investigate the biological effect of Ca^...As a special biofilm structure,microbial attachment is believed to play an important role in the granulation of aerobic granular activated sludge（AGAS）.This experiment was to investigate the biological effect of Ca^2＋,Mg^2＋,Cu^2＋,Fe^2＋,Zn^2＋,and K＋which are the most common ions present in biological wastewater treatment systems,on the microbial attachment of AGAS and flocculent activated sludge（FAS）,from which AGAS is always derived,in order to provide a new strategy for the rapid cultivation and stability control of AGAS.The result showed that attachment biomass of AGAS was about 300%higher than that of FAS without the addition of metal ions.Different metal ions had different effects on the process of microbial attachment.FAS and AGAS reacted differently to the metal ions as well,and in fact,AGAS was more sensitive to the metal ions.Specifically,Ca^2＋,Mg^2＋,and K＋could increase the microbial attachment ability of both AGAS and FAS under appropriate concentrations,Cu^2＋,Fe^2＋,and Zn^2＋were also beneficial to the microbial attachment of FAS at low concentrations,but Cu^2＋,Fe^2＋,and Zn^2＋greatly inhibited the attachment process of AGAS even at extremely low concentrations.In addition,the acylated homoserine lactone（AHL）-based quorum sensing system,the content of extracellular polymeric substances and the relative hydrophobicity of the sludges were greatly influenced by metal ions.As all these parameters had close relationships with the microbial attachment process,the microbial attachment may be affected by changes of these parameters.展开更多
文摘Near the metal-insulator transition, the Hall coefficient R of metal-insulator composites (M-I composite) can be up to 104 times larger than that in the pure metal called Giant Hall effect. Applying the physical model for alloys with phase separation developed in [1] [2], we conclude that the Giant Hall effect is caused by an electron transfer away from the metallic phase to the insulating phase occupying surface states. These surface states are the reason for the granular structure typical for M-I composites. This electron transfer can be described by [1] [2], provided that long-range diffusion does not happen during film production (n is the electron density in the phase A. u<sub>A </sub>and u<sub>B</sub> are the volume fractions of the phase A (metallic phase) and phase B (insulator phase). β is a measure for the average potential difference between the phases A and B). A formula for calculation of R of composites is derived and applied to experimental data of granular Cu<sub>1-y</sub>(SiO<sub>2</sub>)<sub>y</sub> and Ni<sub>1-y</sub>(SiO<sub>2</sub>)<sub>y</sub> films.
基金supported by the National Natural Science Foundation of China (No. 51578069)
文摘As a special biofilm structure,microbial attachment is believed to play an important role in the granulation of aerobic granular activated sludge（AGAS）.This experiment was to investigate the biological effect of Ca^2＋,Mg^2＋,Cu^2＋,Fe^2＋,Zn^2＋,and K＋which are the most common ions present in biological wastewater treatment systems,on the microbial attachment of AGAS and flocculent activated sludge（FAS）,from which AGAS is always derived,in order to provide a new strategy for the rapid cultivation and stability control of AGAS.The result showed that attachment biomass of AGAS was about 300%higher than that of FAS without the addition of metal ions.Different metal ions had different effects on the process of microbial attachment.FAS and AGAS reacted differently to the metal ions as well,and in fact,AGAS was more sensitive to the metal ions.Specifically,Ca^2＋,Mg^2＋,and K＋could increase the microbial attachment ability of both AGAS and FAS under appropriate concentrations,Cu^2＋,Fe^2＋,and Zn^2＋were also beneficial to the microbial attachment of FAS at low concentrations,but Cu^2＋,Fe^2＋,and Zn^2＋greatly inhibited the attachment process of AGAS even at extremely low concentrations.In addition,the acylated homoserine lactone（AHL）-based quorum sensing system,the content of extracellular polymeric substances and the relative hydrophobicity of the sludges were greatly influenced by metal ions.As all these parameters had close relationships with the microbial attachment process,the microbial attachment may be affected by changes of these parameters.
