A local composition expression has been derived from the Guggenheim′s quasi-chemicalequation.On this basic a thermodynamic model,the quasi-chemical local composition model(QCLC)was established.To examine its capabili...A local composition expression has been derived from the Guggenheim′s quasi-chemicalequation.On this basic a thermodynamic model,the quasi-chemical local composition model(QCLC)was established.To examine its capability for correlation and prediction,Baxter′s adhesivehard sphere mixtures were used,and an improved numerical method was proposed to estimate theirthermodynamic properties.By means of this method the excess properties of the mixtures composedof four kinds of adhesive hard spheres were calculated,The activity coefficients from QCLC modelwere compared with those from the Wilson,NRTL and UNIQUAC equations.Results show thatamong these models,the QCLC model is the best one for correlation and prediction.展开更多
A coupled numerical method for the direct numerical simulation of particle-fluid systems is formulated and implemented, resolving an order of magnitude smaller than particle size. The particle motion is described by t...A coupled numerical method for the direct numerical simulation of particle-fluid systems is formulated and implemented, resolving an order of magnitude smaller than particle size. The particle motion is described by the time-driven hard-sphere model, while the hydrodynamic equations governing fluid flow are solved by the lattice Boltzmann method （LBM）, Particle-fluid coupling is realized by an immersed boundary method （IBM）, which considers the effect of boundary on surrounding fluid as a restoring force added to the governing equations of the fluid. The proposed scheme is validated in the classical flow-around-cylinder simulations, and preliminary application of this scheme to fluidization is reported, demonstrating it to be a promising computational strategy for better understanding complex behavior in particle-fluid systems.展开更多
Chokes are one of the most important components of downhole flow-control equipment. The particle erosion mathematical model, which considers particle-particle interaction, was established and used to simulate solid pa...Chokes are one of the most important components of downhole flow-control equipment. The particle erosion mathematical model, which considers particle-particle interaction, was established and used to simulate solid particle movement as well as particle erosion characteristics of the solid-liquid two-phase flow in a choke. The corresponding erosion reduction approach by setting ribs on the inner wall of the choke was advanced. This mathematical model includes three parts： the flow field simulation of the continuous carrier fluid by an Eulerian approach, the particle interaction simulation using the discrete particle hard sphere model by a Lagrangian approach and calculation of erosion rate using semiempirical correlations. The results show that particles accumulated in a narrow region from inlet to outlet of the choke and the dominating factor affecting particle motion is the fluid drag force. As a result, the optimization of rib geometrical parameters indicates that good anti-erosion performance can be achieved by four ribs, each of them with a height （H） of 3 mm and a width （B） of 5 mm equaling the interval between ribs （L）.展开更多
用磁偶极子硬球模型对磁性液体中磁性纳米微粒间相互作用进行了研究。分析表明,微粒间存在着静电排斥、静磁吸引和Van der Waals吸引三种相互作用,无外场时静磁作用非常微弱,可以忽略,静电排斥力作用距离远,起抗团聚作用,Van der Waals...用磁偶极子硬球模型对磁性液体中磁性纳米微粒间相互作用进行了研究。分析表明,微粒间存在着静电排斥、静磁吸引和Van der Waals吸引三种相互作用,无外场时静磁作用非常微弱,可以忽略,静电排斥力作用距离远,起抗团聚作用,Van der Waals作用距离短,是引起团聚主要原因。为确保磁性液体稳定性,制备的离子型磁性液体体积分数应小于5%。展开更多
文摘A local composition expression has been derived from the Guggenheim′s quasi-chemicalequation.On this basic a thermodynamic model,the quasi-chemical local composition model(QCLC)was established.To examine its capability for correlation and prediction,Baxter′s adhesivehard sphere mixtures were used,and an improved numerical method was proposed to estimate theirthermodynamic properties.By means of this method the excess properties of the mixtures composedof four kinds of adhesive hard spheres were calculated,The activity coefficients from QCLC modelwere compared with those from the Wilson,NRTL and UNIQUAC equations.Results show thatamong these models,the QCLC model is the best one for correlation and prediction.
基金sponsored by Ministry of Finance under the grant ZDYZ2008-2National Key Science and Technology Project under the grant 2008ZX05014-003-006HZthe Chinese Academy of Sciences under the grant KGCX2-YW-124
文摘A coupled numerical method for the direct numerical simulation of particle-fluid systems is formulated and implemented, resolving an order of magnitude smaller than particle size. The particle motion is described by the time-driven hard-sphere model, while the hydrodynamic equations governing fluid flow are solved by the lattice Boltzmann method （LBM）, Particle-fluid coupling is realized by an immersed boundary method （IBM）, which considers the effect of boundary on surrounding fluid as a restoring force added to the governing equations of the fluid. The proposed scheme is validated in the classical flow-around-cylinder simulations, and preliminary application of this scheme to fluidization is reported, demonstrating it to be a promising computational strategy for better understanding complex behavior in particle-fluid systems.
基金supported by the Fund of Innovation Research Group of National Natural Science Foundation of China (Grant NO.5052160450323001)Major Program of National Natural Science Foundation of China (Grant No.50536020)
文摘Chokes are one of the most important components of downhole flow-control equipment. The particle erosion mathematical model, which considers particle-particle interaction, was established and used to simulate solid particle movement as well as particle erosion characteristics of the solid-liquid two-phase flow in a choke. The corresponding erosion reduction approach by setting ribs on the inner wall of the choke was advanced. This mathematical model includes three parts： the flow field simulation of the continuous carrier fluid by an Eulerian approach, the particle interaction simulation using the discrete particle hard sphere model by a Lagrangian approach and calculation of erosion rate using semiempirical correlations. The results show that particles accumulated in a narrow region from inlet to outlet of the choke and the dominating factor affecting particle motion is the fluid drag force. As a result, the optimization of rib geometrical parameters indicates that good anti-erosion performance can be achieved by four ribs, each of them with a height （H） of 3 mm and a width （B） of 5 mm equaling the interval between ribs （L）.
文摘用磁偶极子硬球模型对磁性液体中磁性纳米微粒间相互作用进行了研究。分析表明,微粒间存在着静电排斥、静磁吸引和Van der Waals吸引三种相互作用,无外场时静磁作用非常微弱,可以忽略,静电排斥力作用距离远,起抗团聚作用,Van der Waals作用距离短,是引起团聚主要原因。为确保磁性液体稳定性,制备的离子型磁性液体体积分数应小于5%。
