Apically guiding electron/mass transfer reaction induced by Ag/FeN_(x)Mott-Schottky effect within a hollow star reactor toward high performance zinc-air batteries

The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with elevated overpotentials,thereby imposing additional constraints on its utilization.Therefore,the pre-design and target-development of inexpensive,high-performance,and long-term stable bifunctional catalysts are urgently needed.In this work,an apically guiding dual-functional electrocatalyst(Ag-FeN_(x)-N-C)was prepared,in which a hierarchical porous nitrogen-doped carbon with three-dimensional(3D)hollow star-shaped structure is used as a substrate and high-conductivity Ag nanoparticles are coupled with iron nitride(FeN_(x))nanoparticles.Theoretical calculations indicate that the Mott-Schottky heterojunction as an inherent electric field comes from the two-phase bound of Ag and FeN_(x),of which electron accumulation in the FeN_(x)phase region and electron depletion in the Ag phase region promote orientated-guiding charge migration.The effective modulation of local electronic structures felicitously reforms the d-band electron-group distribution,and intellectually tunes the masstransfer reaction energy barriers for both ORR/OER.Additionally,the hollow star-s haped hierarchical porous structure provides an apical region for fast mass transfer.Experimental results show that the halfwave potential for ORR is 0.914 V,and the overpotential for OER is only 327 mV at 10 mA cm^(-2).A rechargeable ZAB with Ag-FeN_(x)-N-C as the air cathode demonstrates long-term cycling performance exceeding 1500 cycles(500 h),with a power density of 180 mW cm^(-2).Moreover,when employing AgFeN_(x)-N-C as the air cathode,flexible ZABs demonstrate a notable open-circuit voltage of 1.42 V and achieve a maximum power density of 65.6 mW cm^(-2).Ag-FeN_(x)-N-C shows guiding electron/mass transfer route and apical reaction microenvironment for the electrocatalyst architecture in the exploration prospects of ZABs.

Structure-preserving algorithms for guiding center dynamics based on the slow manifold of classical Pauli particle

The classical Pauli particle(CPP) serves as a slow manifold, substituting the conventional guiding center dynamics. Based on the CPP, we utilize the averaged vector field(AVF) method in the computations of drift orbits. Demonstrating significantly higher efficiency, this advanced method is capable of accomplishing the simulation in less than one-third of the time of directly computing the guiding center motion. In contrast to the CPP-based Boris algorithm, this approach inherits the advantages of the AVF method, yielding stable trajectories even achieved with a tenfold time step and reducing the energy error by two orders of magnitude. By comparing these two CPP algorithms with the traditional RK4 method, the numerical results indicate a remarkable performance in terms of both the computational efficiency and error elimination. Moreover, we verify the properties of slow manifold integrators and successfully observe the bounce on both sides of the limiting slow manifold with deliberately chosen perturbed initial conditions. To evaluate the practical value of the methods, we conduct simulations in non-axisymmetric perturbation magnetic fields as part of the experiments,demonstrating that our CPP-based AVF method can handle simulations under complex magnetic field configurations with high accuracy, which the CPP-based Boris algorithm lacks. Through numerical experiments, we demonstrate that the CPP can replace guiding center dynamics in using energy-preserving algorithms for computations, providing a new, efficient, as well as stable approach for applying structure-preserving algorithms in plasma simulations.

Exploration and Practice of“Guiding Interactive”Teaching in Advanced Geochemistry Courses from the Perspective of Constructivist Theory

The construction of geochemical disciplines has brought new vitality to the development of traditional geology.In the new round of“Double First-Class”discipline construction at Central South University,the course of Advanced Geochemistry has effectively stimulated students’interest in learning and further improved their scientific thinking and research innovation skills through the implementation of“Guiding Interactive”teaching reform measures,which has important theoretical significance and practical value.

The Guiding Thought and Overall Layout of Major-country Diplomacy with Chinese Characteristics in a New Era

The 19th National Congress of the Communist Party of China(CPC)held in October 2017sends out the mobilization order to the CPC and the Chinese people of all ethnic groups on achieving a decisive victory to build a moderately prosperous society in all respects,and winning the great victory of socialism with Chinese characteristics in a new era,but also declares to

Adaptive energy-preserving algorithms for guiding center system

We develop two types of adaptive energy preserving algorithms based on the averaged vector field for the guiding center dynamics,which plays a key role in magnetized plasmas.The adaptive scheme is applied to the Gauss Legendre’s quadrature rules and time stepsize respectively to overcome the energy drift problem in traditional energy-preserving algorithms.These new adaptive algorithms are second order,and their algebraic order is carefully studied.Numerical results show that the global energy errors are bounded to the machine precision over long time using these adaptive algorithms without massive extra computation cost.

基于Guided BERTopic模型的产业链关键核心技术识别与发展趋势研判--以未来工业互联网为例

产业链关键核心技术不仅是国之重器,而且对推动我国经济的高质量发展和保障国家安全起着至关重要的作用。当前,工业互联网产业链的关键技术发展成为我国的研究重点,该领域的重要性在2023年被提升至国家级重大研究计划。综合收集了1989-2024年中美两国在工业互联网领域的专利数据,基于《关键和新兴技术清单》和《未来工业互联网基础理论与关键技术重大研究计划》,构建了一套工业互联网产业链核心关键技术的种子词库。利用Guided BERTopic模型提取了产业链关键技术主题,并采用Logistic模型评估了这些技术的生命周期,进而对比中美两国的发展情况,提出了针对未来发展的建议。研究结果表明,相比美国,我国在大多数产业链核心技术方面仍处于成长阶段,而美国则已步入技术饱和阶段。展望未来,设备监测系统、设备管理系统、无线通信技术及能耗监测分析系统等被认为是具有巨大发展潜力的技术。研究提出了一种基于政策文件的产业链关键技术识别方法,并通过对工业互联网专利技术的实证分析,为制定相关政策提供了科学指导和建议。

不确定情景下AGV系统调度算法的仿真平台

不确定情境下的完整自动引导车(automated guided vehicle,AGV)系统调度算法,除了要包含常见的任务指派策略和路径规划算法之外,还需要包含冲突应对策略。由于存在随机性,这样的调度算法难以从理论上分析其特性,相关研究也较少。基于离散事件仿真技术,设计并开发了一个AGV系统仿真平台,可以灵活地设置调度问题,并选择调度算法中的任务指派策略、路径规划算法和路径冲突应对策略进行仿真。该平台具有可视化的界面,可以直观地观察AGV的运行状态和调度算法的表现,也可以输出最终的仿真实验统计数据。实验表明:该平台可以准确有效地对不确定情景下的调度算法进行评估与比较。

Guided Care护理模式对老年骨质疏松症患者自我管理能力和生活质量的影响

目的探讨分析Guided Care护理模式对老年骨质疏松症患者自我管理能力和生活质量的影响。方法简单随机选取2022年1月—2023年9月山东省泰安荣军医院收治的60例老年骨质疏松症患者为研究对象,按随机数表法将其分为常规组(实施常规护理干预),模式组(在常规组的基础上给予Guided Care护理模式干预),每组30例,两组均持续干预2个月,比较两组患者干预前后的健康认知水平、跌倒风险、自我管理能力、生活质量、护理满意度。结果干预2个月后,模式组的健康认知水平评分高于常规组,差异有统计学意义(P<0.05)。干预2个月后,模式组的跌倒风险评分低于常规组,差异有统计学意义(P<0.05)。干预2个月后,模式组的自我管理能力评分高于常规组,生活质量评分低于常规组,差异有统计学意义(P均<0.05)。干预2个月后,模式组的护理满意度为93.33%,高于常规组的护理满意度73.33%,差异有统计学意义(χ^(2)=4.320,P<0.05)。结论在老年骨质疏松症患者中,应用Guided Care护理模式,可以有效地提升患者的健康认知水平及自我管理能力,提高患者的生活质量,降低患者跌倒的风险。

A Novel Prescribed-Performance Path-Following Problem for Non-Holonomic Vehicles

The issue of achieving prescribed-performance path following in robotics is addressed in this paper,where the aim is to ensure that a desired path within a specified region is accu-rately converged to by the controlled vehicle.In this context,a novel form of the prescribed performance guiding vector field is introduced,accompanied by a prescribed-time sliding mode con-trol approach.Furthermore,the interdependence among the pre-scribed parameters is discussed.To validate the effectiveness of the proposed method,numerical simulations are presented to demonstrate the efficacy of the approach.

基于数据挖掘技术的税务风险检测方法评述

Tax risk behavior causes serious loss of fiscal revenue,damages the country’s public infrastructure,and disturbs the market economic order of fair competition.In recent years,tax risk detection,driven by information technology such as data mining and artificial intelligence,has received extensive attention.To promote the high-quality development of tax risk detection methods,this paper provides the first comprehensive overview and summary of existing tax risk detection methods worldwide.More specifi-cally,it first discusses the causes and negative impacts of tax risk behaviors,along with the development of tax risk detection.It then focuses on data-mining-based tax risk detection methods utilized around the world.Based on the different principles employed by the algorithms,existing risk detection methods can be divided into two categories:relationship-based and non-relationship-based.A total of 14 risk detection methods are identified,and each method is thoroughly explored and analyzed.Finally,four major technical bottlenecks of current data-driven tax risk detection methods are analyzed and discussed,including the difficulty of integrating and using fiscal and tax fragmented knowledge,unexplainable risk detection results,the high cost of risk detection algorithms,and the reliance of existing algorithms on labeled information.After investigating these issues,it is concluded that knowledge-guided and datadriven big data knowledge engineering will be the development trend in the field of tax risk in the future;that is,the gradual transition of tax risk detection from informatization to intelligence is the future development direction.

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Article Article types Articles commonly fall into one of three main categories:Full-length articles,Review articles and Short communications.Full-length articles are original,unpublished primary research.Extensions of work that has been published previously in short form such as a Communication are usually acceptable.

Pipeline thickness estimation using the dispersion of higher-order SH guided waves

Thickness measurement plays an important role in the monitoring of pipeline corrosion damage. However, the requirement for prior knowledge of the shear wave velocity in the pipeline material for popular ultrasonic thickness measurement limits its widespread application. This paper proposes a method that utilizes cylindrical shear horizontal(SH) guided waves to estimate pipeline thickness without prior knowledge of shear wave velocity. The inversion formulas are derived from the dispersion of higher-order modes with the high-frequency approximation. The waveform of the example problems is simulated using the real-axis integral method. The data points on the dispersion curves are processed in the frequency domain using the wave-number method. These extracted data are then substituted into the derived formulas. The results verify that employing higher-order SH guided waves for the evaluation of thickness and shear wave velocity yields less than1% error. This method can be applied to both metallic and non-metallic pipelines, thus opening new possibilities for health monitoring of pipeline structures.

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Introduction Types of paper Contributions falling into the following categories will be considered for publication: Original research papers, reviews, Research Notes, Short Communication, New technologies, News and Views, Commentary on significant events and topics in global horticultural fields with international interests.

Detection of internal crack growth in polyethylene pipe using guided wave ultrasonic testing

Despite the success of guided wave ultrasonic inspection for internal defect detection in steel pipes,its application on polyethylene(PE)pipe remains relatively unexplored.The growth of internal cracks in PE pipe severely affects its pressure-holding capacity,hence the early detection of internal cracks is crucial for effective pipeline maintenance strategies.This study extends the scope of guided wave-based ultrasonic testing to detect the growth of internal cracks in a natural gas distribution PE pipe.Laboratory experiments and a finite element model were planned to study the wave-crack interaction at different stages of axially oriented internal crack growth with a piezoceramic transducer-based setup arranged in a pitch-catch configuration.Mode dispersion analysis supplemented with preliminary experiments was performed to isolate the optimal inspection frequency,leading to the selection of the T(0,1)mode at 50-kHz for the investigation.A transmission index based on the energy of the T(0,1)mode was developed to trace the extent of simulated crack growth.The findings revealed an inverse linear correlation between the transmission index and the crack depth for crack growth beyond 20%crack depth.

Defining failure of endoluminal biliary drainage in the era of endoscopic ultrasound and lumen apposing metal stents

The role of endoscopy in pathologies of the bile duct and gallbladder has seen notable advancements over the past two decades.With advancements in stent technology,such as the development of lumen-apposing metal stents,and adoption of endoscopic ultrasound and electrosurgical principles in therapeutic endoscopy,what was once considered endoscopic failure has transformed into failure of an approach that could be salvaged by a second-or third-line endoscopic strategy.Incorporation of these advancements in routine patient care will require formal training and multidisciplinary acceptance of established techniques and collaboration for advancement of experimental techniques to generate robust evidence that can be utilized to serve patients to the best of our ability.

On the eigenvalues and eigendisplacement of the critical mode in horizontally layered media

Wave propagation in horizontally layered media is a classical problem in seismic-wave theory.In semi-infinite space,a nondispersive Rayleigh wave mode exists,and the eigendisplacement decays exponentially with depth.In a layered model with increasing layer velocity,the phase velocity of the Rayleigh wave varies between the S-wave velocity of the bottom half-space and that of the classical Rayleigh wave propagated in a supposed half-space formed by the parameters of the top layer.If the phase velocity is the same as the P-or S-wave velocity of the layer,which is called the critical mode or critical phase velocity of surface waves,the general solution of the wave equation is not a homogeneous(expressed by trigonometric functions)or inhomogeneous(expressed by exponential functions)plane wave,but one whose amplitude changes linearly with depth(expressed by a linear function).Theories based on a general solution containing only trigonometric or exponential functions do not apply to the critical mode,owing to the singularity at the critical phase velocity.In this study,based on the classical framework of generalized reflection and transmission coefficients,the propagation of surface waves in horizontally layered media was studied by introducing a solution for the linear function at the critical phase velocity.Therefore,the eigenvalues and eigenfunctions of the critical mode can be calculated by solving a singular problem.The eigendisplacement characteristics associated with the critical phase velocity were investigated for different layered models.In contrast to the normal mode,the eigendisplacement associated with the critical phase velocity exhibits different characteristics.If the phase velocity is equal to the S-wave velocity in the bottom half-space,the eigendisplacement remains constant with increasing depth.

Arbitrary skin metallization by pencil-writing inspired solid-ink rubbing for advanced energy storage and harvesting

The development of a durable metallic coating on diverse substrates is both intriguing and challenging,particularly in the research of metal-conductive materials for applications such as batteries,soft electronics,and beyond.Herein,by learning from the pencil-writing process,a facile solid-ink rubbing technology(SIR-tech)is invented to address the above challenge.The solid-ink is exampled by rational combination of liquid metal and graphite particles.By harnessing the synergistic effects between rubbing and adhesion,controllable metallic skin is successfully formed onto metals,woods,ceramics,and plastics without limitation in size and shape.Moreover,outperforming pure liquid-metal coating,the composite metallic skin by SIR-tech is very robust due to the self-lamination of graphite nanoplate exfoliated by liquid-metal rubbing.The critical factors controlling the structures-properties of the composite metallic skin have been systematically investigated as well.For applications,the SIR-tech is demonstrated to fabricate high-performance composite current collectors for next-generation batteries without traditional metal foils.Meanwhile,advanced skin-electrodes are further demonstrated for stable triboelectricity generation even under temperature fluctuation from-196 to 120℃.This facile and highly-flexible SIR-tech may work as a powerful platform for the studies on functional coatings by liquid metals and beyond.

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INTRODUCTION Types of paper Contributions falling into the following categories will be considered for publication:Original research papers,reviews and short communications.Please ensure that you select the appropriate article type from the list of options when making your submission.Authors contributing to special issues should ensure that they select the special issue article type from this list.

GUIDE FOR AUTHORS

INTRODUCTION.Types of paper.Contributions falling into the following categories will be considered for publication:Original research papers,reviews and short communications.Please ensure that you select the appropriate article type from the list of options when making your submission.Authors contributing to special issues should ensure that they select the special issue article type from this list.

GUIDE FOR AUTHORS

Introduction Types of paper Contributions falling into the following categories will be considered for publication:Original research papers,Reviews,Short communication.Please ensure that you select the appropriate article type from the list of options when making your submission.Authors contributing to special issues should ensure that they select the special issue article type from this list.