Aniline is a vital industrial raw material.However,highly-toxic aniline wastewater usually deteriorated effluent quality,posed a threat to human health and ecosystem safety.Therefore,this study reported a novel intern...Aniline is a vital industrial raw material.However,highly-toxic aniline wastewater usually deteriorated effluent quality,posed a threat to human health and ecosystem safety.Therefore,this study reported a novel internal circulation iron-carbon micro-electrolysis(ICE)reactor to treat aniline wastewater.The effects of reaction time,pH,aeration rate and iron-carbon(Fe/C)ratio on the removal rate of aniline and the chemical oxygen demand were investigated using single-factor experiments.This process exhibited high aniline degradation performance of approximately 99.86% under optimal operating conditions(reaction time=20 min,pH=3,aeration rate=0.5 m3·h^(-1),and Fe/C=1:2).Based on the experimental results,the response surface method was applied to optimize the aniline removal rate.The Box–Behnken method was used to obtain the interaction effects of three main factors.The result showed that the reaction time had a dominant effect on the removal rate of aniline.The highest aniline removal rate was obtained at pH of 2,aeration rate of 0.5 m^(3)·h^(-1)and reaction time of 30 min.Under optional experimental conditions,the aniline content of effluent was reduced to 3 mg·L^(-1)and the removal rate was as high as 98.24%,within the 95% confidence interval(97.84%-99.32%)of the predicted values.The solution was treated and the reaction intermediates were identified by high-performance liquid chromatography,ultraviolet-visible spectroscopy,Fourier-transform infrared spectroscopy,gas chromatography-mass spectrometry,and ion chromatography.The main intermediates were phenol,benzoquinone,and carboxylic acid.These were used to propose the potential mechanism of aniline degradation in the ICE reactor.The results obtained in this study provide optimized conditions for the treatment of industrial wastewater containing aniline and can strengthen the understanding of the degradation mechanism of iron-carbon micro-electrolysis.展开更多
The release of intracellular water during degradation process contributes to the great leachate production and settlement of landfilled high kitchen waste content MSW(HKWC-MSW). An oven-drying and absorbent-paper comb...The release of intracellular water during degradation process contributes to the great leachate production and settlement of landfilled high kitchen waste content MSW(HKWC-MSW). An oven-drying and absorbent-paper combined method was proposed to measure the intracellular and interparticle water contents of HKWC-MSW. Two degradation experiments were carried out to study the release process of intracellular water and its effect on the hydro-mechanical behaviors of HKWC-MSW.It was found that the two degradation experiments showed similar degradation behaviors with BOD/COD decreasing with time in the early stage. In the first degradation experiment, most intracellular water was released during the first two months, and the degradation of degradable matter in kitchen waste(KW) was much slower than the release process of intracellular water. The particle size became smaller and the overall grain specific gravity increased during the fast release process of intracellular water.In the second degradation experiment, after two-year degradation, the total leachate production was about 45.2% of the initial wet weight of HKWC-MSW specimen. Water retention capacity θ_f increased from 0.23 to 0.58 during 1–69 d, which might be caused by the decrease of particle size and compression of waste skeleton. As almost all the intracellular water was released after 80-day degradation, during the latter stage of leachate drainage under gravity, θ_f decreased and was close to the total volumetric water content. The total compression strain was about 0.39. The secondary compression strain during 1–80 d(i.e., about 0.07)was considered to be mainly resulted by the release of intracellular water and the subsequent drainage of leachate, and it accounted for about 22.6% of the total secondary compression strain.展开更多
In order to prevent the powdering of a sintered ore from influencing the smooth operation of a blast furnace,the conventional way to deal with it is that the CaCl2 solution is prepared by tap water,and then the soluti...In order to prevent the powdering of a sintered ore from influencing the smooth operation of a blast furnace,the conventional way to deal with it is that the CaCl2 solution is prepared by tap water,and then the solution is sprayed onto the sintered ore for improving its RDI（low temperature reduction degradation index）.The CaCl2 solution prepared by adding acid and alkaline waste water resulted from cold rolling is sprayed onto the sintered ore to improve its RDI.The values of RDI＋6.3 and RDI＋3.15 of the sintered ore which is sprayed by the CaCl2 solution with the CaCl2 concentration of 3.5%（mass percent） are increased by 17.5% and 11.63%,but the index of RDI-0.5 is decreased by 3.1% when the spraying amount of the solution is making up 0.5% of the total sintered ore sprayed in comparison with those of the sintered ore which is not sprayed by using the CaCl2 solution.Experimental results show that after the CaCl2 solutions prepared by adding the acid and alkaline waste water are sprayed on the sintered ore,RDI of the ore can be remarkably improved and therefore another way for recycling acid and alkaline waste water can be available,by which both cost for treating waste water and cost for producing a sintered ore can be decreased and environment is free of pollution by harmful substances in the waste water.展开更多
基金supported by the National Natural Science Foundation of China(21677018)the Joint Fund of the Beijing Municipal Natural Science Foundation and Beijing Municipal Education Commission(KZ201810017024)the Cross-Disciplinary Science Foundation from Beijing Institute of Petrochemical Technology(BIPTCSF–22032205003/014)。
文摘Aniline is a vital industrial raw material.However,highly-toxic aniline wastewater usually deteriorated effluent quality,posed a threat to human health and ecosystem safety.Therefore,this study reported a novel internal circulation iron-carbon micro-electrolysis(ICE)reactor to treat aniline wastewater.The effects of reaction time,pH,aeration rate and iron-carbon(Fe/C)ratio on the removal rate of aniline and the chemical oxygen demand were investigated using single-factor experiments.This process exhibited high aniline degradation performance of approximately 99.86% under optimal operating conditions(reaction time=20 min,pH=3,aeration rate=0.5 m3·h^(-1),and Fe/C=1:2).Based on the experimental results,the response surface method was applied to optimize the aniline removal rate.The Box–Behnken method was used to obtain the interaction effects of three main factors.The result showed that the reaction time had a dominant effect on the removal rate of aniline.The highest aniline removal rate was obtained at pH of 2,aeration rate of 0.5 m^(3)·h^(-1)and reaction time of 30 min.Under optional experimental conditions,the aniline content of effluent was reduced to 3 mg·L^(-1)and the removal rate was as high as 98.24%,within the 95% confidence interval(97.84%-99.32%)of the predicted values.The solution was treated and the reaction intermediates were identified by high-performance liquid chromatography,ultraviolet-visible spectroscopy,Fourier-transform infrared spectroscopy,gas chromatography-mass spectrometry,and ion chromatography.The main intermediates were phenol,benzoquinone,and carboxylic acid.These were used to propose the potential mechanism of aniline degradation in the ICE reactor.The results obtained in this study provide optimized conditions for the treatment of industrial wastewater containing aniline and can strengthen the understanding of the degradation mechanism of iron-carbon micro-electrolysis.
基金supported by the National Basic Research Program of China(Grant No.2012CB719800)the National Natural Science Foundation of China(Grant Nos.51708508,41402249)the Zhejiang Provincial Natural Science Foundation(Grant Nos.LY17E080021,LY15E080021)
文摘The release of intracellular water during degradation process contributes to the great leachate production and settlement of landfilled high kitchen waste content MSW(HKWC-MSW). An oven-drying and absorbent-paper combined method was proposed to measure the intracellular and interparticle water contents of HKWC-MSW. Two degradation experiments were carried out to study the release process of intracellular water and its effect on the hydro-mechanical behaviors of HKWC-MSW.It was found that the two degradation experiments showed similar degradation behaviors with BOD/COD decreasing with time in the early stage. In the first degradation experiment, most intracellular water was released during the first two months, and the degradation of degradable matter in kitchen waste(KW) was much slower than the release process of intracellular water. The particle size became smaller and the overall grain specific gravity increased during the fast release process of intracellular water.In the second degradation experiment, after two-year degradation, the total leachate production was about 45.2% of the initial wet weight of HKWC-MSW specimen. Water retention capacity θ_f increased from 0.23 to 0.58 during 1–69 d, which might be caused by the decrease of particle size and compression of waste skeleton. As almost all the intracellular water was released after 80-day degradation, during the latter stage of leachate drainage under gravity, θ_f decreased and was close to the total volumetric water content. The total compression strain was about 0.39. The secondary compression strain during 1–80 d(i.e., about 0.07)was considered to be mainly resulted by the release of intracellular water and the subsequent drainage of leachate, and it accounted for about 22.6% of the total secondary compression strain.
基金Item Sponsored by National Natural Science Foundation of China(51274120)
文摘In order to prevent the powdering of a sintered ore from influencing the smooth operation of a blast furnace,the conventional way to deal with it is that the CaCl2 solution is prepared by tap water,and then the solution is sprayed onto the sintered ore for improving its RDI（low temperature reduction degradation index）.The CaCl2 solution prepared by adding acid and alkaline waste water resulted from cold rolling is sprayed onto the sintered ore to improve its RDI.The values of RDI＋6.3 and RDI＋3.15 of the sintered ore which is sprayed by the CaCl2 solution with the CaCl2 concentration of 3.5%（mass percent） are increased by 17.5% and 11.63%,but the index of RDI-0.5 is decreased by 3.1% when the spraying amount of the solution is making up 0.5% of the total sintered ore sprayed in comparison with those of the sintered ore which is not sprayed by using the CaCl2 solution.Experimental results show that after the CaCl2 solutions prepared by adding the acid and alkaline waste water are sprayed on the sintered ore,RDI of the ore can be remarkably improved and therefore another way for recycling acid and alkaline waste water can be available,by which both cost for treating waste water and cost for producing a sintered ore can be decreased and environment is free of pollution by harmful substances in the waste water.
