To optimize the existing slurry for abrasive-free polishing(AFP)of hard disk substrate,a water-soluble free radical initiator,2,2-azobis[2-(2-imidazolin-2-yl)propane]dihydrochloride(AIBI)is introduced to the H2O2-base...To optimize the existing slurry for abrasive-free polishing(AFP)of hard disk substrate,a water-soluble free radical initiator,2,2-azobis[2-(2-imidazolin-2-yl)propane]dihydrochloride(AIBI)is introduced to the H2O2-based slurry.The polishing results show that,the material removal rate(MRR)of hard disk substrate polished with H2O2-based slurry containing AIBI is obviously higher than that without AIBI.The acting mechanism of the improved MRR is investigated.Electron paramagnetic resonances tests show that,by comparison with H2O2 slurry,H2O2-AIBI slurry provides higher concentration of hydroxyl radicals.Auger electron spectrometer analyses further demonstrate that the oxidation ability of H2O2-AIBI slurry is much greater than H2O2 slurry.In addition,potentiodynamic polarization tests show that the corrosion dissolution rate of hard disk substrate in H2O2-AIBI slurry is increased.Therefore that stronger oxidation ability and a higher corrosion dissolution rate of H2O2-AIBI slurry lead to higher MRR can be concluded.展开更多
The microstructures of electroformed copper liners of shaped charges that had undergone high-strain-rate deformation were observed by optical microscopy （OM） and scanning electron microscopy （SEM）. Meanwhile, the ...The microstructures of electroformed copper liners of shaped charges that had undergone high-strain-rate deformation were observed by optical microscopy （OM） and scanning electron microscopy （SEM）. Meanwhile, the orientation distribution of the grains in the recovered jet was examined by electron backscattering Kikuchi pattern （EBSP） technique. EBSP analysis reveals that the fibrous texture observed in the as-electroformed copper liners disappeared after explosive detonation deformation. OM observation shows that the microstructure evolves system- atically from the jet center to its perimeter during cooling from high temperatures after explosive detonation deformation. This microstructural characteristic is similar to that of solidification, i.e. there exist equiaxed grains in the center of the jet and significant columnar grains around the equiaxed grains. The result reveals that there is melting-related phenomenon in the jet center. Corresponding microhardness variations from the jet center to its perimeter is also determined. All the phenomena can be explained by a strong gradient of temperature across the section of the jet during plastic deformation at high-strain-rate.展开更多
基金Project supported by the National Natural Science Foundation of China(51175317)the Doctoral Program of Higher Education of China(20123108110016)
文摘To optimize the existing slurry for abrasive-free polishing(AFP)of hard disk substrate,a water-soluble free radical initiator,2,2-azobis[2-(2-imidazolin-2-yl)propane]dihydrochloride(AIBI)is introduced to the H2O2-based slurry.The polishing results show that,the material removal rate(MRR)of hard disk substrate polished with H2O2-based slurry containing AIBI is obviously higher than that without AIBI.The acting mechanism of the improved MRR is investigated.Electron paramagnetic resonances tests show that,by comparison with H2O2 slurry,H2O2-AIBI slurry provides higher concentration of hydroxyl radicals.Auger electron spectrometer analyses further demonstrate that the oxidation ability of H2O2-AIBI slurry is much greater than H2O2 slurry.In addition,potentiodynamic polarization tests show that the corrosion dissolution rate of hard disk substrate in H2O2-AIBI slurry is increased.Therefore that stronger oxidation ability and a higher corrosion dissolution rate of H2O2-AIBI slurry lead to higher MRR can be concluded.
文摘The microstructures of electroformed copper liners of shaped charges that had undergone high-strain-rate deformation were observed by optical microscopy （OM） and scanning electron microscopy （SEM）. Meanwhile, the orientation distribution of the grains in the recovered jet was examined by electron backscattering Kikuchi pattern （EBSP） technique. EBSP analysis reveals that the fibrous texture observed in the as-electroformed copper liners disappeared after explosive detonation deformation. OM observation shows that the microstructure evolves system- atically from the jet center to its perimeter during cooling from high temperatures after explosive detonation deformation. This microstructural characteristic is similar to that of solidification, i.e. there exist equiaxed grains in the center of the jet and significant columnar grains around the equiaxed grains. The result reveals that there is melting-related phenomenon in the jet center. Corresponding microhardness variations from the jet center to its perimeter is also determined. All the phenomena can be explained by a strong gradient of temperature across the section of the jet during plastic deformation at high-strain-rate.
