The modified graphite anode materials have some prominent advantages over other anode materials in the industrial applications.A novel simple and gentle method is proposed to synthesize the mild expanded graphite micr...The modified graphite anode materials have some prominent advantages over other anode materials in the industrial applications.A novel simple and gentle method is proposed to synthesize the mild expanded graphite microspheres(MEGMs) from flake graphite spheres through a combined modified pressurized oxidation combined with the microwave treatment.The microstructural results demonstrate that moderately expanded MEGMs with an expansion volume between 4 and 10 ml·g^(-1)exhibit a highly microporous structure with an enlarged interlayer spacing,a decreased microcrystalline size,as well as an increased number of functional groups on the surface,resulting in the increased storage sites and spaces for lithium ions and the enhanced diffusion rate of lithium ions.When used as the anode material for lithium-ion batteries,the MEGM-T75t30 obtained by oxidation treatment at 75℃ for 30 min followed by microwave irradiation for expansion displays a high reversible capacity of 446.7 mAh·g^(-1) at 100 mA·g^(-1) after 100 cycles and excellent rate performance(330 and 116 mAh·g^(-1) at 800 and 3200 mA·g^(-1),respectively).Therefore,the MEGMs prepared by this convenient and mild method show excellent electrochemical properties and good application potential.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.51702191,51802325 and U1510134)the Natural Science Foundation of Shanxi Province,China(No.201901D111037)+3 种基金Scientific Research Foundation for Young Scientists of Shanxi Province,China(No.201901D211585)the Science and Technology Innovation Planning Project in Universities and Colleges of Shanxi Province of China(No.2019L0012)the Unveiling Bidding Projects of Shanxi Province,China(No.20191101008)the Shanxi“1331 Project”Key Innovative Research Team。
文摘The modified graphite anode materials have some prominent advantages over other anode materials in the industrial applications.A novel simple and gentle method is proposed to synthesize the mild expanded graphite microspheres(MEGMs) from flake graphite spheres through a combined modified pressurized oxidation combined with the microwave treatment.The microstructural results demonstrate that moderately expanded MEGMs with an expansion volume between 4 and 10 ml·g^(-1)exhibit a highly microporous structure with an enlarged interlayer spacing,a decreased microcrystalline size,as well as an increased number of functional groups on the surface,resulting in the increased storage sites and spaces for lithium ions and the enhanced diffusion rate of lithium ions.When used as the anode material for lithium-ion batteries,the MEGM-T75t30 obtained by oxidation treatment at 75℃ for 30 min followed by microwave irradiation for expansion displays a high reversible capacity of 446.7 mAh·g^(-1) at 100 mA·g^(-1) after 100 cycles and excellent rate performance(330 and 116 mAh·g^(-1) at 800 and 3200 mA·g^(-1),respectively).Therefore,the MEGMs prepared by this convenient and mild method show excellent electrochemical properties and good application potential.
