Isotope Tracking of Surface Water Groundwater Interaction in the Beninese Part of the Iullemeden Aquifer System

The Kandi basin is located in northeast Benin (West Africa). This study is focused on the estimation of water fluxes exchanged between the river Niger (and its tributaries) and the transboundary Iullemeden Aquifer System. In that framework, an innovative approach based on the application of the Bayesian Mixing Model (MixSIAR) analysis on water isotopes (oxygen-18, deuterium and tritium) was performed. Moreover, to assess the relevance of the model outputs, Pearson’s correlation and Principal Component Analysis (PCA) have been done. A complex relationship between surface water and groundwater has been found. Sixty percent (60%) of groundwater samples are made of more than 70% river water and rainwater;while 31.25% of surface water samples are made of about 84% groundwater. To safeguard sustainable water resources for the well-being of the local communities, surface water and groundwater must be managed as a unique component in the Kandi basin.

Hydro-geochemistry of groundwater and surface water in Dschang town(West Cameroon):Alkali and alkaline-earth elements ascertain lithological and anthropogenic constraints

The study aims to identify a suitable site for open and bore well in a farmhouseusing ground magnetic survey in south India.It also aims to define depth to granitoid and structural elements which traverse the selected area.Magnetic data(n=84)measured,processed and interpreted as qualitative and quantitatively.The results of total magnetic intensities indicate that the area is composed of linear magnetic lows trending NE-SW direction and circular to semi-circular causative bodies.The magnetic values ranged from-137 nT to 2345 nT with a mean of 465 nT.Reduction to equator shows significant shifting of causative bodies in the southern and northern directions.Analytical signal map shows exact boundary of granitic bodies.Cosine directional filter has brought out structural element trending NE-SW direction.Results of individual profile brought to light structurally weak zone between 90 m and 100 m in all the profile lines.Sudden decrease of magnetic values from 2042 nT to 126 nT noticed in profile line 6 between 20 m and 30 m indicates fault occurrence.Magnetic breaks obtained from these maps were visualized,interpreted and identified two suitable sites for open and bore well.Radially averaged power spectrum estimates depth of shallow and deep sources in 5 m and 50 m,respectively.Euler method has also been applied to estimate depth of granitoid and structural elements using structural indexes 0,1,2,and 3 and found depth ranges from<10 m to>90 m.Study indicates magnetic method is one of the geophysical methods suitable for groundwater exploration and site selection for open and borewells.

Linking bacterial and archaeal community dynamics to related hydrological,geochemical and environmental characteristics between surface water and groundwater in a karstic estuary

Subterranean estuaries(STEs)are characterized by the mixing of terrestrial fresh groundwater and seawater in coastal aquifers.Although microorganisms are important components of coastal groundwater ecosystems and play critical roles in biogeochemical transformations in STEs,limited information is available about how their community dynamics interact with hydrological,geochemical and environmental characteristics in STEs.Here,we studied bacterial and archaeal diversities and distributions with 16S rRNA-based Illumina MiSeq sequencing technology between surface water and groundwater in a karstic STE.Principal-coordinate analysis found that the bacterial and archaeal communities in the areas where algal blooms occurred were significantly separated from those in other stations without algal bloom occurrence.Canonical correspondence analysis showed that nutrients and salinity can explain the patterns of bacterial and archaeal community dynamics.The results suggest that hydrological,geochemical and environmental characteristics between surface water and groundwater likely control the bacterial and archaeal diversities and distributions in STEs.Furthermore,we found that some key species can utilize terrestrial pollutants such as nitrate and ammonia in STEs,indicating that these species(e.g.,Nitrosopumilus maritimus,Limnohabitans parvus and Simplicispira limi)may be excellent candidates for in situ degradation/remediation of coastal groundwater contaminations concerned with the nitrate and ammonia.Overall,this study reveals the coupling relationship between the microbial communities and hydrochemical environments in STEs,and provides a perspective of in situ degradation/remediation for coastal groundwater quality management.

The Effects of Surface Water Velocity on Hyporheic Interchange

When evaluating hyporheic exchange in a flowing stream, it is inappropriate to directly compare stream stage with subsurface hydraulic head (h) to determine direction and magnitude of the gradient between the stream and the subsurface. In the case of moving water, it is invalid to ignore velocity and to assume that stage equals the net downward pressure on the streambed.? The Bernoulli equation describes the distribution of energy within flowing fluids and implies that net pressure decreases as a function of velocity, i.e., the Venturi Effect, which sufficiently reduces the pressure on the streambed to create the appearance of a downward gradient when in fact the gradient may be upward with stream flow drawing water from the subsurface to the surface. A field study correlating the difference between subsurface head and stream stage in a low-gradient stream indicates that the effect is present and significant: shallow subsurface head increases less quickly than stage while deeper subsurface head increases more quickly. These results can substantially improve conceptual models and simulations of hyporheic flow.

Stable isotopes of water as a tracer for revealing spatial and temporal characteristics of groundwater recharge surrounding Qinghai Lake,China

Studying spatial and temporal characteristics of regional groundwater recharge will guide the scientific management and sustainable development of regional water resources.This study investigated stable isotopes(δ^(18)O and δ^(2) H)of precipitation,groundwater,river water and lake water during 2019-2020 in Qinghai Lake Basin to reveal the spatial and temporal characteristics of groundwater recharge.The local meteoric water line was simulated using ordinary least squares regression(δ^(2) H=7.80δ^(18)O+10.60).The local evaporation lines of the river water,lake water and groundwater were simulated asδ^(2) H=6.21δ^(18)O-0.72,δ^(2) H=5.73δ0-3.60 and δ^(2) H=6.59δ0+1.76,respectively.The δ^(2) H and δ^(18)O of river water and groundwater were in more depleted values due to the recharge by precipitation at high altitudes or precipitation effects,and theδ^(2) H andδ^(18)O of the lake water were in more enriched values because of evaporation.The relationship between the δ^(2) H and δ^(18)O of groundwater and river water was not significantly different,indicating a strong hydrological connection between the groundwater and river water surrounding Qinghai Lake.Additionally,the maximum values of δ^(18)O and the minimum values of lc-excess of groundwater in most regions were both in August,and the minimum values of δ^(18)O and the maximum values of lc-excess of groundwater in most regions were both in October.Therefore,the groundwater was recharged by soil water with strong evaporation in August and recharged by precipitation at high altitudes in October.The recharge rate of groundwater was relatively fast in areas with large slopes and large hydraulic gradients(e.g.,south of Qinghai Lake),and in areas with strong hydrological connections between the groundwater and river water(e.g.,the Buha River Valley).Those results can provide data support for protection and utilization of water resources in Qinghai Lake Basin,and provide reference for groundwater research in closed lake basins on the Qinghai-Tibet Plateau.

Effect of Water Resources Allocation on Groundwater Environment and Soil Salinity Accumulation under Climate Change

The combined surface and groundwater allocation practice by wells and canals had contributed to the safety of groundwater environment and agriculture sustainable production. The typical area in the People＇s Victory Canal irrigation district was taken as a case, drawing together the irrigation district agriculture water consumption and precipitation from 1954 to 2014 in the People＇s Victory Canal irrigation district, ratios of surface to groundwater irrigation amount, dynamic of groundwater depth and hydrochemical characteristic of groundwater from 2008 to 2014 in the research area, the relationship between groundwater depth and ratio of surface to groundwater irrigation amount was analyzed, in order to ascertain the influence of precipitation on ratios of surface to groundwater irrigation amount and its effect on soil and groundwater environment. The results indicated that positive correlation between the ratios of surface to groundwater irrigation amount and annual precipitation was appeared, affected by climate change, average irrigation amount from surface in the recent 5 years was 2.90 x 108 cubic meters, accounted for 75.52% of total irrigation amount, on the other hand, decreasing tendency of precipitation was obvious, and groundwater depth dynamic in upstream of the branch canals was more dramatic than downstream because of surface water irrigation infiltration, under the unified condition of water use efficiency, ratio of surface to groundwater irrigation amount was negative correlation with area of the groundwater depth beyond 11 m, meanwhile, groundwater depth demonstrated negative correlation with the ratio of surface to groundwater irrigation amount, moreover, alkaline trend of groundwater hydrochemistry during the normal season in the research area was obvious because of phreatic evaporation and the agricultural irrigation from wells, along with irrigation from surface inflow of Yellow River, quality of groundwater hydrochemistry during the dry season was ameliorative greatly. Consequently, it was very important to the agriculture sustainable production that well-canal combined irrigation patterns alleviated extremely alkaline trend of the groundwater hydrochemistry and played a positive role of root layer soil salinity leaching.

Hydrochemical Assessment of Groundwater and Dominant Water-Rock Interactions in Ooeides Aquifer System, North Greece

This paper deals with the assessment of main controls on groundwater chemistry in the aquifer system of Ooeides, Orestiada Region, NE Greece, contributing to the assessment of groundwater and surface water interaction, as well as water-rock interactions in the study area. Statistical analysis and relevant hydrochemical plots were employed in the analysis of groundwater samples from the study area during sampling campaigns for the years 2018, 2019 and 2020. The process included the collection and analysis of hydrochemical, hydrological and hydrogeological information and data regarding the aquifer system of the study area. Based on the statistical processing and the spatial analysis of the relevant results of the research, interesting and useful information emerged regarding: i) the recharge procedure of the aquifer from surface water of rivers and streams in the study area;ii) the relationship of groundwater composition with the type of rock through which water flows;iii) the impact on groundwater quality from anthropogenic activities (cultivation activities, municipal waste). From the elaboration of all the above, interesting findings and suggestions came out, which are considered useful for the optimal management of the hydrogeological regime of the study area.

Transformation of surface water and groundwater and water balance in the agricultural irrigation area of the Manas River Basin,China

Calculation of the water balance is very important to relieve the pressure on water resources in arid agricultural irrigation areas.This research focused on irrigation water balance calculations in the Manas River Basin of the southern margin of the Junggar Basin of China,and aimed to analyze the groundwater level dynamic trend and response characteristics of the basin water cycle under water-saving irrigation measures.The surface water and groundwater coupling model of MIKE 11-Visual MODFLOW was used to simulate rainfall runoff in mountainous areas,and quantify the contribution of water balance components in the plain irrigation area.Convergence of the delayed watershed in the mountain area was obvious,and when the river runoff exceeded 200 m^(3)/s,the error in the runoff simulation was large.The water balance in the plain agricultural irrigation area was in a negative equilibrium state,and the difference between recharge and discharge was−2.65 billion m^(3).The evapotranspiration was 24.49 billion m^(3) under drip irrigation,accounting for only approximately 51%of the total discharge.The lateral discharge of the unsaturated and saturated aquifers was 15.38 billion m^(3),accounting for approximately 32%of the total discharge.The main reason for the groundwater decline in the irrigation area was closely related to the extraction of groundwater,because the amount of recharge and discharge in the natural state was approximately identical.The MIKE 11-Visual MODFLOW model produced accurate results,and the research method provided a new exploration technique to quantify the effect of water supply mode on the groundwater table.The model is suitable for the management of water resources in arid areas.

Field scale interaction and nutrient exchange between surface water and shallow groundwater in the Baiyang Lake region,North China Plain

Fertilizer input for agricultural food production, as well as the discharge of domestic and industrial water pollutants, increases pressures on locally scarce and vulnerable water resources in the North China Plain. In order to：（a） understand pollutant exchange between surface water and groundwater,（b） quantify nutrient loadings, and（c） identify major nutrient removal pathways by using qualitative and quantitative methods, including the geochemical model PHREEQC） a one-year study at a wheat（Triticum aestivum L.） and maize（Zea mays L.） double cropping system in the Baiyang Lake area in Hebei Province, China, was undertaken. The study showed a high influence of low-quality surface water on the shallow aquifer. Major inflowing pollutants into the aquifer were ammonium and nitrate via inflow from the adjacent Fu River（up to 29.8 mg/L NH4-N and 6.8 mg/L NO3-N）, as well as nitrate via vertical transport from the field surface（up to 134.8 mg/L NO3-N in soil water）. Results from a conceptual model show an excess nitrogen input of about 320 kg/ha/a. Nevertheless,both nitrogen species were only detected at low concentrations in shallow groundwater,averaging at 3.6 mg/L NH4-N and 1.8 mg/L NO3-N. Measurement results supported by PHREEQC-modeling indicated cation exchange, denitrification, and anaerobic ammonium oxidation coupled with partial denitrification as major nitrogen removal pathways. Despite the current removal capacity, the excessive nitrogen fertilization may pose a future threat to groundwater quality. Surface water quality improvements are therefore recommended in conjunction with simultaneous monitoring of nitrate in the aquifer, and reduced agricultural N-inputs should be considered.

Utilization threshold of surface water and groundwater based on the system optimization of crop planting structure

Based on the diversity of the agricultural system, this research calculates the planting structures of rice, maize and soybean considering the optimal economic-social-ecological aspects. Then, based on the uncertainty and randomness of the water resources system,the interval two-stage stochastic programming method,which introduces the uncertainty of the interval number, is used to calculate the groundwater exploitation and the use efficiency of surface water. The method considers the minimum cost of water as the objective of the uncertainty model for surface water and groundwater joint scheduling optimization for different planting structures. Finally, by calculating harmonious entropy, the optimal exploitation utilization interval of surface water and groundwater is determined for optimal cultivation in the Sanjiang Plain.The optimal matching of the planting structure under the economic system is suitable when the mining ratio of the surface is in 44.13%–45.45% and the exploitation utilization of groundwater is in 54.82%–66.86%, the optimal planting structure under the social system is suitable when surface water mining ratio is in 47.84%–48.04% and the groundwater exploitation threshold is in 67.07%–72.00%. This article optimizes the economicsocial-ecological-water system, which is important for the development of a water- and food-conserving society and providing a more accurate management environment.

Fully integrated modeling of surface water and groundwater in coastal areas

This paper presents an improved model based on a three-dimensional non-hydrostatic wave model NHWAVE to simulate the interactions between the surface water and the groundwater affected by tides or waves in coastal areas. With the model, both the surface water flow and the groundwater flow are calculated based on the well-balanced Volume-averaged Reynolds-averaged Navier-Stokes equations. The spatially varying porosity and hydraulic conductivity are used to identifiy the domains for the surface water and the groundwater. The model is calibrated and validated using a wide range of laboratory measurements reported in the literature, involving the tide propagation through a sandy embankment, the tide-induced groundwater table fluctuation in a sandy beach, and the wave setup in a sloping sandy beach. The interactions between the surface water and the groundwater are analyzed and the influencing factors on the groundwater flow are discussed. The phase lag between the surface water elevation and the groundwater table fluctuation is mainly influenced by the hydraulic conductivity of the porous media. The wave attenuation in the groundwater is proportional to its propagation distance. The computed wave setup elevationin the permeable beach is smaller than in the impermeable beach. It is shown that the fully integrated model is capable of simulating the interactions between the surface water and the groundwater affected by tides or waves in coastal areas. It can be an efficient tool to study the tide and wave dynamics in the permeable sandy beach.

Hydrochemical insights on the signatures and genesis of water resources in a high-altitude city on the Qinghai-Xizang Plateau, South-west China

Water resources have crucial implications for the steady development of the urban social economy.This study investigated the hydrochemical signatures and genesis of water resources in the urban area of Lhasa City(UALC).To this end,several analyses,such as ion ratio analysis and correlation analysis,were performed by comprehensively applying mathematical statistics and integrated hydrochemical methods.The results show relatively low concentrations of major ions in the groundwater and surface water(GSW)of the UALC.The primary anions and cations are HCO3-and Ca2+,reflecting the HCOg-Ca water type.Nevertheless,groundwater exhibits higher concentrations of key chemical components compared to surface water.GsW are weakly alkaline,with pH values of 7.78 and 7.61,respectively,and they have low salinity with average concentrations of total dissolved solids being 190.74 and 112.17 mg/L,respectively.Anthropogenic inputs have minimal influence on the hydrochemical features of GSw,whereas rock weathering is the dominant controlling factor.Furthermore,cation exchange.is a significant hydrogeochemical.process influencing their hydrochemical features.According to the isotope analysis(H and 180),the primary source of recharge for GSW is atmospheric precipitation,with some input from melted ice and snow.Moreover,GSW samples from the UALC show relatively similar 2H and 18O isotopic compositions,indicating the existence of a discernible hydraulic connection linking the two water sources.The research findings can serve as a valuable scientific reference and foundation for the sustainable development,effective utilization,and proper safeguarding of regional water resources in high-altitude areas.

Legacy of herbicides in water from Hailun City,Northeast China:Occurrence,source,and ecological risk assessment

Herbicides(HBCs)are extensively used in modern agriculture.However,their potential negative impacts on environmental media have emerged as a significant environmental concern.In this study,we employed positivematrix factorization(PMF)to identify the potential sources of HBCs.Furthermore,we utilized amulti-matrix ecological riskmodel to assess the risks associated with HBCs in both surface water and groundwater in the black soil region of Northeast China.The findings revealed that the levels of15HBCs in surface water and groundwater ranged from585.84 to 6466.96 ng/L and 4.80 to 11,774.64 ng/L,respectively.The PMF results indicated that surface runoff and erosion accounted for 50%of the total HBCs in water,serving as the primary sources.All tested HBCs exhibited acute risk values within acceptable levels.The risk index for the∑15HBCs was categorized as“moderate risk”in 31%of the surface waters and 13%of the groundwaters.However,4%of the groundwater sampling sites reached the“high risk”level.The chronic risk quotient of∑15HBCs in surface water and groundwater was 92%and 62%at the“high risk”level,respectively.Interestingly,noncarcinogenic HBCs contributed more significantly to the ecotoxicology of the aquatic system than carcinogenic HBCs.This study provides comprehensive information on the legacy of HBCs in water bodies and emphasizes the potential risks posed by HBCs to aquatic systems.The results obtained from this study could help relevant management authorities in developing and implementing effective regulations tomitigate the ecological and environmental risks associated with HBCs.

Environmental Isotopes and Cl/Br Ratios Evidences for Delineating Arsenic Mobilization in Aquifer System of the Jianghan Plain,Central China

Environment isotopes(δ18O andδ2H)and Cl/Br ratios in surface water and groundwater are combined to investigate arsenic mobilization in aquifer system of the Jianghan Plain.The groundwater has relatively high arsenic concentrations,ranging from 3.6 to 1055.3μg/L with an average of 102.2μg/L,which exceeds China’s drinking water standard(10μg/L).The arsenic content of surface water samples is quite low with the range of 6.0–14.3μg/L,averaging 9.5μg/L.δ18O andδ2H values for surface water and groundwater samples plot close to the local meteoric water line(LMWL),reflecting their meteoric origin;a subset of the samples(shallow wells,10 m)shows a shift to LMWL,commensurate with mixing with surface water and evaporation.The correlations betweenδ18O values and Cl concentration and Cl/Br ratios as well as arsenic concentration demonstrated that surface water and groundwater interactions,including active exchange between river/pond water and groundwater and vertical infiltration from agricultural and aquacultural soils,were dominated processes affecting arsenic mobilization in shallow groundwater system and lateral recharge was the main process controlling arsenic behavior in deep groundwater system.The results of this study will be beneficial to understanding the causes of arsenic mobilization in Jianghan groundwaters at different depths.