A highly sensitive method is developed for the determination of trace amounts of some heavy metal ions in aqueous solution based on the classical Belousov-Zhabotinskii (BZ) oscillating chemical system. Introducing o...A highly sensitive method is developed for the determination of trace amounts of some heavy metal ions in aqueous solution based on the classical Belousov-Zhabotinskii (BZ) oscillating chemical system. Introducing of S^2- ion makes the new oscillating system Ce(SO4)2 - KBrO3 - CH2(COOH)2 - Na2S - H2SO4 have to a high sensitivity for some heavy metal ions such as Ag^+, Pb^2+, Hg^2+, Cd^2+, Cu^2+and Bi^3+ with detection limits down to 10^-12 mol·L^- 1展开更多
基金supported in part by the Project of International Cooperation between China and Ukraine(043-05)the National Natural Science Foundation(No.20475044)the Invention Project of Science&Technology(KJCXGC-01,NWNU),China.
文摘A highly sensitive method is developed for the determination of trace amounts of some heavy metal ions in aqueous solution based on the classical Belousov-Zhabotinskii (BZ) oscillating chemical system. Introducing of S^2- ion makes the new oscillating system Ce(SO4)2 - KBrO3 - CH2(COOH)2 - Na2S - H2SO4 have to a high sensitivity for some heavy metal ions such as Ag^+, Pb^2+, Hg^2+, Cd^2+, Cu^2+and Bi^3+ with detection limits down to 10^-12 mol·L^- 1