Observations collected in the Badan Jaran desert hinterland and edge during 19-23 August 2009 and in the Jinta Oasis during 12-16 June 2005 are used to assess three methods for calculating the heat storage of the5-20-...Observations collected in the Badan Jaran desert hinterland and edge during 19-23 August 2009 and in the Jinta Oasis during 12-16 June 2005 are used to assess three methods for calculating the heat storage of the5-20-cm soil layer.The methods evaluated include the harmonic method,the conduction-convection method,and the temperature integral method.Soil heat storage calculated using the harmonic method provides the closest match with measured values.The conduction-convection method underestimates nighttime soil heat storage.The temperature integral method best captures fluctuations in soil heat storage on sub-diurnal timescales,but overestimates the amplitude and peak values of the diurnal cycle.The relative performance of each method varies with the underlying land surface.The land surface energy balance is evaluated using observations of soil heat flux at 5-cm depth and estimates of ground heat flux adjusted to account for soil heat storage.The energy balance closure rate increases and energy balance is improved when the ground heat flux is adjusted to account for soil heat storage.The results achieved using the harmonic and temperature integral methods are superior to those achieved using the conduction-convection method.展开更多
For heat energy storage application, polyurea microcapsules containing phase change material, n-eicosane, were synthesized by using interfacial polymerization method with toluene-2,4-diisocyanate (TDI) and diethylenet...For heat energy storage application, polyurea microcapsules containing phase change material, n-eicosane, were synthesized by using interfacial polymerization method with toluene-2,4-diisocyanate (TDI) and diethylenetriamine (DETA) as monomers in an emulsion system. Poly(ethylene glycol)octyl-phenyl ether (OP), a nonionic surfactant, was the emulsifier for the system. The experimental result indicates that TDI was reacted with DETA in a mass ratio of 3 to 1. FT-IR spectra confirm the formation of wall material, polyurea, from the two monomers, TDI and DETA. Encapsulation efficiency of n-eicosane is about 75%. Microcapsule of n-eicosane melts at a temperature close to that of n-eicosane, while its stored heat energy varies with core material n-eicosane when wall material fixed. Thermo-gravimetric analysis shows that core material n-eicosane, micro-n-eicosane and wall material polyurea can withstand temperatures up to 130, 170 and 250 ℃, respectively.展开更多
基金Supported by the National Science and Technology Support Program of China(2012BAH29B03)National(Key) Basic Research and Development(973)Program of China(2009CB421402)
文摘Observations collected in the Badan Jaran desert hinterland and edge during 19-23 August 2009 and in the Jinta Oasis during 12-16 June 2005 are used to assess three methods for calculating the heat storage of the5-20-cm soil layer.The methods evaluated include the harmonic method,the conduction-convection method,and the temperature integral method.Soil heat storage calculated using the harmonic method provides the closest match with measured values.The conduction-convection method underestimates nighttime soil heat storage.The temperature integral method best captures fluctuations in soil heat storage on sub-diurnal timescales,but overestimates the amplitude and peak values of the diurnal cycle.The relative performance of each method varies with the underlying land surface.The land surface energy balance is evaluated using observations of soil heat flux at 5-cm depth and estimates of ground heat flux adjusted to account for soil heat storage.The energy balance closure rate increases and energy balance is improved when the ground heat flux is adjusted to account for soil heat storage.The results achieved using the harmonic and temperature integral methods are superior to those achieved using the conduction-convection method.
基金Project supported by the National Natural Science Foundation of China (No. 20373072).
文摘For heat energy storage application, polyurea microcapsules containing phase change material, n-eicosane, were synthesized by using interfacial polymerization method with toluene-2,4-diisocyanate (TDI) and diethylenetriamine (DETA) as monomers in an emulsion system. Poly(ethylene glycol)octyl-phenyl ether (OP), a nonionic surfactant, was the emulsifier for the system. The experimental result indicates that TDI was reacted with DETA in a mass ratio of 3 to 1. FT-IR spectra confirm the formation of wall material, polyurea, from the two monomers, TDI and DETA. Encapsulation efficiency of n-eicosane is about 75%. Microcapsule of n-eicosane melts at a temperature close to that of n-eicosane, while its stored heat energy varies with core material n-eicosane when wall material fixed. Thermo-gravimetric analysis shows that core material n-eicosane, micro-n-eicosane and wall material polyurea can withstand temperatures up to 130, 170 and 250 ℃, respectively.
