The solid-phase extraction using Pd-Al2O3 as the stationary phase was employed to pre-separate the sulfur compounds in straight-run diesel. The isolating effect was evaluated quantitatively by gas chromatography with ...The solid-phase extraction using Pd-Al2O3 as the stationary phase was employed to pre-separate the sulfur compounds in straight-run diesel. The isolating effect was evaluated quantitatively by gas chromatography with a sulfur chemiluminescence detector to harvest a satisfactory result. The identification of the structure of sulfur compounds by comprehensive two-dimensional gas chromatography coupled with the time-of-flight mass spectrometry indicated that cyclo-sulfides, benzothiophenes, dibenzothiophenes, dihydro-benzothiophenes and tetrahydro-dibenzothiophenes were included in straightrun diesel obtained from the Arab medium crude(AM). A total of 259 individual compounds were detected and their molecular structures were identified. The analytical method was approved as an effective way to characterize the composition of sulfur compounds, which reduced the interference of other compounds, facilitated the data presentation and provided more detailed information about molecular composition of sulfur compounds.展开更多
Internal combustion engines′ fuel economy is an important role for engine designers,engine manufacturers over the past 30 years,especially passenger car motor oils.In heavy duty diesel engine,over the past 20 years,f...Internal combustion engines′ fuel economy is an important role for engine designers,engine manufacturers over the past 30 years,especially passenger car motor oils.In heavy duty diesel engine,over the past 20 years,fuel economy has in some cases been sacrificed for exhaust gas emission optimizations.Now,Heavy Duty Automotive and the related industries have strong interest in fuel economy and the lubricants.It is driven by competitive market forces as well as government mandates and new emission regulations.Japan was the first country in the world to establish and implement heavy duty trucks and buses fuel economy standards.Other countries also have followed either by establishing direct fuel economy standards or greenhouse gas(GHG) emissions standards which are directly tied to fuel economy.This paper is discussing that heavy duty diesel engine lubricants can contribute on fuel economy.The contribution of various aspects of engine oil formulations on fuel economy will be discussed such as lubricant viscosity grade,lubricant additives and friction modifiers.In this paper,the evaluation discussions are based on fuel economy measurements in some bench tests,standardized laboratory engine tests and field tests.展开更多
Co-contamination of diesel fuel and heavy metals can be challenging for microbial remediation due to the complex composition of the fuel and the inhibitory effect of heavy metals.There is an urgent need to study this ...Co-contamination of diesel fuel and heavy metals can be challenging for microbial remediation due to the complex composition of the fuel and the inhibitory effect of heavy metals.There is an urgent need to study this interaction to improve the pollutant removal efficiency in the Polar Regions.The growth of an Antarctic bacterium,Rhodococcus sp.was studied by comparing the growth at the logarithmic phase under the effect of selected heavy metals(Pb,Cr,As,Cd,Cu,Zn,Ni,Hg and Co).The selected heavy metals inhibited the growth of the Rhodococcus sp.on diesel fuel in an order from highest to lowest of:Hg>Zn>Cd>Cu>Co>Ni>As>Pb>Cr.Growth on diesel fuel co-contaminated with Hg and Zn were 2.95%and 5.71%,respectively compared to the no-metal control.A further experiment with various Zn concentrations was conducted.The specific growth rate of Rhodococcus sp.co-contaminated with different concentrations of Zn showed a correlation coefficient(r)of 0.916,and was modelled with an exponential decay model.Additional investigation is needed to determine the effect of low concentration of Zn on hydrocarbon degradation.It is important to understand the relationships between microbes,hydrocarbons and heavy metals,especially in the Polar Regions because this interaction might be promising in treating hydrocarbon-polluted sites containing heavy metals.The data and results also provide baseline tools of bioremediation processes at low temperatures and the knowledge of the ecological roles of Rhodococcus sp.in Antarctica.展开更多
The method for refining the straight-run diesel fuel was studied in laboratory scale in order to make the acid number of diesel fraction comply with the standard while removing the naphthenic acids contained in diesel...The method for refining the straight-run diesel fuel was studied in laboratory scale in order to make the acid number of diesel fraction comply with the standard while removing the naphthenic acids contained in diesel without causing environmental pollution. After comparing the effect of refining using three solvents, the isopropyl alcohol-HOA was specified as the best solvent. Meanwhile, the relationship between the acid number of diesel fraction and the amount of solvent used and the relationship between the concentration of solvent and temperature and the stability of diesel in terms of its acid number were also investigated. Experimental results had shown that when the mass fraction of the HOA-IPA solvent was 20% at a dosage of 17 mL of the solvent and a temperature of 30℃, the acid number of the refined diesel fraction was 0.015 mg KOH/g with a good stability of acidity in the diesel fraction.展开更多
基金financially supported by the National Basic Research Program of China (973 Program) (2012CB224800)
文摘The solid-phase extraction using Pd-Al2O3 as the stationary phase was employed to pre-separate the sulfur compounds in straight-run diesel. The isolating effect was evaluated quantitatively by gas chromatography with a sulfur chemiluminescence detector to harvest a satisfactory result. The identification of the structure of sulfur compounds by comprehensive two-dimensional gas chromatography coupled with the time-of-flight mass spectrometry indicated that cyclo-sulfides, benzothiophenes, dibenzothiophenes, dihydro-benzothiophenes and tetrahydro-dibenzothiophenes were included in straightrun diesel obtained from the Arab medium crude(AM). A total of 259 individual compounds were detected and their molecular structures were identified. The analytical method was approved as an effective way to characterize the composition of sulfur compounds, which reduced the interference of other compounds, facilitated the data presentation and provided more detailed information about molecular composition of sulfur compounds.
文摘Internal combustion engines′ fuel economy is an important role for engine designers,engine manufacturers over the past 30 years,especially passenger car motor oils.In heavy duty diesel engine,over the past 20 years,fuel economy has in some cases been sacrificed for exhaust gas emission optimizations.Now,Heavy Duty Automotive and the related industries have strong interest in fuel economy and the lubricants.It is driven by competitive market forces as well as government mandates and new emission regulations.Japan was the first country in the world to establish and implement heavy duty trucks and buses fuel economy standards.Other countries also have followed either by establishing direct fuel economy standards or greenhouse gas(GHG) emissions standards which are directly tied to fuel economy.This paper is discussing that heavy duty diesel engine lubricants can contribute on fuel economy.The contribution of various aspects of engine oil formulations on fuel economy will be discussed such as lubricant viscosity grade,lubricant additives and friction modifiers.In this paper,the evaluation discussions are based on fuel economy measurements in some bench tests,standardized laboratory engine tests and field tests.
基金supported by Universiti Putra Malaysia attached to WLWJ(Grant no.GP-IPM/2013/9422700)。
文摘Co-contamination of diesel fuel and heavy metals can be challenging for microbial remediation due to the complex composition of the fuel and the inhibitory effect of heavy metals.There is an urgent need to study this interaction to improve the pollutant removal efficiency in the Polar Regions.The growth of an Antarctic bacterium,Rhodococcus sp.was studied by comparing the growth at the logarithmic phase under the effect of selected heavy metals(Pb,Cr,As,Cd,Cu,Zn,Ni,Hg and Co).The selected heavy metals inhibited the growth of the Rhodococcus sp.on diesel fuel in an order from highest to lowest of:Hg>Zn>Cd>Cu>Co>Ni>As>Pb>Cr.Growth on diesel fuel co-contaminated with Hg and Zn were 2.95%and 5.71%,respectively compared to the no-metal control.A further experiment with various Zn concentrations was conducted.The specific growth rate of Rhodococcus sp.co-contaminated with different concentrations of Zn showed a correlation coefficient(r)of 0.916,and was modelled with an exponential decay model.Additional investigation is needed to determine the effect of low concentration of Zn on hydrocarbon degradation.It is important to understand the relationships between microbes,hydrocarbons and heavy metals,especially in the Polar Regions because this interaction might be promising in treating hydrocarbon-polluted sites containing heavy metals.The data and results also provide baseline tools of bioremediation processes at low temperatures and the knowledge of the ecological roles of Rhodococcus sp.in Antarctica.
文摘The method for refining the straight-run diesel fuel was studied in laboratory scale in order to make the acid number of diesel fraction comply with the standard while removing the naphthenic acids contained in diesel without causing environmental pollution. After comparing the effect of refining using three solvents, the isopropyl alcohol-HOA was specified as the best solvent. Meanwhile, the relationship between the acid number of diesel fraction and the amount of solvent used and the relationship between the concentration of solvent and temperature and the stability of diesel in terms of its acid number were also investigated. Experimental results had shown that when the mass fraction of the HOA-IPA solvent was 20% at a dosage of 17 mL of the solvent and a temperature of 30℃, the acid number of the refined diesel fraction was 0.015 mg KOH/g with a good stability of acidity in the diesel fraction.
