Arsenic and fluoride co-enrichment of groundwater in the loess areas and associated human health risks:A case study of Dali County in the Guanzhong Basin

This study aims to reveal the occurrence and origin of typical groundwater with high arsenic and fluoride concentrations in the loess area of the Guanzhong Basin—a Neogene faulted basin.Key findings are as follows:(1)Groundwater samples with high arsenic and fluoride concentrations collected from the loess area and the terraces of the Weihe River accounted for 26%and 30%,respectively,of the total samples,with primary hydrochemical type identified as HCO_(3)-Na.The karst and sand areas exhibit relatively high groundwater quality,serving as preferred sources for water supply.It is recommended that local governments fully harness groundwater in these areas;(2)groundwater with high arsenic and fluoride concentrations in the loess area and the alluvial plain of rivers in Dali County is primarily distributed within the Guanzhong Basin,which represents the drainage zone of groundwater;(3)arsenic and fluoride in groundwater originate principally from natural and anthropogenic sources;(4)the human health risk assessments reveal that long-term intake of groundwater with high arsenic and fluoride concentrations pose cancer or non-cancer risks,which are more serious to kids compared to adults.This study provides a theoretical basis for the prevention and treatment of groundwater with high arsenic and fluoride concentrations in loess areas.

Analysis on the Hydrochemical Characteristics of Groundwater and the Formation Reason in Wadi Bay Area of Libya

[Objective] The research aimed to analyze the formation reason of groundwater hydrochemical characteristics in the dry valley area of Wadi Bay of Libya and provide the scientific basis for the reasonable development utilization and the environmental protection of groundwater.[Method] Took Wadi Bay area（dry valley）of Libya as the example,Piper trilinear graphic representation method,the descriptive statistics,the ion ratio coefficient method and the isotope evidence were used to systematically study the special hydrochemical characteristics of shallow groundwater in the arid climate condition in Wadi Bay area of Libya.[Result] The salt content of groundwater in the area was very high,and TDS was during 3.2-8.4 g/L.The main groundwater type was Cl·SO4-Na·Ca,then was Cl·SO4-Na·Ca·Mg.The concentrations of Cl-,Na＋ and SO2-4,etc.in the groundwater in 70 km from the sea had the remarkable variation,but the concentrations of Mn2＋,Ba2＋,Si2＋,NH＋4 and NO-3 didn＇t have the same variation phenomenon.[Conclusion] The hydrochemical characteristics of shallow groundwater didn＇t relate to the dissolution infiltration reaction,the evaporation concentration effect and human activities.The major cause was the mixing effect of salt and fresh water in the invasion process of seawater.

Impact of coal gangue on the level of main trace elements in the shallow groundwater of a mine reclamation area

Coal gangue is the most used filling material during reclamation of areas suffering subsidence from min- ing. Main trace element levels (F, As, Hg, and Pb) in shallow groundwater in the reclamation area may be affected by leaching from the gangue. This can has an impact on the application of the water for agricul- tural irrigation or use as drinking water. Therefore, it is of great significance to understand the effect coal gangue has on the shallow groundwater of a reclaimed area. We studied the effect of coal gangue on fluo- rine, arsenic, mercury, and lead levels in the shallow groundwater of a reclamation area by testing the water and the coal gangue. One well near the reclamation area was used as a control well and element levels in water from this well and from the soil next to the well were also measured. The results show that the levels of these elements are increasing in the reclamation area over time. The increase in fluorine, arsenic, mercury, and lead in monitor wells varies from 7.42% to 8.26%, from 7.13% to 7.90%, from 4.85% to 6.48%, and from 4.69% to 6.42%, respectively. Fluorine and arsenic levels are lower in monitor wells than in the control water. The other elements are found in greater concentration than in the control. The Nemerow index also indicates that the shallow groundwater in the reclamation area I is moderately affected by the back-filling coal gangue, while the shallow groundwater in the reclamation area II and III are slightly affected by the back-filling coal gangue. This shallow groundwater could be used for agri- cultural irrigation or for drinking.

Impact of coal mining on groundwater of Luohe Formation in Binchang mining area

Groundwater of Luohe Formation is the main water source for industrial and agricultural and residential use in Binchang mining area,which is one of the key elements to water conservation coal mining.However,few studies are available to document the enrichment characteristics and influence of underground coal mining on groundwater for the Luohe Formation.This study evaluates the changes of groundwater levels and spring flow caused by mining activities to explore the influence mechanism of coal mining on groundwater by comparatively analysing existing mining data and survey data combined with a series of mapping methods.The results show that the aquifer of Luohe Formation are gradually thinning south-eastwards,disappeared at the mining boundary.In the vertical direction,the lithological structure is distinct,due to alternative sedimentation of meandering river facies and braided river facies.According to the yielding property,the aquifer is divided into three sections,namely,strong water-rich section,medium water-rich section,and weak water-rich section,which are located in northwest and central part,southwest,and the rest part of the mining area,respectively.Mining of Tingnan Coal Mine since 2004 has caused a 3.16 to 194.87 meters drop in groundwater level of Luohe Formation.Until 2015,70.10%of the mining area undergoes a groundwater level drop larger than 10.00 meters.Another influence of underground mining is that the total flow from 34 springs in 8 southern coal mines of the area has decreased by 286.48 L/s with a rate of decrease at 46.95%from 2007 to 2017.The areas that groundwater level falls or spring flow declines are manly located in the mine gob areas.Results also indicate that the ratio of the height of water conducted fracture zone to the mining height in Binchang mining area is between 16.85 and 27.92.This may increase ground water flow in vertical direction,causing a water level in the aquifer system to drop and ultimately decreasing the flow from the springs.The research results will provide data and theoretical support for the protection of groundwater resources and water conservation coal mining of Luohe Formation in Binchang mining area.

Hydrochemical characteristics and water quality evaluation of shallow groundwater in Suxian mining area,Huaibei coalfield,China

The aim of this study is to evaluate the hydrogeochemical characteristics and water environmental quality of shallow groundwater in the Suxian mining area of Huaibei coalfield,China.The natural formation process of shallow groundwater in Suxian is explored using Piper trilinear charts and Gibbs diagrams,and by examining the ratios between the major ions.United States Salinity Laboratory(USSL)charts,Wilcox diagrams,and the water quality index(WQI)are further employed to quantify the differences in water quality.The results reveal that the main hydrochemical facies of groundwater are HC03-Ca,and that silicate dissolution is the main factor controlling the ion content in shallow groundwater.The USSL charts and Wilcox diagrams show that most of the water samples would be acceptable for use in irrigation systems.The WQI results for each water sample are compared and analyzed,and the quality of groundwater samples around collapse ponds is found to be relatively poor.

Numerical simulation of groundwater and early warnings from the simulated dynamic evolution trend in the plain area of Shenyang,Liaoning Province(P.R. China)

Groundwater level is the most direct factor reflecting whether groundwater is in a virtuous cycle. It is the most important benchmark for deciding whether a balance can be struck between groundwater discharge and recharge and whether groundwater exploitation will trigger problems pertinent to environment, ecology and environmental geology. According to the borehole and long-term monitoring wells data in the plain area of Shenyang, a numerical groundwater model is established and used to identify and verify the hydrogeological parameters and balanced items of groundwater. Then the concept of red line levels, the control levels of groundwater is proposed, the dynamic evolution trend of groundwater under different scenarios is analyzed and predicted and groundwater alerts are given when groundwater tables are not between the lower limit and the upper limit. Results indicated:(1) The results of identification and verification period fitted well, and the calculation accuracy of balanced items was high;(2) with the implementation of shutting wells, groundwater levels in urban areas of Shenyang would exceed the upper limit water level after 2020 and incur some secondary disasters;(3) under the recommended scenario of water resources allocation, early-warnings for groundwater tables outside the range would occur in the year of 2020, 2023, 2025 respectively for successive wet, normal and dry years. It was imperative to reopen some groundwater sources and enhance real-time supervision and early-warning to prevent the occurrence of potential problems.

Study on the change rule of groundwater level and its impacts on vegetation at arid mining area

The shallow groundwater in Shendong mining area was broken because of large-scale underground mining activities. Selecting 32201 working-face as research area, analyzed the change rule of groundwater level and aquifer thickness under mining impact with a large number of water level observation data. Then, the impacts of groundwater level change on vegetation were analyzed by the relationship theory of arid area groundwater and vegetation. The results show that the aquifer structure and the water condition of supply flow and drainage are changed by the water proof mining. The groundwater level recovere only a little compared with the original groundwater level in two years. But the great change of groundwater level do not have notable influences on vegetation of this mining area, and further study indicates that there are certain conditions where groundwater level change impacted on vegetation. When the influence of groundwater level change was evaluated, the plant ecological water level, warning water level and spatial distribution character of original groundwater and mining-impacted groundwater-level change should be integrated.

Changes of hydrochemical composition and heavy metals concentration in shallow groundwater from karst hilly areas in Guiyang region,China

The quality changes of shallow groundwater from karst hilly areas in Guiyang region of China impacted by the urbanization were investigated. The results show that the major ions in shallow groundwater from the karst hilly areas are mainly composed of HCO3^-, SO4^2-, Ca^2＋ and Mg^2＋, and the concentrations scopes of NO3^-, Cl^-, K^＋ and Na^＋ of the groundwater in agricultural, residential and industrial areas are 4.5-9.6, 2.8-7.1, 3.9-6.3 and 2.5-4.9 times higher than those in the forest areas, respectively. The concentrations of As, Pb and Cd of shallow groundwater in the industrial areas are also significantly enhanced, followed by those in the residential areas and the agricultural areas. The concentrations of NO3^-, SO4^2- , As, Pb and Cd of the groundwater in the industrial areas and those of NO3^- , SO4^2-, As and Cd of shallow groundwater in the residential areas reach grade Ⅲ of the Groundwater Quality Standard of China （GB/T 14848-93）, while the concentration of NO3^- in the groundwater from the industrial areas exceeds grade V. With the process of urbanization, NO3^- is the key factor to influence the groundwater quality in karst hilly areas, followed by SO4^2-, As, Pb and Cd.

Assessment of Groundwater Source of Piedmont Plain Area of China Northwest Arid Region Based On Numerical Modeling

After the middle of 1960s,along with the appearance and extensive utilization of computer featured in large capacity and rapid speed,numerical method(mainly include finite difference method and finite element

Evaluating Groundwater Pollution Using Hydrochemical Data: Case Study (Al Wahat Area East of Libya)

Water is one of the most challenging current and future natural resources, which will directly affect the environment and development by the changes in its quantity, quality and regional distribution. However, Water quality is the critical factor that influences human health and irrigation proposer. This work aims to investigate hydrochemical analysis and geochemical processes influencing the groundwater of Al Wahat area (Jalou, Awjla and Jukherra), which is located in central east Libya. Thirty four water samples collected from domestic and agricultural water wells were analyzed and used for conventional classification techniques which were Piper, Durov and Stiff diagrams to evaluate geochemical processes. Cluster analysis was used to identify the water type and ions concentration and distribution. Results show significant increase of dissolved salts, especially Nitrates. Elevated nitrates concentration can be attributed to either the disposal of untreated sewage water from disposal ponds and septic tanks or the infiltration of irrigation water saturated with fertilizing chemicals. Therefore, irrigation wells revealed that suffering from nitrate contamination caused an increase of the chance of nitrate pollution. In addition, contour maps present a sudden increase in the total dissolved salts (TDS) in the northeastern part?coincident with the highest of secondary ions of NO3 content, indicating the infiltration of irrigation water which is responsible partially for the groundwater degradation. Hydrogeochemical facie is NaCl type and enrichment of Na+ and Cl- can be attributed to urban untreated wastewaters and high rate of evapotranspiration. The concentrations of heavy elements such as Zn, Pb, Cu, Cd, Ni and Cr were low and within the WHO ranges.

Influence of underground space development mode on the groundwater flow field in Xiong’an new area

The degree and scale of underground space development are growing with the continuous advancement of urbanization in China.The lack of research on the change of the groundwater flow field before and after the development of underground space has led to various problems in the process of underground space development and operation.This paper took the key development zone of the Xiong’an New Area as the study area,and used the Groundwater modeling system software(GMS)to analyse the influence on the groundwater flow field under the point,line,and surface development modes.The main results showed that the underground space development would lead to the expansion and deepening of the cone of depression in the aquifer.The groundwater level on the upstream face of the underground structure would rise,while the water level on the downstream face would drop.The“line”concurrent development has the least impact on the groundwater flow field,and the maximum rise of water level on the upstream side of the underground structure is expected to be approximately 3.05 m.The“surface”development has the greatest impact on the groundwater flow field,and the maximum rise of water level is expected to be 7.17 m.

Characteristics of karst groundwater system in the northern basin of Laiyuan Spring area

Guided by the theory of groundwater system, based on the groundwater level data from the northern basin of Laiyuan Spring area, the authors took into account factors such as the lithology, geological structure and topography to study the relationship between groundwater recharge, runoff and drainage in this area. It was concluded that the infiltration of atmospheric precipitation is the main source of groundwater supply in this area; the upper layer of the Spring area is distributed with the Cambrian-Lower Ordovician karst water, and the lower layer is filled with the Jixian system karst water. The upper layer of karst water supplies to the lower layer of karst water or the pore water in loose strata through the fault while the lower layer of karst water runs to the three strong runoff belts from the east and west sides of the watershed, southwards into the basin, partially replenishing the pore water in loose strata, or forming fault Springs(e.g. Nanguan Spring, Beihai Spring) when dolomite movement encounters faults. Replenished by atmospheric precipitation and the upper and lower layers of karst waters, the pore water in loose strata joins the groundwater in the southern basin and then flows eastwards, in the end it flows out of the system in Shangfanpu. Through the analyses of groundwater level data and hydrogeological drilling data, based on groundwater D and ^(18) O isotope test results, the karst groundwater circulation system in the northern basin of Laiyuan Spring area is further verified, which provides hydrogeological basis for water resources development and utilization as well as protection in this area.

Hydrogeochemical characteristics of groundwater and pore-water and the paleoenvironmental evolution in the past 3.10 Ma in the Xiong’an New Area,North China

The groundwater level has been continuously decreasing due to climate change and long-time overexploitation in the Xiong’an New Area,North China,which caused the enhanced mixing of groundwater in different aquifers and significant changes in regional groundwater chemistry characteristics.In this study,groundwater and sediment pore-water in drilling cores obtained from a 600 m borehole were investigated to evaluate hydrogeochemical processes in shallow and deep aquifers and paleo-environmental evolution in the past ca.3.10 Ma.Results showed that there was no obvious change overall in chemical composition along the direction of groundwater runoff,but different hydrochemical processes occurred in shallow and deep groundwater in the vertical direction.Shallow groundwater(<150 m)in the Xiong’an New Area was characterized by high salinity(TDS>1000 mg/L)and high concentrations of Mn and Fe,while deep groundwater had better water quality with lower salinity.The high TDS values mostly occurred in aquifers with depth<70 m and>500 m below land surface.Water isotopes showed that aquifer pore-water mostly originated from meteoric water under the influence of evaporation,and aquitard pore-water belonged to Paleo meteoric water.In addition,the evolution of the paleoclimate since 3.10 Ma BP was reconstructed,and four climate periods were determined by theδ18O profiles of pore-water and sporopollen records from sediments at different depths.It can be inferred that the Quaternary Pleistocene(0.78‒2.58 Ma BP)was dominated by the cold and dry climate of the glacial period,with three interglacial intervals of warm and humid climate.What’s more,this study demonstrates the possibilities of the applications of pore-water on the hydrogeochemical study and further supports the finding that pore-water could retain the feature of paleo-sedimentary water.

The Source of Groundwater Recharge Based on Entropy Theory in the Arid Areas of North China

Objective Any natural system is constantly exchanging material, energy and information with the environment, and all tkese processes follow the basic law of thermodynamics, with no exception of groundwater recharge and discharge process. On the basis of the principle of the first law of thermodynamics, the reverse geochemical simulation method is widely used in the study of groundwater recharge, runoff and drainage process. However, some studies only consider the material conservation in theprocess, but ignore the probability of the transformation.

Calculating and Evaluating the Groundwater Resource of Jian San Jiang Area

According to the method of water balance,the parameters of groundwater resouce of Jian San Jiang area have been calculated in the paper.At the same time,the quality of water supplying and water mining can be calculated.Furthermore,the groundwater resource have been evaluated.Thus,the paper provides the important references for managers to using groundwater reasonable.

Groundwater Quality Analysis and Vulnerability Assessment in Longdong Area

Groundwater is important drinking water source in Longdong area. In recent years,as gradual expanding of industrial and agricultural production scales,seen from change trend of water quality,major impact factors of groundwater in the zone were ammonia nitrogen,COD,sulfate and total dissolved solid. By using specific thought of parameter system method,vulnerability assessment factor system of groundwater and meter point system calculation model in the zone were established. Via calculation and analysis,vulnerability distribution of groundwater in the zone was obtained. According to vulnerability index（ higher,moderate and lower）,zone dividing was conducted,and the areas were respectively 623. 25,4 005. 00 and 6 621. 75 km2,which respectively accounted for 5.54%,35. 60% and 58. 86%. The evaluation provided research basis for prevention,control and protection of groundwater environment in Longdong area.

Dynamic assessment of pollution risk of groundwater source area in Northern China

Based on the dynamic analysis and research of pollution risk of groundwater sources, this paper creates the dynamic assessment method of pollution risk of groundwater source area under the theory of "source-pathway-receptor", and applies this method to one typical fissure karst groundwater source area in northern China. Following the 30-year petroleum pollutant migration simulation and pollution risk assessment of groundwater source area, this study finds that the very high risk zone is mainly located in Q Petrochemical Company and the surrounding area and the area adjacent to River Z. Within this period of thirty years, the pollution risk of groundwater source area has showed a dynamic trend that features an inverted "V" shape. The ratio of very high risk zone to the total area will be 18.1%, 17.47% and 16.62% during the tenth year, the twentieth year and the thirtieth year separately, and will reach the highest level of 19.45% during the fifteenth year. Meanwhile, the vertical migration distance of pollutant centre concentration changed from the surface soil at the outset to the deepest point of about 250 meters underground during the tenth year. The results of this risk assessment indicate the dynamic feature of pollution risk. The dilution, degradation and migration of petroleum pollutants in groundwater system contribute to an ultimate decline in pollution risk.

An Overview of the Geological Control on Groundwater Potential in Lacamutu River, Alaua Kraik Area, Baucau Municipality, Timor-Leste

Timor island has a tropical climate with relatively little rainfall and surface water is often not available throughout the year with groundwater relied on to fulfill daily domestic necessities. Geological reconnaissance mapping, hydrogeological investigation, and resistivity survey were undertaken in this study to systematically understand the hydrogeologic system (e.g., aquifer system, hydrostratigraphic units, groundwater flow direction) and its potentiality for water supply to human consumption in Alaua Kraik area, Baucau Municipality, Timor-Leste. Res2DInv, Dips 5.1, Surfer 16, Global Mapper 13, and ArcGIS 10.6 software was used to create geological reconnaissance maps, resistivity interpretation profile lines, and a hydrostratigraphic model. Rainfall precipitation, rainfall intensity, maximum rate of runoff and infiltration data are also used to interpret the groundwater potential in the study area. Two rock units occur in the study area;permeable alluvial deposits which unconformable overlie impermeable interbedded red marl-chert and calcareous shale. Structurally the area comprises the Lacamutu anticline, thrust fault, left slip fault, and normal right slip fault. Resistivity lines indicate three (3) types of lithologies: alluvial deposit, an intercalated layer of red marl-chert, calcareous shale and wet calcareous shale. The alluvial deposit and red marl-chert layer intercalated with calcareous shale units are classified as a hydrostratigraphic unit of intergranular and localised aquifer systems with low productivity. The groundwater flows through the existing fractures of the shear joint and tends to flow towards the left slip fault plane zone from the North to South direction. Much of the rainwater in the study area is most likely intercepted, evaporated, and or transpiration as opposed to running off and infiltrating into the ground. The permeable and heavily fractured impermeable rock units in the study area have good porosity but low permeability and represent poor aquifers. The springs and Lacamutu River have low discharge and are generally dry in the dry season as it does not have an adequate aquifer that can accumulate and pass groundwater with significant volumes even if the rainfall in the study area is classified as moderate rainfall.