Environmental stress level evaluation approach based on physical model and interval grey association degree

Associating environmental stresses （ESs） with built-in test （BIT） output is an important means to help diagnose intermittent faults （IFs）. Aiming at low efficiency in association of traditional time stress measurement device （TSMD）, an association model is built. Thereafter, a novel approach is given to evaluate the integrated environmental stress （IES） level. Firstly, the selection principle and approach of main environmental stresses （MESs） and key characteristic parameters （KCPs） are presented based on fault mode, mechanism, and ESs analysis （FMMEA）. Secondly, reference stress events （RSEs） are constructed by dividing IES into three stress levels according to its impact on faults; and then the association model between integrated environmental stress event （IESE） and BIT output is built. Thirdly, an interval grey association approach to evaluate IES level is proposed due to the interval number of IES value. Consequently, the association output can be obtained as well. Finally, a case study is presented to demonstrate the proposed approach. Results show the proposed model and approach are effective and feasible. This approach can be used to guide ESs measure, record, and association. It is well suited for on-line assistant diagnosis of faults, especially IFs.

Association discovery and outlier detection of air pollution emissions from industrial enterprises driven by big data

Air pollution is a major issue related to national economy and people's livelihood.At present,the researches on air pollution mostly focus on the pollutant emissions in a specific industry or region as a whole,and is a lack of attention to enterprise pollutant emissions from the micro level.Limited by the amount and time granularity of data from enterprises,enterprise pollutant emissions are stll understudied.Driven by big data of air pollution emissions of industrial enterprises monitored in Beijing-Tianjin-Hebei,the data mining of enterprises pollution emissions is carried out in the paper,including the association analysis between different features based on grey association,the association mining between different data based on association rule and the outlier detection based on clustering.The results show that:(1)The industries affecting NOx and SO2 mainly are electric power,heat production and supply industry,metal smelting and processing industries in Beijing-Tianjin-Hebei;(2)These districts nearby Hengshui and Shijiazhuang city in Hebei province form strong association rules;(3)The industrial enterprises in Beijing-Tianjin-Hebei are divided into six clusters,of which three categories belong to outliers with excessive emissions of total vOCs,PM and NH3 respectively.

Synthesis and characterization of unsymmetric silylated PNP single-active central chromium catalyst

A silylated PNP ligand with asymmetric structure was synthesized using(γ-aminopropyl)triethoxysilane and chlorodiphenyl phosphine as raw materials.The optimal synthetic conditions of the PNP ligand were obtained by conditional experiments and were as follows:dichloromethane was solvent,triethylamine was acid acceptor,the mole ratio of chlorodiphenylphosphine and(γ-aminopropyl)triethoxysilane was 2.1∶1,the dropping temperature of chlorodiphenylphosphine was-5℃,the dropping time was 30 min,the reaction temperature was 25℃and the reaction time was 12 h.Under the conditions,the yield of the silylated PNP ligand was 91.20%.Based on grey correlation analysis,the dropping temperature was the main factor for the yield of the silylated PNP ligand.The single-active central chromium catalyst based on the silylated PNP ligand was synthesized by complexation reaction with the silylated PNP ligand and chromium chloride tetrahydrofuran complex as materials,and the yield was 95.25%.The chemical structures of the silylated PNP ligand and the corresponding chromium catalyst were confirmed by elemental analysis,FT-IR,^(1)H NMR,MS and ICP.The single-active central chromium catalyst based on the silylated PNP ligand had good catalytic activity for ethylene oligomerization,and the content of C_(8)olefin was 72.40%,which was superior to Si-Schiff-Cr based on intermolecular coordination.