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Analysis and Assessment on the Heavy Metals in a Severely Degraded Subtropical Red Soil Region
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作者 Fang Wang Yun Zhou +5 位作者 Xiangping Fu Yuxiao Zhao Yiyao Wen Xintao Cui Shunbao Lu Yanjie Zhang 《American Journal of Plant Sciences》 CAS 2024年第2期110-121,共12页
5 different forests of Pinus massoniana, Schima superba, Liquidambar formosana, P. massoniana × S. superba, P. massoniana × L. formosana as the research object were set up to study the Cr, Cu and Zn content ... 5 different forests of Pinus massoniana, Schima superba, Liquidambar formosana, P. massoniana × S. superba, P. massoniana × L. formosana as the research object were set up to study the Cr, Cu and Zn content of degraded red soil region in subtropics. The soil heavy metal pollution degree was evaluated by national environmental quality standard (II class). The results showed that three soil metals of P. massoniana × S. superba were the highest, and the soil metals enrichment ability was strong. The order of single factor pollution index of metal elements was Cu (1.38) > Cr (0.81) > Zn (0.42), and moderately pollution, pollution warning and no pollution, respectively. There was no significant correlation between three soil heavy metals and soil total carbon (TC), total nitrogen (TN) and total phosphorus (TP). These results suggested that the accumulation of heavy metal elements was not derived from the parent material of soil. There was a significant positive correlation between the three metal elements which indicated that the sources of the three elements were similar. The structural equation model showed that the direct and indirect effects among the influencing factors ultimately affected the activity of heavy metals by cascade effects. 展开更多
关键词 Subtropical Forest Type Degraded Red Soil heavy Metals Pollution Evaluation
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Microplastic and Heavy Metals Distributions in Urban Rivers Sediments,China
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作者 SONG Dandan SHANG Yujun +4 位作者 WANG Xiuli ZHUANG Yuwei GUO Hui BI Shuping HU Jianjun 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第4期1015-1025,共11页
This study investigated the distribution of microplastics and heavy metals,along with the interaction between the two in the sediments of urban rivers in China.Results showed that the abundance of microplastics ranged... This study investigated the distribution of microplastics and heavy metals,along with the interaction between the two in the sediments of urban rivers in China.Results showed that the abundance of microplastics ranged from 2412±187.5 to 7638±1312items kg^(-1)dry sediment across different survey stations,with an average abundance at(4388±713)items kg^(-1)dry sediment.Upon further categorization,it was found that transparent fragments were the primary color and type of microplastics present.The potential ecological risk index(RI)of heavy metals in sediments suggested a low level of ecological risk within a majority of the urban rivers studied.Cd was identified as the main potential ecological risk factor in the sediments of the studied areas.There was a relatively good significant linear relationship between the RI of heavy metals and the abundance of microplastics,bolstering the linkage between these two environmental pollutants.However,the concentrations of heavy metals in microplastics were not dependent on their corresponding contents in sediments.In fact,the concentration of Cu,Cd,and As in microplastics were higher than those in the sediments.This finding confirmed that microplastics could serve as carriers of heavy metals and introduce potential risks to aquatic wildlife and human through the food chain. 展开更多
关键词 microplastic heavy metals risk assessment river sediments
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Magnetism, heat capacity, magnetocaloric effect, and magneto-transport properties of heavy fermion antiferromagnet CeGaSi
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作者 张黎博 董庆新 +8 位作者 白建利 刘乔宇 程靖雯 李存东 刘品宇 孙英睿 黄宇 任治安 陈根富 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期495-502,共8页
We synthesize high-quality single crystal of CeGaSi by a Ga self-flux method and investigate its physical properties through magnetic susceptibility,specific heat and electrical resistivity measurements as well as hig... We synthesize high-quality single crystal of CeGaSi by a Ga self-flux method and investigate its physical properties through magnetic susceptibility,specific heat and electrical resistivity measurements as well as high pressure effect.Magnetic measurements reveal that an antiferromagnetic order develops below T_(m)~10.4 K with magnetic moments orientated in the ab plane.The enhanced electronic specific heat coefficient and the negative logarithmic slope in the resistivity of CeGaSi indicate that the title compound belongs to the family of Kondo system with heavy fermion ground states.The max magnetic entropy change-ΔS_(M)^(max)(μ_(0)H⊥c,μ_(0)H=7 T) around T_(m) is found to reach up to 11.85 J·kg^(-1)·K^(-1).Remarkably,both the antiferromagnetic transition temperature and-ln T behavior increase monotonically with pressure applied to 20 kbar(1 bar=10~5 Pa),indicating that much higher pressure will be needed to reach its quantum critical point. 展开更多
关键词 heavy fermion antiferromagnetic order magnetocaloric effect
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Heavy metal pollution of river water and eco-friendly remediation using potent microalgal species
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作者 Amudham Radha Amal Raj Prabhakaran Mylsamy +3 位作者 V.Sivasankar B.Sathish Kumar Kiyoshi Omine T.G.Sunitha 《Water Science and Engineering》 EI CAS CSCD 2024年第1期41-50,共10页
Pollution of rivers is mainly caused by anthropogenic activities such as discharge of effluent from industrial facilities,maintenance of sewage/effluent treatment plants,and dumping of solid waste on river banks.This ... Pollution of rivers is mainly caused by anthropogenic activities such as discharge of effluent from industrial facilities,maintenance of sewage/effluent treatment plants,and dumping of solid waste on river banks.This study dealt with the pollution issues of the Cooum River in the well-known city of Chennai in South India.Water samples from 27 locations were collected and analyzed for 12 elements,including Ba,B,and Al,as well as heavy metals such as Pb,Cr,Mn,Fe,Co,Ni,Cu,Zn,and Cd.The samples showed levels of these elements that exceeded World Health Organization recommendations.Pearson correlation analysis revealed the inter-dependency among elements,and the contribution of each element based on factor loadings showed its percentage contribution compared to others.Water samples from six significant locations were chosen for remediation with three algae:Chlorella vulgaris,Scenedesmus dimorphus,and Phormedium sp.The uptake of pollutants led to the continuous growth of algae during the incubation period of 15 d,effectively removing heavy metals from the river water.The increasing levels of algal counts and the chlorophyll a content confirmed the algal growth during the incubation period,followed by a declining stage after the incubation period.The scanning electron microscopic images of algae before and after the remediation showed no remarkable modification of morphological patterns.This study showed that the uptake of heavy metals using algae is an effective water pollution remediation measure,making the process practicable in the field on a large scale in the near future. 展开更多
关键词 heavy metal Cooum river Phycoremediation MICROALGAE Factor analysis
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Uniformity Control of Scanned Beam in 300 MeV Proton and Heavy Ion Accelerator Complex at SESRI
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作者 HOU Lingxiao YUAN Youjin +10 位作者 SHEN Guodong RUAN Shuang LIU Jie ZHU Yunpeng WANG Geng GUO Hongliang LYU Mingbang GAO Daqing XU Zhiguo SHENG Lina YANG Jiancheng 《原子能科学技术》 EI CAS CSCD 北大核心 2024年第4期705-713,共9页
In recent years,heavy ion accelerator technology has been rapidly developing worldwide and widely applied in the fields of space radiation simulation and particle therapy.Usually,a very high uniformity in the irradiat... In recent years,heavy ion accelerator technology has been rapidly developing worldwide and widely applied in the fields of space radiation simulation and particle therapy.Usually,a very high uniformity in the irradiation area is required for the extracted ion beams,which is crucial because it directly affects the experimental precision and therapeutic effect.Specifically,ultra-large-area and high-uniformity scanning are crucial requirements for spacecraft radiation effects assessment and serve as core specification for beamline terminal design.In the 300 MeV proton and heavy ion accelerator complex at the Space Environment Simulation and Research Infrastructure(SESRI),proton and heavy ion beams will be accelerated and ultimately delivered to three irradiation terminals.In order to achieve the required large irradiation area of 320 mm×320 mm,horizontal and vertical scanning magnets are used in the extraction beam line.However,considering the various requirements for beam species and energies,the tracking accuracy of power supplies(PSs),the eddy current effect of scanning magnets,and the fluctuation of ion bunch structure will reduce the irradiation uniformity.To mitigate these effects,a beam uniformity optimization method based on the measured beam distribution was proposed and applied in the accelerator complex at SESRI.In the experiment,the uniformity is successfully optimized from 75%to over 90%after five iterations of adjustment to the PS waveforms.In this paper,the method and experimental results were introduced. 展开更多
关键词 heavy ion accelerator beam uniformity scanning magnet MIC
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Relativistic Heavy Ion Collider and the Large Hadron Collider for Heavy Ion Fusion
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作者 Ardeshir Irani 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2024年第2期825-827,共3页
Heavy Ion Fusion makes use of the Relativistic Heavy Ion Collider at Brookhaven National Lab and the Large Hadron Collider in Geneva, Switzerland for Inertial Confinement Fusion. Two Storage Rings, which may or may no... Heavy Ion Fusion makes use of the Relativistic Heavy Ion Collider at Brookhaven National Lab and the Large Hadron Collider in Geneva, Switzerland for Inertial Confinement Fusion. Two Storage Rings, which may or may not initially be needed, added to each of the Colliders increases the intensity of the Heavy Ion Beams making it comparable to the Total Energy delivered to the DT target by the National Ignition Facility at the Lawrence Livermore Lab. The basic Physics involved gives Heavy Ion Fusion an advantage over Laser Fusion because heavy ions have greater penetration power than photons. The Relativistic Heavy Ion Collider can be used as a Prototype Heavy Ion Fusion Reactor for the Large Hadron Collider. 展开更多
关键词 heavy Ion Fusion Relativistic heavy Ion Collider Large Hadron Collider Inertial Confinement Fusion National Ignition Facility
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Nanoscale Zero-Valent Iron(nZVI)for Heavy Metal Wastewater Treatment:A Perspective
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作者 Shaolin Li Lei Li Weixian Zhang 《Engineering》 SCIE EI CAS CSCD 2024年第5期16-20,共5页
Industries such as non-ferrous metal smelting discharge billions of gallons of highly toxic heavy metal wastewater(HMW)worldwide annually,posing a severe challenge to conventional wastewater treatment plants and harmi... Industries such as non-ferrous metal smelting discharge billions of gallons of highly toxic heavy metal wastewater(HMW)worldwide annually,posing a severe challenge to conventional wastewater treatment plants and harming the environment.HMW is traditionally treated via chemical precipitation using lime,caustic,or sulfide,but the effluents do not meet the increasingly stringent discharge standards.This issue has spurred an increase in research and the development of innovative treatment technologies,among which those using nanoparticles receive particular interest.Among such initiatives,treatment using nanoscale zero-valent iron(nZVI)is one of the best developed.While nZVI is already well known for its site-remediation use,this perspective highlights its application in HMW treatment with metal recovery.We demonstrate several advantages of nZVI in this wastewater application,including its multifunctionality in sequestrating a wide array of metal(loid)s(>30 species);its capability to capture and enrich metal(loid)s at low concentrations(with a removal capacity reaching 500 mg·g^(-1)nZVI);and its operational convenience due to its unique hydrodynamics.All these advantages are attributable to nZVI’s diminutive nanoparticle size and/or its unique iron chemistry.We also present the first engineering practice of this application,which has treated millions of cubic meters of HMW and recovered tons of valuable metals(e.g.,Cu and Au).It is concluded that nZVI is a potent reagent for treating HMW and that nZVI technology provides an eco-solution to this toxic waste. 展开更多
关键词 Nanoscale zero-valent iron WASTEWATER heavy metal Resource recovery
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Characterization of Nutrients,Heavy Metals,Petroleum and Their Impact on Phytoplankton in Laizhou Bay:Implications for Environmental Management and Monitoring
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作者 WANG Kai ZHAO Linlin +3 位作者 ZHU Yugui YANG Liqiang WANG Yunfeng HONG Xuguang 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第3期822-834,共13页
The Laizhou Bay(LB)represents a substantial ecological area that is vulnerable to human activities and confronts diverse environmental challenges.This study provides a comprehensive characterization of nutrients,petro... The Laizhou Bay(LB)represents a substantial ecological area that is vulnerable to human activities and confronts diverse environmental challenges.This study provides a comprehensive characterization of nutrients,petroleum,heavy metals,and phytoplankton community structure across seven distinct areas in LB.The results indicate relatively high concentrations of NO_(2)-N,SiO_(4)-Si,and NO_(3)-N in the Southwest Laizhou Bay(SWLB)and Huanghe River Estuary(HRE).In contrast,the East Laizhou bay(ELB)and the North of Huanghe River Estuary(NHRE)exhibit the highest concentrations of heavy metals(As,Cr and Hg).The areas with high phytoplankton density and community diversity are mainly located in the SWLB.After adjusting for basic environmental factors,phytoplankton density and Margalef richness index D are significantly associated with nutrients(NO_(3)-N,NO_(2)-N,NH_(4)-N,SiO_(4)-Si),and heavy metal(Cr)concentrations.We highlight that,in addition to Xiaoqinghe River,nutrients brought by the Mihe River in the SWLB and heavy metal(Cr)pollution in the ELB resulting from industrial and mining activities along the coast significantly influence phytoplankton growth and community structure.Therefore,it is recommended that more monitoring and management efforts be focused on these regions in the future. 展开更多
关键词 Huanghe River Estuary Laizhou Bay NUTRIENTS heavy metals PHYTOPLANKTON BIODIVERSITY
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Spatio-Temporal Characteristics of Heavy Precipitation Forecasts from ECMWF in Eastern China
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作者 徐同 谭燕 顾问 《Journal of Tropical Meteorology》 SCIE 2024年第1期29-41,共13页
This study examines the spatio-temporal characteristics of heavy precipitation forecasts in eastern China from the European Centre for Medium-Range Weather Forecasts(ECMWF) using the time-domain version of the Method ... This study examines the spatio-temporal characteristics of heavy precipitation forecasts in eastern China from the European Centre for Medium-Range Weather Forecasts(ECMWF) using the time-domain version of the Method for Object-based Diagnostic Evaluation(MODE-TD). A total of 23 heavy rainfall cases occurring between 2018 and 2021 are selected for analysis. Using Typhoon “Rumbia” as a case study, the paper illustrates how the MODE-TD method assesses the overall simulation capability of models for the life history of precipitation systems. The results of multiple tests with different parameter configurations reveal that the model underestimates the number of objects’ forecasted precipitation tracks, particularly at smaller radii. Additionally, the analysis based on centroid offset and area ratio tests for different classified precipitation objects indicates that the model performs better in predicting large-area, fast-moving, and longlifespan precipitation objects. Conversely, it tends to have less accurate predictions for small-area, slow-moving, and shortlifespan precipitation objects. In terms of temporal characteristics, the model overestimates the forecasted movement speed for precipitation objects with small-area, slow movement, or both long and short lifespans while underestimating it for precipitation with fast movement. In terms of temporal characteristics, the model tends to overestimate the forecasted movement speed for precipitation objects with small-area, slow movement, or both long and short lifespans while underestimating it for precipitation with fast movement. Overall, the model provides more accurate predictions for the duration and dissipation of precipitation objects with large-area or long-lifespan(such as typhoon precipitation) while having large prediction errors for precipitation objects with small-area or short-lifespan. Furthermore, the model’s simulation results regarding the generation of precipitation objects show that it performs relatively well in simulating the generation of large-area and fast-moving precipitation objects. However, there are significant differences in the forecasted generation of small-area and slow-moving precipitation objects after 9 hours. 展开更多
关键词 MODE-TD ECMWF heavy precipitation Eastern China
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Impacts of Future Changes in Heavy Precipitation and Extreme Drought on the Economy over South China and Indochina
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作者 Bin TANG Wenting HU +4 位作者 Anmin DUAN Yimin LIU Wen BAO Yue XIN Xianyi YANG 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第6期1184-1200,I0022-I0034,共30页
Heavy precipitation and extreme drought have caused severe economic losses over South China and Indochina(INCSC)in recent decades.Given the areas with large gross domestic product(GDP)in the INCSC region are distribut... Heavy precipitation and extreme drought have caused severe economic losses over South China and Indochina(INCSC)in recent decades.Given the areas with large gross domestic product(GDP)in the INCSC region are distributed along the coastline and greatly affected by global warming,understanding the possible economic impacts induced by future changes in the maximum consecutive 5-day precipitation(RX5day)and the maximum consecutive dry days(CDD)is critical for adaptation planning in this region.Based on the latest data released by phase 6 of the Coupled Model Intercomparison Project(CMIP6),future projections of precipitation extremes with bias correction and their impacts on GDP over the INCSC region under the fossil-fueled development Shared Socioeconomic Pathway(SSP5-8.5)are investigated.Results indicate that RX5day will intensify robustly throughout the INCSC region,while CDD will lengthen in most regions under global warming.The changes in climate consistently dominate the effect on GDP over the INCSC region,rather than the change of GDP.If only considering the effect of climate change on GDP,the changes in precipitation extremes bring a larger impact on the economy in the future to the provinces of Hunan,Jiangxi,Fujian,Guangdong,and Hainan in South China,as well as the Malay Peninsula and southern Cambodia in Indochina.Thus,timely regional adaptation strategies are urgent for these regions.Moreover,from the sub-regional average viewpoint,over two thirds of CMIP6 models agree that maintaining a lower global warming level will reduce the economic impacts from heavy precipitation over the INCSC region. 展开更多
关键词 CMIP6 heavy precipitation extreme drought South China INDOCHINA economic impact
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Accumulation of Heavy Metals in Maga-Pouss Rice Fields (Far-North Region, Cameroon) and Transfer to Rice Grains
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作者 Diane Madomguia Gilbert Bello Basokdou +3 位作者 Kalieu W. Appoline Isabelle Patrice Kuitekam Dongo Edouard Nya Serge Hubert Zebaze Togouet 《Agricultural Sciences》 2024年第3期311-326,共16页
Monitoring of heavy metals contamination of agricultural products and their transfer and bioaccumulation in crops like rice has become a hot topic worldwide over the last two decades. The present study was carried out... Monitoring of heavy metals contamination of agricultural products and their transfer and bioaccumulation in crops like rice has become a hot topic worldwide over the last two decades. The present study was carried out to determine the accumulation of heavy metals in rice fields and their transfer to rice grains. Soil, irrigation water and rice grains samples were gathered in Maga-Pouss, Far-North, Cameroon. Concentrations of six heavy metals (lead, cadmium, zinc, copper, iron and mercury) were evaluated by Atomic Absorption Spectrophotometer (AAS). Mercury was not detected in this study. Average concentrations of metals were in this order (in mg/kg): Fe (188.60 ± 97.06) > Pb (63.63 ± 7.11) > Cd (2.59 ± 0.29) > Zn (1.10 ± 1.05) > Cu (0.80 ± 0.73) in water and Pb (105.50 ± 31.11) > Fe (105.50 ± 31.11) > Cu (45.93 ± 14.39) > Zn (22.52 ± 6.40) > Cd (3.15 ± 0.49) in soil. Water in Maga-Pouss rice fields appears to be more harmful than the soil, notably for lead, cadmium and copper. In rice grains, heavy metals were found in this order (mg/kg): Fe (188.01 ± 82.62) > Cu (27.20 ± 0.00) > Zn (23.61 ± 12.42) > Pb (19.50 ± 19.91) > Cd (2.02 ± 1.05). The mean bioconcentration factor (BCF) of metals from soil to rice grains was in the following order: Fe (2.60) > Zn (1.05) > Cd (0.64) > Cu (0.59) > Pb (0.18). From water to rice grains, the order is: Cu (37.26) > Zn (22.49) > Cd (6.97) > Pb (2.74) > Fe (1.94). Rice field pH and electrical conductivity favored the uptake of lead, copper and cadmium by rice grains. The findings of this study will be good documentation for risk assessment, and decision-making by environmental managers in this region. 展开更多
关键词 heavy Metals Rice Field Bioconcenration Factor Maga-Pouss ACCUMULATION
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Abnormal Thyroid Stimulating Hormone Level and Heavy Menstrual Bleeding
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作者 Varatharaja Vasantharaja Registrar 《Open Journal of Obstetrics and Gynecology》 2024年第1期110-123,共14页
Heavy Menstrual Bleeding is one of the common Gynaecological issues. There are several causes. Some of the women presented with these issues found to have underling thyroid abnormality which was not discovered earlier... Heavy Menstrual Bleeding is one of the common Gynaecological issues. There are several causes. Some of the women presented with these issues found to have underling thyroid abnormality which was not discovered earlier. This research tries to find the prevalence of the Thyroid Disorder among the women present with Heavy menstrual bleeding in Sri Lankan women. 展开更多
关键词 heavy Menstrual Bleeding TSH Levels Thyroid Disorders
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Assessment of Heavy Metals Contamination of Topsoil and Street Dust around Cement Factory in Southern Jordan
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作者 Omar Ali Al-Khashman Alia Omar Al-Khashman +2 位作者 Navasingh Rajesh Jesudoss Hynes Hani M. Alnawafleh Pitchumani Shenbaga Velu 《Journal of Environmental Protection》 2024年第6期672-696,共25页
Evaluation of assessment of the metal processes governing the metals distribution in soil and dust samples is very significant and protects the health of human and ecological system. Recently, special attention has gi... Evaluation of assessment of the metal processes governing the metals distribution in soil and dust samples is very significant and protects the health of human and ecological system. Recently, special attention has given to the assessment of metals pollution impact on soil and dust within industrial areas. This study aims to assess the metal contamination levels in the topsoil and street dust around the cement factory in Qadissiya area, southern Jordan. The levels of seven metals (namely Fe, Zn, Cu, Pb, Cr, Cd, and Mn) were analyzed using Flame Atomic Absorption Spec-trophotometer (FAAS) to monitor, evaluate, and to compare topsoil and road dust pollution values of metals of the different types of urban area. The physicochemical parameters which believed to affect the mobility of metals in the soil of the study area were determined such as pH, EC, TOM, CaCO3 and CEC. The levels of metal in soil samples are greater on the surface but decrease in the lower part as a result of the basic nature of soil. The mean values of the metals in soil can be arranged in the following order: Zn > Pb > Mn > Fe > Cu > Cr > Cd. The relatively high concentration of metals in the soil sample was attributed to anthropogenic activities such as traffic emissions, cement factory and agricultural activities. Correlation coefficient analysis and the spatial distribution of indices and the results of statistical analysis indicate three groups of metals: Fe and Mn result by natural origin, Zn, Pb, Cu and Zn result by anthropogenic origin (mainly motor vehicle traffic and abrasion of tires) while Cd is mixed origin. The higher content level values of metals of anthropogenic source in soil samples indicate that it is a source of contamination of air in the studied area. . 展开更多
关键词 Cement Dust heavy Metals Contamination Risk Assessment Statistical Analysis JORDAN
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Evaluation of Agricultural Contamination Level by Heavy Metals and Pesticides in Sediments of Rivers and Water Bodies for Shrimp Fishing in the Lower Ouémé: Case of the Aguigadji, Ahlan and Sele Stations in Benin
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作者 Souradjou Orou Goura Fadéby Modeste Gouissi +3 位作者 Armelle Sabine Yélignan Hounkpatin Wakili Bolatito Yessoufou Tayéwo Sylvain Biaou Nonvignon Martial Fassinou 《Advances in Materials Physics and Chemistry》 CAS 2024年第2期25-46,共22页
This study assessed sediment contamination by heavy metals and pesticide active ingredients linked to chemical inputs used in agricultural activities in the lower Ouémé. Pesticide residues from the organochl... This study assessed sediment contamination by heavy metals and pesticide active ingredients linked to chemical inputs used in agricultural activities in the lower Ouémé. Pesticide residues from the organochlorine, pyrethroid and organophosphorus families were investigated by gas chromatography, and heavy metals (Cd, Pb, As, Ni, Zn, Fe, Mg, Cr and Hg) by atomic absorption spectrophotometry. The metallic pollution indices, the contamination factor (CF) and the ecological risk index were calculated. The results revealed 8 active ingredients in the rainy season and 9 in the dry season. Glyphosate was the active ingredient with the highest concentration at all stations, 9.65 ± 0.84 mg/kg recorded in the dry season at the Aguigadji station. All glyphosate values were above the EQS. DDT, Atrazine and Endosulfan also showed high concentrations in the dry and rainy seasons. Emamectin, Abamectin and Lambda Cyhalothrin also showed high concentrations in the dry season at Aguigadji, Ahlan and Sele. Only glyphosate was recorded at the control station (Toho), but in very low concentrations. Lead showed the highest concentrations at all the stations, 265.96 ± 21.02 mg/Kg in the rainy season and 255.38 ± 79.09 mg/Kg in the dry season, all detected at the Aguigadji station and above the EQS. Zn, Ni, Fe, Cu and Cr were all representative in both the dry and rainy seasons at the contaminated stations. Manganese showed high concentrations in the rainy season. Pb showed very high contamination (FC ≥ 6) at the Aguigadji and Ahlan stations and significant contamination (3 ≤ FC 6) at the Sele station in both the rainy and dry seasons. Ni, Hg and Cd, showed either moderate or significant contamination at the contaminated stations. The risk values showed a considerable ecological Ri (190 ≤ Ri < 380) in the rainy season and a moderate ecological Ri (95 ≤ Ri < 190) in the dry season at these contaminated stations. 展开更多
关键词 PESTICIDES heavy Metals SEDIMENTS Shrimp Fishing Area Lower Ouémé
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Heavy Metal Levels and Ecological Risk in Crude Oil-Contaminated Soils from Okpare-Olomu, Niger Delta, Nigeria
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作者 Adedoyin Olubunmi Bankole Akinyemi Olufemi Ogunkeyede +5 位作者 Harrison Agboro Prince Alex Ekhorutomwen Osasenaga Israel Otuomagie Khadijah Ateda Isimekhai Ekaette Akpan Fadairo Efe Jeffery Isukuru 《Journal of Environmental Protection》 2024年第4期415-438,共24页
Crude oil spills have inflicted extensive disruption upon the Niger Delta ecosystem, resulting in crop loss and severe environmental damage. Such spills exacerbate heavy metal concentration within soil due to the pres... Crude oil spills have inflicted extensive disruption upon the Niger Delta ecosystem, resulting in crop loss and severe environmental damage. Such spills exacerbate heavy metal concentration within soil due to the presence of metallic ions. The Okpare-Olomu community has borne the brunt of crude oil pollution from illicit bunkering, sabotage, and equipment malfunction. This study targets an evaluation of ecological hazards linked to heavy metals (HMs) in crude oil impacted agriculturally soils within Okpare-Olomu in Ughelli South LGA of Delta State. In this study, 24 topsoil samples were obtained from areas affected by crude oil pollution;the heavy metal content was evaluated through atomic absorption spectrometry. The concentration ranges for HMs (mg/kg) in soil were: 24.1 - 23,174 (Cu);0.54 - 37.1 (Cd);9.05 - 54 (Cr);12 - 174 (Ni);18.5 - 8611 (Pb);and 148 - 9078 (Zn) at a soil depth of 0 - 15 cm. Notably, metal concentrations were recorded to be above permissible World Health Organization limits. Predominantly, Zn and Pb recorded higher heavy metal concentration when compared to other heavy metals analysed, notably at sampling points PT7 through PT24. Zinc and Pb contamination exhibited highly significant contamination factors, and contamination severity was evidenced across all sample points, signifying a grave risk level. Pollution load indices indicated pervasive extreme pollution levels. Geoaccumulation indices signaled moderate to strong pollution, mainly by Pb and Zn. Ecological risk assessments revealed variable levels of heavy metal contamination, from low to very high, with potential ecological risk reflecting markedly elevated levels. This study underscores the imperative for soil remediation to rectify ecological imbalances in agriculturally affected soil constituents. 展开更多
关键词 heavy Metals Crude Oil POLLUTION Degree of Contamination Potential Risk Index
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A Real-time Prediction System for Molecular-level Information of Heavy Oil Based on Machine Learning
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作者 Yuan Zhuang Wang Yuan +8 位作者 Zhang Zhibo Yuan Yibo Yang Zhe Xu Wei Lin Yang Yan Hao Zhou Xin Zhao Hui Yang Chaohe 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第2期121-134,共14页
Acquiring accurate molecular-level information about petroleum is crucial for refining and chemical enterprises to implement the“selection of the optimal processing route”strategy.With the development of data predic... Acquiring accurate molecular-level information about petroleum is crucial for refining and chemical enterprises to implement the“selection of the optimal processing route”strategy.With the development of data prediction systems represented by machine learning,it has become possible for real-time prediction systems of petroleum fraction molecular information to replace analyses such as gas chromatography and mass spectrometry.However,the biggest difficulty lies in acquiring the data required for training the neural network.To address these issues,this work proposes an innovative method that utilizes the Aspen HYSYS and full two-dimensional gas chromatography-time-of-flight mass spectrometry to establish a comprehensive training database.Subsequently,a deep neural network prediction model is developed for heavy distillate oil to predict its composition in terms of molecular structure.After training,the model accurately predicts the molecular composition of catalytically cracked raw oil in a refinery.The validation and test sets exhibit R2 values of 0.99769 and 0.99807,respectively,and the average relative error of molecular composition prediction for raw materials of the catalytic cracking unit is less than 7%.Finally,the SHAP(SHapley Additive ExPlanation)interpretation method is used to disclose the relationship among different variables by performing global and local weight comparisons and correlation analyses. 展开更多
关键词 heavy distillate oil molecular composition deep learning SHAP interpretation method
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Effect of Nozzle Inclination Angle on Fuel-Air Mixing and Combustion in a Heavy Fuel Engine
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作者 Zhigang Wang Bin Zheng +4 位作者 Peidong Zhao Baoli Wang Fanyan Meng Wenke Xu Jian Meng 《Fluid Dynamics & Materials Processing》 EI 2024年第2期365-382,共18页
Heavy-fuel engines are widely used in UAVs(Unmanned Autonomous Vehicles)because of their reliability and high-power density.In this study,a combustion model for an in-cylinder direct injection engine has been imple-me... Heavy-fuel engines are widely used in UAVs(Unmanned Autonomous Vehicles)because of their reliability and high-power density.In this study,a combustion model for an in-cylinder direct injection engine has been imple-mented using the AVL FIRE software.The effects of the angle of nozzle inclination on fuel evaporation,mixture distribution,and combustion in the engine cylinder have been systematically studied at 5500 r/min and consider-ing full load cruise conditions.According to the results,as the angle of nozzle inclination increases,the maximum combustion explosion pressure in the cylinderfirst increases and then it decreases.When the angle of nozzle incli-nation is less than 45°,the quality of the mixture in the cylinder and the combustion performance can be improved by increasing the angle.When the angle of nozzle inclination is greater than 45°,however,the mixture unevenness increases slightly with the angle,leading to a deterioration of the combustion performances.When the angle of nozzle inclination is between 35°and 55°,the overall combustion performance of the engine is rela-tively good.When the angle of nozzle inclination is 45°,the combustion chamber’s geometry and the cylinder’s airflow are well matched with the fuel spray,and the mixture quality is the best.Compared with 25°,the peak heat release rate increases by 20%,and the maximum combustion burst pressure increases by 5.5%. 展开更多
关键词 Aviation heavy fuel piston engine nozzle inclination angle COMBUSTION fuel-air mixing
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Preliminary safety analysis for heavy water-moderated molten salt reactor
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作者 Gao-Ang Wen Jian-Hui Wu +3 位作者 Chun-Yan Zou Xiang-Zhou Cai Jin-Gen Chen Man Bao 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第6期202-217,共16页
The heavy water-moderated molten salt reactor(HWMSR)is a newly proposed reactor concept,in which heavy water is adopted as the moderator and molten salt dissolved with fissile and fertile elements is used as the fuel.... The heavy water-moderated molten salt reactor(HWMSR)is a newly proposed reactor concept,in which heavy water is adopted as the moderator and molten salt dissolved with fissile and fertile elements is used as the fuel.Issues arising from graphite in traditional molten salt reactors,including the positive temperature coefficient and management of highly radio-active spent graphite waste,can be addressed using the HWMSR.Until now,research on the HWMSR has been centered on the core design and nuclear fuel cycle to explore the viability of the HWMSR and its advantages in fuel utilization.However,the core safety of the HWMSR has not been extensively studied.Therefore,we evaluate typical accidents in a small modular HWMSR,including fuel salt inlet temperature overcooling and overheating accidents,fuel salt inlet flow rate decrease,heavy water inlet temperature overcooling accidents,and heavy water inlet mass flow rate decrease accidents,based on a neutronics and thermal-hydraulics coupled code.The results demonstrated that the core maintained safety during the investigated accidents. 展开更多
关键词 heavy water-moderated molten salt reactor Neutronics and thermal-hydraulics coupling Transient analysis Accident analysis
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Analysis of Heavy Precipitation Event in Northeast China from August 1 to 5, 2023
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作者 Songyang Wang 《Journal of Geoscience and Environment Protection》 2024年第5期176-187,共12页
This study delves into the multiple weather systems and their interaction mechanisms that caused the severe rainfall event in Northeast China in early August 2023. The analysis reveals that the atmospheric circulation... This study delves into the multiple weather systems and their interaction mechanisms that caused the severe rainfall event in Northeast China in early August 2023. The analysis reveals that the atmospheric circulation in the mid-to-high latitudes of the Eurasian continent exhibited a significant “two troughs and two ridges” structure, with Northeast China located precisely in the peripheral region of the subtropical high, significantly influenced by its marginal airflows. Additionally, the residual circulation of Typhoon “Doksuri” interacting with the subtropical high and upper-level troughs significantly increased the rainfall intensity and duration in the region. In particular, the continuous and powerful transport of the southwest jet provided the necessary moisture and unstable conditions for the generation and development of convective systems. The rainfall event resulted in nearly 40,000 people affected and crop damage covering an area of approximately 4000 hectares, demonstrating the severity of extreme weather. The study emphasizes that strengthening meteorological monitoring and early warning systems, as well as formulating and improving emergency response mechanisms, are crucial for reducing potential disaster losses caused by heavy rainfall. Future research can further explore the interaction mechanisms among weather systems, limitations of data sources, and the connection between long-term trends of heavy rainfall events and global climate change. 展开更多
关键词 heavy Precipitation Eurasian Circulation Typhoon Doksuri Water Vapor Transport Regional heavy Rainfall Mechanism
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Heavy Metal Remediation in AgoèNyivéLandfill Soils: Enhancing Stability through Organic Amendments
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作者 Bassaï Magnoudéwa Bodjona Diyakadola Dihéénane Bafai Gado Tchangbedji 《Open Journal of Applied Sciences》 2024年第4期961-975,共15页
The burial of waste in developing countries, which is often carried out without respect for environmental standards, constitutes a risk of contamination of soils and even groundwater given the toxic elements they cont... The burial of waste in developing countries, which is often carried out without respect for environmental standards, constitutes a risk of contamination of soils and even groundwater given the toxic elements they contain. The objective of this work is to carry out a study of the retention of heavy metals through the contribution of cattle manure to soil samples from the final Agoè Nyivé landfill in Lomé, Togo. Soil samples from the final landfill were taken from the surface and depth at several locations to form a composite sample. The amendment of the composite sample was carried out with bovine manure on the mock-up in the Laboratory for six months. The determination of the total contents of heavy metals by the atomic absorption spectrophotometer (SAA) on the composite sample showed high contents exceeding the thresholds recommended by the AFNOR NF U 44-041 standard. Sequential extraction on these composite samples showed that the mobile portions of lead, cadmium, copper and zinc are respectively estimated at 78.06%, 50%, 28.89% and 91.59%. The bovine manure used to amend the landfill samples presents physicochemical parameters that can contribute to rendering heavy metals immobile in the soil matrix under natural conditions. The addition of manure initially made it possible to increase the values of pH, electrical conductivity, cation exchange capacity and organic matter, which promote the retention of heavy metals. Secondly, the addition of manure made it possible to reduce the mobile portion of the heavy metals studied;from 78.06% to 14.39% for lead, from 50% to 11.52% for cadmium, from 28.89% to almost 0% for copper and from 91.15% to 80.58% for zinc. The use of cattle manure as an amendment on the composite sample was decisive in reducing the mobility of heavy metals in the polluted soils of the final landfill. 展开更多
关键词 POLLUTION heavy Metals Soil Sequential Extraction DISCHARGE
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