Siderite is a prevalent authigenic mineral in siliciclastic rocks, which usually occurred in eodiagensis period and could be used as an indicator of sedimentary environment. Some siderite precipitated in burial depth ...Siderite is a prevalent authigenic mineral in siliciclastic rocks, which usually occurred in eodiagensis period and could be used as an indicator of sedimentary environment. Some siderite precipitated in burial depth with geochemical information of basin fluid evolution. The crystal morphology, geochemical composition, and isotope values are influenced by physical and geochemical environment of precipitation. In this study, samples from the Early Cretaceous of Erlian basin in the northwestern China were collected, and mineralogy, bulk and in-situ geochemistry, C and O isotopes were analyzed to comprehensively investigate the sedimentary and diagenetic environment that the sediments experienced. Six lithofaices with three types of crystal habits were recognized in the siderite-rich sandstone, bundle crystal in spherical forms, blocky rhombs in intergranular pore and cleavage of muscovite, and micro bundle and mosaic crystals aggregates in nodular. The siderite growth proceeds through micro bundle and mosaic crystals to bundle siderite aggregates and then into blocky rhombs. The crystal evolution is also reflected by geochemical composition. The micro bundle and mosaic crystals are Casiderite. The spheritic shaped bundle aggregates are Ca-Mn-siderite. The blocky rhomb siderite shows gray part and bight part with Ca, Mg and Mn varies. Increase of Ca in block rhomb siderite suggests burial and mesodiagenesis, the high content of Mn may have linkage with eogenetic effects. The relatively positive and slightly negative δ13C value indicates meteoric water domination and influence of organic matter evolution in shallow buried time. The narrow ranges negative δ18O value suggest a small span of temperature of siderite formation.展开更多
The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofa...The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofacies of subaqueous eruptive pyroclastic rocks is discussed and the facies model is established by taking the tuff cone of Cretaceous Huoshiling Formation in the Chaganhua area of the Changling fault depression,Songliao Basin as the research object.The results indicate that the subaqueous eruptive pyroclastic rocks in the Songliao Basin can be divided into two facies and four subfacies.The two facies are the subaqueous explosive facies and the volcanic sedimentary facies that is formed during the eruption interval.The subaqueous explosive facies can be further divided into three subfacies:gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies.The volcanic sedimentary facies consists of pyroclastic sedimentary rocks containing terrigenous clast subfacies.A typical facies model of the tuff cone that is formed by subaqueous eruptions in the Songliao Basin was established.The tuff cone is generally composed of multiple subaqueous eruption depositional units and can be divided into two facies associations:near-source facies association and far-source facies association.The complete vertical succession of one depositional unit of the near-source facies association is composed of pyroclastic sedimentary rocks containing terrigenous clast subfacies,gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies from bottom to top.The depositional unit of the far-source facies association is dominated by the subaqueous fallout subfacies and contains several thin interlayered deposits of the water-laid density current subfacies.The gas-supported hot pyroclastic flow subfacies and the pyroclastic sedimentary rocks containing terrigenous clast subfacies are favorable subaqueous eruptive facies for reservoirs in continental lacustrine basins.展开更多
Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin,China.The insufficient understanding of their sedimentary processes,depositional patterns,and controlling factors restric...Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin,China.The insufficient understanding of their sedimentary processes,depositional patterns,and controlling factors restricts efficient exploration and development.Coarse-grained subaqueous fans in the Yong′an area,Dongying Depression,are investigated in this study.These fans include nearshore subaqueous fans,and sublacustrine fans,and their sedimentary processes,depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology.Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence.Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction.While the topography was gentle,sublacustrine fans did not develop.During the late weak tectonic activity stage,late sublacustrine fans developed with multiple stages superimposed.Frequent fault activity and related earthquakes steepened the basin margin,and the boundary fault slopes were 25.9°–34°.During the early–middle deposition stage,hyperpycnal flows triggered by outburst floods developed.During the late deposition stage,with weak tectonic activity,seasonal floods triggered hyperpycnal flows,and hybrid event beds developed distally.展开更多
Through the long development processes of reservoir sedimentation and diagenesis, acidic and alkaline fluids play key roles in controlling deep reservoir development. However, the ways in which deep fluids control and...Through the long development processes of reservoir sedimentation and diagenesis, acidic and alkaline fluids play key roles in controlling deep reservoir development. However, the ways in which deep fluids control and transform the reservoir under complex fault conditions remain unclear. In this study, a 2D model was established based on a typical sub-salt to intra-salt vertical profile in the Qaidam Basin, China. Based on measured data, multiphase flow reaction and solute transport simulation technology were used to analyze fluids flow and migration in the intra-salt and sub-salt reservoirs, determine the mineral dissolution, precipitation, and transformation in the reservoir caused by the deep fluids, and calculate the changes in reservoir porosity. Results show that deep fluid migrates preferentially along dominant channels and triggers a series of fluid–rock chemical reactions. In the first stage, a large amount of anhydrite precipitated in the fault as a result of upward migration of deep saline fluid, resulting in the formation of anhydrite veins and blockage at the base of the fault. In the second stage, organic acids caused minerals dissolution and a vertical channel was opened in previously blocked area, which promoted continuous upward migration of organic acids and the formation of secondary pores. This study clarifies the transformative effects of deep alkaline and acidic fluids on the reservoir. Moreover, the important fluid transport role of faults and their effect on reservoir development were determined.展开更多
Typical reefs in the Paleogene and early Neogene strata of the Qaidam Basin, Tibetan Plateau, China, reveal their internal structures and sedimentation environments and consist mainly of algal reef, stromatolite reef ...Typical reefs in the Paleogene and early Neogene strata of the Qaidam Basin, Tibetan Plateau, China, reveal their internal structures and sedimentation environments and consist mainly of algal reef, stromatolite reef and thrombolite reef with distinct reef structures, fore-reef, back-reef and reef-plateau. The fore-reef is characterized by a combination of pinnacle reef, thrombolite and algal reef. The back reef is composed of stromatolite reef and algal reef. The pinnacle reefs (micro-atoll), most of which are several tens of centimeters in diameter (whereas some exceptionally big ones are over 200 cm in diameter), and several tens of centimeter to 2 m in height, are situated on the far front-edge of the reef; the pinnacle reef is also often of recumbent form with a gravel-filled circular hole in the center. The algal reef is in the form of dome and irregular beds, and filled with algal detritus, ostracodes, spirorbis fossils, ooid and terrigenous debris, and worm traces; cavities and scour marks are often developed. The algal reef is gray commonly when fresh and weathers to a brown color. The lacustrine thrombolite in the Qaidam Basin is light gray or deep gray when fresh, white-gray or brown when weathered, dense and homogeneous with abundant pores filled by oil and bitumen. Observed under the microscope, the thrombolite consists mainly of brown or brown-black clots with a little algal debris, ooid, pellet, ostracodes, spirorbis fossils and terrigenous debris, in some cases, terrigenous debris, even gravel, is abundant. Many features of the thrombolite suggest that it is formed in a high-energy envkonment. The stromatolite reefs developed on the lacustrine algal reef in the Qaidam Basin are very complex whether in shape or in internal structure. The simplest ones form laminated layers and the most complex ones have intensely branching structures. The size is also variable.展开更多
Based on the studies of the Songliao Basin characterized by Cretaceous down-warping, of the Jurassic compressional flexural Junggar basin and of the Bohai Bay Basin characterized by Paleogene rifting, the multiple-gra...Based on the studies of the Songliao Basin characterized by Cretaceous down-warping, of the Jurassic compressional flexural Junggar basin and of the Bohai Bay Basin characterized by Paleogene rifting, the multiple-grades slope break has developed in lacustrine basins of different origins. Their genetic types can be divided into tectonic slope break, depositional slope break and erodent slope break. The dominant agent of the slope break is tectogenesis, and the scale of slope breaks relates with the size of tectogenesis. The results of the study show that control of mutual grades slope breaks on atectonic traps mainly represent: 1) Atectonic traps develop close to mutual grades slope breaks, with beads-shaped distribution along the slope breaks. 2) In the longitudinal direction, the development of atectonic traps is characterized by the inheritance. 3) Different slope breaks and their different geographical positions can lead to different development types of atectonic traps. 4) A slope break can form different kinds of atectonic traps because of its great lateral variation. 5) The existence of mutual-grade slope breaks leads to different responses of erosion and deposition at different geographical positions in the basin. The oil source bed, reservoir and cap rock combination of atectonic traps is fine. 6) The oil-bearing condition of atectonic traps controlled by slope breaks is very favorable.展开更多
Lacustrine shale from the Qingshankou Formatin of Songliao basin and the Shahejie Formation of Bohai Bay basin, and marine shale from the lower Cambrian Jinmenchong Formation of Qiannan depression were analysed by usi...Lacustrine shale from the Qingshankou Formatin of Songliao basin and the Shahejie Formation of Bohai Bay basin, and marine shale from the lower Cambrian Jinmenchong Formation of Qiannan depression were analysed by using rock pyrolysis, TOC (total organic carbon), XRD (X-ray diffraction), SEM (scanning electron microscope), FE-SEM (field emission scanning electron microscope), high pressure mercury intrusion, and low pressure N2 and CO2 gas adsorption experiments, in aim to reveal their reservoir features. The results show that: (1) the width of micro-pores of all the studied samples mainly ranges from 0.45 to 0.7 nm indicated by CO2 isotherms, and the width of meso-pores is less than 10 nm, with type IV adsorption isotherms and type H2 hysteresis loop, indicative of "ink-bottle"-shaped pores. Good correlations exist among pore volume, surface area and averaged pore diameter, and a good positive correlation exists between micro-pore volume and TOC content; however, there is no obvious correlation between meso-pore volume and TOC content; (2) interparticle pores, pores among the edge of mineral grains and organic matter pores were all identified in marine and lacustrine shale, among which the interparticle pores may be influence by dissolution effect. Not all bitumen develops organic matter pore, and only high to over mature bitumen present pores. Now the description methods of micrometer scale pores developed in shale are very lack. Micro- fractures developed in Jiyang depression and dissolution interparticle pores developed in Songliao Basin should be the accumulation sites for shale oil in lacustrine shale, and can be as sweet spots.展开更多
Diagenetic traps in conglomerate in nearshore subaqueous fans in the steep slope zones of rift basins have been important exploration targets for subtle reservoirs in eastern China. However, the mechanism of how those...Diagenetic traps in conglomerate in nearshore subaqueous fans in the steep slope zones of rift basins have been important exploration targets for subtle reservoirs in eastern China. However, the mechanism of how those traps were formed is not clear, which inhibits further exploration for this type of reservoir. In order to solve the problem, we take as an example nearshore subaqueous fans in the upper part of the fourth member of the Shahejie Formation (Es4s) on the north slope of the Minfeng Subsag in the Dongying Sag. Combining different research methods, such as core observation, thin section examination, scanning electron microscope (SEM) observation, fluid-inclusion analysis, carbon and oxygen isotope analysis of carbonate cements, and analysis of core properties, we studied the genetic mechanisms of diagenetic traps on the basis of diagenetic environment evolution and diagenetic evolution sequence in different sub/micro-facies. Conglomerate in Es4s in the north Minfeng Subsag experienced several periods of transition between alkaline and acidic environments as "alkaline-acidic-alkaline-acidic-weak alkaline". As a result, dissolution and cementation are also very complex, and the sequence is "early pyrite cementation / siderite cementation / gypsum cementation / calcite and dolomite cementation- feldspar dissolution / quartz overgrowth quartz dissolution / ferroan calcite cementation / ankerite cementation / lime-mud matrix recrystallization / feldspar overgrowth carbonate dissolution / feldspar dissolution / quartz overgrowth / pyrite cementation". The difference in sedimentary characteristics between different sub/micro-facies of nearshore subaqueous fans controls diagenetic characteristics. Inner fan conglomerates mainly experienced compaction and lime-mud matrix recrystallization, with weak dissolution, which led to a reduction in the porosity and permeability crucial to reservoir formation. Lime-mud matrix recrystallization results in a rapid decrease in porosity and permeability in inner fan conglomerates in middle-to-deep layers. Because acid dissolution reworks reservoirs and hydrocarbon filling inhibits cementation, reservoirs far from mudstone layers in middle fan braided channels develop a great number of primary pores and secondary pores, and are good enough to be effective reservoirs of hydrocarbon. With the increase of burial depth, both the decrease of porosity and permeability of inner fan conglomerates and the increase of the physical property difference between inner fans and middle fans enhance the quality of seals in middle-to-deep layers. As a result, inner fan conglomerates can be sealing layers in middle-to-deep buried layers. Reservoirs adjacent to mudstones in middle fan braided channels and reservoirs in middle fan interdistributaries experienced extensive cementation, and tight cemented crusts formed at both the top and bottom of conglomerates, which can then act as cap rocks. In conclusion, diagenetic traps in conglomerates of nearshore subaqueous fans could be developed with inner fan conglomerates as lateral or vertical sealing layers, tight carbonate crusts near mudstone layers in middle fan braided channels as well as lacustrine mudstones as cap rocks, and conglomerates far from mudstone layers in middle fan braided channels as reservoirs. Lime-mud matrix recrystallization of inner fan conglomerates and carbonate cementation of conglomerates adjacent to mudstone layers in middle fan braided channels took place from 32 Ma B.R to 24.6 Ma B.P., thus the formation of diagenetic traps was from 32 Ma B.R to 24.6 Ma B.R and diagenetic traps have a better hydrocarbon sealing ability from 24 Ma B.P.. The sealing ability of inner fans gradually increases with the increase of burial depth and diagenetic traps buried more than 3,200 m have better seals.展开更多
To investigate the influence of extractable organic matter (EOM) on pore evolution of lacustrine shales, Soxhlet extraction, using dichloromethane, was performed on a series of Chang 7 shale samples (Ordos Basin, C...To investigate the influence of extractable organic matter (EOM) on pore evolution of lacustrine shales, Soxhlet extraction, using dichloromethane, was performed on a series of Chang 7 shale samples (Ordos Basin, China) with vitrinite reflectance of 0.64% to 1.34%. Low-pressure gas adsorption experiments were conducted on the samples before and after extraction. The pore structure parameters were calculated from the gas adsorption data. The results show complex changes to the pore volumes and surface areas after extraction. The pore development of both the initial and extracted samples is strongly controlled by total organic carbon (TOC) content. Micropores developed mainly in organic matter (OM), while mesopores and macropores predominantly developed in fractions other than OM. The influence of EOM on micropores is stronger than on mesopores and macropores. Organic solvents with a higher boiling point should be used to explore the effect of EOM on pore structure in the future.展开更多
Pore structure plays an important role in the gas storage and flow capacity of shale gas reservoirs. Fieldemission environmental scanning electron microscopy(FE-SEM) in combination with low-pressure carbon dioxide g...Pore structure plays an important role in the gas storage and flow capacity of shale gas reservoirs. Fieldemission environmental scanning electron microscopy(FE-SEM) in combination with low-pressure carbon dioxide gas adsorption(CO2GA),nitrogen gas adsorption(N2GA),and high-pressure mercury intrusion(HPMI) were used to study the nanostructure pore morphology and pore-size distributions(PSDs) of lacustrine shale from the Upper Triassic Yanchang Formation,Ordos Basin. Results show that the pores in the shale reservoirs are generally nanoscale and can be classified into four types: organic,interparticle,intraparticle,and microfracture. The interparticle pores between clay particles and organic-matter pores develop most often,l with pore sizes that vary from several to more than 100 nm. Mercury porosimetry analysis shows total porosities ranging between 1.93 and 7.68%,with a mean value of 5.27%. The BET surface areas as determined by N2 adsorption in the nine samples range from 10 to 20 m2/g and the CO2 equivalent surface areas(2 nm)vary from 18 to 71 m2/g. Together,the HPMI,N2 GA,and CO2 GA curves indicate that the pore volumes are mainly due to pores 100 nm in size. In contrast,however,most of the specific surface areas are provided by the micropores. The total organic carbon(TOC) and clay minerals are the primary controls of the structures of nanoscale pores(especially micropores and mesopores). Micropores are predominantly determined by the content of the TOC,and mesopores are possibly related to the content of clay minerals,particularly the illite-montmorillonite mixed-layer content.展开更多
The Shan 2 Member, Shan 1 Member and He 8 Member of the Mid-Late Permian Shanxi and lower Xiashihezi formations, in the southeastern Ordos Basin, together comprise -150 m of deltaic deposits. This sequence records an ...The Shan 2 Member, Shan 1 Member and He 8 Member of the Mid-Late Permian Shanxi and lower Xiashihezi formations, in the southeastern Ordos Basin, together comprise -150 m of deltaic deposits. This sequence records an overall evolution from deep marine environment to shallow lake associated with braided river, braided river delta and meandering river delta. Core description, well log interpretation, and stable isotope analysis, including carbon, oxygen and strontium, were conducted to understand the sedimentary evolution of Shan 2 to He 8 Member. The Shanxi Formation, which consists of the Shan 2 and Shan 1 members, is characterized by a tidal-influenced meandering river delta environment and a higher j13C value and S7Sr/S6Sr ratio and a lower jlSo value. The He 8 Member, the basal part of the Xiashihezi Formation, is featured by a braided river to braided river delta system and a lower j13C value, S7Sr/S6Sr ratio, and a higher jlSo value. Four third-order depositional sequences separated by five sequence boundaries are determined. Coarsening upward sequences of the Shan 2 Member-He 8 Member indicate a general regression trend, which can be correlated to global sea-level fall occurring during the Roadian-Wuchiapingian, as also evidenced by previous published zircon U-Pb results. The coal-bearing sequence (Shanxi Formation) to non-coal-bearing sequence (He 8 Member), as well as a decrease of 87Sr/86Sr, suggest a trend from humid to arid climates. A combined effect of sea-level drop and a small uplift at the end of Shanxi Formation are proposed.展开更多
In recent years, with the development of terrestrial sequence stratigraphy, more attention has been focused on the study of the terrestrial lacustrine sequence stratigraphic model globally. Different viewpoints are pr...In recent years, with the development of terrestrial sequence stratigraphy, more attention has been focused on the study of the terrestrial lacustrine sequence stratigraphic model globally. Different viewpoints are preferred by researchers. Under the guidance of the theory of sequence stratigraphy, the findings of this paper indicate that climate is a major factor controlling the formation of the fourth-order sequence, based upon the study of the sequence stratigraphy in the Green River Formation of the Uinta basin in the USA. It also divides the fourth-order sequence in the terrestrial lacustrine basin into two system tracts: the wet (rising) half-cycle and the dry (falling) half- cycle, establishing a new-style fourth-order sequence stratigraphic model for the terrestrial lacustrine basin, that is, the climate-genetic sequence stratigraphic model. As a result, the theory of sequence stratigraphy is greatly enriched.展开更多
Three types of turbidites are identified in the studied area, including proximal turbidite along the northern steep slope (alluvial fans, fan delta, and subaqueous fans via short-distance transportation), distal tur...Three types of turbidites are identified in the studied area, including proximal turbidite along the northern steep slope (alluvial fans, fan delta, and subaqueous fans via short-distance transportation), distal turbidites along the southern gentle slope (stacked sliding of delta and fan delta front), and fluxoturbidite in the central depression. Detailed studies of several case histories and the relationship between sedimentary facies and faults suggest a significant role of tectonic setting and faults in the development of turbidite, which created source areas, effected slope topography, controlled the climate and paleo-environment, and formed enough slope angle and slope break for sedimentary instabilities and massive block movement to form turbidite. According to statistics, 0.86%, with an average value of 40.3%, of the trap volumes in the 69 identified Tertiary lacustrine turbidites in the Jiyang Superdepression in the Bohai Bay Basin are filled with oil. The porosity and permeability of turbidite sands vary widely. The productive reservoirs are generally those from the braided channels of both distal and proximal turbidite, and from the main channel of proximal turbidite, with a low carbonate content and the porosity and permeability higher than 12% and 1 mD respectively. Most of the lithologic oil pools in the Jiyang Superdepression are enveloped by the effective source rocks, and the percentage of the trap volume generally increases with the hydrocarbon expulsion intensity of source rocks. This is in contrast with structural-lithologic traps (i.e. proximal turbidite along the steep slope and distal turbidite along the gentle slope), in which, graben-boundary faults play an important role in oil migration, as the turbidites are not in direct contact with effective hydrocarbon source rocks.展开更多
Micropores of shale are significant to the gas content and production potential of shale, which has been verified in the research of marine shale gas; while, few studies have been conducted on lacustrine shales. This ...Micropores of shale are significant to the gas content and production potential of shale, which has been verified in the research of marine shale gas; while, few studies have been conducted on lacustrine shales. This study collected 42 samples from three wells in the Late Cretaceous Qingshankou Formation of the southern Songliao Basin, NE China, and investigated these samples by the focused ion beam-scanning electron microscope(FIB–SEM) and nitrogen adsorption analysis techniques. Four types of micropores were identified in the samples, i.e., intergranular pore, intracellular pore, organic matter pore and microfracture. The pore structure type is characterized by open slit pores and "ink type" pores which are mainly 1.5–5 nm in diameter with mesopores as the main pores. The mesopores account for 74.01% of the pore volume and 54.68% of the pore surface area. Compared with the lacustrine shales from the Triassic Yanchang Formation in the Ordos Basin and Xujiahe Formation in the Sichuan Basin, the intergranular clay mineral interlayer pores are considered to be the main reservoir space for shale gas storage in the study area, followed by intraparticle pores, organic matter pores and microfractures. Maturity and micropore are the key controlling factors which affect the shale gas content of the Qingshankou Formation in southern Songliao Basin.展开更多
The genesis of the fine crystalline dolomites that exhibit good to excellent reservoir properties in the upper fourth member of the Eocene Shahejie Formation(Es4s)around the Sikou Sag, Bohai Bay Basin, is uncertain....The genesis of the fine crystalline dolomites that exhibit good to excellent reservoir properties in the upper fourth member of the Eocene Shahejie Formation(Es4s)around the Sikou Sag, Bohai Bay Basin, is uncertain. This paper investigates the formation mechanisms of this fine crystalline dolomite using XRD, SEM, thin section analysis and geochemical data. The stratigraphy of the Sikou lacustrine carbonate is dominated by the repetition of metre-scale, high-frequency deposition cycles, and the amount of dolomite within a cycle increases upward from the cycle bottom. These dolomite crystals are 2–30 μm in length, subhedral to anhedral in shape and typically replace both grains and matrix. They also occur as rim cement and have thin lamellae within ooid cortices. Textural relations indicate that the dolomite predates equant sparry calcite cement and coarse calcite cement. The Sr concentrations of dolomites range from 900 to 1200 ppm. Dolomite δ18O values(-11.3 to-8.2 ‰ PDB) are depleted relative to calcite mudstone(-8.3 to-5.4 ‰ PDB) that precipitated from lake water, while δ13C values(0.06–1.74 ‰ PDB) are within the normal range of calcite mudstone values(-2.13 to 1.99 ‰ PDB). High87Sr/86Sr values(0.710210–0.710844) indicate that amounts of Ca2+ and Mg2+have been derived from the chemical weathering of Palaeozoic carbonate bedrocks. The high strontium concentration indicates that hypersaline conditions were maintainedduring the formation of the dolomites and that the dolomites were formed by the replacement of precursor calcite or by direct precipitation.展开更多
Comparative analyses of petroleum generation potential,reservoir volume,frackability,and oil mobility were conducted on 102 shale cores from the Dongpu Depression.Results show the shale has high organic matter content...Comparative analyses of petroleum generation potential,reservoir volume,frackability,and oil mobility were conducted on 102 shale cores from the Dongpu Depression.Results show the shale has high organic matter contents composed of oil-prone type I and type II kerogens within the oil window.Various types of pores and fractures exist in the shale,with a porosity of up to 14.9%.The shale has high brittle mineral contents,extensive fractures,and high potential for oil mobility due to high seepage capacity and overpressure.Although the petroleum generation potential of the shale at Well PS18-8 is relatively greater than that at Well PS18-1,oil content of the latter is greater due to the greater TOC.The porosity and fracture density observed in Well PS18-1 are greater and more conducive to shale oil enrichment.Although the shales in Wells PS18-1 and PS18-8 have similar brittle mineral contents,the former is more favorable for anthropogenic fracturing due to a higher preexisting fracture density.Besides,the shale at Well PS18-1 has a higher seepage capacity and overpressure and therefore a higher oil mobility.The fracture density and overpressure play key roles in shale oil enrichment.展开更多
A new type of shale oil in alkaline lacustrine sediments has been discovered in the Late Paleozoic Fengcheng Formation,Mahu Sag,Junggar Basin,China.The fine-grained sedimentary rocks deposited in this alkaline lacustr...A new type of shale oil in alkaline lacustrine sediments has been discovered in the Late Paleozoic Fengcheng Formation,Mahu Sag,Junggar Basin,China.The fine-grained sedimentary rocks deposited in this alkaline lacustrine environment can be divided into four types and eight sub-types:mudstone(with no alkali minerals),including massive dolomitic mudstone,and massive and laminated calcareous mudstone;dolomite,including massive argillaceous dolomite(with alkali minerals),and massive and laminated argillaceous dolomite(with no alkali minerals);evaporites;and pyroclastic rocks.The massive argillaceous dolomite(with alkali minerals)and pyroclastic rocks have the highest shale oil potential,with average oil saturation index(OSI)values of 344.67 and 124.65 mg HC/g TOC,respectively.Shale oil exploration in the representative well MY1 indicates that the Fengcheng Formation is thick and contains abundant natural fractures,brittle minerals,and mobile oil.The entire Fengcheng Formation is oilbearing and contains three concentrated stratigraphic intervals of shale oil(i.e.,sweet spots).Well MY1 indicates that,compared with source rocks developed in marine and sulfate-type saline basins,the fine-grained sedimentary rocks deposited in alkaline lacustrine environments can also have high shale oil potential.The co-existence and regular distribution of conventional and unconventional reservoirs in the Fengcheng Formation indicate that it is an ideal exploration target for multiple resource types.展开更多
The Songliao Basin is one of the most important petroliferous basins in northern China. With a recent gradual decline in conventional oil production in the basin, the exploration and development of unconventional reso...The Songliao Basin is one of the most important petroliferous basins in northern China. With a recent gradual decline in conventional oil production in the basin, the exploration and development of unconventional resources are becoming increasingly urgent. The Qingshankou Formation consists of typical Upper Cretaceous continental strata, and represents a promising and practical replacement resource for shale oil in the Songliao Basin. Previous studies have shown that low-mature to mature Qingshankou shale mainly preserves type Ⅰ and type Ⅱ1 organic matter, with relatively high total organic carbon(TOC) content. It is estimated that there is a great potential to explore for shale oil resources in the Qingshankou Formation in this basin. However, not enough systematic research has been conducted on pore characteristics and their main controlling factors in this lacustrine shale reservoir. In this study, 19 Qingshankou shales from two wells drilled in the study area were tested and analyzed for mineral composition, pore distribution and feature evolution using Xray diffraction(XRD), scanning electron microscopy(SEM), low-pressure nitrogen gas adsorption(N2-GA), and thermal simulation experiments. The XRD results show that clay, quartz, and feldspar are the dominant mineral constituents of Qingshankou shale. The clay minerals are mostly illite/smectite mixed layers with a mean content of 83.5%, followed by illite, chlorite, and kaolinite. There are abundant deposits of clay-rich shale in the Qingshankou Formation in the study area, within which many mineral and organic matter pores were observed using SEM. Mineral pores contribute the most to shale porosity;specifically, clay mineral pores and carbonate pores comprise most of the mineral pores in the shale. Among the three types of organic matter pores, type B is more dominant the other two. Pores with diameters greater than 10 nm supply the main pore volume;most are half-open slits and wedge-shaped pores. The total pore volume had no obvious linear relationship with TOC content, but had some degree of positive correlation with the content of quartz + feldspar and clay minerals respectively. However, it was negatively correlated with carbonate mineral content. The specific surface area of the pores is negatively related to TOC content, average pore diameter, and carbonate mineral content. Moreover, it had a somewhat positive correlation with clay mineral content and no clear linear relationship with the content of quartz + feldspar. With increases in maturity, there was also an increase in the number of carbonate mineral dissolution pores and organic matter pores, average pore diameter, and pore volume, whereas there was a decrease in specific surface area of the pores. Generally, the Qingshankou shale is at a low-mature to mature stage with a TOC content of more than 1.0%, and could be as thick as 250 m in the study area. Pores with diameters of more than 10 nm are well-developed in the shale. This research illustrates that there are favorable conditions for shale oil occurrence and enrichment in the Qingshankou shale in the study area.展开更多
Braid-delta depositional systems are widely developed in most continental basins in China. Research indicates that, for different types of braid delta, the facies sequence and association, which are critical to the pr...Braid-delta depositional systems are widely developed in most continental basins in China. Research indicates that, for different types of braid delta, the facies sequence and association, which are critical to the prediction of the distribution of reservoirs, differ greatly. This study illustrates the differences in braid-delta depositional systems in terms of sedimentary characteristics, associated systems and reser- voir distributions using three typical paleodeltas in western China: the Zhenbei delta of the upper Triassic Yanchang Formation in the Ordos Basin, the Yuanba delta of the upper Triassic Xujiahe Formation in the Sichuan Basin and the Jimsar delta of the upper Permian Wutonggou Formation in the Junggar Basin. A stratigraphic framework was established using seismic data, logs and cores by choosing stable mud sections as regional correlation markers and, topographies of these deltas were reconstructed based on the decompaction and paleobathymetric corrections. Based on both the paleotopography of these deltas and the differences of their sedimentary facies, these braided deltas can be classified into two systems: steep-gradient braid-delta-turbidite system and low-gradient braid-delta-lacustrine system. Moreover, the low-gradient braid-delta-lacustrine system can be further divided into interfingered and sharp contact sub-types according to the contact relation between the delta sands and lacustrine muds. This study shows that the paleotopography of basin margins strongly controls the accommodation as braid deltas prograde into lacustrine basins and, influences the location of the shoreline in response to changes in the lake level. Furthermore, paleotopography plays a significant role in facies and reservoir distribution which is important for petroleum exploration and development.展开更多
Carbonate concretions are conspicuous in organic-rich shales and are generally related to decomposition of organic matter.The black shales from the Chang 7 Member of the Upper Triassic Yanchang Formation of the southe...Carbonate concretions are conspicuous in organic-rich shales and are generally related to decomposition of organic matter.The black shales from the Chang 7 Member of the Upper Triassic Yanchang Formation of the southern Ordos Basin host abundant carbonate concretions,which provide a unique record of depositional and early diagenetic conditions of the paleo-lake sediments.However,little attention has been given to the genesis and growth processes of the concretions in these lacustrine petroleum source rocks.New petrographic observations and geochemical analysis show that the concretions are composed of calcite,phosphate fossil fragments,K-NH4-feldspar,quartz,bitumen,and minor Fe-dolomite.Phosphate minerals,mainly carbonate fluorapatite(CFA),show pervasive replacement by calcite,most of which contains phosphorus,ranging in concentration from 0.26 to 2.35 wt%.This suggests that the phosphate minerals are the precursors for concretion growth.Positiveδ13C(+5.6 to+12.4‰V-PDB)signatures and the absence of pyrite indicate that microbial methanogenesis was the dominant driver for concretion growth,rather than bacterial sulfate reduction.Quartz,bitumen,and Fe-dolomite are the last cements that occurred,at deep burial depths and high temperatures.The formation of phosphate minerals might have been induced by upwelling of phosphate-enriched deep water in the Late Triassic paleo-lake,which promoted phytoplankton blooms and further enrichment of organic matter.Extremely slow sedimentation rates of fine-grained detrital minerals,relative to dead organism accumulation,led to the high permeabilities of the organic-rich sediments and rapid concretion growth during shallow burial.The close association of phosphate-bearing carbonate concretions and organic-rich shales reflects that upwelling played a critical role in the formation of the high-quality petroleum source rocks in the Triassic paleo-Ordos lake.展开更多
文摘Siderite is a prevalent authigenic mineral in siliciclastic rocks, which usually occurred in eodiagensis period and could be used as an indicator of sedimentary environment. Some siderite precipitated in burial depth with geochemical information of basin fluid evolution. The crystal morphology, geochemical composition, and isotope values are influenced by physical and geochemical environment of precipitation. In this study, samples from the Early Cretaceous of Erlian basin in the northwestern China were collected, and mineralogy, bulk and in-situ geochemistry, C and O isotopes were analyzed to comprehensively investigate the sedimentary and diagenetic environment that the sediments experienced. Six lithofaices with three types of crystal habits were recognized in the siderite-rich sandstone, bundle crystal in spherical forms, blocky rhombs in intergranular pore and cleavage of muscovite, and micro bundle and mosaic crystals aggregates in nodular. The siderite growth proceeds through micro bundle and mosaic crystals to bundle siderite aggregates and then into blocky rhombs. The crystal evolution is also reflected by geochemical composition. The micro bundle and mosaic crystals are Casiderite. The spheritic shaped bundle aggregates are Ca-Mn-siderite. The blocky rhomb siderite shows gray part and bight part with Ca, Mg and Mn varies. Increase of Ca in block rhomb siderite suggests burial and mesodiagenesis, the high content of Mn may have linkage with eogenetic effects. The relatively positive and slightly negative δ13C value indicates meteoric water domination and influence of organic matter evolution in shallow buried time. The narrow ranges negative δ18O value suggest a small span of temperature of siderite formation.
基金Supported by the National Natural Science Foundation of China (41790453,41972313)。
文摘The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofacies of subaqueous eruptive pyroclastic rocks is discussed and the facies model is established by taking the tuff cone of Cretaceous Huoshiling Formation in the Chaganhua area of the Changling fault depression,Songliao Basin as the research object.The results indicate that the subaqueous eruptive pyroclastic rocks in the Songliao Basin can be divided into two facies and four subfacies.The two facies are the subaqueous explosive facies and the volcanic sedimentary facies that is formed during the eruption interval.The subaqueous explosive facies can be further divided into three subfacies:gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies.The volcanic sedimentary facies consists of pyroclastic sedimentary rocks containing terrigenous clast subfacies.A typical facies model of the tuff cone that is formed by subaqueous eruptions in the Songliao Basin was established.The tuff cone is generally composed of multiple subaqueous eruption depositional units and can be divided into two facies associations:near-source facies association and far-source facies association.The complete vertical succession of one depositional unit of the near-source facies association is composed of pyroclastic sedimentary rocks containing terrigenous clast subfacies,gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies from bottom to top.The depositional unit of the far-source facies association is dominated by the subaqueous fallout subfacies and contains several thin interlayered deposits of the water-laid density current subfacies.The gas-supported hot pyroclastic flow subfacies and the pyroclastic sedimentary rocks containing terrigenous clast subfacies are favorable subaqueous eruptive facies for reservoirs in continental lacustrine basins.
基金supported by the National Science Foundation of China(Grant Nos.41972099,4217020246)the National Science and Technology Major of China(Grant Nos.2017ZX05009-002,2017ZX05072-002)。
文摘Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin,China.The insufficient understanding of their sedimentary processes,depositional patterns,and controlling factors restricts efficient exploration and development.Coarse-grained subaqueous fans in the Yong′an area,Dongying Depression,are investigated in this study.These fans include nearshore subaqueous fans,and sublacustrine fans,and their sedimentary processes,depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology.Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence.Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction.While the topography was gentle,sublacustrine fans did not develop.During the late weak tectonic activity stage,late sublacustrine fans developed with multiple stages superimposed.Frequent fault activity and related earthquakes steepened the basin margin,and the boundary fault slopes were 25.9°–34°.During the early–middle deposition stage,hyperpycnal flows triggered by outburst floods developed.During the late deposition stage,with weak tectonic activity,seasonal floods triggered hyperpycnal flows,and hybrid event beds developed distally.
基金supported by the Natural Science Foundation of China(No.41902045,41702249)the Strategic Priority Research Program of the Chinese Academy of Sciences,Grant No.XDA14010401.
文摘Through the long development processes of reservoir sedimentation and diagenesis, acidic and alkaline fluids play key roles in controlling deep reservoir development. However, the ways in which deep fluids control and transform the reservoir under complex fault conditions remain unclear. In this study, a 2D model was established based on a typical sub-salt to intra-salt vertical profile in the Qaidam Basin, China. Based on measured data, multiphase flow reaction and solute transport simulation technology were used to analyze fluids flow and migration in the intra-salt and sub-salt reservoirs, determine the mineral dissolution, precipitation, and transformation in the reservoir caused by the deep fluids, and calculate the changes in reservoir porosity. Results show that deep fluid migrates preferentially along dominant channels and triggers a series of fluid–rock chemical reactions. In the first stage, a large amount of anhydrite precipitated in the fault as a result of upward migration of deep saline fluid, resulting in the formation of anhydrite veins and blockage at the base of the fault. In the second stage, organic acids caused minerals dissolution and a vertical channel was opened in previously blocked area, which promoted continuous upward migration of organic acids and the formation of secondary pores. This study clarifies the transformative effects of deep alkaline and acidic fluids on the reservoir. Moreover, the important fluid transport role of faults and their effect on reservoir development were determined.
文摘Typical reefs in the Paleogene and early Neogene strata of the Qaidam Basin, Tibetan Plateau, China, reveal their internal structures and sedimentation environments and consist mainly of algal reef, stromatolite reef and thrombolite reef with distinct reef structures, fore-reef, back-reef and reef-plateau. The fore-reef is characterized by a combination of pinnacle reef, thrombolite and algal reef. The back reef is composed of stromatolite reef and algal reef. The pinnacle reefs (micro-atoll), most of which are several tens of centimeters in diameter (whereas some exceptionally big ones are over 200 cm in diameter), and several tens of centimeter to 2 m in height, are situated on the far front-edge of the reef; the pinnacle reef is also often of recumbent form with a gravel-filled circular hole in the center. The algal reef is in the form of dome and irregular beds, and filled with algal detritus, ostracodes, spirorbis fossils, ooid and terrigenous debris, and worm traces; cavities and scour marks are often developed. The algal reef is gray commonly when fresh and weathers to a brown color. The lacustrine thrombolite in the Qaidam Basin is light gray or deep gray when fresh, white-gray or brown when weathered, dense and homogeneous with abundant pores filled by oil and bitumen. Observed under the microscope, the thrombolite consists mainly of brown or brown-black clots with a little algal debris, ooid, pellet, ostracodes, spirorbis fossils and terrigenous debris, in some cases, terrigenous debris, even gravel, is abundant. Many features of the thrombolite suggest that it is formed in a high-energy envkonment. The stromatolite reefs developed on the lacustrine algal reef in the Qaidam Basin are very complex whether in shape or in internal structure. The simplest ones form laminated layers and the most complex ones have intensely branching structures. The size is also variable.
文摘Based on the studies of the Songliao Basin characterized by Cretaceous down-warping, of the Jurassic compressional flexural Junggar basin and of the Bohai Bay Basin characterized by Paleogene rifting, the multiple-grades slope break has developed in lacustrine basins of different origins. Their genetic types can be divided into tectonic slope break, depositional slope break and erodent slope break. The dominant agent of the slope break is tectogenesis, and the scale of slope breaks relates with the size of tectogenesis. The results of the study show that control of mutual grades slope breaks on atectonic traps mainly represent: 1) Atectonic traps develop close to mutual grades slope breaks, with beads-shaped distribution along the slope breaks. 2) In the longitudinal direction, the development of atectonic traps is characterized by the inheritance. 3) Different slope breaks and their different geographical positions can lead to different development types of atectonic traps. 4) A slope break can form different kinds of atectonic traps because of its great lateral variation. 5) The existence of mutual-grade slope breaks leads to different responses of erosion and deposition at different geographical positions in the basin. The oil source bed, reservoir and cap rock combination of atectonic traps is fine. 6) The oil-bearing condition of atectonic traps controlled by slope breaks is very favorable.
基金jointly supported by grants from the Natural Science Foundation of China(grants No.41402110 and 41330313)“Fundamental Research Funds for the Central Universities”(grants No.14CX05017A and 13CX05013A)
文摘Lacustrine shale from the Qingshankou Formatin of Songliao basin and the Shahejie Formation of Bohai Bay basin, and marine shale from the lower Cambrian Jinmenchong Formation of Qiannan depression were analysed by using rock pyrolysis, TOC (total organic carbon), XRD (X-ray diffraction), SEM (scanning electron microscope), FE-SEM (field emission scanning electron microscope), high pressure mercury intrusion, and low pressure N2 and CO2 gas adsorption experiments, in aim to reveal their reservoir features. The results show that: (1) the width of micro-pores of all the studied samples mainly ranges from 0.45 to 0.7 nm indicated by CO2 isotherms, and the width of meso-pores is less than 10 nm, with type IV adsorption isotherms and type H2 hysteresis loop, indicative of "ink-bottle"-shaped pores. Good correlations exist among pore volume, surface area and averaged pore diameter, and a good positive correlation exists between micro-pore volume and TOC content; however, there is no obvious correlation between meso-pore volume and TOC content; (2) interparticle pores, pores among the edge of mineral grains and organic matter pores were all identified in marine and lacustrine shale, among which the interparticle pores may be influence by dissolution effect. Not all bitumen develops organic matter pore, and only high to over mature bitumen present pores. Now the description methods of micrometer scale pores developed in shale are very lack. Micro- fractures developed in Jiyang depression and dissolution interparticle pores developed in Songliao Basin should be the accumulation sites for shale oil in lacustrine shale, and can be as sweet spots.
基金co-funded by the National Natural Science Foundation of China (41102058)the National Science and Technology Special Grant (2011ZX05006-003)the Fundamental Research Funds for the Central Universities (12CX04001A)
文摘Diagenetic traps in conglomerate in nearshore subaqueous fans in the steep slope zones of rift basins have been important exploration targets for subtle reservoirs in eastern China. However, the mechanism of how those traps were formed is not clear, which inhibits further exploration for this type of reservoir. In order to solve the problem, we take as an example nearshore subaqueous fans in the upper part of the fourth member of the Shahejie Formation (Es4s) on the north slope of the Minfeng Subsag in the Dongying Sag. Combining different research methods, such as core observation, thin section examination, scanning electron microscope (SEM) observation, fluid-inclusion analysis, carbon and oxygen isotope analysis of carbonate cements, and analysis of core properties, we studied the genetic mechanisms of diagenetic traps on the basis of diagenetic environment evolution and diagenetic evolution sequence in different sub/micro-facies. Conglomerate in Es4s in the north Minfeng Subsag experienced several periods of transition between alkaline and acidic environments as "alkaline-acidic-alkaline-acidic-weak alkaline". As a result, dissolution and cementation are also very complex, and the sequence is "early pyrite cementation / siderite cementation / gypsum cementation / calcite and dolomite cementation- feldspar dissolution / quartz overgrowth quartz dissolution / ferroan calcite cementation / ankerite cementation / lime-mud matrix recrystallization / feldspar overgrowth carbonate dissolution / feldspar dissolution / quartz overgrowth / pyrite cementation". The difference in sedimentary characteristics between different sub/micro-facies of nearshore subaqueous fans controls diagenetic characteristics. Inner fan conglomerates mainly experienced compaction and lime-mud matrix recrystallization, with weak dissolution, which led to a reduction in the porosity and permeability crucial to reservoir formation. Lime-mud matrix recrystallization results in a rapid decrease in porosity and permeability in inner fan conglomerates in middle-to-deep layers. Because acid dissolution reworks reservoirs and hydrocarbon filling inhibits cementation, reservoirs far from mudstone layers in middle fan braided channels develop a great number of primary pores and secondary pores, and are good enough to be effective reservoirs of hydrocarbon. With the increase of burial depth, both the decrease of porosity and permeability of inner fan conglomerates and the increase of the physical property difference between inner fans and middle fans enhance the quality of seals in middle-to-deep layers. As a result, inner fan conglomerates can be sealing layers in middle-to-deep buried layers. Reservoirs adjacent to mudstones in middle fan braided channels and reservoirs in middle fan interdistributaries experienced extensive cementation, and tight cemented crusts formed at both the top and bottom of conglomerates, which can then act as cap rocks. In conclusion, diagenetic traps in conglomerates of nearshore subaqueous fans could be developed with inner fan conglomerates as lateral or vertical sealing layers, tight carbonate crusts near mudstone layers in middle fan braided channels as well as lacustrine mudstones as cap rocks, and conglomerates far from mudstone layers in middle fan braided channels as reservoirs. Lime-mud matrix recrystallization of inner fan conglomerates and carbonate cementation of conglomerates adjacent to mudstone layers in middle fan braided channels took place from 32 Ma B.R to 24.6 Ma B.P., thus the formation of diagenetic traps was from 32 Ma B.R to 24.6 Ma B.R and diagenetic traps have a better hydrocarbon sealing ability from 24 Ma B.P.. The sealing ability of inner fans gradually increases with the increase of burial depth and diagenetic traps buried more than 3,200 m have better seals.
基金funded by the National Science Foundation of China(41502144,41503034)the Foundation of the State Key Laboratory of Petroleum Resources and Prospecting,China University of Petroleum,Beijing(No.PRP/open-1612)+2 种基金the Fund of the Education Department of Sichuan Province(16ZA0075)the Youth Scientific Innovation Team of Hydrocarbon Accumulation and Geochemistry,Southwest Petroleum University(2015CXTD02)the Sichuan Province University Scientific Innovation Team Construction Project(USITCP)
文摘To investigate the influence of extractable organic matter (EOM) on pore evolution of lacustrine shales, Soxhlet extraction, using dichloromethane, was performed on a series of Chang 7 shale samples (Ordos Basin, China) with vitrinite reflectance of 0.64% to 1.34%. Low-pressure gas adsorption experiments were conducted on the samples before and after extraction. The pore structure parameters were calculated from the gas adsorption data. The results show complex changes to the pore volumes and surface areas after extraction. The pore development of both the initial and extracted samples is strongly controlled by total organic carbon (TOC) content. Micropores developed mainly in organic matter (OM), while mesopores and macropores predominantly developed in fractions other than OM. The influence of EOM on micropores is stronger than on mesopores and macropores. Organic solvents with a higher boiling point should be used to explore the effect of EOM on pore structure in the future.
文摘Pore structure plays an important role in the gas storage and flow capacity of shale gas reservoirs. Fieldemission environmental scanning electron microscopy(FE-SEM) in combination with low-pressure carbon dioxide gas adsorption(CO2GA),nitrogen gas adsorption(N2GA),and high-pressure mercury intrusion(HPMI) were used to study the nanostructure pore morphology and pore-size distributions(PSDs) of lacustrine shale from the Upper Triassic Yanchang Formation,Ordos Basin. Results show that the pores in the shale reservoirs are generally nanoscale and can be classified into four types: organic,interparticle,intraparticle,and microfracture. The interparticle pores between clay particles and organic-matter pores develop most often,l with pore sizes that vary from several to more than 100 nm. Mercury porosimetry analysis shows total porosities ranging between 1.93 and 7.68%,with a mean value of 5.27%. The BET surface areas as determined by N2 adsorption in the nine samples range from 10 to 20 m2/g and the CO2 equivalent surface areas(2 nm)vary from 18 to 71 m2/g. Together,the HPMI,N2 GA,and CO2 GA curves indicate that the pore volumes are mainly due to pores 100 nm in size. In contrast,however,most of the specific surface areas are provided by the micropores. The total organic carbon(TOC) and clay minerals are the primary controls of the structures of nanoscale pores(especially micropores and mesopores). Micropores are predominantly determined by the content of the TOC,and mesopores are possibly related to the content of clay minerals,particularly the illite-montmorillonite mixed-layer content.
基金supported by the National Natural Science Foundation of China(Grant No.41706063)the Basic Scientific Fund for National Public Research Institute of China(Grant No.2017Q08)the China Postdoctoral Science Foundation(Grant No.2016M602087)
文摘The Shan 2 Member, Shan 1 Member and He 8 Member of the Mid-Late Permian Shanxi and lower Xiashihezi formations, in the southeastern Ordos Basin, together comprise -150 m of deltaic deposits. This sequence records an overall evolution from deep marine environment to shallow lake associated with braided river, braided river delta and meandering river delta. Core description, well log interpretation, and stable isotope analysis, including carbon, oxygen and strontium, were conducted to understand the sedimentary evolution of Shan 2 to He 8 Member. The Shanxi Formation, which consists of the Shan 2 and Shan 1 members, is characterized by a tidal-influenced meandering river delta environment and a higher j13C value and S7Sr/S6Sr ratio and a lower jlSo value. The He 8 Member, the basal part of the Xiashihezi Formation, is featured by a braided river to braided river delta system and a lower j13C value, S7Sr/S6Sr ratio, and a higher jlSo value. Four third-order depositional sequences separated by five sequence boundaries are determined. Coarsening upward sequences of the Shan 2 Member-He 8 Member indicate a general regression trend, which can be correlated to global sea-level fall occurring during the Roadian-Wuchiapingian, as also evidenced by previous published zircon U-Pb results. The coal-bearing sequence (Shanxi Formation) to non-coal-bearing sequence (He 8 Member), as well as a decrease of 87Sr/86Sr, suggest a trend from humid to arid climates. A combined effect of sea-level drop and a small uplift at the end of Shanxi Formation are proposed.
基金These research results are part of a key international cooperation project carried out during 2003 and 2005 and financially supported by SINOPEC.
文摘In recent years, with the development of terrestrial sequence stratigraphy, more attention has been focused on the study of the terrestrial lacustrine sequence stratigraphic model globally. Different viewpoints are preferred by researchers. Under the guidance of the theory of sequence stratigraphy, the findings of this paper indicate that climate is a major factor controlling the formation of the fourth-order sequence, based upon the study of the sequence stratigraphy in the Green River Formation of the Uinta basin in the USA. It also divides the fourth-order sequence in the terrestrial lacustrine basin into two system tracts: the wet (rising) half-cycle and the dry (falling) half- cycle, establishing a new-style fourth-order sequence stratigraphic model for the terrestrial lacustrine basin, that is, the climate-genetic sequence stratigraphic model. As a result, the theory of sequence stratigraphy is greatly enriched.
文摘Three types of turbidites are identified in the studied area, including proximal turbidite along the northern steep slope (alluvial fans, fan delta, and subaqueous fans via short-distance transportation), distal turbidites along the southern gentle slope (stacked sliding of delta and fan delta front), and fluxoturbidite in the central depression. Detailed studies of several case histories and the relationship between sedimentary facies and faults suggest a significant role of tectonic setting and faults in the development of turbidite, which created source areas, effected slope topography, controlled the climate and paleo-environment, and formed enough slope angle and slope break for sedimentary instabilities and massive block movement to form turbidite. According to statistics, 0.86%, with an average value of 40.3%, of the trap volumes in the 69 identified Tertiary lacustrine turbidites in the Jiyang Superdepression in the Bohai Bay Basin are filled with oil. The porosity and permeability of turbidite sands vary widely. The productive reservoirs are generally those from the braided channels of both distal and proximal turbidite, and from the main channel of proximal turbidite, with a low carbonate content and the porosity and permeability higher than 12% and 1 mD respectively. Most of the lithologic oil pools in the Jiyang Superdepression are enveloped by the effective source rocks, and the percentage of the trap volume generally increases with the hydrocarbon expulsion intensity of source rocks. This is in contrast with structural-lithologic traps (i.e. proximal turbidite along the steep slope and distal turbidite along the gentle slope), in which, graben-boundary faults play an important role in oil migration, as the turbidites are not in direct contact with effective hydrocarbon source rocks.
基金financially supported by the National Natural Science Foundation of China (grant No. 41702171)a National Science and Technology Major Project (grant No. 2016ZX05034002)
文摘Micropores of shale are significant to the gas content and production potential of shale, which has been verified in the research of marine shale gas; while, few studies have been conducted on lacustrine shales. This study collected 42 samples from three wells in the Late Cretaceous Qingshankou Formation of the southern Songliao Basin, NE China, and investigated these samples by the focused ion beam-scanning electron microscope(FIB–SEM) and nitrogen adsorption analysis techniques. Four types of micropores were identified in the samples, i.e., intergranular pore, intracellular pore, organic matter pore and microfracture. The pore structure type is characterized by open slit pores and "ink type" pores which are mainly 1.5–5 nm in diameter with mesopores as the main pores. The mesopores account for 74.01% of the pore volume and 54.68% of the pore surface area. Compared with the lacustrine shales from the Triassic Yanchang Formation in the Ordos Basin and Xujiahe Formation in the Sichuan Basin, the intergranular clay mineral interlayer pores are considered to be the main reservoir space for shale gas storage in the study area, followed by intraparticle pores, organic matter pores and microfractures. Maturity and micropore are the key controlling factors which affect the shale gas content of the Qingshankou Formation in southern Songliao Basin.
基金supported by the National Basic Research Program of China (Grant No. 2014CB239002)Natural Science Foundation of Shandong Province, China (Grant No. ZR2014DQ016)
文摘The genesis of the fine crystalline dolomites that exhibit good to excellent reservoir properties in the upper fourth member of the Eocene Shahejie Formation(Es4s)around the Sikou Sag, Bohai Bay Basin, is uncertain. This paper investigates the formation mechanisms of this fine crystalline dolomite using XRD, SEM, thin section analysis and geochemical data. The stratigraphy of the Sikou lacustrine carbonate is dominated by the repetition of metre-scale, high-frequency deposition cycles, and the amount of dolomite within a cycle increases upward from the cycle bottom. These dolomite crystals are 2–30 μm in length, subhedral to anhedral in shape and typically replace both grains and matrix. They also occur as rim cement and have thin lamellae within ooid cortices. Textural relations indicate that the dolomite predates equant sparry calcite cement and coarse calcite cement. The Sr concentrations of dolomites range from 900 to 1200 ppm. Dolomite δ18O values(-11.3 to-8.2 ‰ PDB) are depleted relative to calcite mudstone(-8.3 to-5.4 ‰ PDB) that precipitated from lake water, while δ13C values(0.06–1.74 ‰ PDB) are within the normal range of calcite mudstone values(-2.13 to 1.99 ‰ PDB). High87Sr/86Sr values(0.710210–0.710844) indicate that amounts of Ca2+ and Mg2+have been derived from the chemical weathering of Palaeozoic carbonate bedrocks. The high strontium concentration indicates that hypersaline conditions were maintainedduring the formation of the dolomites and that the dolomites were formed by the replacement of precursor calcite or by direct precipitation.
基金This study was fnancially supported by the China Postdoctoral Science Foundation(2019M660054)Science Foundation of China University of Petroleum(Beijing)(2462019BJRC005)+3 种基金Strategic Cooperation Technology Projects of CNPC and CUPB(ZLZX2020-01-05)Natural Science Foundation of China(41872148,41872128)NSFC Basic Research Program on Deep Petroleum Resource Accumulation and Key Engineering Technologies(U19B6003-02)the Science Projects of the Sinopec Zhongyuan Oilfeld Company(P15022).
文摘Comparative analyses of petroleum generation potential,reservoir volume,frackability,and oil mobility were conducted on 102 shale cores from the Dongpu Depression.Results show the shale has high organic matter contents composed of oil-prone type I and type II kerogens within the oil window.Various types of pores and fractures exist in the shale,with a porosity of up to 14.9%.The shale has high brittle mineral contents,extensive fractures,and high potential for oil mobility due to high seepage capacity and overpressure.Although the petroleum generation potential of the shale at Well PS18-8 is relatively greater than that at Well PS18-1,oil content of the latter is greater due to the greater TOC.The porosity and fracture density observed in Well PS18-1 are greater and more conducive to shale oil enrichment.Although the shales in Wells PS18-1 and PS18-8 have similar brittle mineral contents,the former is more favorable for anthropogenic fracturing due to a higher preexisting fracture density.Besides,the shale at Well PS18-1 has a higher seepage capacity and overpressure and therefore a higher oil mobility.The fracture density and overpressure play key roles in shale oil enrichment.
基金funded by PetroChina Science and Technology Major Project(Grant No.2019E-2602)。
文摘A new type of shale oil in alkaline lacustrine sediments has been discovered in the Late Paleozoic Fengcheng Formation,Mahu Sag,Junggar Basin,China.The fine-grained sedimentary rocks deposited in this alkaline lacustrine environment can be divided into four types and eight sub-types:mudstone(with no alkali minerals),including massive dolomitic mudstone,and massive and laminated calcareous mudstone;dolomite,including massive argillaceous dolomite(with alkali minerals),and massive and laminated argillaceous dolomite(with no alkali minerals);evaporites;and pyroclastic rocks.The massive argillaceous dolomite(with alkali minerals)and pyroclastic rocks have the highest shale oil potential,with average oil saturation index(OSI)values of 344.67 and 124.65 mg HC/g TOC,respectively.Shale oil exploration in the representative well MY1 indicates that the Fengcheng Formation is thick and contains abundant natural fractures,brittle minerals,and mobile oil.The entire Fengcheng Formation is oilbearing and contains three concentrated stratigraphic intervals of shale oil(i.e.,sweet spots).Well MY1 indicates that,compared with source rocks developed in marine and sulfate-type saline basins,the fine-grained sedimentary rocks deposited in alkaline lacustrine environments can also have high shale oil potential.The co-existence and regular distribution of conventional and unconventional reservoirs in the Fengcheng Formation indicate that it is an ideal exploration target for multiple resource types.
基金financial support of Special Scientific Research Project of Public Welfare Industry of Ministry of Land and Resources (Grant No.20121111051)the National Natural Science Foundation of China (Grant No.41272159 and 41572099)+1 种基金supported by Anhui Provincial Natural Science Foundation (Grant No.1908085MD105)China Postdoctoral Science Foundation funded project (Grant No.2019M662200).
文摘The Songliao Basin is one of the most important petroliferous basins in northern China. With a recent gradual decline in conventional oil production in the basin, the exploration and development of unconventional resources are becoming increasingly urgent. The Qingshankou Formation consists of typical Upper Cretaceous continental strata, and represents a promising and practical replacement resource for shale oil in the Songliao Basin. Previous studies have shown that low-mature to mature Qingshankou shale mainly preserves type Ⅰ and type Ⅱ1 organic matter, with relatively high total organic carbon(TOC) content. It is estimated that there is a great potential to explore for shale oil resources in the Qingshankou Formation in this basin. However, not enough systematic research has been conducted on pore characteristics and their main controlling factors in this lacustrine shale reservoir. In this study, 19 Qingshankou shales from two wells drilled in the study area were tested and analyzed for mineral composition, pore distribution and feature evolution using Xray diffraction(XRD), scanning electron microscopy(SEM), low-pressure nitrogen gas adsorption(N2-GA), and thermal simulation experiments. The XRD results show that clay, quartz, and feldspar are the dominant mineral constituents of Qingshankou shale. The clay minerals are mostly illite/smectite mixed layers with a mean content of 83.5%, followed by illite, chlorite, and kaolinite. There are abundant deposits of clay-rich shale in the Qingshankou Formation in the study area, within which many mineral and organic matter pores were observed using SEM. Mineral pores contribute the most to shale porosity;specifically, clay mineral pores and carbonate pores comprise most of the mineral pores in the shale. Among the three types of organic matter pores, type B is more dominant the other two. Pores with diameters greater than 10 nm supply the main pore volume;most are half-open slits and wedge-shaped pores. The total pore volume had no obvious linear relationship with TOC content, but had some degree of positive correlation with the content of quartz + feldspar and clay minerals respectively. However, it was negatively correlated with carbonate mineral content. The specific surface area of the pores is negatively related to TOC content, average pore diameter, and carbonate mineral content. Moreover, it had a somewhat positive correlation with clay mineral content and no clear linear relationship with the content of quartz + feldspar. With increases in maturity, there was also an increase in the number of carbonate mineral dissolution pores and organic matter pores, average pore diameter, and pore volume, whereas there was a decrease in specific surface area of the pores. Generally, the Qingshankou shale is at a low-mature to mature stage with a TOC content of more than 1.0%, and could be as thick as 250 m in the study area. Pores with diameters of more than 10 nm are well-developed in the shale. This research illustrates that there are favorable conditions for shale oil occurrence and enrichment in the Qingshankou shale in the study area.
文摘Braid-delta depositional systems are widely developed in most continental basins in China. Research indicates that, for different types of braid delta, the facies sequence and association, which are critical to the prediction of the distribution of reservoirs, differ greatly. This study illustrates the differences in braid-delta depositional systems in terms of sedimentary characteristics, associated systems and reser- voir distributions using three typical paleodeltas in western China: the Zhenbei delta of the upper Triassic Yanchang Formation in the Ordos Basin, the Yuanba delta of the upper Triassic Xujiahe Formation in the Sichuan Basin and the Jimsar delta of the upper Permian Wutonggou Formation in the Junggar Basin. A stratigraphic framework was established using seismic data, logs and cores by choosing stable mud sections as regional correlation markers and, topographies of these deltas were reconstructed based on the decompaction and paleobathymetric corrections. Based on both the paleotopography of these deltas and the differences of their sedimentary facies, these braided deltas can be classified into two systems: steep-gradient braid-delta-turbidite system and low-gradient braid-delta-lacustrine system. Moreover, the low-gradient braid-delta-lacustrine system can be further divided into interfingered and sharp contact sub-types according to the contact relation between the delta sands and lacustrine muds. This study shows that the paleotopography of basin margins strongly controls the accommodation as braid deltas prograde into lacustrine basins and, influences the location of the shoreline in response to changes in the lake level. Furthermore, paleotopography plays a significant role in facies and reservoir distribution which is important for petroleum exploration and development.
基金This work was supported by the National Natural Science Foundation of China(Program No.41330315)the Natural Science Foundation of Shaanxi Province(Program No.2020JQ-766)+1 种基金the Scientific Research Program Funded by Shaanxi Provincial Education Department(Program No.20JK0838)the Opening Foundation of Shandong Key Laboratory of Depositional Mineralization&Sedimentary Mineral,Shandong University of Science and Technology(Program No.DMSM20190034).
文摘Carbonate concretions are conspicuous in organic-rich shales and are generally related to decomposition of organic matter.The black shales from the Chang 7 Member of the Upper Triassic Yanchang Formation of the southern Ordos Basin host abundant carbonate concretions,which provide a unique record of depositional and early diagenetic conditions of the paleo-lake sediments.However,little attention has been given to the genesis and growth processes of the concretions in these lacustrine petroleum source rocks.New petrographic observations and geochemical analysis show that the concretions are composed of calcite,phosphate fossil fragments,K-NH4-feldspar,quartz,bitumen,and minor Fe-dolomite.Phosphate minerals,mainly carbonate fluorapatite(CFA),show pervasive replacement by calcite,most of which contains phosphorus,ranging in concentration from 0.26 to 2.35 wt%.This suggests that the phosphate minerals are the precursors for concretion growth.Positiveδ13C(+5.6 to+12.4‰V-PDB)signatures and the absence of pyrite indicate that microbial methanogenesis was the dominant driver for concretion growth,rather than bacterial sulfate reduction.Quartz,bitumen,and Fe-dolomite are the last cements that occurred,at deep burial depths and high temperatures.The formation of phosphate minerals might have been induced by upwelling of phosphate-enriched deep water in the Late Triassic paleo-lake,which promoted phytoplankton blooms and further enrichment of organic matter.Extremely slow sedimentation rates of fine-grained detrital minerals,relative to dead organism accumulation,led to the high permeabilities of the organic-rich sediments and rapid concretion growth during shallow burial.The close association of phosphate-bearing carbonate concretions and organic-rich shales reflects that upwelling played a critical role in the formation of the high-quality petroleum source rocks in the Triassic paleo-Ordos lake.