Evaluation of surface temperature and pressure derived from MERRA-2 and ERA5 reanalysis datasets and their applications in hourly GNSS precipitable water vapor retrieval over China

Temperature and pressure play key roles in Global Navigation Satellite System(GNSS) precipitable water vapor(PWV) retrieval. The National Aeronautics and Space Administration(NASA) and European Center for Medium-Range Weather Forecasts(ECMWF) have released their latest reanalysis product: the modern-era retrospective analysis for research and applications, version 2(MERRA-2) and the fifthgeneration ECMWF reanalysis(ERA5), respectively. Based on the reanalysis data, we evaluate and analyze the accuracy of the surface temperature and pressure products in China using the the measured temperature and pressure data from 609 ground meteorological stations in 2017 as reference values.Then the accuracy of the two datasets and their performances in estimating GNSS PWV are analyzed. The PWV derived from the pressure and temperature products of ERA5 and MERRA-2 has high accuracy. The annual average biases of pressure and temperature for ERA5 are-0.07 hPa and 0.45 K, with the root mean square error(RMSE) of 0.95 hPa and 2.04 K, respectively. The annual average biases of pressure and temperature for MERRA-2 are-0.01 hPa and 0.38 K, with the RMSE of 1.08 h Pa and 2.66 K, respectively.The accuracy of ERA5 is slightly higher than that of MERRA-2. The two reanalysis data show negative biases in most regions of China, with the highest to lowest accuracy in the following order: the south,north, northwest, and Tibet Plateau. Comparing the GNSS PWV calculated using MERRA-2(GNSS MERRA-2 PWV) and ERA5(GNSS ERA5 PWV) with the radiosonde-derived PWV from 48 co-located GNSS stations and the measured PWV of the co-location radiosonde stations, it is found that the accuracy of GNSS ERA5 PWV is better than that of GNSS MERRA-2 PWV. These results show the different applicability of surface temperature and pressure products from MERRA-2 and ERA5 data, indicating that both have important applications in meteorological research and GNSS water vapor monitoring in China.

Centimeter-sized Cs_(3)Cu_(2)I_(5)single crystals grown by oleic acid assisted inverse temperature crystallization strategy and their films for high-quality X-ray imaging

Low-dimensional halide perovskites have become the most promising candidates for X-ray imaging,yet the issues of the poor chemical stability of hybrid halide perovskite,the high poisonousness of lead halides and the relatively low detectivity of the lead-free halide perovskites which seriously restrain its commercialization.Here,we developed a solution inverse temperature crystal growth(ITCG)method to bring-up high quality Cs_(3)Cu_(2)I_(5)crystals with large size of centimeter order,in which the oleic acid(OA)is introduced as an antioxidative ligand to inhibit the oxidation of cuprous ions effieiently,as well as to decelerate the crystallization rate remarkalby.Based on these fine crystals,the vapor deposition technique is empolyed to prepare high quality Cs_(3)Cu_(2)I_(5)films for efficient X-ray imaging.Smooth surface morphology,high light yields and short decay time endow the Cs_(3)Cu_(2)I_(5)films with strong radioluminescence,high resolution(12 lp/mm),low detection limits(53 nGyair/s)and desirable stability.Subsequently,the Cs_(3)Cu_(2)I_(5)films have been applied to the practical radiography which exhibit superior X-ray imaging performance.Our work provides a paradigm to fabricate nonpoisonous and chemically stable inorganic halide perovskite for X-ray imaging.

Impact of Increasing Stratospheric Water Vapor on Ozone Depletion and Temperature Change

Using a detailed, fully coupled chemistry climate model （CCM）, the effect of increasing stratospheric H20 on ozone and temperature is investigated. Different CCM time-slice runs have been performed to investigate the chemical and radiative impacts of an assumed 2 ppmv increase in H20. The chemical effects of this H20 increase lead to an overall decrease of the total column ozone （TCO） by ～1% in the tropics and by a maximum of 12% at southern high latitudes. At northern high latitudes, the TCO is increased by only up to 5% due to stronger transport in the Arctic. A 2-ppmv H2O increase in the model＇s radiation scheme causes a cooling of the tropical stratosphere of no more than 2 K, but a cooling of more than 4 K at high latitudes. Consequently, the TCO is increased by about 2%-6%. Increasing stratospheric H2O, therefore, cools the stratosphere both directly and indirectly, except in the polar regions where the temperature responds differently due to feedbacks between ozone and H2O changes. The combined chemical and radiative effects of increasing H2O may give rise to more cooling in the tropics and middle latitudes but less cooling in the polar stratosphere. The combined effects of H2O increases on ozone tend to offset each other, except in the Arctic stratosphere where both the radiative and chemical impacts give rise to increased ozone. The chemical and radiative effects of increasing H2O cause dynamical responses in the stratosphere with an evident hemispheric asymmetry. In terms of ozone recovery, increasing the stratospheric H2O is likely to accelerate the recovery in the northern high latitudes and delay it in the southern high latitudes. The modeled ozone recovery is more significant between 2000 ～2050 than between 2050～2100, driven mainly by the larger relative change in chlorine in the earlier period.

Temperature Dependency of Water Vapor Permeability of Shape Memory Polyurethane

Solution-cast films of shape memory polyurethane have been investigated.Differential scanning calorimetry, DMA, tensile test, water vapor permeability and the shape memory effect were carried out to characterize these polyurethane membranes. Samples cast at higher temperatures contained more hard segment in the crystalline state than a sample cast at lower temperature. The change in the water vapor permeability (WVP) of SMPU films with respect to the temperature follows an S-shaped curve, and increases abruptly at T m of the soft segment for the fractional free volume (FFV, the ratio of free volume and specific volume in polymers) increased linearly with temperature. The water vapor permeability dependency of the temperature and humidity contribute to the result of the change of diffusion and solubility with the surrounding air condition. The diffusion coefficient (D) are the function of temperature and show good fit the Arrhenius form but show different parameter values when above and below T g. The crystalline state hard-segment is necessary for the good shape memory

Seasonal and Interannual Variations of Upper Tropospheric Water Vapor Band Brightness Temperature over the Global Monsoon Regions

The upper-troposphere water vapor (UTWV) band brightness temperature (BT) dataset derived from the High-resolution Infrared Radiation Sounder (HIRS) channel 12 of the National Oceanic and Atmospheric Administration (NOAA) polar satellites from 1979 to 1995 is used to analyze the seasonal and interannual variations for the global monsoon regions. Results show that (i) there are three major regions where the UTWV band BT varies significantly with season, i.e., South Asia, the western coastal South-North America tropical region and the low-latitude African region; (ii) UTWV band BT clearly reveals the water vapor temporal/spatial features as well as the atmospheric circulation structure over the low-latitude during the monsoon onset; and (iii) there is a remarkable relationship between the interannual variation of the UTWV band BT over the monsoon regions and the sea surface temperature anomaly in the eastern equatorial Pacific.

Influence of Vapor Cloud Shape on Temperature Field of Unconfined Vapor Cloud Explosion

In order to analyze the influence of vapor cloud shape on temperature field effect of unconfined vapor cloud explosion(UVCE)and obtain creditable prediction method of explosion temperature effect,the transient temperature fields of cylindrical and hemispherical UVCEs with same methane concentration and mass were numerically studied by computational fluid dynamics(CFD)technology.According to numerical simulation results, the concepts of UVCE’s temperature-near-field and temperature-far-field were proposed,the corresponding ranges were given,and the temperature attenuation laws and differences in corresponding regions with different vapor cloud shapes were presented.Through comparing with Baker fireball model,the accuracy and visualizability in acquisition of entire temperature effect based on numerical simulation were further validated.The functional relations among maximum temperature,horizontal distance,initial temperature and vapor cloud mass in temperature-near-field and temperature-far-field were deduced by means of data fitting,respectively.These conclusions provided quantitative basis for forecast and protection of UVCE disaster.

Simulation of the Effect of Water-vapor Increase on Temperature in the Stratosphere

To analyze the mechanism by which water vapor increase leads to cooling in the stratosphere, the effects of water-vapor increases on temperature in the stratosphere were simulated using the two-dimensional, interactive chemical dynamical radiative model （SOCRATES） of NCAR. The results indicate that increases in stratospheric water vapor lead to stratospheric cooling, with the extent of cooling increasing with height, and that cooling in the middle stratosphere is stronger in Arctic regions. Analysis of the radiation process showed that infrared radiative cooling by water vapor is a pivotal factor in middle-lower stratospheric cooling. However, in the upper stratosphere （above 45 km）, infrared radiation is not a factor in cooling; there, cooling is caused by the decreased solar radiative heating rate resulting from ozone decrease due to increased stratospheric water vapor. Dynamical cooling is important in the middle-upper stratosphere, and dynamical feedback to temperature change is more distinct in the Northern Hemisphere middle-high latitudes than in other regions and signiffcantly affects temperature and ozone in winter over Arctic regions. Increasing stratospheric water vapor will strengthen ozone depletion through the chemical process. However, ozone will increase in the middle stratosphere. The change in ozone due to increasing water vapor has an important effect on the stratospheric temperature change.

Correlation between Atmospheric Water Vapor and Diurnal Temperature Range over China

Diurnal temperature range （DTR） is an im- portant measure in studies of climate change and variability. The changes of DTR in different regions are affected by many different factors. In this study, the degree of correlation between the DTR and atmospheric precipitable water （PW） over China is explored using newly homogenized surface weather and sounding observations. The results show that PW changes broadly reflect the geographic patterns of DTR long-term trends over most of China during the period 1970-2012, with significant anticorrelations of trend patterns between the DTR and PW, especially over those regions with higher magnitude DTR trends. PW can largely explain about 40% or more （re 0.40） of the DTR changes, with a d（PW）/d（DTR） slope of -2% to -10% K^-1 over most of northwestern and southeastern China, despite certain seasonal dependencies. For China as whole, the significant anticorrelations between the DTR and PW anomalies range from -0.42 to -0.75, with a d（PW）/d（DTR） slope of-6% to -11% K^-1. This implies that long-term DTR changes are likely to be associated with opposite PW changes, approximately following the Clausius-Clapeyron equation. Furthermore, the relationship is more significant in the warm season than in the cold season. Thus, it is possible that PW can be considered as one potential factor when exploring long-term DTR changes over China. It should be noted that the present study has a largely statistical focus and that the underlying physical processes should therefore be examined in future work.

A CASE STUDY OF THE UNCORRELATED RELATIONSHIP BETWEEN TROPICAL TROPOPAUSE TEMPERATURE ANOMALIES AND STRATOSPHERIC WATER VAPOR ANOMALIES

Using the measurements from the Halogen Occultation Experiment(HALOE)and the European Centre for Medium-Range Weather Forecasts(ECMWF)Interim reanalysis data for the period 1994-2005,we analyzed the relationship between tropical tropopause temperature anomalies and stratospheric water vapor anomalies.It is found that tropical tropopause temperature is correlated with stratospheric water vapor,i.e.,an anomalously high(low)tropical tropopause temperature corresponds to anomalously high(low)stratospheric water vapor during the period 1994-2005,except for 1996.The occurrence frequency and strength of deep convective activity during the‘mismatched'months is less and weaker than that during the‘matched'months in 1996.However,the instantaneous intensity of four short periods of deep convective activity,caused by strong surface cyclones and high sea surface temperatures,are greater during the‘mismatched'months than during the‘matched'months.Water vapor is transported from the lower troposphere to the lower stratosphere through a strong tropical upwelling,leading to an increase in stratospheric water vapor.On the other hand,deep convective activity can lift the tropopause and cool its temperature.In short,the key factor responsible for the poor correlation between tropical tropopause temperature and stratospheric water vapor in1996 is the instantaneous strong deep convective activity.In addition,an anomalously strong Brewer-Dobson circulation brings more water vapor into the stratosphere during the‘mismatched'months in 1996,and this exacerbates the poor correlation between tropical tropopause temperature and stratospheric water vapor.

Selective Area Growth and Characterization of GaN Nanorods Fabricated by Adjusting the Hydrogen Flow Rate and Growth Temperature with Metal Organic Chemical Vapor Deposition

CaN nanorods are successfully fabricated by adjusting the flow rate ratio of hydrogen （H2）/nitrogen （N2） and growth temperature of the selective area growth （SAG） method with metal organic chemical vapor deposition （MOCVD）. The SAG template is obtained by nanospherical-lens photolithography. It is found that increasing the flow rate of 1-12 will change the CaN crystal shape from pyramid to vertical rod, while increasing the growth temperature will reduce the diameters of GaN rods to nanometer scale. Finally the CaN nanorods with smooth lateral surface and relatively good quality are obtained under the condition that the H2：N2 ratio is 1：1 and the growth temperature is 1030℃. The good crystal quality and orientation of GaN nanorods are confirmed by high resolution transmission electron microscopy. The cathodoluminescence spectrum suggests that the crystal and optical quality is also improved with increasing the temperature.

Empirical model for mean temperature and assessment of precipitable water vapor derived from GPS

The estimation of Precipitable Water Vapor （PWV） derived from Global Positioning System （GPS） data at the IGS site WUHN is assessed by comparing with PWV obtained from radiosonde data （No.57494） in Wuhan. The applicability of Saastamoinen （SAAS）, Hopfield and Black models used for estimating Zenith Hydrostatic Delay （ZHD） and Zenith Wet Delay （ZWD） and different models is verified in the estimation of GPS-derived PWV for the applied area. The experimental results demonstrated that ： 1 ） the precision of PWV estimated from Black model used for calculating ZHD （ ZHDs ） is lower than that of SAAS （ ZHDsAAs ） model and Hopfield model （ZHDn） with the RMS of 4. 16 ram; 2） the RMS of PWV estimated from SAAS model used for calculating ZWD （SAAS） is 3.78 ram; 3 ） the well-known Bevis model gives similar accuracy compared with the site-specific models for Tm in terms of surface temperature （ Ts ） and surface pressure （Ps）, which can reach the accuracy inside 1 mm in the GPS-derived PWV estimates.

Room Temperature and Reduced Pressure Chemical Vapor Deposition of Silicon Carbide on Various Materials Surface

At room temperature, 300 K, silicon carbide film was formed using monomethylsilane gas on the reactive surface prepared using argon plasma. Entire process was performed at reduced pressure of 10 Pa in the argon plasma etcher, without a substrate transfer operation. By this process, the several-nanometer-thick amorphous thin film containing silicon-carbon bonds was obtained on various substrates, such as semiconductor silicon, aluminum and stainless steel. It is concluded that the room temperature silicon carbide thin film formation is possible even at significantly low pressure, when the substrate surface is reactive.

Numerical Analysis of Temperature Distributions in Single Cell of PEFC by Heat Transfer Model Considering Vapor Transfer

Polymer Electrolyte Fuel Cell(PEFC)is required to be operated at temperature at 100℃ for fuel cell vehicle applications during the period from 2020 to 2025 in Japan.It is expected that micro porous layer(MPL)and thinner polymer electrolyte membrane(PEM)would enhance the power generation performance of PEFC at this temperature.The key objective of this study is to analyse the impact of MPL and thickness of PEM on the temperature distributions of interface between the PEM and catalyst layer at the cathode(i.e.,the reaction surface)in a single PEFC.A 1D multi-plate heat transfer model,considering vapor transfer,which is based on temperature data of separator measured using thermograph in power generation process.It is developed to evaluate temperature at the reaction surface.This study is investigated the effect of flow rate and relative humidity of supply gases on temperature distribution on reaction surface.The study reveals that the impact of flow rate of supply gas on temperature distribution on reaction surface is smaller with and without MPL.It is observed that the even temperature distribution on reaction surface as well as higher power generation performance can be obtained with MPL irrespective of thickness of PEM and relative humidity conditions.

Determination of Nickel and Palladium in Environmental Samples by Low Temperature ETV-ICP-OES Coupled with Liquid-liquid Extraction with Dimethylglyoxime as Both Extractant and Chemical Modifier

A novel method for the determination of nickel and palladium in environmental samples by low temperature ETV-ICP-OES with dimethylglyoxime（DMG） as both the extractant and chemical modifier has been developed. In this study, it was found that nickel and palladium can form complexes with dimethylglyoxime（0. 05%, mass fraction） at pH 6.0 and can be extracted into chloroform quantitatively. The complexes can be evaporated into plasma at a suita-ble temperature（ 1400℃） for ICP-OES detection. Under the optimized conditions, the detection limits of nickel and palladium are 0.48 and 0. 40 ng/mL, respectively, while the RSD values are separately 5.0% and 3.1% （p = 50 ng/mL, n = 7）. The proposed method was applied to the determination of the target analytes in environmental sam-ples with satisfactory results.

Effect of deposition temperature on properties of boron-doped diamond films on tungsten carbide substrate

Boron-doped diamond(BDD)films were deposited on the tungsten carbide substrates at different substrate temperatures ranging from 450 to 850°C by hot filament chemical vapor deposition(HFCVD)method.The effect of deposition temperature on the properties of the boron-doped diamond films on tungsten carbide substrate was investigated.It is found that boron doping obviously enhances the growth rate of diamond films.A relatively high growth rate of 544 nm/h was obtained for the BDD film deposited on the tungsten carbide at 650°C.The added boron-containing precursor gas apparently reduced activation energy of film growth to be 53.1 kJ/mol,thus accelerated the rate of deposition chemical reaction.Moreover,Raman and XRD analysis showed that heavy boron doping(750 and 850°C)deteriorated the diamond crystallinity and produced a high defect density in the BDD films.Overall,600-700°C is found to be an optimum substrate temperature range for depositing BDD films on tungsten carbide substrate.

An Experimental Study on the Drag Property of High-Temperature Particles Falling into Cold Liquid Pool

This experiment is to study the special resistant induced by the high-speed evaporation surrounding themoving high-temperature particles. An observable equipment was designed, in which the first 11 experiments wereperformed by pouring one or several Zirconia spheres with various high-temperature and a diameter of 3～ 10 mminto a water pool. The particles falling-down speeds were recorded by high-speed photographic instrumentation,and pressures and water temperatures were measured. A comparison between the experiments with cold and hotspheres respectively, employing three different sphere types each, was presented. The experimental data, com-pared with the theory of the evaporation drag model, are nearly identical.

Impact of Separator Thickness on Temperature Distribution in Single Polymer Electrolyte Fuel Cell Based on 1D Heat Transfer

It is known from the New Energy and Industry Technology Development Organization (NEDO) roam map Japan, 2017 that the polymer electrolyte fuel cell (PEFC) power generation system is required to operate at 100°C for application of mobility usage from 2020 to 2025. This study aims to clarify the effect of separator thickness on the distribution of the temperature of reaction surface (Treact) at the initial temperature of cell (Tini) with flow rate, relative humidity (RH) of supply gases as well as RH of air surrounding cell of PEFC. The distribution of Treact is estimated by means of the heat transfer model considering the H2O vapor transfer proposed by the authors. The relationship between the standard deviation of Treact-Tini and total voltage obtained in the experiment is also investigated. We can know the effect of the flow rate of supply gas as well as RH of air surrounding cell of PEFC on the distribution of Treact-Tini is not significant. It is observed the wider distribution of Treact-Tini provides the reduction in power generation performance irrespective of separator thickness. In the case of separator thickness of 1.0 mm, the standard deviation of Treact-Tini has smaller distribution range and the total voltage shows a larger variation compared to the other cases.

Effect of pyrolysis temperature on properties of ACF/CNT composites

Activated carbon fiber/carbon nanotube(ACF/CNT) composites were fabricated by chemical vapor deposition(CVD) process.The effects of pyrolysis temperature on properties of ACF/CNT composites,including BET specific surface area,mass increment rate and adsorption efficiency for rhodamine B in solution,were investigated by scanning electron microscopy.The results show that the pyrolysis temperature is a key factor affecting the qualities of ACF/CNT composites.The mass increment rate and BET specific surface area sharply decrease with the increase of pyrolysis temperatures from 550 ℃ to 850 ℃ and the minimum diameter of CNTs appears at 750 ℃.The maximum adsorption efficiency of ACF/CNT composites for rhodamine B is obtained at 650 ℃.ACF/CNT composites are expected to be useful in adsorption field.

FY-4A数据在2021年1月6—8日寒潮监测中应用

基于静止气象卫星图像解译理论和位涡理论,应用FY-4A水汽图像、干涉式大气垂直探测仪(GIIRS)产品和欧洲中心第五代大气再分析资料(ERA5)对2021年1月6—8日我国中东部地区寒潮天气进行分析。结果表明:高空冷涡和地面冷高压是影响此次寒潮天气的主要影响系统,冷空气5日08:00从贝加尔湖南部向东、向南加强发展,8日20:00减弱;对比FY-4A/GIIRS与ERA5850 hPa 24 h变温数据发现:两种数据反映的对流层低层冷空气东移南下特征和正负变温区域分布特征基本一致,FY-4A/GIIRS 850 hPa 24 h负变温中心和0℃等变温线的位置与ERA5数据接近,FY-4A/GIIRS 850 hPa 24 h变温中心值强度略大于ERA5。水汽图像暗区变暗附近的高层位涡的增加激发高层气旋性环流后侧下沉运动增强,干空气下沉造成了地面高压增强;500 hPa冷涡中心附近绝对涡度增加是引起冷空气增强的原因之一;冷空气急剧增强时段,中低层位涡的加大引起地面冷空气堆积,寒潮增强。FY-4A/GIIRS温度产品反映的冷空气移动特征与位涡理论对冷空气增强原因分析结果一致,说明应用FY-4A/GIIRS温度产品能够有效监测分析寒潮冷空气演变特征。