The regulation of ferrocene-based catalysts on heat transfer in highpressure combustion of ammonium perchlorate/hydroxyl-terminated polybutadiene/aluminum composite propellants

The regulation of the burning rate pressure exponent for the ammonium perchlorate/hydroxylterminated polybutadiene/aluminum(AP/HTPB/Al)composite propellants under high pressures is a crucial step for its application in high-pressure solid rocket motors.In this work,the combustion characteristics of AP/HTPB/Al composite propellants containing ferrocene-based catalysts were investigated,including the burning rate,thermal behavior,the local heat transfer,and temperature profile in the range of 7-28 MPa.The results showed that the exponent breaks were still observed in the propellants after the addition of positive catalysts(Ce-Fc-MOF),the burning rate inhibitor((Ferrocenylmethyl)trimethylammonium bromide,Fc Br)and the mixture of Fc Br/catocene(GFP).However,the characteristic pressure has increased,and the exponent decreased from 1.14 to 0.66,0.55,and 0.48 when the addition of Ce-FcMOF,Fc Br and Fc Br/GFP in the propellants.In addition,the temperature in the first decomposition stage was increased by 7.50℃ and 11.40℃ for the AP/Fc Br mixture and the AP/Fc Br/GFP mixture,respectively,compared to the pure AP.On the other hand,the temperature in the second decomposition stage decreased by 48.30℃ and 81.70℃ for AP/Fc Br and AP/Fc Br/GFP mixtures,respectively.It was also found that Fc Br might generate ammonia to cover the AP surface.In this case,a reaction between the methyl in Fc Br and perchloric acid caused more ammonia to appear at the AP surface,resulting in the suppression of ammonia desorption.In addition,the coarse AP particles on the quenched surface were of a concave shape relative to the binder matrix under low and high pressures when the catalysts were added.In the process,the decline at the AP/HTPB interface was only exhibited in the propellant with the addition of Ce-Fc-MOF.The ratio of the gas-phase temperature gradient of the propellants containing catalysts was reduced significantly below and above the characteristic pressure,rather than 3.6 times of the difference in the blank propellant.Overall,the obtained results demonstrated that the pressure exponent could be effectively regulated and controlled by adjusting the propellant local heat and mass transfer under high and low pressures.

Numerical Investigation of Heat and Mass Transfer in Nanofluid-Filled Porous Medium

In this work, we numerically study the laminar mixed convection of fluid flow in a vertical channel filled with porous media during the drying process. The porous medium, modeled as a vertical wall, consists of solid and nanofluid phase (Water-Al2O3 or Water-Cu), as well as a gas phase. The established model is developed based on Whitaker’s theory and resolved by our numerical code using Fortran. Results principally show the influence of various physical parameters, such as nanoparticle volume fraction, ambient temperature, and saturation on heat and mass transfer on the drying process. This study brings the effect of the presence of nanofluids in porous media. It contributes not only to our fundamental understanding of drying processes but also provides practical insights that can guide the development of more efficient and sustainable drying technologies. .

Research on shell-side heat and mass transfer with multi-component in LNG spiral-wound heat exchanger under sloshing conditions

The spiral-wound heat exchanger(SWHE) is the primary low-temperature heat exchanger for large-scale LNG plants due to its high-pressure resistance, compact structure, and high heat exchange efficiency. This paper studied the shell-side heat and mass transfer characteristics of vapor-liquid two-phase mixed refrigerants in an SWHE by combining a multi-component model in FLUENT software with a customized multicomponent mass transfer model. Besides, the mathematical model under the sloshing condition was obtained through mathematical derivation, and the corresponding UDF code was loaded into FLUENT as the momentum source term. The results under the sloshing conditions were compared with the relevant parameters under the steady-state condition. The shell-side heat and mass transfer characteristics of the SWHE were investigated by adjusting the component ratio and other working conditions. It was found that the sloshing conditions enhance the heat transfer performance and sometimes have insignificant effects. The sloshing condition is beneficial to reduce the flow resistance. The comprehensive performance of multi-component refrigerants has been improved and the improvement is more significant under sloshing conditions, considering both the heat transfer and pressure drop.These results will provide theoretical support for the research and design of multi-component heat and mass transfer enhancement of LNG SWHE under ocean sloshing conditions.

Effect of bipolar-plates design on corrosion,mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers:A review

Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)are promising devices for hydrogen production,given their high efficiency,rapid responsiveness,and compactness.Bipolar plates account for a relatively high percentage of the total cost and weight compared with other components of PEMWEs.Thus,optimization of their design may accelerate the promotion of PEMWEs.This paper reviews the advances in materials and flow-field design for bipolar plates.First,the working conditions of proton-exchange membrane fuel cells(PEMFCs)and PEMWEs are compared,including reaction direction,operating temperature,pressure,input/output,and potential.Then,the current research status of bipolar-plate substrates and surface coatings is summarized,and some typical channel-rib flow fields and porous flow fields are presented.Furthermore,the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are explored.Finally,this review discusses the potential directions of the development of bipolar-plate design,including material fabrication,flow-field geometry optimization using threedimensional printing,and surface-coating composition optimization based on computational materials science.

Effect of phosphorus content on interfacial heat transfer and film deposition behavior during the high-temperature simulation of strip casting

The interfacial wettability and heat transfer behavior are crucial in the strip casting of high phosphorus-containing steel.A hightemperature simulation of strip casting was conducted using the droplet solidification technique with the aims to reveal the effects of phosphorus content on interfacial wettability,deposited film,and interfacial heat transfer behavior.Results showed that when the phosphorus content increased from 0.014wt%to 0.406wt%,the mushy zone enlarged,the complete solidification temperature delayed from1518.3 to 1459.4℃,the final contact angle decreased from 118.4°to 102.8°,indicating improved interfacial contact,and the maximum heat flux increased from 6.9 to 9.2 MW/m2.Increasing the phosphorus content from 0.081wt%to 0.406wt%also accelerated the film deposition rate from 1.57 to 1.73μm per test,resulting in a thickened naturally deposited film with increased thermal resistance that advanced the transition point of heat transfer from the fifth experiment to the third experiment.

Impact of a Magnetic Dipole on Heat Transfer in Non-Conducting Magnetic Fluid Flow over a Stretching Cylinder

The thermal behavior of an electrically non-conducting magnetic liquid flowing over a stretching cylinder under the influence of a magnetic dipole is considered.The governing nonlinear differential equations are solved numerically using a finite element approach,which is properly validated through comparison with earlier results available in the literature.The results for the velocity and temperature fields are provided for different values of the Reynolds number,ferromagnetic response number,Prandtl number,and viscous dissipation parameter.The influence of some physical parameters on skin friction and heat transfer on the walls of the cylinder is also investigated.The applicability of this research to heat control in electronic devices is discussed to a certain extent.

Near-field radiative heat transfer between nanoporous GaN films

Photon tunneling effects give rise to surface waves,amplifying radiative heat transfer in the near-field regime.Recent research has highlighted that the introduction of nanopores into materials creates additional pathways for heat transfer,leading to a substantial enhancement of near-field radiative heat transfer(NFRHT).Being a direct bandgap semiconductor,GaN has high thermal conductivity and stable resistance at high temperatures,and holds significant potential for applications in optoelectronic devices.Indeed,study of NFRHT between nanoporous GaN films is currently lacking,hence the physical mechanism for adding nanopores to GaN films remains to be discussed in the field of NFRHT.In this work,we delve into the NFRHT of GaN nanoporous films in terms of gap distance,GaN film thickness and the vacuum filling ratio.The results demonstrate a 27.2%increase in heat flux for a 10 nm gap when the nanoporous filling ratio is 0.5.Moreover,the spectral heat flux exhibits redshift with increase in the vacuum filling ratio.To be more precise,the peak of spectral heat flux moves fromω=1.31×10^(14)rad·s^(-1)toω=1.23×10^(14)rad·s^(-1)when the vacuum filling ratio changes from f=0.1 to f=0.5;this can be attributed to the excitation of surface phonon polaritons.The introduction of graphene into these configurations can highly enhance the NFRHT,and the spectral heat flux exhibits a blueshift with increase in the vacuum filling ratio,which can be explained by the excitation of surface plasmon polaritons.These findings offer theoretical insights that can guide the extensive utilization of porous structures in thermal control,management and thermal modulation.

Thermal runaway evolution of a 280 Ah lithium-ion battery with LiFePO_(4) as the cathode for different heat transfer modes constructed by mechanical abuse

Lithium iron phosphate batteries have been increasingly utilized in recent years because their higher safety performance can improve the increasing trend of recurring thermal runaway accidents.However,the safety performance and mechanism of high-capacity lithium iron phosphate batteries under internal short-circuit challenges remain to be explored.This work analyzes the thermal runaway evolution of high-capacity LiFePO_(4) batteries under different internal heat transfer modes,which are controlled by different penetration modes.Two penetration cases involving complete penetration and incomplete penetration were detected during the test,and two modes were performed incorporating nails that either remained or were removed after penetration to comprehensively reveal the thermal runaway mechanism.A theoretical model of microcircuits and internal heat conduction is also established.The results indicated three thermal runaway evolution processes for high-capacity batteries,which corresponded to the experimental results of thermal equilibrium,single thermal runaway,and two thermal runaway events.The difference in heat distribution in the three phenomena is determined based on the microstructure and material structure near the pinhole.By controlling the heat dissipation conditions,the time interval between two thermal runaway events can be delayed from 558 to 1417 s,accompanied by a decrease in the concentration of in-situ gas production during the second thermal runaway event.

Study of Flow and Heat Transfer in an Ejector-Driven Swirl Anti-Icing Chamber

The formation of ice on the leading edge of aircraft engines is a serious issue,as it can have catastrophic consequences.The Swirl Anti-Icing(SAI)system,driven by ejection,circulates hot fluid within a 360°annular chamber to heat the engine inlet lip surface and prevent icing.This study employs a validated Computational Fluid Dynamics(CFD)approach to study the impact of key geometric parameters of this system on flow and heat transfer characteristics within the anti-icing chamber.Additionally,the entropy generation rate and exergy efficiency are analyzed to assess the energy utilization in the system.The research findings indicate that,within the considered flow range,reducing the nozzle specific areaφfrom 0.03061 to 0.01083 can enhance the ejection coefficient by over 60.7%.This enhancement increases the air circulating rate,thereby intensifying convective heat transfer within the SAI chamber.However,the reduction inφalso leads to a significant increase in the required bleed air pressure and a higher entropy generation rate,indicating lower exergy efficiency.The nozzle angleθnotably affects the distribution of hot and cold spots on the lip surface of the SAI chamber.Increasingθfrom 0°to 20°reduces the maximum temperature difference on the anti-icing chamber surface by 60 K.

Experiments and Analyses on Heat Transfer Characteristics from a Solid Wall to a Strip-ShapedWick Structure

Centered or striped wick structures have been used to develop ultrathin heat pipes.Differing from traditional heat pipes,the centered or striped wick structures leave noncontact container surfaces with the wick structure.In this study,experiments andnumerical analyseswere conductedtoinvestigate the influenceof thesenoncontact surfaces.In the experiments,a strip-shaped wick structure was placed vertically,the top was sandwiched between wider rods and the bottom was immersed in a working fluid.The rod width was greater than the wick width;thus,noncontact surfaces were left between the rod and the wick structure.The heat was applied from the rod to the wick structure,and the evaporation heat transfer characteristics of the working fluid from the wick structure were evaluated.Water was used as the working fluid.The experiments were conducted by varying the rod and wick widths.The experimental results were obtained when the wick structures were placed separately.In the numerical analyses,the temperature and heat flux distributions in the rod were obtained.From the experimental and numerical results,it was confirmed that the noncontact surfaces caused the heat flux in the rod near both surfaces of the wick structure to concentrate,which increased the evaporation thermal resistance of the wick structure.A reduction in the noncontact surface area by increasing the wick width was found to be effective in decreasing the evaporation thermal resistance and increasing themaximumheat transfer rate of the wick structure.The separation of the wick structure increased the evaporation surface area.However,its effectiveness was limited when the heat transfer rate was small.

Radiative heat transfer analysis of a concave porous fin under the local thermal non-equilibrium condition:application of the clique polynomial method and physics-informed neural networks

The heat transfer through a concave permeable fin is analyzed by the local thermal non-equilibrium(LTNE)model.The governing dimensional temperature equations for the solid and fluid phases of the porous extended surface are modeled,and then are nondimensionalized by suitable dimensionless terms.Further,the obtained nondimensional equations are solved by the clique polynomial method(CPM).The effects of several dimensionless parameters on the fin's thermal profiles are shown by graphical illustrations.Additionally,the current study implements deep neural structures to solve physics-governed coupled equations,and the best-suited hyperparameters are attained by comparison with various network combinations.The results of the CPM and physicsinformed neural network(PINN)exhibit good agreement,signifying that both methods effectively solve the thermal modeling problem.

Numerical Investigations on Fluid Flow and Heat Transfer Characteristics of an Ultra-Thin Heat Pipe with Separated Wick Structures

Thermal and fluid-flow characteristics were numerically analyzed for ultra-thin heat pipes.Many studies have been conducted for ultra-thin heat pipes with a centered wick structure,but this study focused on separated wick structures to increase the evaporation/condensation surface areas within the heat pipe and to reduce the concentration of heat flux within the wick structure.A mathematical heat-pipe model was made in the threedimensional coordinate system,and the model consisted of three regions:a vapor channel,liquid-wick,and container wall regions.The conservation equations for mass,momentum,and energy were solved numerically with boundary conditions by using a code developed by one of the authors.The numerical results with the separated wick structures were compared with those with the centered,which confirmed the effectiveness of the separation of the wick structure.However,the effectiveness of the separation was affected by the position of the separated wick structure.A simple equation was presented to determine the optimum position of the separated wick structures.Numerical analyses were also conducted when the width of the heat pipe was increased with the cooled section,which clarified that the increase in the cooled-section width with the addition of wick structures wasmore effective than the increase in the cooled-section length.A 44%reduction in the total temperature difference of the heat pipe was obtained under the present numerical conditions.Furthermore,a comparison wasmade between experimental results and numerical results.

Air-Side Heat Transfer Performance Prediction for Microchannel Heat Exchangers Using Data-Driven Models with Dimensionless Numbers

This study explores the effectiveness of machine learning models in predicting the air-side performance of microchannel heat exchangers.The data were generated by experimentally validated Computational Fluid Dynam-ics(CFD)simulations of air-to-water microchannel heat exchangers.A distinctive aspect of this research is the comparative analysis of four diverse machine learning algorithms:Artificial Neural Networks(ANN),Support Vector Machines(SVM),Random Forest(RF),and Gaussian Process Regression(GPR).These models are adeptly applied to predict air-side heat transfer performance with high precision,with ANN and GPR exhibiting notably superior accuracy.Additionally,this research further delves into the influence of both geometric and operational parameters—including louvered angle,fin height,fin spacing,air inlet temperature,velocity,and tube temperature—on model performance.Moreover,it innovatively incorporates dimensionless numbers such as aspect ratio,fin height-to-spacing ratio,Reynolds number,Nusselt number,normalized air inlet temperature,temperature difference,and louvered angle into the input variables.This strategic inclusion significantly refines the predictive capabilities of the models by establishing a robust analytical framework supported by the CFD-generated database.The results show the enhanced prediction accuracy achieved by integrating dimensionless numbers,highlighting the effectiveness of data-driven approaches in precisely forecasting heat exchanger performance.This advancement is pivotal for the geometric optimization of heat exchangers,illustrating the considerable potential of integrating sophisticated modeling techniques with traditional engineering metrics.

Numerical Simulation of Liquified Natural Gas Boiling Heat Transfer Characteristics in Helically Coiled Tube-in-Tube Heat Exchangers

Helically coiled tube-in-tube(HCTT)heat exchangers are widely applied to the process technology because of their compactness and higher heat transfer efficiency.HCTT heat exchangers play an important role in liquified natural gas(LNG)use and cold energy recovery.The heat transfer characteristics,pressure distribution,and degree of vaporization of LNG in HCTT heat exchangers are numerically investigated.By comparing the simulation results of the computational model with existing experimental results,the effectiveness of the computational model is verified.The numerical simulation results show the vapor volume fraction of the HCTT heat exchanger is related to the inlet Reynolds number,inner tube diameters,and helix diameter.The vapor volume fraction increases rapidly from the fourth to the seventh equal division points of the helix tube length.On condition that the inlet Reynolds number is greater than 33500,the pressure drop rate gradually increases.When the magnitude of the vapor volume fraction is below 0.2,the heat transfer coefficient increase rate is greater than that when the vapor volume fraction is above 0.2.The heat exchange efficiency of HCTT heat exchangers increases with the decrease of the ratio of helix diameter to inner tube diameter.

Flow and Heat Transfer Features of Supercritical Pressure CO_(2) in Horizontal Flows under Whole-Wall Heating Conditions

Based on the first and second laws of thermodynamics,the heat transfer and flow(thermohydraulic)characteristics of horizontal supercritical pressure CO_(2)(S-CO_(2))in a circular pipe under heating conditions were investigated numerically.Heating flows in two different diameters(d)of 4 and 6 mm were simulated in pipes with pressures of 8 MPa,mass fluxes(G)of 300 and 400 kg/(m^(2)·s),and heat fluxes(q)of 50,75 and 100 kW/m^(2).In the d=4 mm pipe,the peak heat transfer coefficient(hb)was about 3 times higher than in the d=6 mm pipe,while the entropy production due to fluid friction in the 4 mm pipe was on average 1.1 times higher,and the entropy production due to heat transfer was on average about 67%lower.A 4 mm tube was employed to further evaluate the influence of the applied wall heat flux,the results demonstrated that the irreversibility due to heat transfer was on average more than 4 times higher when heat flux density was 100 kW/m^(2)than when the heat flux density was 50 kW/m^(2),while the peak of heat transfer coefficient increased by 1.4 times as q was decreased from 100 to 50 kW/m^(2).The effect of thermal acceleration was ignored,while the buoyancy effect resulted in secondary flow and significantly affected the flow and heat transfer features.The jet flows were found in the vicinity of the lower wall of the pipe,which made the two fields of velocity and temperature gradient more synergistic,leading to an enhancement in heat transfer in the vicinity of the upper wall.The aggravation of heat transfer resulted in high irreversibility of heat transfer in the cross-sectional area near the wall,while the local friction irreversibility was less affected by the buoyancy effect,and the distribution was uniform.The uneven distribution of thermophysical properties also confirmed that the enhanced heat transfer occurred near the wall area at the bottom of the pipe.

Comparative Numerical Analysis of Heat and Mass Transfer Characteristics in Sisko Al_(2)O_(3)-Eg and TiO_(2)-Eg Fluids on a Stretched Surface

In the current research,a thorough examination unfolds concerning the attributes of magnetohydrodynamic(MHD)boundary layer flow and heat transfer inherent to nanoliquids derived from Sisko Al_(2)O_(3)-Eg and TiO_(2)-Eg compositions.Such nanoliquids are subjected to an extending surface.Consideration is duly given to slip boundary conditions,as well as the effects stemming from variable viscosity and variable thermal conductivity.The analytical approach applied involves the application of suitable similarity transformations.These conversions serve to transform the initial set of complex nonlinear partial differential equations into a more manageable assembly of ordinary differential equations.Through the utilization of the FEM,these reformulated equations are solved,considering the specified boundary conditions.The outcomes attained are graphically depicted by means of plots and tables.These visual aids facilitate a comprehensive exploration of how diverse parameters exert influence over the distributions of velocity,temperature,and concentration.Furthermore,detailed scrutiny is directed towards the fluctuations characterizing pivotal parameters,viz.,Nusselt number,skin-friction coefficient,and Sherwood number.It is identified that the Nusselt number showcases a diminishing trend coinciding with increasing values of the volume fraction parameter(φ).This trend remains consistent regardless of whether the nanoliquid under consideration is Al_(2)O_(3)-Eg or TiO_(2)-Eg based.In contrast,both the skin-friction coefficient and Sherwood number assume lower values as the volume fraction parameter(φ)escalates.This pattern remains congruent across both classifications of nanoliquids.The findings of the study impart valuable insights into the complex interplay governing the characteristics of HMT pertaining to Sisko Al_(2)O_(3)-Eg and TiO_(2)-Eg nanoliquids along an extending surface.

Heat transfer behavior of AZ80-1%Y alloy during low-frequency electromagnetic casting

Heat transfer behaviors of AZ80?1%Y alloy during low frequency electromagnetic casting (LFEC) and direct chilling casting were studied by in-situ temperature measurement. The results demonstrated that the low frequency electromagnetic field (EM) caused forced convection in the melt during LFEC. The forced convection led to uniform solidification velocity and temperature field. EM frequency, excitation current intensity and casting temperature could control the heat transfer behavior. The forced convection could improve the microstructure and degrade the difference in microstructure between the edge and center of billet. Appropriate parameters of low frequency EM for casting Mg alloy are 20 Hz of frequency and 60 A of electric current intensity.

Solid-phase sintering process and forced convective heat transfer performance of porous-structured micro-channels

A solid-phase sintering process for the low-cost fabrication of composite micro-channels was developed. Three kinds of composite micro-channels with metallic porous structures were designed. The sintering process was studied and optimized to obtain porous-structured micro-channels with high porosity. The flow resistance and heat transfer performance in the composite micro-channels were investigated. The composite micro-channels show acceptable flow resistance, significant enhancement of heat transfer and dramatic improvement of flow boiling stability, which indicates a promising prospect for the application in forced convective heat transfer.

Heat transfer model for microwave hot in-place recycling of asphalt pavements

In order to solve for temperature fields in microwave heating for recycling asphalt mixtures, a two-dimensional heat transfer model for the asphalt mixtures within the heating range is built based on the theory of unsteady heat conduction. Four onedimensional heat transfer models are established for the asphalt mixtures outside the heating range, which are simplified into four half-infinite solids. The intensity of the radiation electric field is calculated through experiment by using heating water loads. It is suggested that the mathematical model of boundary conditions can be established in two ways, which are theoretical deduction and experimental reverse. The actual temperature field is achieved by fitting temperatures of different positions collected in the heating experiment. The simulant temperature field, which is solved with the Matlab PDE toolbox, is in good agreement with the actual temperature field. The results indicate that the proposed models have high precision and can be directly used to calculate the temperature distribution of asphalt pavements.

A Two-dimensional Heat Transfer Model for Atmosphere-land System in the Lake-dominated Alaskan Arctic

Understanding lake ice growth and its sensitivity to climate change is vital to understand the thermal regime of thaw lake systems and predict their response to climate change. In this paper, a physically-based, two-dimensional, non-steady mathematical model is developed for studying the role of shallow tundra lakes in the Alaskan Arctic. Both the radiation absorption in lake water and the phase change in permafrost are considerd in the model. The materials the model includes are snow, ice, water, unfrozen and frozen soil (peat, silt, sand and gravel). The basic inputs to the model observed mean daily air temperature and snow depth. The ability of this model to simulate lake ice growth and thickness variation, lake water temperature distribution, the thermal regime of permafrost and talik dynamics beneath lakes, and thawing rate of permafrost below and adjacent to shallow thaw lakes offers the potential to describe the effects of climate change in the Alaskan Arctic.