Spatiotemporal phase change materials for thermal energy long-term storage and controllable release

Phase change materials(PCMs)have attracted much attention in the field of solar thermal utilization recently,due to their outstanding thermal energy storage performance.However,PCMs usually release their stored latent heat spontaneously as the temperature below the phase transition temperature,rendering thermal energy storage and release uncontrollable,thus hindering their practical application in time and space.Herein,we developed erythritol/sodium carboxymethylcellulose/tetrasodium ethylenediaminetetraacetate(ERY/CMC/EDTA-4Na)composite PCMs with novel spatiotemporal thermal energy storage properties,defined as spatiotemporal PCMs(STPCMs),which exhibit the capacity of thermal energy long-term storage and controllable release.Our results show that the composite PCMs are unable to lose latent heat due to spontaneous crystallization during cooling,but can controllably release thermal energy through cold crystallization during reheating.The cold-crystallization temperature and enthalpy of composite PCMs can be adjusted by proportional addition of EDTA-4Na to the composite.When the mass fractions of CMC and EDTA-4Na are both 10%,the composite PCMs can exhibit the optical coldcrystallization temperature of 51.7℃ and enthalpy of 178.1 J/g.The supercooled composite PCMs without latent heat release can be maintained at room temperature(10-25℃)for up to more than two months,and subsequently the stored latent heat can be controllably released by means of thermal triggering or heterogeneous nucleation.Our findings provide novel insights into the design and construction of new PCMs with spatiotemporal performance of thermal energy long-term storage and controllable release,and consequently open a new door for the development of advanced solar thermal utilization techniques on the basis of STPCMs.

A brand new green coating technology for realizing the regulation of spherical propellant energy release process

To achieve the controllable release of energy of nitrocellulose-based propellants,this paper combines the cellulose-based nanocomposites aqueous coating(Surelease®-NC)with fluidized bed coating equipment to successfully prepare the coated spherical propellant for the first time.The effects of fluidized bed coating temperature,air velocity,flow speed and atomization pressure on the adhesion rate,coating integrity and coating uniformity of the coated spherical propellant were investigated,and the preparation of coated spherical propellant with homogeneous size and structural integrity was achieved for the first time.The microscopic morphology,chemical structure,water vapor adsorption behavior,combustion performance,and ageing resistance property of the coated spherical propellant were systematically investigated by,Fourier transforms infrared spectroscopy(FTIR),Micro confocal raman spectrometer,field scanning electron microscopy(SEM),dynamic vapor adsorption techniques,and closed bomb test,confirming the surface core-shell structure and the tightly bonded interfacial structure of coated spherical propellant.Meanwhile,the coated spherical propellant has good hygroscopic,excellent progressive burning and long storage stability.

Optimal Scheduling Method of Cogeneration System with Heat Storage Device Based on Memetic Algorithm

Electric-heat coupling characteristics of a cogeneration system and the operating mode of fixing electricity with heat are the main reasons for wind abandonment during the heating season in the Three North area.To improve the wind-power absorption capacity and operating economy of the system,the structure of the system is improved by adding a heat storage device and an electric boiler.First,aiming at the minimum operating cost of the system,the optimal scheduling model of the cogeneration system,including a heat storage device and electric boiler,is constructed.Second,according to the characteristics of the problem,a cultural gene algorithm program is compiled to simulate the calculation example.Finally,through the system improvement,the comparison between the conditions before and after and the simulation solutions of similar algorithms prove the effectiveness of the proposed scheme.The simulation results show that adding the heat storage device and electric boiler to the scheduling optimization process not only improves the wind power consumption capacity of the cogeneration system but also reduces the operating cost of the system by significantly reducing the coal consumption of the unit and improving the economy of the system operation.The cultural gene algorithm framework has both the global evolution process of the population and the local search for the characteristics of the problem,which has a better optimization effect on the solution.

Research on Operation Optimization of Heating System Based on Electric Storage Coupled Solar Energy and Air Source Heat Pump

For heating systems based on electricity storage coupled with solar energy and an air source heat pump(ECSA),choosing the appropriate combination of heat sources according to local conditions is the key to improving economic efficiency.In this paper,four cities in three climatic regions in China were selected,namely Nanjing in the hot summer and cold winter region,Tianjin in the cold region,Shenyang and Harbin in the severe cold winter region.The levelized cost of heat(LCOH)was used as the economic evaluation index,and the energy consumption and emissions of different pollutants were analyzed.TRNSYS software was used to simulate and analyze the system performance.The Hooke-Jeeves optimization algorithm and GenOpt software were used to optimize the system parameters.The results showed that ECSA systemhad an excellent operation effect in cold region and hot summer and cold winter region.Compared with ECS system,the systemenergy consumption,and the emission of different pollutants of ECSA system can be reduced by a maximum of 1.37 times.In cold region,the initial investment in an air source heat pump is higher due to the lower ambient temperature,resulting in an increase in the LOCH value of ECSA system.After the LOCH value of ECSA system in each region was optimized,the heating cost of the system was reduced,but also resulted in an increase in energy consumption and the emission of different pollutant gases.

Storage and Timed Release of Acetaminophen from Porous Carbonaceous Materials

Six carbon powders with varied surface areas and porosities were used to store and release acetaminophen (ACT). A 10 mg/mL solution of acetaminophen in phosphate buffer solution (pH = 7.0) at 25℃ with exposure to carbon powder for 72 hours was used to drive the maximum loading of acetaminophen into the powders. Carboxen 1012 (BET surface area of1500 m2/g) powder exhibited the greatest maximum adsorption of ACT (up to 62% by mass). The maximum ACT adsorption was correlated with surface area and porosity. The most effective carbon powders for binding ACT were ones containing high mesopore volumes. Loaded carbon powder was separated from the ACT solution and then phosphate buffer solution (pH = 7.0) was combined with the loaded carbon powder and ACT absorbance readings at 243 nm were taken over time. The various carbon powders were able to release a portion of the ACT that they originally adsorbed. The Carboxen 1012 powder displayed the greatest ACT release with a rapid initial release followed by a steady but slightly declining release over a time period of 2 to 11 weeks. The results were supportive of mesoporous carbons such as Carboxen 1012 being suitable for drug loading and release.

Impact of Anthropogenic Heat Release on Regional Climate in Three Vast Urban Agglomerations in China

We simulated the impact of anthropogenic heat release （AHR） on the regional climate in three vast city agglomerations in China using the Weather Research and Forecasting model with nested high-resolution modeling.Based on energy consumption and high-quality land use data,we designed two scenarios to represent no-AHR and current-AHR conditions.By comparing the results of the two numerical experiments,changes of surface air temperature and precipitation due to AHR were quantified and analyzed.We concluded that AHR increases the temperature in these urbanized areas by about 0.5℃-1℃,and this increase is more pronounced in winter than in other seasons.The inclusion of AHR enhances the convergence of water vapor over urbanized areas.Together with the warming of the lower troposphere and the enhancement of ascending motions caused by AHR,the average convective available potential energy in urbanized areas is increased.Rainfall amounts in summer over urbanized areas are likely to increase and regional precipitation patterns to be altered to some extent.

Interannual variability of mixed layer depth and heat storage of upper layer in the tropical Pacific Ocean

By using the upper layer data(downloaded from the web of the Scripps Institution of Oceanography),the interannual variability of the heat storage of upper layer(from surface to 400 m depth) and the mixed layer depth in the tropical Pacific Ocean are investigated. The abnormal signal of the warm event comes from the central and west Pacific Ocean, whereas it is regarded that the abnormal signal of the warm event comes from the east Pacific Ocean in the popular viewpoint. From the viewpoint on the evolution of the interannual variability of the mixed layer depth and the heat storage of the whole upper layer, the difference between the two types of El Nino is so small that it can be neglected. During these two El Nino/La Nina events(1972/1973 and 1997/1998), other than the case of the heat storage or for the mixed layer depth, the abnormal signal propagates from the central and west Pacific Ocean to the east usually by the path along the equator whereas the abnormal signal propagates from the east to the west by the path northern to the equator. For the interannual variability, the evolution of the mixed layer depth corresponds to that of the heat storage in the upper layer very well. This is quite different from the evolution of seasonality.

Synthesis and characterization of salt-impregnated anodic aluminum oxide composites for low-grade heat storage

Thermochemical heat storage(THS)systems have recently attracted a lot of attention in research and development.In this study,an anodic aluminum oxide(AAO)template,fabricated by a two-step anodization method,was used for the first time as the matrix material for a THS system.Different salts were studied as thermochemical materials for their suitability in low-grade heat storage application driven by solar energy for an open system.Compositions were prepared by absorbing CaCl2,MgCl2,LiCl,LiNO3 and mixtures of these salts under a vacuum in an AAO matrix.Field Emission Scanning Electron Microscopy was used to examine the morphology of the produced AAO composites.Thermal energy storage capacities of the composites were characterized using a differential scanning calorimeter.Characterization analysis showed that anodized Al plates were suitable matrix materials for THS systems,and composite sorbent prepared with a 1:1 ratio LiCl/LiNO3 salt mixture had the highest energy value among all composites,with an energy density of 468.1 k J·kg-1.

Heat transfer and parametric studies of an encapsulated phase change material based cool thermal energy storage system

This work investigates the transient behaviour of a phase change material based cool thermal energy storage (CTES) system comprised of a cylindrical storage tank filled with encapsulated phase change materials (PCMs) in spherical container integrated with an ethylene glycol chiller plant. A simulation program was developed to evaluate the temperature histories of the heat transfer fluid (HTF) and the phase change material at any axial location during the charging period. The results of the model were validated by comparison with experimental results of temperature profiles of HTF and PCM. The model was also used to investigate the effect of porosity, Stanton number, Stefan number and Peclet number on CTES system performance. The results showed that increase in porosity contributes to a higher rate of energy storage. However, for a given geometry and heat transfer coefficient, the mass of PCM charged in the unit decreases as the increase in porosity. The St number as well as the Ste number is also influential in the performance of the unit. The model is a convenient and more suitable method to determine the heat transfer characteristics of CTES system. The results reported are much useful for designing CTES system.

Operation Performance of Central Solar Heating System with Seasonal Storage Water Tank in Harbin

This paper presented a preliminary research on the central solar heating system with seasonal storage(CSHSSS)used in cold climate in China.A mathematical model of the solar energy seasonal storage water tank used in the central solar heating system was firstly developed based on energy conservation.This was followed by the simulation of the CSHSSS used in a two-floor villa in Harbin,and analysis of the impacts on storage water temperature of tank volume,solar collector area,tank burial depth,insulation thickness around the tank,etc.The results show there is a relatively economical tank volume to optimize the system efficiency,which decreases with increasing tank volume at the constant collector area,and increases with increasing collector area at the constant tank volume.Furthermore,the insulation thickness has obvious effect on avoiding heat loss,while the tank burial depth doesn't.In addition,the relationship between the solar collector efficiency and storage water temperature is also obtained,it decreases quickly with increasing storing water temperature,and then increases slowly after starting space heating system.These may be helpful for relevant design and optimization in cold climates in China and all over the world.

Performance of underground heat storage system in a double-film-covered greenhouse

An underground heat storage system in a double-film-covered greenhouse and an adjacent greenhouse without the heat storage system were designed on the basis of plant physiology to reduce the energy consumption in greenhouses. The results indicated that the floor temperature was respectively 5.2℃, 4.6℃ and 2.0 ℃ higher than that of the soil in the adjacent reference greenhouse after heat storage in a clear, cloudy and overcast sky in winter. Results showed that the temperature and humidity were feasible for plant growth in the heat saving greenhouse.

Numerical simulation of heat release performance of filling body under condition of heat extracted by fluid flowing in buried tube

It is the basic requirement of the synergetic exploitation of deep mineral resources and geothermal resources to arrange the heat transfer tube in filling body. The heat release performance of filling body directly impacts on the exploiting efficiency of geothermal energy. Based on heat transfer theory, a three-dimensional unsteady heat transfer model of filling body is established by using FLUENT simulation software. Taking the horizontal U-shaped buried pipe as research object, the variation of temperature field in filling body around buried pipe is analyzed during the heat release process of filling body;the initial temperature of filling body, the diameter of buried pipe, the inlet temperature and inlet velocity of heat transfer fluid influencing of coupling heat transfer, which exists between heat transfer fluid and surrounding filling body within a certain axial distance of buried tube, and influencing of temperature difference between inlet and outlet of heat transfer fluid and on heat transfer performance of filling body are also discussed. It not only lays a theoretical foundation for the synergetic exploitation of mineral resources and geothermal energy in deep mines, but also provides a reference basis for the arrangement of buried pipes in filling body as well as the selection of working conditions for heat transfer fluid.

Roles of Mesoscale Terrain and Latent Heat Release in Typhoon Precipitation: A Numerical Case Study

The mesoscale orographic effects on typhoon Aere＇s precipitation are simulated using an Advanced Regional Eta-coordinate Model （AREM） version 3.0. In particular, the effects of the latent heat release are studied by two comparable experiments： with and without condensational heating. The results show that the typhoon rainfall is tripled by the southeastern China mesoscale terrain, and the condensational heating is responsible for at least half of the increase. One role of the latent heat release is to warm the atmosphere, leading to a depression of the surface pressure, which then causes a larger pressure difference in the zonal direction. This pressure gradient guides the water vapour to flow into the foothills, which in turn amplifies the water vapour flux divergence amplified, causing the typhoon rainfall to increase eventually. The other role of the latent heat release is to make the convection more organized, resulting in a relatively smaller rain area and stronger precipitation.

Numerical Analysis of Doublet Wells for Cold Energy Storage on Heat Damage Treatment in Deep Mines

Deep mining is an inevitable tendency in the development of coal industry. There are many heat damage problems with the increase of mining depth. The technology of using doublet wells, together with Heat Exchange Machine Systems （HEMSs）, to store cold energy is a key to solve the heat damage problems in deep mines. Based on the geological conditions, thermodynamic and hydraulic parameters of Jiahe Mine, the isotherms in the period of cold energy storage and refrigeration and the volumes of cold water within different temperature ranges of the cold energy storage well were numerically analyzed. The results show that 1） with the same pumped and injected water volumes, the lower the temperature of injected water is, the larger the volume.of cold water in the cold energy storage well is. With the larger volume, the effect of cold energy storage is better. 2） the larger the volumes of pumped and reinjected water frigeration is better. And 3） without disturbance, the volume and temperature of cold water in the cold energy storage well can keep unchanged or have only a little change for a long time. Therefore the technology of doublet wells for cold energy storage is feasible and the cold energy storage aquifers can meet the requirement of the technology.

Operating performance of novel reverse-cycle defrosting method based on thermal energy storage for air source heat pump

To solve the fundamental problem of insufficient heat available during defrosting while ensuring the efficient and safe system operation for air-source heat pumps (ASHPs). A novel reverse-cycle defrosting (NRCD) method based on thermal energy storage to eliminate frost off the outdoor coil surface was developed. Comparative experiments using both the stand reverse cycle defrosting (SRCD) method and the NRCD method were carried out on an experimental ASHP unit with a nominal 2.5 kW heating capacity. The results indicate that during defrosting operation, using the NRCD method improves discharge and suction pressures by 0.24 MPa and 0.19 MPa, respectively, shortens defrosting duration by 60%, and reduces the defrosting energy consumption by 48.1% in the experimental environment, compared with those by the use of SRCD method. Therefore, using the NRCD method can shorten the defrosting duration, improve the indoor thermal comfort, and reduce the defrosting energy consumption in defrosting.

Effect of Radial Porosity Oscillation on the Thermal Performance of Packed Bed Latent Heat Storage

Owing to its high heat storage capacity and fast heat transfer rate,packed bed latent heat storage(LHS)is considered as a promising method to store thermal energy.In a packed bed,the wall effect can impact the packing arrangement of phase change material(PCM)capsules,inducing radial porosity oscillation.In this study,an actual-arrangement-based three-dimensional packed bed LHS model was built to consider the radial porosity oscillation.Its fluid flow and heat transfer were analyzed.With different cylindrical sub-surfaces intercepted along the radial direction in the packed bed,the corresponding relationships between the arrangement of capsules and porosity oscillation were identified.The oscillating distribution of radial porosity led to a non-uniform distribution of heat transfer fluid(HTF)velocity.As a result,radial temperature distributions and liquid fraction distributions of PCMs were further affected.The effects of different dimensionless parameters(e.g.,tube-to-capsule diameter ratio,Reynolds number,and Stefan number)on the radial characteristics of HTF and PCMs were discussed.The results showed that different diameter ratios correspond to different radial porosity distributions.Further,with an increase in diameter ratio,HTF velocity varies significantly in the near wall region while the non-uniformity of HTF velocity in the center region will decrease.The Reynolds and Stefan numbers slightly impact the relative velocity distribution of the HTF-while higher Reynolds numbers can lead to a proportional improvement of velocity,an increase in Stefan number can promote heat storage of the packed bed LHS system.

Melting heat transfer enhancement of a horizontal latent heat storage unit by fern-fractal fins

The latent heat storage(LHS)technique is of crucial importance in chemical energy engineering.Inspired by multi-bifurcated fern leaves,a mimic fern-fractal fin is designed to improve the thermal energy charging efficiency.This paper develops a transient melting model of a rectangular LHS unit using fern-fractal fins,and their melting behaviors are compared with the conventional fins.Besides,a parametric optimization of fernfractal fins is conducted for maximizing the thermal efficiency based on the response surface method(RSM).The results indicate that the temperature uniformity is more superior and the melting duration is shorter for the fern-fractal LHS unit when compared with the conventional one.Interestingly,the fern-fractal LHS device presents a slower heat storage rate during the initial conduction-dominated and early convection-dominated melting stages,while a prominent melting enhancement is achieved during the later melting stage.The shortest melting time is obtained based on the RSM technique when a fern-fractal fin with length ratio α=0.94 and branch angle θ=54.7°is utilized.Compared with a conventional fin,the averaged heat storage rate increases by 88.3%,and the total melting time is declined by 40.3%for an optimized fern-fractal fin.

Fabrication of Al_2O_3-NaCl Composite Heat Storage Materials by One-step Synthesis Method

Thermal energy storage is an attractive option for effectiveness since it gives flexibility and reduces energy consumption and costs. New composite materials for storage and transformation of heat of NaCl-Al2O3composite materials were synthesized by one-step synthesis method. The chemical composition, morphology, structure, and thermal properties were investigated by XRD, EDS, SEM, and DSC. The results show that NaCl can be absorbed by Al2O3particle from 800 to 900 ℃ for Al2O3particle surface is rich active structure. The results also indicate that the leakage of NaCl when the phase change can be prevented by Al2O3particles and the enthalpy of phase change of NaCl-Al2O3material is 362 J/g. The composites have an excellent heat storage capacity. Therefore, this study contributes to one new thought and method to prepare high temperature heat storage material and this material can be applied in future thermal engineering.

Simultaneous CO_(2) capture and thermochemical heat storage by modified carbide slag in coupled calcium looping and CaO/Ca(OH)2 cycles

The simultaneous CO_(2) capture and heat storage performances of the modified carbide slag with byproduct of biodiesel were investigated in the process coupled calcium looping and CaO/Ca(OH)2 thermochemical heat storage using air as the heat transfer fluid.The modified carbide slag with by-product of biodiesel exhibits superior CO_(2) capture and heat storage capacities in the coupled calcium looping and heat storage cycles.The hydration conversion and heat storage density of the modified carbide slag after 30 heat storage cycles are 0.65 mol·mol^(-1) and 1.14 GJ·t^(-1),respectively,which are 1.6 times as high as those of calcined carbide slag.The negative effect of CO_(2) in air as the heat storage fluid on the heat storage capacity of the modified carbide slag is overcome by introducing CO_(2) capture cycles.In addition,the CO_(2) capture reactivity of the modified carbide slag after the multiple calcium looping cycles is enhanced by the introduction of heat storage cycles.By introducing 10 heat storage cycles after the 10th and 15th CO_(2) capture cycles,the CO_(2) capture capacities of the modified carbide slag are subsequently improved by 32%and 43%,respectively.The porous and loose structure of modified carbide slag reduces the diffusion resistances of CO_(2) and steam in the material in the coupled process.The formed CaCO_(3)in the modified carbide slag as a result of air as the heat transfer fluid in heat storage cycles decomposes to regenerate CaO in calcium looping cycles,which improves heat storage capacity.Therefore,the modified carbide slag with by-product of biodiesel seems promising in the coupled calcium looping and CaO/Ca(OH)_(2) heat storage cycles.

Increases in Anthropogenic Heat Release from Energy Consumption Lead to More Frequent Extreme Heat Events in Urban Cities

With economic development and rapid urbanization,increases in Gross Domestic Product and population in fastgrowing cities since the turn of the 21st Century have led to increases in energy consumption.Anthropogenic heat flux released to the near-surface atmosphere has led to changes in urban thermal environments and severe extreme temperature events.To investigate the effects of energy consumption on urban extreme temperature events,including extreme heat and cold events,a dynamic representation scheme of anthropogenic heat release(AHR)was implemented in the Advanced Research version of the Weather Research and Forecasting(WRF)model,and AHR data were developed based on energy consumption and population density in a case study of Beijing,China.Two simulations during 1999−2017 were then conducted using the developed WRF model with 3-km resolution with and without the AHR scheme.It was shown that the mean temperature increased with the increase in AHR,and more frequent extreme heat events were produced,with an annual increase of 0.02−0.19 days,as well as less frequent extreme cold events,with an annual decrease of 0.26−0.56 days,based on seven extreme temperature indices in the city center.AHR increased the sensible heat flux and led to surface energy budget changes,strengthening the dynamic processes in the atmospheric boundary layer that reduce AHR heating efficiency more in summer than in winter.In addition,it was concluded that suitable energy management might help to mitigate the impact of extreme temperature events in different seasons.