100 W-class green hydrogen production from ammonia at a dual-layer electrode containing a Pt-Ir catalyst for an alkaline electrolytic process

Ammonia allows storage and transport of hydrogen over long distances and is an attractive potential hydrogen carrier.Electrochemical decomposition has recently been used for the conversion of ammonia to hydrogen and is regarded as a future technology for production of CO_(2)-free pure hydrogen.Herein,a heterostructural Pt-Ir dual-layer electrode is developed and shown to achieve successful long-term operation in an ammonia electrolyzer with an anion exchange membrane(AEM).This electrolyzer consisted of eight membra ne electrode assemblies(MEAs)with a total geometric area of 200 cm~2 on the anode side,which resulted in a hydrogen production rate of 25 L h~(-1).We observed the degradation in MEA performance attributed to changes in the anode catalyst layer during hydrogen production via ammonia electrolysis.Furthermore,we demonstrated the relationship between the ammonia oxidation reaction(AOR)and the oxygen evolution reaction(OER).

A Mechanism for Digital Finance to Drive Green and Low-Carbon Development

Given the global focus on green and low-carbon development and the increasing prominence of digital finance,it is particularly important to explore how to leverage digital finance to achieve these environmental goals.This study,through mechanism analysis,deeply examines how China’s digital finance promotes green and low-carbon development and elucidates the positive interaction between digital finance and the green industry.The study found that digital finance,through more flexible and efficient financial functions,alters the cost structure of carbon emissions,and reduces the risks and costs of green investments,thereby creating a cooperative green mechanism benefiting all parties,and guiding social groups toward a green and low-carbon transformation.Additionally,the rapid development of digital finance has strengthened the implementation of environmental protection policies,effectively promoted the expansion of the environmental protection industry,and established the green ethos as a mainstream concept in financial development.This study aims to provide reference perspectives and suggestions,assist policymakers in promoting the green and lowcarbon development of digital finance,and offer insights into the integrated development of digital finance and the green environmental protection industry.

Green‑Solvent Processed Blade‑Coating Organic Solar Cells with an Efficiency Approaching 19%Enabled by Alkyl‑Tailored Acceptors

Power-conversion-efficiencies(PCEs)of organic solar cells(OSCs)in laboratory,normally processed by spin-coating technology with toxic halogenated solvents,have reached over 19%.However,there is usually a marked PCE drop when the bladecoating and/or green-solvents toward large-scale printing are used instead,which hampers the practical development of OSCs.Here,a new series of N-alkyl-tailored small molecule acceptors named YR-SeNF with a same molecular main backbone are developed by combining selenium-fused central-core and naphthalene-fused endgroup.Thanks to the N-alkyl engineering,NIR-absorbing YR-SeNF series show different crystallinity,packing patterns,and miscibility with polymeric donor.The studies exhibit that the molecular packing,crystallinity,and vertical distribution of active layer morphologies are well optimized by introducing newly designed guest acceptor associated with tailored N-alkyl chains,providing the improved charge transfer dynamics and stability for the PM6:L8-BO:YRSeNF-based OSCs.As a result,a record-high PCE approaching 19%is achieved in the blade-coating OSCs fabricated from a greensolvent o-xylene with high-boiling point.Notably,ternary OSCs offer robust operating stability under maximum-power-point tracking and well-keep>80%of the initial PCEs for even over 400 h.Our alkyl-tailored guest acceptor strategy provides a unique approach to develop green-solvent and blade-coating processed high-efficiency and operating stable OSCs,which paves a way for industrial development.

Performance Evaluation of Low-Carbon and Clean Transformation of China’s Coal Economy

In China,the oversupply of coal occurred in 2009,and from that year onwards,China’s coal economy began a low-carbon and clean transformation.Evaluating transformation performance is the research goal of this paper.The data collection for this paper includes data on deep processing of Chinese coal products from 2009 to 2020,as well as data on asset structure evolution and financial performance of 34 listed companies in the Chinese coal mining.Entropy value method is used to calculate the entropy value of low-carbon transformation,and the regression analysis is used to study the performance of cleaner transformation,the conclusion is as follows:(1)From 2009 to 2020,in China’s total energy consumption,coal consumption accounted for 71.6%in 2009 and 56.8%in 2020,the goals set by the state have been achieved.(2)The national goal of reducing the proportion of coal consumption and reducing carbon emissions has forced the transformation of deep processing of coal products.The transformation of coal enterprises towards low-carbon and clean production has achieved remarkable results.(3)From 2009 to 2020,the non coal industry income of 34 listed companies in China’s coal mining industry increased by 8.21%annually.At the same time,the asset structure was adjusted,and nearly 80%of the asset structure evolution showed an orderly development trend.(4)The regression analysis results show that the entropy value of coal deep processing products and the entropy value of asset structure adjustment are significantly related to transformation performance.The paper proposes to summarize the successful experience of China’s coal energy economic transformation,lay a foundation for achieving the carbon peak and carbon neutral goals in the future,further increase the intensity of coal deep processing,increase the proportion of clean energy in total energy consumption,and strive to control asset operation towards the goal of increasing the proportion of non coal industry income.

Research on Quality Management Measures of Green Building Construction

Urbanization has led to the rapid development of the construction industry.However,this has also led to higher requirements for the construction engineering management.Other than the quality monitoring of engineering construction,the energy-saving properties of the building should also be considered.Therefore,a scientific management approach should be adopted to improve green building management.This paper primarily examines the importance of quality management in green building construction,along with the factors influencing it.It also identifies the quality issues present in current green building construction.Finally,it proposes measures for quality management in the green building construction process to facilitate the industry’s healthy development.

Consideration of green intelligent steel processes and narrow window stability control technology on steel quality

In order to promote the intelligent transformation and upgrading of the steel industry, intelligent technology features based on the current situation and challenges of the steel industry are discussed in this paper. Based on both domestic and global research, functional analysis, reasonable positioning, and process optimization of each aspect of steel making are expounded. The current state of molten steel quality and implementation under narrow window control is analyzed. A method for maintaining stability in the narrow window control technology of steel quality is proposed, controlled by factors including composition, temperature, time, cleanliness, and consumption(raw material). Important guidance is provided for the future development of a green and intelligent steel manufacturing process.

Opportunities and Challenges of Artificial Intelligence for Green Manufacturing in the Process Industry

Smart manufacturing is critical in improving the quality of the process industry. In smart manufacturing, there is a trend to incorporate different kinds of new-generation information technologies into process- safety analysis. At present, green manufacturing is facing major obstacles related to safety management, due to the usage of large amounts of hazardous chemicals, resulting in spatial inhomogeneity of chemical industrial processes and increasingly stringent safety and environmental regulations. Emerging informa- tion technologies such as arti cial intelligence (AI) are quite promising as a means of overcoming these dif culties. Based on state-of-the-art AI methods and the complex safety relations in the process industry, we identify and discuss several technical challenges associated with process safety: ① knowledge acquisition with scarce labels for process safety;② knowledge-based reasoning for process safety;③ accurate fusion of heterogeneous data from various sources;and ④ effective learning for dynamic risk assessment and aided decision-making. Current and future works are also discussed in this context.

Nitrogen removal for low-carbon wastewater in reversed A^2/O process by regulation technology

Full scale experimental study on nitrogen removal for low-carbon wastewater was conducted in reversed A2/O process in Jiguanshi waste water treatment plant in Chongqing,in order to aid the operation and maintenance of similar WWTP. When the proposed measures,such as using 0.1% (volume fraction of wastewater) landfill leachate,shortening HRT by 2/3 in the primary sedimentation tank and controlling DO at 0.5 mg/L in the 3rd section of aerobic zone,are applied,15% of the carbon source can be complemented,the favorable property of activated sludge is achieved,and the nitrogen removal effect is significantly improved. The effluent NH3-N is 2 mg/L and the removal rate is 90%. The effluent TN is 17 mg/L and the removal rate is 54%. The up-to-standard discharge of the effluent is achieved. And after the optimization,the unit electricity consumption also reaches 0.21 kW/h and saves 20%.

Spatial Process of Green Infrastructure Changes Associated with Rapid Urbanization in Shenzhen,China

Through a case study of Shenzhen City,China,this study focused on a quantitative method for analyzing the spatial processes involved in green infrastructure changes associated with rapid urbanization.Based on RS,GIS and SPSS statistics software,the approach includes selection of the square analysis units and representative landscape metrics,quantification of the change types of landscape metrics in all analysis units through two indices and hierarchical cluster analysis of the above analysis units with different landscape metric change types(i.e.spatial attributes).The analyses verify that there is a significant sequence of continuous changes in green infrastructure in Shenzhen.They are the perforation,the segmentation,the fragmentation,the evanescence and the filling-in processes,which have a good spatio-temporal correspondence with urbanization and reflect the synthetic influence of urban planning,government policies and landforms.Compared with other studies on quantifying the spatial pattern,this study provides an alternative probe into linking the spatial pattern to spatial processes and the corresponding ecological processes in the future.These spatio-temporal processes offer many opportunities for identifying,protecting and restoring key elements in an urban green infrastructure network for areas in the early stages of urbanization or for non-urbanized areas.

Plasma-electrified up-carbonization for low-carbon clean energy

Low-value,renewable,carbon-rich resources,with different biomass feedstocks and their derivatives as typical examples,represent virtually inexhaustive carbon sources and carbon-related energy on Earth.Upon conversion to higher-value forms(referred to as“up-carbonization”here),these abundant feedstocks provide viable opportunities for energy-rich fuels and sustainable platform chemicals production.However,many of the current methods for such up-carbonization still lack sufficient energy,cost,and material efficiency,which affect their economics and carbon-emissions footprint.With external electricity precisely delivered,discharge plasmas enable many stubborn reactions to occur under mild conditions,by creating locally intensified and highly reactive environments.This technology emerges as a novel,versatile technology platform for integrated or stand-alone conversion of carbon-rich resources.The plasma-based processes are compatible for integration with increasingly abundant and cost-effective renewable electricity,making the whole conversion carbon-neutral and further paving the plasma-electrified upcarbonization to be performance-,environment-,and economics-viable.Despite the chief interest in this emerging area,no review article brings together the state-of-the-art results from diverse disciplines and underlies basic mechanisms and chemistry underpinned.As such,this review aims to fill this gap and provide basic guidelines for future research and transformation,by providing an overview of the application of plasma techniques for carbon-rich resource conversion,with particular focus on the perspective of discharge plasmas,the fundamentals of why plasmas are particularly suited for upcarbonization,and featured examples of plasma-enabled resource valorization.With parallels drawn and specificity highlighted,we also discuss the technique shortcomings,current challenges,and research needs for future work.

Mechanical and corrosion properties of low-carbon steel prepared by friction stir processing

Low-carbon steel plates were successfully subjected to normal friction stir processing(NFSP) in air and submerged friction stir processing(SFSP) under water, and the microstructure, mechanical properties, and corrosion behavior of the NFSP and SFSP samples were investigated. Phase transformation and dynamic recrystallization resulted in fine-grained ferrite and martensite in the processed zone. The SFSP samples had smaller ferrites(5.1 μm), finer martensite laths(557 nm), and more uniform distribution of martensite compared to the NFSP samples. Compared to the base material(BM), the microhardness of the NFSP and SFSP samples increased by 19.8% and 27.1%, respectively because of the combined strengthening effects of grain refinement, phase transformation, and dislocation. The ultimate tensile strengths(UTSs) of the NFSP and SFSP samples increased by 27.1% and 38.7%, respectively. Grain refinement and martensite transformation also improved the electrochemical corrosion properties of the low-carbon steel. Overall, the SFSP samples had better mechanical properties and electrochemical corrosion resistance than the NFSP samples.

Study on the Retention Rate of Green Tea Catechins Components and Tea Polyphenol by Different Processing Technology

The aim of this research was to explore the effect of fixation,rolling,and drying processing technology on the retention rate of green tea catechins components and tea polyphenol.Different fixation processes(rotary drumfiring,microwave,steam-blasting),rolling process(weight of rolling,gently press rolling and traditional rolling),drying process(stove drying,roasting dehydration,baked fried drying) were adopted.The effect of different tea processing technology on the retention rate of catechins component and tea polyphenol was analyzed.It showed that the microwave fixation process,gently press rolling process,baked fried dry process were beneficial to keep high levels of EGCG,C,EGC,EC,ECG.

Assessment of Effects of Green Construction by Analytic Hierarchy Process and Fuzzy Synthetic Judgment Method

The index system, code system, and weights of indexes are established to assess the effects of green construction. The index system consists of index level, factor level and sub-factor level. The analytic hierarchy process is used to determine the weights of indexes, and the consistency test indicate that the weight assignment is reasonable. Using fuzzy synthetic judgment method, the assessment model is built, which includes factor set, weight set and conclusion set. An example is given to demonstrate the assessment procedures.

A Novel Application in Green Chemical Processing Using Reject Brines and Carbon Dioxide as Raw Materials

In this paper, the concept of “green processing” will be applied, while explaining the role of sustainable development strategy with respect to the environmental issue. Two parameters are considered in the study by utilizing carbon dioxide and reject brine from desalination plants as raw materials to produce valuable chemical products and partially desalinated water.

Green and Low-carbon Development Strategy for Large Energy Enterprises

Green and low-carbon development is the critical countermeasure to cope with climate change and to promote energy production and consumption revolution.China National Offshore Oil Corporation(“CNOOC”)has thoroughly implemented the requirements of the country’s ecological civilisation construction,highlighting the mission and responsibility of large central energy enterprises.Combined with the characteristics of its industry,CNOOC put forward a green low-carbon development strategy.CNOOC has put into practice the concept and practice of green and lowcarbon development by optimising the design of management systems,innovating energy conservation and emission reduction management and practice,promoting the construction of a green manufacturing system,and strengthening the supply of low-carbon clean energy.The main path and direction of the follow-up of the sustainable development are clearly defined.These practices provide a useful reference for promoting the transformation of China’s economic development mode to being more green and low-carbon,constructing an ecological civilization and development that is sustainable.

A decision-making model of gear process for green manufacturing

A decision-making model of gear process for green manufacturing is presented, which integrates the five objectives including the time, quality, cost, resource consumption and environmental impact of gear process together into the development of a strategy. Mathematical description is provided for the multi-objectives decision-making model. The expert judgment and the multi-fuzzy assessment theory are introduced to do sensible comparisons and give quantitative results. A case study on practical cutting tool selection in gear machining demonstrates that the proposed model is applicable.

Analysis on Green Accounting Information Disclosure of Chemical Enterprises Under Low-Carbon Economy

In the current era of low-carbon economy,environmental governance and energy conservation have become major issues,in which chemical enterprises with high pollution and consumption have naturally attracted much attention.The disclosure of green accounting information is indispensable to the continuous development of chemical enterprises and even the whole society.Therefore,based on existing research results,this paper analyzes the existing problems and causes of green accounting information disclosure of chemical enterprises in China under low-carbon economy,and puts forward suggestions for solutions.

Green Processes： Transforming Waste into Valuable Resources

1.引言未来几年,随着有限的原材料供应不断减少,低价的化石燃料越来越少,全球制造业将面临严峻挑战。许多传统制造工艺将会因环境问题而被淘汰。对于工程师和科学家来说,这些相互关联的问题也提供了巨大的契机。我们需要强大的新技术:这些新技术必须具备较高的成本效益和能效,必须最大限度地减少污染。应对挑战的解决方案可能藏在另一个全球性问题中——工业废物(包括有毒废物)的快速积累。

Two-stage reproduction derived from cells of thallus could directly contribute to seeds for green tidal algal Enteromorpha(Ulva) prolifera/clathrata bloom,with disclosure of their ephemeral trait

Green tidal algal Enteromorpha species complete their life cycles by the isomorphic alternation of generations.The provenance of green tide caused by them in the western Yellow Sea has been disputed. The cell reproduction derived from adult thallus was observed on E. clathrata collected from Shantou City, Guangdong Province in this study. Subsequently, it further found that E. proliferia collected from Qingdao City, Shandong Province and Qinhuangdao City, Hebei Province, produced reproductive cells by somatic cells of its early infantile thallus or branch. The latter is functionally similar to that the seedlings of red alga Porphyra yezoensis produce the monospores, and could exquisitely explain the ephemeral or opportunistic trait and environmental adaptation ability of Enteromorpha species. Changes in growth conditions may induce the two types of cell reproduction.They contribute to the bloom, and can effectively reveal the seasonally occurring large-scale and on-year and offyear phenomenon. The latter may have played a decisive role in its formation. This paper analyses the legal status of the species name, the type of generation during bloom, ephemeral traits, the role of microscopic propagule, the area of origin, on-year and off-year phenomenon, early warning and prevention and control of the species, and so on. On this basis, further study on the influence of environmental factors on cell reproduction of early infantile thalli or branches will achieve a positive effect for early warning and prevention and control of the green tidal algal bloom.

绿色加工技术在农业机械制造中的应用

随着现代化农业的快速发展,农业机械需求量日益增加。在国家“节能减排”“碳中和”“碳达峰”的政策要求下,绿色加工技术是现代化农业机械生产发展的新方向。该文通过介绍绿色加工技术的概念和意义,说明农业机械制造中利用绿色加工技术的作用,从原料、加工方式、切削技术等角度出发,阐述绿色加工技术在农业机械制造中的具体应用,并进行展望,为绿色加工技术在农业机械制造的发展提供一定的思路。