Hot-filament chemical vapor deposition ( HFCVD) is a promising method for commercial production of diamond films. Filament performance in heat transfer and hydrogen decomposition in reactive environment was investigat...Hot-filament chemical vapor deposition ( HFCVD) is a promising method for commercial production of diamond films. Filament performance in heat transfer and hydrogen decomposition in reactive environment was investigated. Power consumption by the filament in vacuum, helium and 2% CH4/H2 was experimentally determined in temperature range 1300℃-2200℃. Filament heat transfer mechanism in C-H reactive environment was calculated and analyzed. The result shows that due to surface carburization and slight carbon deposition, radiation in stead of hydrogen dissociation, becomes the largest contributor to power consumption. Filament-surface dissociation of H2 was observed at temperatures below 1873K, demonstrating the feasibility of diamond growth at low filament temperatures. The effective activation energies of hydrogen dissociation on several clean refractory flaments were derived from power consumption data in literatures. They are all lower than that of thermal dissociation of hydrogen revealing the nature of catalytic dissociation of hydrogen on filament surface. Observation of substrate temperature suggested a weaker role of atomic hydrogen recombination in heating substrates in C-H environment than in pure hydrogen.展开更多
Metal organic chemical vapor deposition(MOCVD) is a key equipment in the manufacturing of semiconductor optoelectronic devices and microwave devices in industry. Heating system is a vital part of MOCVD. Specific heati...Metal organic chemical vapor deposition(MOCVD) is a key equipment in the manufacturing of semiconductor optoelectronic devices and microwave devices in industry. Heating system is a vital part of MOCVD. Specific heating device and thermal control technology are needed for each new reactor design. By using resistance-wire heating MOCVD reaction chamber model, thermal analysis and structure optimization of the reactor were developed from the vertical position and the distance between coils of the resistance-wire heater. It is indicated that, within a certain range, the average temperature of the graphite susceptor varies linearly with the vertical distance of heater to susceptor, and with the changed distances between the coils; furthermore, single resistance-wire heater should be placed loosely in the internal and tightly in the external. The modulate accuracy of the temperature field approximately equals the change of the average temperature corresponding to the change of the coil position.展开更多
In this paper the influences of the drawing temperature on physical structures and properties of PET filaments have been studied. The results show that the temperatures of the first-stage drawing will have significant...In this paper the influences of the drawing temperature on physical structures and properties of PET filaments have been studied. The results show that the temperatures of the first-stage drawing will have significant effects on birefringence development of filaments during the second stage drawing, as well as the oriented amorphous filaments change to crystanine-oriented filaments after heat treatment. Increasing temperature of the second-stage drawing can be greatly increasing the crystallinity and decreasing the dry heat shrinkage of the filaments.展开更多
Boron has been considered a promising powdered metal fuel for enhancing composite propellants'energy output due to its high energy density.However,the high ignition temperature and low combustion efficiency limit ...Boron has been considered a promising powdered metal fuel for enhancing composite propellants'energy output due to its high energy density.However,the high ignition temperature and low combustion efficiency limit the application of boron powder due to the high boiling point of the boron oxide layer.Much research is ongoing to overcome these shortcomings,and one potential approach is to introduce a small quantity of metal oxide additives to promote the reaction of boron.This study prepared boron-rich fuels with 10 wt%of eight nano-metal oxide additives by mechanical ball milling.The effect of metal oxides on the thermo-oxidation,ignition,and combustion properties of boron powder was comprehensively studied by the thermogravimetric analysis(TG),the electrically heated filament setup(T-jump),and the laser-induced combustion experiments.TG experiments at 5 K/min found that Bi_(2)O_(3),MoO_(3),TiO_(2),Fe_(2)O_(3),and CuO can promote thermo-oxidation of boron.Compared to pure boron,Tonsetcan be reduced from 569℃to a minimum of 449℃(B/Bi_(2)O_(3)).Infrared temperature measurement in T-jump tests showed that when heated by an electric heating wire at rates from 1000 K/s to 25000 K/s,the ignition temperatures of B/Bi_(2)O_(3) are the lowest,even lower than the melting point of boron oxide.Ignition images and SEM for the products further showed that the high heating rate is beneficial to the rapid reaction of boron powder in the single-particle combustion state.Fuels(B/Bi_(2)O_(3),B/MoO_(3),and B/CuO)were mixed with the oxidant AP and ignited by laser to study the combustion performance.The results showed that B/CuO/AP has the largest flame area,the highest BO_(2) characteristic spectral intensity,and the largest burn rate for powder lines.To combine the advantages of CuO and Bi_(2)O_(3),binary metal oxide(CBO,mass ratio of 3:1)was prepared and the test results showed that CBO can very well improve both ignition and combustion properties of boron.Especially B/CBO/AP has the highest burn rate compared with all fuels containing other additives.It was found that multi-component metal-oxide additive can more synergistically improve the reaction characteristics of boron powder than unary additive.These findings contribute to the development of boron-rich fuels and their application in propellants.展开更多
为了进一步提高电子束流发生系统工作的可靠性和稳定性,提高电子束加工质量,采用AC-DC-AC-DC-AC-DC的拓扑电路、新型功率变压器、高压脉冲检测技术、优化的束流反馈控制与灯丝加热电流闭环反馈控制技术等,分别优化了高压加速电源、偏压...为了进一步提高电子束流发生系统工作的可靠性和稳定性,提高电子束加工质量,采用AC-DC-AC-DC-AC-DC的拓扑电路、新型功率变压器、高压脉冲检测技术、优化的束流反馈控制与灯丝加热电流闭环反馈控制技术等,分别优化了高压加速电源、偏压电源与灯丝加热电源。将所研制逆变电源与150 k V/30 k W电子枪、真空系统等组成了一套电子束流发生系统,测试了该电子束流发生系统输出的高压、最大束流以及灯丝加热电流、偏压变化对束流输出的影响。试验结果表明:经过优化的逆变电源高压输出达到-150 k V,高压输出线性度较好,最大束流达到200 m A;高压、灯丝加热电流给定时,随着偏压降低,束流输出逐渐增大;高压、偏压给定时,随着灯丝加热电流增大,束流输出存在死区、线性增大区和恒流区。展开更多
基金Supported by the National Natural Science Foundation of China under contract No.59976038.
文摘Hot-filament chemical vapor deposition ( HFCVD) is a promising method for commercial production of diamond films. Filament performance in heat transfer and hydrogen decomposition in reactive environment was investigated. Power consumption by the filament in vacuum, helium and 2% CH4/H2 was experimentally determined in temperature range 1300℃-2200℃. Filament heat transfer mechanism in C-H reactive environment was calculated and analyzed. The result shows that due to surface carburization and slight carbon deposition, radiation in stead of hydrogen dissociation, becomes the largest contributor to power consumption. Filament-surface dissociation of H2 was observed at temperatures below 1873K, demonstrating the feasibility of diamond growth at low filament temperatures. The effective activation energies of hydrogen dissociation on several clean refractory flaments were derived from power consumption data in literatures. They are all lower than that of thermal dissociation of hydrogen revealing the nature of catalytic dissociation of hydrogen on filament surface. Observation of substrate temperature suggested a weaker role of atomic hydrogen recombination in heating substrates in C-H environment than in pure hydrogen.
基金Projects(61376076,61274026,61377024)supported by the National Natural Science Foundation of ChinaProjects(12C0108,13C321)supported by the Scientific Research Fund of Hunan Provincial Education Department,ChinaProjects(2013FJ2011,2013FJ4232)supported by the Science and Technology Plan of Hunan Province,China
文摘Metal organic chemical vapor deposition(MOCVD) is a key equipment in the manufacturing of semiconductor optoelectronic devices and microwave devices in industry. Heating system is a vital part of MOCVD. Specific heating device and thermal control technology are needed for each new reactor design. By using resistance-wire heating MOCVD reaction chamber model, thermal analysis and structure optimization of the reactor were developed from the vertical position and the distance between coils of the resistance-wire heater. It is indicated that, within a certain range, the average temperature of the graphite susceptor varies linearly with the vertical distance of heater to susceptor, and with the changed distances between the coils; furthermore, single resistance-wire heater should be placed loosely in the internal and tightly in the external. The modulate accuracy of the temperature field approximately equals the change of the average temperature corresponding to the change of the coil position.
文摘In this paper the influences of the drawing temperature on physical structures and properties of PET filaments have been studied. The results show that the temperatures of the first-stage drawing will have significant effects on birefringence development of filaments during the second stage drawing, as well as the oriented amorphous filaments change to crystanine-oriented filaments after heat treatment. Increasing temperature of the second-stage drawing can be greatly increasing the crystallinity and decreasing the dry heat shrinkage of the filaments.
基金State Key Laboratory of Explosion Science and Safety Protection of China (Grant No.QNKT21-8)National Natural Science Foundation of China (Grant No.12302432)to provide financial support。
文摘Boron has been considered a promising powdered metal fuel for enhancing composite propellants'energy output due to its high energy density.However,the high ignition temperature and low combustion efficiency limit the application of boron powder due to the high boiling point of the boron oxide layer.Much research is ongoing to overcome these shortcomings,and one potential approach is to introduce a small quantity of metal oxide additives to promote the reaction of boron.This study prepared boron-rich fuels with 10 wt%of eight nano-metal oxide additives by mechanical ball milling.The effect of metal oxides on the thermo-oxidation,ignition,and combustion properties of boron powder was comprehensively studied by the thermogravimetric analysis(TG),the electrically heated filament setup(T-jump),and the laser-induced combustion experiments.TG experiments at 5 K/min found that Bi_(2)O_(3),MoO_(3),TiO_(2),Fe_(2)O_(3),and CuO can promote thermo-oxidation of boron.Compared to pure boron,Tonsetcan be reduced from 569℃to a minimum of 449℃(B/Bi_(2)O_(3)).Infrared temperature measurement in T-jump tests showed that when heated by an electric heating wire at rates from 1000 K/s to 25000 K/s,the ignition temperatures of B/Bi_(2)O_(3) are the lowest,even lower than the melting point of boron oxide.Ignition images and SEM for the products further showed that the high heating rate is beneficial to the rapid reaction of boron powder in the single-particle combustion state.Fuels(B/Bi_(2)O_(3),B/MoO_(3),and B/CuO)were mixed with the oxidant AP and ignited by laser to study the combustion performance.The results showed that B/CuO/AP has the largest flame area,the highest BO_(2) characteristic spectral intensity,and the largest burn rate for powder lines.To combine the advantages of CuO and Bi_(2)O_(3),binary metal oxide(CBO,mass ratio of 3:1)was prepared and the test results showed that CBO can very well improve both ignition and combustion properties of boron.Especially B/CBO/AP has the highest burn rate compared with all fuels containing other additives.It was found that multi-component metal-oxide additive can more synergistically improve the reaction characteristics of boron powder than unary additive.These findings contribute to the development of boron-rich fuels and their application in propellants.
文摘为了进一步提高电子束流发生系统工作的可靠性和稳定性,提高电子束加工质量,采用AC-DC-AC-DC-AC-DC的拓扑电路、新型功率变压器、高压脉冲检测技术、优化的束流反馈控制与灯丝加热电流闭环反馈控制技术等,分别优化了高压加速电源、偏压电源与灯丝加热电源。将所研制逆变电源与150 k V/30 k W电子枪、真空系统等组成了一套电子束流发生系统,测试了该电子束流发生系统输出的高压、最大束流以及灯丝加热电流、偏压变化对束流输出的影响。试验结果表明:经过优化的逆变电源高压输出达到-150 k V,高压输出线性度较好,最大束流达到200 m A;高压、灯丝加热电流给定时,随着偏压降低,束流输出逐渐增大;高压、偏压给定时,随着灯丝加热电流增大,束流输出存在死区、线性增大区和恒流区。
